GB1113722A - Aerobically polymerisable compositions - Google Patents
Aerobically polymerisable compositionsInfo
- Publication number
- GB1113722A GB1113722A GB20054/65A GB2005465A GB1113722A GB 1113722 A GB1113722 A GB 1113722A GB 20054/65 A GB20054/65 A GB 20054/65A GB 2005465 A GB2005465 A GB 2005465A GB 1113722 A GB1113722 A GB 1113722A
- Authority
- GB
- United Kingdom
- Prior art keywords
- compositions
- meth
- acrylate
- monomer
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
- A61K6/884—Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
- A61K6/887—Compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
Landscapes
- Health & Medical Sciences (AREA)
- Oral & Maxillofacial Surgery (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Plastic & Reconstructive Surgery (AREA)
- Epidemiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Veterinary Medicine (AREA)
- Dental Preparations (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerisation Methods In General (AREA)
- Paints Or Removers (AREA)
Abstract
Compositions which are aerobically polymerizable in the presence of a free radical catalyst comprise one or more mono- and/or bisacrylate or methacrylate monomers and 0.05-6% by weight of the monomer(s) of a triarylborane complex of the formula R3B-Am in which R represents an aryl radical of 6-12 carbon atoms and Am represents sodium hydroxide, ammonia, benzene or an amine. The radical R is preferably free from hydroxyl, carboxyl and amino groups but may contain substituents such as halo, alkyl and alkoxy groups. The (meth)acrylate monomer is one which normally polymerizes only with difficulty with a free radical catalyst unless oxygen is almost completely absent; suitable esters are alkyl, allyl and fusel oil (meth)acrylates, the bisesters of glycols and bisphenols, and the bisester condensation products of phenols and glycidyl(meth)acrylate (which may contain additional ethylenic unsaturation). The composition may also include an oxirane-type monomer, e.g. glycidyl acrylate or methacrylate or a diluent monomer such as phenyl acrylate, hydroxyethyl methacrylate or acrylonitrile. A free base may also be included as a co-catalyst component, e.g. dimethyl-p-toluidine, tri-nbutylamine, diethylenetriamine, N-methylpiperidine, N-methylmorpholine, 2,5-dimethylpiperazine or 1,2,4-trimethylpiperazine. Other optional components include solvents, fillers (e.g. silica, alumina or synthetic fluorapatite), pigments, dyes and plasticizers. To effect polymerization a free radical catalyst is added, e.g. benzoyl peroxide, methyl ethyl ketone peroxide, t-butyl hydroperoxide or azobisisobutyronitrile, and the composition is then activated by heating or acidifying, e.g. with an inorganic or organic acid; the latter is preferably a compound which will copolymerize with the (meth)acrylate monomer, e.g. acrylic, methacrylic, maleic or citraconic acid. The compositions may be stored as multi-component kit, each component containing some of the ingredients of the composition in stable form. The compositions are suitable for coating, moulding, potting, embedding or sealing and, particularly, for use as a vehicle in dental filling compositions, as described in Specification 1,113,723.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US36927764A | 1964-05-21 | 1964-05-21 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1113722A true GB1113722A (en) | 1968-05-15 |
Family
ID=23454812
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB20054/65A Expired GB1113722A (en) | 1964-05-21 | 1965-05-12 | Aerobically polymerisable compositions |
GB58597/67A Expired GB1113723A (en) | 1964-05-21 | 1965-05-12 | Dental filling material |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB58597/67A Expired GB1113723A (en) | 1964-05-21 | 1965-05-12 | Dental filling material |
Country Status (6)
Country | Link |
---|---|
JP (1) | JPS4827735B1 (en) |
CH (2) | CH475762A (en) |
DE (1) | DE1570971A1 (en) |
FR (1) | FR1458180A (en) |
GB (2) | GB1113722A (en) |
SE (1) | SE349236B (en) |
Cited By (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4515724A (en) * | 1982-03-01 | 1985-05-07 | Henkel Kommanditgesellschaft Auf Aktien | Boron alkyl compounds and processes for their manufacture and use |
US4638092A (en) * | 1982-01-21 | 1987-01-20 | Henkel Kommanditgesellschaft Auf Aktien | New organic boron polymers and their use |
US4676858A (en) * | 1982-03-01 | 1987-06-30 | Henkel Kommanditgesellschaft Auf Aktien | Organoboron containing mixtures and their manufacture and use |
US5539070A (en) * | 1994-02-22 | 1996-07-23 | Minnesota Mining And Manufacturing Company | Polymerizable compositions made with polymerization initiator systems based on organoborane amine complexes |
US5616796A (en) * | 1995-04-14 | 1997-04-01 | Minnesota Mining And Manufacturing Company | Organoborane polyamine complexes and adhesive composition made therewith |
US5621143A (en) * | 1995-04-14 | 1997-04-15 | Minnesota Mining And Manufacturing Company | Organoborane polyoxyalkylenepolyamine complexes and adhesive compositions made therewith |
US5686544A (en) * | 1995-08-11 | 1997-11-11 | Minnesota Mining And Manufacturing Company | Organoborane polyamine complex initiator systems and polymerizable compositions made therewith |
US5691065A (en) * | 1995-02-22 | 1997-11-25 | Minnesota Mining And Manufacturing Company | Polymerizable compositions made with polymerization initiator systems based on organoborane amine complexes |
US5872197A (en) * | 1995-08-11 | 1999-02-16 | Minnesota Mining & Manufacturing Company | Initiator system and adhesive composition made therewith |
US5883208A (en) * | 1995-11-07 | 1999-03-16 | Minnesota Mining And Manufacutring Company | Initiator system and adhesive composition made therewith |
US5935711A (en) * | 1996-10-23 | 1999-08-10 | 3M Innovative Properties Company | Organoborane amine complex initiator systems and polymerizable compositions made therewith |
US5952409A (en) | 1996-01-31 | 1999-09-14 | 3M Innovative Properties Company | Compositions and methods for imparting stain resistance and stain resistant articles |
EP0985684A2 (en) * | 1998-09-10 | 2000-03-15 | MERCK PATENT GmbH | New reactive systems of polymerisable monomers containing peroxyds and stabilised alkyl boron compounds |
WO2000066069A1 (en) * | 1999-04-29 | 2000-11-09 | 3M Espe Ag | Dental materials |
US6252023B1 (en) | 1999-03-19 | 2001-06-26 | 3M Innovative Properties Company | Organoborane amine complex inatator systems and polymerizable compositions made therewith |
DE19959514C1 (en) * | 1999-12-09 | 2001-08-30 | Heraeus Kulzer Gmbh & Co Kg | Dental investment material |
US6383655B1 (en) | 1998-06-12 | 2002-05-07 | 3M Innovative Properties Company | Low odor polymerizable compositions useful for bonding low surface energy substrates |
US6479602B1 (en) | 2000-03-15 | 2002-11-12 | 3M Innovative Properties | Polymerization initiator systems and bonding compositions comprising vinyl aromatic compounds |
US6630555B2 (en) | 2001-11-06 | 2003-10-07 | Lord Corporation | Internally blocked organoborate initiators and adhesives therefrom |
US6799966B1 (en) | 1999-03-04 | 2004-10-05 | 3M Innovative Properties Company | Fluoropolymeric orthodontic article |
US6812308B2 (en) | 2000-11-21 | 2004-11-02 | 3M Innovative Properties Company | Initiator systems and adhesive compositions made therewith |
WO2006026065A2 (en) * | 2004-08-30 | 2006-03-09 | Ultradent Products, Inc. | Gas releasing sealing and filling compositions |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5137092B2 (en) * | 1972-04-28 | 1976-10-13 | ||
IE37703B1 (en) * | 1972-11-16 | 1977-09-28 | Loctite Ltd | Protective adhesive-carrying tape |
CA1117685A (en) * | 1976-11-15 | 1982-02-02 | Narayanan Madhavan | One paste polymeric dental restorative composition |
JP6883300B1 (en) * | 2020-03-04 | 2021-06-09 | 株式会社球体研究所 | Negative thermal expansion fine particles and their manufacturing method |
-
1965
- 1965-05-12 GB GB20054/65A patent/GB1113722A/en not_active Expired
- 1965-05-12 GB GB58597/67A patent/GB1113723A/en not_active Expired
- 1965-05-17 DE DE19651570971 patent/DE1570971A1/en active Pending
- 1965-05-20 CH CH707665A patent/CH475762A/en not_active IP Right Cessation
- 1965-05-20 FR FR17704A patent/FR1458180A/en not_active Expired
- 1965-05-20 CH CH14668A patent/CH471165A/en not_active IP Right Cessation
- 1965-05-21 SE SE06654/65A patent/SE349236B/xx unknown
- 1965-05-21 JP JP40029655A patent/JPS4827735B1/ja active Pending
Cited By (42)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4638092A (en) * | 1982-01-21 | 1987-01-20 | Henkel Kommanditgesellschaft Auf Aktien | New organic boron polymers and their use |
US4515724A (en) * | 1982-03-01 | 1985-05-07 | Henkel Kommanditgesellschaft Auf Aktien | Boron alkyl compounds and processes for their manufacture and use |
US4676858A (en) * | 1982-03-01 | 1987-06-30 | Henkel Kommanditgesellschaft Auf Aktien | Organoboron containing mixtures and their manufacture and use |
US5539070A (en) * | 1994-02-22 | 1996-07-23 | Minnesota Mining And Manufacturing Company | Polymerizable compositions made with polymerization initiator systems based on organoborane amine complexes |
US6248846B1 (en) | 1994-02-22 | 2001-06-19 | 3M Innovative Properties Company | Polymerizable compositions comprising organoborane amine complexes |
US6284381B1 (en) * | 1994-02-22 | 2001-09-04 | 3M Innovative Properties Company | Polymerizable compositions made with polymerization initiator systems based on organoborane amine complexes |
US5690780A (en) * | 1995-02-22 | 1997-11-25 | Minnesota Mining And Manufacturing Company | Polymerizable compositions made with polymerization initiator systems based on organoborane amine complexes |
US5691065A (en) * | 1995-02-22 | 1997-11-25 | Minnesota Mining And Manufacturing Company | Polymerizable compositions made with polymerization initiator systems based on organoborane amine complexes |
US5621143A (en) * | 1995-04-14 | 1997-04-15 | Minnesota Mining And Manufacturing Company | Organoborane polyoxyalkylenepolyamine complexes and adhesive compositions made therewith |
US5616796A (en) * | 1995-04-14 | 1997-04-01 | Minnesota Mining And Manufacturing Company | Organoborane polyamine complexes and adhesive composition made therewith |
US5681910A (en) * | 1995-04-14 | 1997-10-28 | Minnesota Mining And Manufacturing Company | Organoborane polyoxyalkylenepolyamine complexes and adhsesive compositions made therewith |
US5718977A (en) * | 1995-04-14 | 1998-02-17 | Minnesota Mining And Manufacturing Company | Organoborane polyoxyalkylenepolyamine complexes and adhesive compositions made therewith |
US5795657A (en) * | 1995-04-14 | 1998-08-18 | Minnesota Mining And Manufaturing Company | Organoborane polyamine complexes and adhesive compositions made therewith |
US5684102A (en) * | 1995-04-14 | 1997-11-04 | Minnesota Mining And Manufacturing Company | Organoborane polyamine complexes and adhesive compositions made therewith |
US5872197A (en) * | 1995-08-11 | 1999-02-16 | Minnesota Mining & Manufacturing Company | Initiator system and adhesive composition made therewith |
US5686544A (en) * | 1995-08-11 | 1997-11-11 | Minnesota Mining And Manufacturing Company | Organoborane polyamine complex initiator systems and polymerizable compositions made therewith |
US6093778A (en) * | 1995-08-11 | 2000-07-25 | 3M Innovative Properties Company | Organoborane polyamine complex initiator systems and polymerizable compositions made therewith |
US5990036A (en) * | 1995-08-11 | 1999-11-23 | 3M Innovative Properties Company | Initiator system and adhesive composition made therewith |
US5994484A (en) * | 1995-08-11 | 1999-11-30 | 3M Innovative Properties Company | Organoborane polyamine complex initiator systems and polymerizable compositions made therewith |
US6008308A (en) * | 1995-08-11 | 1999-12-28 | 3M Innovative Properties Company | Organoborane polyamine complex initiator systems and polymerizable compositions made therewith |
US6027813A (en) * | 1995-11-07 | 2000-02-22 | 3M Innovative Properties Company | Initiator system and adhesive composition made therewith |
US5883208A (en) * | 1995-11-07 | 1999-03-16 | Minnesota Mining And Manufacutring Company | Initiator system and adhesive composition made therewith |
US5952409A (en) | 1996-01-31 | 1999-09-14 | 3M Innovative Properties Company | Compositions and methods for imparting stain resistance and stain resistant articles |
US5935711A (en) * | 1996-10-23 | 1999-08-10 | 3M Innovative Properties Company | Organoborane amine complex initiator systems and polymerizable compositions made therewith |
US7189303B2 (en) | 1998-06-12 | 2007-03-13 | 3M Innovative Properties Company | Initiator systems and adhesive compositions made therewith |
US6383655B1 (en) | 1998-06-12 | 2002-05-07 | 3M Innovative Properties Company | Low odor polymerizable compositions useful for bonding low surface energy substrates |
EP0985684A2 (en) * | 1998-09-10 | 2000-03-15 | MERCK PATENT GmbH | New reactive systems of polymerisable monomers containing peroxyds and stabilised alkyl boron compounds |
EP0985684A3 (en) * | 1998-09-10 | 2000-04-26 | MERCK PATENT GmbH | New reactive systems of polymerisable monomers containing peroxyds and stabilised alkyl boron compounds |
US6799966B1 (en) | 1999-03-04 | 2004-10-05 | 3M Innovative Properties Company | Fluoropolymeric orthodontic article |
US6252023B1 (en) | 1999-03-19 | 2001-06-26 | 3M Innovative Properties Company | Organoborane amine complex inatator systems and polymerizable compositions made therewith |
US6384165B1 (en) | 1999-03-19 | 2002-05-07 | 3M Innovative Properties Co. | Organoborane amine complex initiator systems and polymerizable compositions made therewith |
WO2000066069A1 (en) * | 1999-04-29 | 2000-11-09 | 3M Espe Ag | Dental materials |
US6652281B1 (en) | 1999-04-29 | 2003-11-25 | 3M Espe Ag | Dental materials |
US6575750B2 (en) | 1999-12-09 | 2003-06-10 | Heraeus Kulzer Gmbh & Co. Kg | Dental embedding material, dental kit and method for making a prosthesis |
DE19959514C1 (en) * | 1999-12-09 | 2001-08-30 | Heraeus Kulzer Gmbh & Co Kg | Dental investment material |
US6479602B1 (en) | 2000-03-15 | 2002-11-12 | 3M Innovative Properties | Polymerization initiator systems and bonding compositions comprising vinyl aromatic compounds |
US6812308B2 (en) | 2000-11-21 | 2004-11-02 | 3M Innovative Properties Company | Initiator systems and adhesive compositions made therewith |
US6841635B2 (en) | 2001-11-06 | 2005-01-11 | Lord Corporation | Internally blocked organoborate initiators and adhesives therefrom |
US6630555B2 (en) | 2001-11-06 | 2003-10-07 | Lord Corporation | Internally blocked organoborate initiators and adhesives therefrom |
WO2006026065A2 (en) * | 2004-08-30 | 2006-03-09 | Ultradent Products, Inc. | Gas releasing sealing and filling compositions |
WO2006026065A3 (en) * | 2004-08-30 | 2006-10-05 | Ultradent Products Inc | Gas releasing sealing and filling compositions |
US7173075B2 (en) | 2004-08-30 | 2007-02-06 | Ultradent Products, Inc. | Gas releasing sealing and filling compositions |
Also Published As
Publication number | Publication date |
---|---|
FR1458180A (en) | 1966-11-10 |
JPS4827735B1 (en) | 1973-08-25 |
GB1113723A (en) | 1968-05-15 |
CH471165A (en) | 1969-04-15 |
DE1570971A1 (en) | 1970-09-24 |
CH475762A (en) | 1969-07-31 |
SE349236B (en) | 1972-09-25 |
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