GB1095847A - Laundry-retexturing agent - Google Patents

Laundry-retexturing agent

Info

Publication number
GB1095847A
GB1095847A GB29325/66A GB2932566A GB1095847A GB 1095847 A GB1095847 A GB 1095847A GB 29325/66 A GB29325/66 A GB 29325/66A GB 2932566 A GB2932566 A GB 2932566A GB 1095847 A GB1095847 A GB 1095847A
Authority
GB
United Kingdom
Prior art keywords
fatty acid
quaternary ammonium
diethanolamine
triethanolamine
mono
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB29325/66A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of GB1095847A publication Critical patent/GB1095847A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/008—Polymeric surface-active agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Detergent Compositions (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

An oligomeric amino-alcohol having a mean molecular weight of from 180-300 and which is obtained by oligo-condensation of diethanolamine or mixtures thereof with mono- and/or triethanolamine is esterified with 2 to 5 mols. fatty acid of C10 to C20 chain length per mole of the oligomeric amino alcohol and the product converted to a quaternary ammonium salt which has application in laundry retexturing agents. The oligomerization of the diethanolamine which may contain up to 50% by weight of mono- or triethanolamine may be effected by heating to 200-270 DEG C. in the presence of an alkali hydroxide or a tungsten, thorium or aluminium oxide or by heating to 200-300 DEG C. in the absence of a catalyst and an inert gas may be present. The esterification may be carried out by direct esterification or by trans-esterification of the oligomer, e.g. with a fatty acid methyl or ethyl ester in the presence of an alkali metal alcoholate as catalyst and the fatty acid may be derived from a natural fat such as tallow, coconut oil, palm nut oil, colza oil or cottonseed oil or it may be a hardened or synthetic fatty acid. The quaternary salt may be obtained by reacting the ester with a quaternating agent such as methyl or ethyl chloride, ethylene chlorhydrin or chloracetic acid. The quaternization may be partial or complete but generally at least 50% of the ester is converted to the quaternary ammonium salt.ALSO:Textiles are treated with a retexturing agent containing a quaternary ammonium salt of an ester of an oligomeric amino alcohol with 2 to 5 moles of a fatty acid of C10 to C20 chain length per mole of the oligomeric alcohol, the latter having a molecular weight of from 180-300 and being obtained by oligo-condensation of diethanolamine or of mixtures p thereof with mono- and/or triethanolamine. For use the agent is diluted with water, generally employing 0.05 to 1 gram active substance per litre of water and a bath ratio of from 1:4 to 1:30 and the treatment of textiles is suitably effected during rinsing after the washing process proper. The textiles may be of vegetable, animal or synthetic fibres, e.g. cotton fabric or cell wool yarn. Additives and fillers such as sodium-sulphate, -chloride or -acetate, dyestuffs, perfuming agents, optical brighteners and organic solvents such as C1-C3 alkanols, glycols, polyglycols and ketones may be present in the treating bath.ALSO:A stable emulsion is obtained by dispersing in water a quaternary ammonium salt of an oligomeric amino alcohol esterified with 2 to 5 mols of a fatty acid of C10 to C20 chain length for each mol of the oligomeric amino alcohol, the latter being obtained by oligocondensation of diethanolamine or mixtures thereof with mono- and/or triethanolamine. The quaternary ammonium salts may be present in amounts of 3% to 15% by weight of the emulsion. The emulsion may additionally contain small amounts of polyglycols, polyglycol ethers or fatty acid alkanolamides or neutral salts; e.g. sodium sulphate, chloride or acetate, dyestuffs, perfume, optical brighteners, and organic solvents such as glycols, polyglycols, ketones, and C1 - C3 alkanols.
GB29325/66A 1965-07-01 1966-06-30 Laundry-retexturing agent Expired GB1095847A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEH0056455 1965-07-01

Publications (1)

Publication Number Publication Date
GB1095847A true GB1095847A (en) 1967-12-20

Family

ID=7159389

Family Applications (1)

Application Number Title Priority Date Filing Date
GB29325/66A Expired GB1095847A (en) 1965-07-01 1966-06-30 Laundry-retexturing agent

Country Status (10)

Country Link
AT (1) AT265199B (en)
BE (1) BE683431A (en)
CH (1) CH482054A (en)
DE (1) DE1469399A1 (en)
DK (1) DK112934B (en)
ES (1) ES328561A1 (en)
FR (1) FR1485159A (en)
GB (1) GB1095847A (en)
NL (1) NL6607756A (en)
SE (1) SE318855B (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4243550C1 (en) * 1992-12-22 1994-06-01 Henkel Kgaa Fiber auxiliaries and their use

Also Published As

Publication number Publication date
FR1485159A (en) 1967-06-16
AT265199B (en) 1968-09-25
DE1469399A1 (en) 1968-12-12
SE318855B (en) 1969-12-22
BE683431A (en) 1966-12-30
CH482054A (en) 1970-01-15
DK112934B (en) 1969-02-03
NL6607756A (en) 1967-01-02
CH954466A4 (en) 1970-01-15
ES328561A1 (en) 1967-08-16

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