GB1088441A - Recovery of bromine - Google Patents

Recovery of bromine

Info

Publication number
GB1088441A
GB1088441A GB552565A GB552565A GB1088441A GB 1088441 A GB1088441 A GB 1088441A GB 552565 A GB552565 A GB 552565A GB 552565 A GB552565 A GB 552565A GB 1088441 A GB1088441 A GB 1088441A
Authority
GB
United Kingdom
Prior art keywords
cerium
catalyst
copper
zirconia
free
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB552565A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Universal Oil Products Co
Original Assignee
Universal Oil Products Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Universal Oil Products Co filed Critical Universal Oil Products Co
Publication of GB1088441A publication Critical patent/GB1088441A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B7/00—Halogens; Halogen acids
    • C01B7/09—Bromine; Hydrogen bromide
    • C01B7/096—Bromine

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The oxidation of HBr to Br2 by a free-O2 containing gas is catalysed by copper or cerium oxides on an inert metal oxide support. The catalyst may be 2-50% of a copper or cerium oxide supported on zirconia, or alpha- or theta-alumina having a surface area of 5-100 m.2/g. The free-O2 containing gas may be air and may be in 20% stoichiometric excess. The gases may be passed over the catalyst, at 300-600 DEG C., atmospheric pressure, and at a combined velocity of 700-1500 volumes of gas per hour per volume of space occupied by catalyst.ALSO:A catalyst of cerium or copper oxide on an inert metal oxide support, for the oxidation of HBr to Br2 by a free O2-containing gas, is made by co-precipitating an aqueous solution of a copper or cerium compound e.g. copper or cerium nitrate, or cerium sulphate, with a salt of the inert support e.g. zirconyl chloride in the case of zirconia, by means of alkali e.g. NaOH, KOH, washing the precipitate, drying and calcining at 400 - 800 DEG C. The catalyst may be 2 - 50% CuO or CeO2 on zirconia, or a - or #qalumina having a surface area of 5-100 m2/g.
GB552565A 1964-02-13 1965-02-09 Recovery of bromine Expired GB1088441A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US34454364A 1964-02-13 1964-02-13

Publications (1)

Publication Number Publication Date
GB1088441A true GB1088441A (en) 1967-10-25

Family

ID=23350967

Family Applications (1)

Application Number Title Priority Date Filing Date
GB552565A Expired GB1088441A (en) 1964-02-13 1965-02-09 Recovery of bromine

Country Status (4)

Country Link
DE (1) DE1567854B1 (en)
ES (1) ES309292A1 (en)
GB (1) GB1088441A (en)
NL (1) NL6501624A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5674464A (en) * 1992-07-13 1997-10-07 European Economic Community Desulphurization of waste gases

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2163877A (en) * 1937-07-01 1939-06-27 Dow Chemical Co Process of making bromine

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5674464A (en) * 1992-07-13 1997-10-07 European Economic Community Desulphurization of waste gases

Also Published As

Publication number Publication date
DE1567854B1 (en) 1971-02-25
NL6501624A (en) 1965-08-16
ES309292A1 (en) 1965-06-16

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