GB1079561A - Novel heterocycle polymers - Google Patents
Novel heterocycle polymersInfo
- Publication number
- GB1079561A GB1079561A GB30661/64A GB3066164A GB1079561A GB 1079561 A GB1079561 A GB 1079561A GB 30661/64 A GB30661/64 A GB 30661/64A GB 3066164 A GB3066164 A GB 3066164A GB 1079561 A GB1079561 A GB 1079561A
- Authority
- GB
- United Kingdom
- Prior art keywords
- bis
- reacting
- oxadiazole
- polymers
- aminophenyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 125000000623 heterocyclic group Chemical group 0.000 title abstract 5
- 229920000642 polymer Polymers 0.000 title abstract 5
- 125000000524 functional group Chemical group 0.000 abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 abstract 2
- VLDPXPPHXDGHEW-UHFFFAOYSA-N 1-chloro-2-dichlorophosphoryloxybenzene Chemical compound ClC1=CC=CC=C1OP(Cl)(Cl)=O VLDPXPPHXDGHEW-UHFFFAOYSA-N 0.000 abstract 1
- HJLLHYNMAUWCNS-UHFFFAOYSA-N 3-[5-(3-aminophenyl)-1,3,4-oxadiazol-2-yl]aniline Chemical compound NC1=CC=CC(C=2OC(=NN=2)C=2C=C(N)C=CC=2)=C1 HJLLHYNMAUWCNS-UHFFFAOYSA-N 0.000 abstract 1
- MQQNVOPCVHQBTI-UHFFFAOYSA-N 3-[5-(3-aminophenyl)-4-phenyl-1,2,4-triazol-3-yl]aniline Chemical compound NC1=CC=CC(C=2N(C(C=3C=C(N)C=CC=3)=NN=2)C=2C=CC=CC=2)=C1 MQQNVOPCVHQBTI-UHFFFAOYSA-N 0.000 abstract 1
- YFTBUSOGIKCONQ-UHFFFAOYSA-N 3-[5-(3-carboxyphenyl)-1,3,4-oxadiazol-2-yl]benzoic acid Chemical compound OC(=O)C1=CC=CC(C=2OC(=NN=2)C=2C=C(C=CC=2)C(O)=O)=C1 YFTBUSOGIKCONQ-UHFFFAOYSA-N 0.000 abstract 1
- IOPGDXLYFPHBLA-UHFFFAOYSA-N 4-(2-phenyl-1,3-thiazol-4-yl)aniline Chemical compound C1=CC(N)=CC=C1C1=CSC(C=2C=CC=CC=2)=N1 IOPGDXLYFPHBLA-UHFFFAOYSA-N 0.000 abstract 1
- DRRBETBQLHESTQ-UHFFFAOYSA-N 4-[5-(3,4-diaminophenyl)-1,3,4-oxadiazol-2-yl]benzene-1,2-diamine Chemical compound C1=C(N)C(N)=CC=C1C1=NN=C(C=2C=C(N)C(N)=CC=2)O1 DRRBETBQLHESTQ-UHFFFAOYSA-N 0.000 abstract 1
- MJZXFMSIHMJQBW-UHFFFAOYSA-N 4-[5-(4-aminophenyl)-1,3,4-oxadiazol-2-yl]aniline Chemical compound C1=CC(N)=CC=C1C1=NN=C(C=2C=CC(N)=CC=2)O1 MJZXFMSIHMJQBW-UHFFFAOYSA-N 0.000 abstract 1
- 125000002373 5 membered heterocyclic group Chemical group 0.000 abstract 1
- 125000004070 6 membered heterocyclic group Chemical group 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- 239000004305 biphenyl Substances 0.000 abstract 1
- FHESUNXRPBHDQM-UHFFFAOYSA-N diphenyl benzene-1,3-dicarboxylate Chemical compound C=1C=CC(C(=O)OC=2C=CC=CC=2)=CC=1C(=O)OC1=CC=CC=C1 FHESUNXRPBHDQM-UHFFFAOYSA-N 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/0683—Polycondensates containing six-membered rings, condensed with other rings, with nitrogen atoms as the only ring hetero atoms
- C08G73/0688—Polycondensates containing six-membered rings, condensed with other rings, with nitrogen atoms as the only ring hetero atoms with only one nitrogen atom in the ring, e.g. polyquinolines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/0605—Polycondensates containing five-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/0683—Polycondensates containing six-membered rings, condensed with other rings, with nitrogen atoms as the only ring hetero atoms
- C08G73/0694—Polycondensates containing six-membered rings, condensed with other rings, with nitrogen atoms as the only ring hetero atoms with only two nitrogen atoms in the ring, e.g. polyquinoxalines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/08—Polyhydrazides; Polytriazoles; Polyaminotriazoles; Polyoxadiazoles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
- C08G73/1085—Polyimides with diamino moieties or tetracarboxylic segments containing heterocyclic moieties
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/18—Polybenzimidazoles
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
Abstract
The invention comprises linear heterocyclic polymers containing at least two different multivalent 5 or 6-membered heterocyclic units occurring in regularly ordered sequence in the chain, and having interposed between each of the hererocyclic units a multivalent hydrocarbo unit. The polymers are obtained by reacting a monomer containing at least one heterocyclic ring and at least two reactive functional groups with another monomer containing at least two reactive functional groups and may or may not contain heterocyclic rings, additional heterocyclic rings being formed during the polymerization. In examples polymers are obtained by reacting pyromellitic dianhydride with 2, 5-bis(p-aminophenyl)-1,3,4-oxadiazole, with 2,5 - bis(m - aminophenyl) - 1,3,4 - oxadiazole, with 3,5 - bis(m - aminophenyl) - 4-phenyl - 1,2,4 - triazole, with m - bis(4 - p-aminophenylthiazole - 2 - yl - benzene), by reacting 2,5 - bis(3,4 - diaminophenyl) - 1,3,4-oxadiazole with diphenyl isophthalate and with sebacic acid, by reacting 2,5-bis(m-carbohydrazinophenyl)-1,3,4-oxadiazole with N,N1-diphenyl - isophthalimidoyl chloride, by reacting N,N1 - bis(m - carbohydrazinophenyl) hydrazide with N,N1-diphenylisophthalimidoyl chloride, and by reacting 3,31-diaminobenzidine with 2,5 - bis(m - carboxyphenyl) - 1,3,4 - oxadiazole. Other starting materials and polymers are mentioned.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US29639563A | 1963-07-19 | 1963-07-19 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1079561A true GB1079561A (en) | 1967-08-16 |
Family
ID=23141836
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB30661/64A Expired GB1079561A (en) | 1963-07-19 | 1964-08-04 | Novel heterocycle polymers |
Country Status (7)
| Country | Link |
|---|---|
| BE (1) | BE650774A (en) |
| CH (1) | CH513222A (en) |
| DE (1) | DE1570886C3 (en) |
| FR (1) | FR1447154A (en) |
| GB (1) | GB1079561A (en) |
| LU (1) | LU46567A1 (en) |
| NL (1) | NL129240C (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2408426C2 (en) * | 1974-02-21 | 1981-12-03 | Vsesojuznyj naučno-issledovatel'skij i proektnyj institut monomerov, Tula | Process for the preparation of polyarylene-1,3,4-oxadiazoles and their use |
-
1964
- 1964-07-18 LU LU46567A patent/LU46567A1/en unknown
- 1964-07-20 NL NL6408298A patent/NL129240C/en active
- 1964-07-20 DE DE1570886A patent/DE1570886C3/en not_active Expired
- 1964-07-20 BE BE650774D patent/BE650774A/en unknown
- 1964-07-20 CH CH948764A patent/CH513222A/en not_active IP Right Cessation
- 1964-07-20 FR FR982361A patent/FR1447154A/en not_active Expired
- 1964-08-04 GB GB30661/64A patent/GB1079561A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR1447154A (en) | 1966-07-29 |
| CH513222A (en) | 1971-09-30 |
| LU46567A1 (en) | 1965-01-19 |
| BE650774A (en) | 1965-01-20 |
| NL6408298A (en) | 1965-01-20 |
| DE1570886B2 (en) | 1973-06-20 |
| DE1570886C3 (en) | 1974-01-17 |
| NL129240C (en) | 1970-02-16 |
| DE1570886A1 (en) | 1970-01-29 |
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