GB1082693A - Silylation of hydroxy aromatic compounds - Google Patents
Silylation of hydroxy aromatic compoundsInfo
- Publication number
- GB1082693A GB1082693A GB33738/64A GB3373864A GB1082693A GB 1082693 A GB1082693 A GB 1082693A GB 33738/64 A GB33738/64 A GB 33738/64A GB 3373864 A GB3373864 A GB 3373864A GB 1082693 A GB1082693 A GB 1082693A
- Authority
- GB
- United Kingdom
- Prior art keywords
- groups
- phenol
- mono
- alkoxy
- radials
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 hydroxy aromatic compounds Chemical class 0.000 title abstract 6
- 238000006884 silylation reaction Methods 0.000 title 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 3
- 125000003545 alkoxy group Chemical group 0.000 abstract 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- 125000004104 aryloxy group Chemical group 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- IZUPBVBPLAPZRR-UHFFFAOYSA-N pentachlorophenol Chemical compound OC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl IZUPBVBPLAPZRR-UHFFFAOYSA-N 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 125000003342 alkenyl group Chemical group 0.000 abstract 1
- 125000003302 alkenyloxy group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 1
- 125000004093 cyano group Chemical group *C#N 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- MIHINWMALJZIBX-UHFFFAOYSA-N cyclohexa-2,4-dien-1-ol Chemical compound OC1CC=CC=C1 MIHINWMALJZIBX-UHFFFAOYSA-N 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 125000002950 monocyclic group Chemical group 0.000 abstract 1
- 125000003367 polycyclic group Polymers 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical compound [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/10—Compounds having one or more C—Si linkages containing nitrogen having a Si-N linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
- C07F7/1804—Compounds having Si-O-C linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
Abstract
Compounds of formula R1R2R3SiOR wherein R is residue of a mono-hydric phenol or, together with R3, represents the divalent residue of a dihydric phenol; and each R1, R2 and R3 is an aliphatic, cycloaliphatic, aryl or hydrocarboxy group, are prepared by reacting the appropriate aromatic hydroxy compound, with a compound selecte from <FORM:1082693/C3/1> <FORM:1082693/C3/2> <FORM:1082693/C3/3> <FORM:1082693/C3/4> wherein n is an integer. The reaction is preferably effected in the presence of an alkali-metal salt of the phenol reactant. The silazanes I to III and the amino silane IV may be prepared by reacting ammonia with a di- or mono-halosilane, respectively. Specified R1, R2 and R3 radials are alkyl, cycloalkyl, alkenyl, mono-and poly-cyclic aryl, alkoxy, alkenyloxy and aryloxy radials. The group R may contain one or more halogen, ether, esterified carboxyl, keto, amino or cyano-groups; specified groups are those derived from 2,21-dihydroxy-diphenyl and pentachlorophenol, but others are exemplified. Where R1 and R2 are C1- 4 alkoxy groups in the product these groups may be replaced by C8- 22 alkoxy, aralkoxy, or aryloxy groups by reaction with the corresponding alcohol or phenol.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEJ25363A DE1244183B (en) | 1964-02-29 | 1964-02-29 | Process for the production of aroxysilanes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1082693A true GB1082693A (en) | 1967-09-06 |
Family
ID=7202195
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB33738/64A Expired GB1082693A (en) | 1964-02-29 | 1964-08-18 | Silylation of hydroxy aromatic compounds |
Country Status (3)
| Country | Link |
|---|---|
| AT (1) | AT249690B (en) |
| DE (1) | DE1244183B (en) |
| GB (1) | GB1082693A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0114148A2 (en) * | 1983-01-12 | 1984-07-25 | Ciba-Geigy Ag | Dioxasilepin and dioxasilocin stabilizers |
| CN109790190A (en) * | 2016-07-13 | 2019-05-21 | 硝基化学阿绍有限公司 | Curing agent for organic silicon rubber material |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4278804A (en) * | 1980-05-30 | 1981-07-14 | General Electric Company | Ultraviolet light absorbing agents and compositions and articles containing same |
-
1964
- 1964-02-29 DE DEJ25363A patent/DE1244183B/en active Pending
- 1964-06-30 AT AT560464A patent/AT249690B/en active
- 1964-08-18 GB GB33738/64A patent/GB1082693A/en not_active Expired
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0114148A2 (en) * | 1983-01-12 | 1984-07-25 | Ciba-Geigy Ag | Dioxasilepin and dioxasilocin stabilizers |
| JPS59134799A (en) * | 1983-01-12 | 1984-08-02 | チバ−ガイギ−・アクチエンゲゼルシヤフト | Dioxasilebin, dioxasilosin and stabilizing composition containing them |
| EP0114148A3 (en) * | 1983-01-12 | 1985-12-27 | Ciba-Geigy Ag | Dioxasilepin and dioxasilocin stabilizers |
| JPH0460117B2 (en) * | 1983-01-12 | 1992-09-25 | Ciba Geigy | |
| CN109790190A (en) * | 2016-07-13 | 2019-05-21 | 硝基化学阿绍有限公司 | Curing agent for organic silicon rubber material |
| CN109790190B (en) * | 2016-07-13 | 2022-08-02 | 硝基化学阿绍有限公司 | Curing agent for silicone rubber material |
Also Published As
| Publication number | Publication date |
|---|---|
| AT249690B (en) | 1966-10-25 |
| DE1244183B (en) | 1967-07-13 |
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