GB1113039A - Sizing of fibrous materials - Google Patents

Sizing of fibrous materials

Info

Publication number
GB1113039A
GB1113039A GB185967A GB185967A GB1113039A GB 1113039 A GB1113039 A GB 1113039A GB 185967 A GB185967 A GB 185967A GB 185967 A GB185967 A GB 185967A GB 1113039 A GB1113039 A GB 1113039A
Authority
GB
United Kingdom
Prior art keywords
fibrous
methyl
alkyl
carbon atoms
groups
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB185967A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Co
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of GB1113039A publication Critical patent/GB1113039A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/09—Sulfur-containing compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/61—Polyamines polyimines
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/11—Halides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Paper (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

A composition for sizing fibrous materials comprises (a) a compound of the formula <FORM:1113039/C3/1> wherein R is a hydrophobic organic group, R1 is a hydrogen atom, or a methyl or chloromethyl group, n is 0, 1 or 2, and X is a halogen atom; and (b) a polyalkyleneimine having 2 or 3 carbon atoms in each alkylene group. It is preferred that X is a chlorine or bromine atom and that the ratio by weight of (a) to (b) is from 1:10 to 10:1. Suitable hydrophobic organic groups are alkyl, alkenyl, alkyl-phenyl and alkylcycloalkyl groups, optionally containing inert substituents such as carboalkoxy, alkyloxy, aryloxy, arylalkyloxy, keto-(carbonyl), tertiary amide, halogens attached to aromatic carbon atoms, or non-aromatic heterocyclic groups. The polyalkyleneimines include the poly-(N-methylalkyleneimines) which are the polymerization products of N-methyl-ethyleneimine, N-methylpropyleneimine or mixtures thereof. The ingredients of composition may be combined in a solution or dispersion. Optional ingredients include alkali metal hydroxides and cationic starch.ALSO:Fibrous materials, such as textile and cellulose fibres, threads, yarns or fabrics, are sized by treatment with (a) a compound of the formula <FORM:1113039/D1-D2/1> wherein R is a hydrophobic organic group, R1 is a hydrogen atom, or a methyl or chloromethyl group, n is 0, 1, or 2, and X is a halogen atom; and (b) a polyalkyleneimine having 2 or 3 carbon atoms in each alkylene group. Suitable hydrophobic organic groups are alkyl, alkenyl, alkylphenyl and alkyl-cycloalkyl groups, optionally containing inert substituents such as carboalkoxy, alkyloxy, aryloxy, arylalkyloxy, keto (carbonyl), tertiary amide, halogens attached to aromatic carbon atoms, or non-aromatic heterocyclic groups. The polyalkyleneimines include the poly (N-methylalkyleneimines) which are the polymerisation products of N-methyl-ethyleneimine, N-methyl-propyleneimine or mixtures thereof. The ratio of (a) to (b) is pereferably from 1:10 to 10:1 by weight and the combined weight of (a) and (b) is preferably at least 0.1 per cent of the weight of the fibrous p material. The ingredients of the composition may be combined in one solution or dispersion and added to an anqueous fibrous slurry or pulp slurry, or they may be sprayed on to a fibrous mat. They may also be applied by tub sizing methods comprising passing the fibrous material through combined or separate solutions of the two ingredients. Optional additives are alkali metal hydroxides and cationic starch. The fibrous material may be subsequently dried to give a finished sized product.
GB185967A 1966-01-14 1967-01-13 Sizing of fibrous materials Expired GB1113039A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US52063966A 1966-01-14 1966-01-14

Publications (1)

Publication Number Publication Date
GB1113039A true GB1113039A (en) 1968-05-08

Family

ID=24073464

Family Applications (1)

Application Number Title Priority Date Filing Date
GB185967A Expired GB1113039A (en) 1966-01-14 1967-01-13 Sizing of fibrous materials

Country Status (6)

Country Link
BE (1) BE692596A (en)
FI (1) FI45781C (en)
FR (1) FR1507894A (en)
GB (1) GB1113039A (en)
NO (1) NO122288B (en)
SE (1) SE311276B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4627889A (en) * 1983-03-30 1986-12-09 Ciba-Geigy Corporation Process for sizing paper with anionic hydrophobic sizing agents and cationic retention aids

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4627889A (en) * 1983-03-30 1986-12-09 Ciba-Geigy Corporation Process for sizing paper with anionic hydrophobic sizing agents and cationic retention aids

Also Published As

Publication number Publication date
SE311276B (en) 1969-06-02
FR1507894A (en) 1967-12-29
BE692596A (en) 1967-07-13
FI45781B (en) 1972-05-31
FI45781C (en) 1972-09-11
NO122288B (en) 1971-06-07

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