GB1095800A - Process for the recovery of monomers from polymerisation reaction mixtures - Google Patents

Process for the recovery of monomers from polymerisation reaction mixtures

Info

Publication number
GB1095800A
GB1095800A GB1041966A GB1041966A GB1095800A GB 1095800 A GB1095800 A GB 1095800A GB 1041966 A GB1041966 A GB 1041966A GB 1041966 A GB1041966 A GB 1041966A GB 1095800 A GB1095800 A GB 1095800A
Authority
GB
United Kingdom
Prior art keywords
solvent
monomers
zone
reaction mixture
recovery
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1041966A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of GB1095800A publication Critical patent/GB1095800A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F6/00Post-polymerisation treatments
    • C08F6/001Removal of residual monomers by physical means
    • C08F6/003Removal of residual monomers by physical means from polymer solutions, suspensions, dispersions or emulsions without recovery of the polymer therefrom

Abstract

Vaporizable unreacted monomers are recovered from the liquid reaction mixture resulting from a polymerization reaction involving at least two alpha-olefins and at least one C6- 22 non-conjugated diene by contacting the reaction mixture with a vaporized solvent for the monomers under conditions such that at least part of the solvent is condensed, the condensation thereof providing energy for vaporization of the monomers which are then removed together with any uncondensed solvent vapour. The reaction mixture may first have been subjected to flashing. The solvent is preferably of higher boiling point than any of the monomers present, and if a solvent has been used in the polymerization reaction the same solvent is used in the recovery. The process is preferably carried out under anhydrous conditions, and more than one contacting zone may be employed, the liquid effluent from each zone being further treated in the next zone. The recovered monomer/solvent mixture may be returned to the polymerization zone. The example is of recovering ethylene, propylene and 1,4-hexadiene using n-hexane vapour.
GB1041966A 1965-03-10 1966-03-09 Process for the recovery of monomers from polymerisation reaction mixtures Expired GB1095800A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US43865165A 1965-03-10 1965-03-10

Publications (1)

Publication Number Publication Date
GB1095800A true GB1095800A (en) 1967-12-20

Family

ID=23741466

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1041966A Expired GB1095800A (en) 1965-03-10 1966-03-09 Process for the recovery of monomers from polymerisation reaction mixtures

Country Status (3)

Country Link
DE (1) DE1543411A1 (en)
GB (1) GB1095800A (en)
NL (1) NL6603094A (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2091128C (en) * 1992-03-08 1999-07-27 Michael A. Taylor Removal of organic volatiles from polymer solutions and dispersions
DE4300921C1 (en) * 1993-01-15 1994-04-14 Hoechst Ag Solvent and diluent recovery for re-use - esp. in polymer prodn., processing or moulding, e.g. spinning

Also Published As

Publication number Publication date
DE1543411A1 (en) 1969-08-07
NL6603094A (en) 1966-09-12

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