GB1109543A - A method of processing the reaction mixture from the oxidation of cyclohexane - Google Patents
A method of processing the reaction mixture from the oxidation of cyclohexaneInfo
- Publication number
- GB1109543A GB1109543A GB138/66A GB13866A GB1109543A GB 1109543 A GB1109543 A GB 1109543A GB 138/66 A GB138/66 A GB 138/66A GB 13866 A GB13866 A GB 13866A GB 1109543 A GB1109543 A GB 1109543A
- Authority
- GB
- United Kingdom
- Prior art keywords
- cyclohexanol
- cyclohexane
- reaction mixture
- separating
- residue
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 title abstract 3
- 239000011541 reaction mixture Substances 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- 230000003647 oxidation Effects 0.000 title abstract 2
- 238000007254 oxidation reaction Methods 0.000 title abstract 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 abstract 4
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 abstract 4
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 abstract 4
- 239000003513 alkali Substances 0.000 abstract 3
- 235000011037 adipic acid Nutrition 0.000 abstract 2
- 239000001361 adipic acid Substances 0.000 abstract 2
- 239000008346 aqueous phase Substances 0.000 abstract 2
- 239000012074 organic phase Substances 0.000 abstract 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 abstract 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 238000010533 azeotropic distillation Methods 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- HPXRVTGHNJAIIH-PTQBSOBMSA-N cyclohexanol Chemical class O[13CH]1CCCCC1 HPXRVTGHNJAIIH-PTQBSOBMSA-N 0.000 abstract 1
- 150000001991 dicarboxylic acids Chemical class 0.000 abstract 1
- 238000004821 distillation Methods 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 150000007524 organic acids Chemical class 0.000 abstract 1
- 235000005985 organic acids Nutrition 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 238000007127 saponification reaction Methods 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/31—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting
- C07C51/313—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting with molecular oxygen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/487—Separation; Purification; Stabilisation; Use of additives by treatment giving rise to chemical modification
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEZ0011299 | 1965-01-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1109543A true GB1109543A (en) | 1968-04-10 |
Family
ID=26003581
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB138/66A Expired GB1109543A (en) | 1965-01-30 | 1966-01-03 | A method of processing the reaction mixture from the oxidation of cyclohexane |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US3439041A (enExample) |
| BE (1) | BE675206A (enExample) |
| DE (1) | DE1518255B1 (enExample) |
| FR (1) | FR1464399A (enExample) |
| GB (1) | GB1109543A (enExample) |
| NL (1) | NL6600638A (enExample) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1559604A (enExample) * | 1967-05-29 | 1969-03-14 | ||
| PL70457B1 (enExample) * | 1970-03-11 | 1974-02-28 | ||
| BE790104A (fr) * | 1971-10-14 | 1973-04-13 | Stamicarbon | Procede continu d'obtention de cyclohexanone |
| US4163027A (en) * | 1976-11-06 | 1979-07-31 | Basf Aktiengesellschaft | Working-up of reaction mixtures containing cyclohexanol and cyclohexanone |
| NL7808416A (nl) * | 1978-08-12 | 1980-02-14 | Stamicarbon | Werkwijze voor het verwijderen van aldehyden uit cyclo- alkanon bevattende mengsels verkregen bij oxidatie van cycloalkanen. |
| NL7904651A (nl) * | 1979-06-14 | 1980-12-16 | Stamicarbon | Werkwijze voor het verwijderen van alkalimetaalcarboxy- laten uit cycloalkanon en cycloalkanol bevattende meng- sels verkregen bij oxidatie van cycloalkanen. |
| DE3526412A1 (de) * | 1985-07-24 | 1987-02-05 | Basf Ag | Verfahren zur stabilisierung von sauren waschwaessern |
| DE10240816A1 (de) * | 2002-08-30 | 2004-03-11 | Basf Ag | Oxidationsverfahren |
| CN105315128B (zh) * | 2015-10-28 | 2017-04-12 | 江西科苑生物药业有限公司 | 一种环己烷氧化制备ka油的方法 |
| CN105601486A (zh) * | 2015-12-23 | 2016-05-25 | 衢州巨化锦纶有限责任公司 | 一种环己烷液相氧化法制备环己酮的方法 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2931834A (en) * | 1960-04-05 | Ctclohexane oxidation process | ||
| US3047629A (en) * | 1962-07-31 | Process of preparing cyclohexanone | ||
| US2552670A (en) * | 1951-05-15 | Purification of cyclic ketones | ||
| US2565087A (en) * | 1947-10-30 | 1951-08-21 | Allied Chem & Dye Corp | Process for oxidation of cycloaliphatic compounds |
| US2703331A (en) * | 1953-11-06 | 1955-03-01 | Du Pont | Process for separating adipic acid precursors |
| DE1046610B (de) * | 1955-06-15 | 1958-12-18 | Basf Ag | Verfahren zur Herstellung von Cyclohexanol und Cyclohexanon durch Oxydation von Cyclohexan |
| DE1114810B (de) * | 1957-10-08 | 1961-10-12 | Basf Ag | Verfahren zur Herstellung von Alkoholen und Ketonen durch Oxydation von cycloaliphatischen Kohlenwasserstoffen |
| LU39533A1 (enExample) * | 1959-12-14 | 1961-02-14 | ||
| DE1125917B (de) * | 1959-12-14 | 1962-03-22 | Scient Design Co | Verfahren zur Gewinnung von Cyclohexanon und Cyclohexanol |
| DE1233858B (de) * | 1959-12-16 | 1967-02-09 | Basf Ag | Verfahren zur Gewinnung von reinem Cyclohexanon und Cyclohexanol |
| NL288272A (enExample) * | 1963-01-28 |
-
1965
- 1965-01-30 DE DE19651518255 patent/DE1518255B1/de active Pending
-
1966
- 1966-01-03 GB GB138/66A patent/GB1109543A/en not_active Expired
- 1966-01-17 BE BE675206D patent/BE675206A/xx unknown
- 1966-01-17 FR FR46171A patent/FR1464399A/fr not_active Expired
- 1966-01-18 NL NL6600638A patent/NL6600638A/xx unknown
- 1966-02-01 US US524206A patent/US3439041A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| BE675206A (enExample) | 1966-05-16 |
| DE1518255B1 (de) | 1969-12-11 |
| FR1464399A (fr) | 1966-12-30 |
| US3439041A (en) | 1969-04-15 |
| NL6600638A (enExample) | 1966-08-01 |
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