GB1072983A - Pigmented polystyrene - Google Patents

Pigmented polystyrene

Info

Publication number
GB1072983A
GB1072983A GB3703264A GB3703264A GB1072983A GB 1072983 A GB1072983 A GB 1072983A GB 3703264 A GB3703264 A GB 3703264A GB 3703264 A GB3703264 A GB 3703264A GB 1072983 A GB1072983 A GB 1072983A
Authority
GB
United Kingdom
Prior art keywords
pigment
styrene
pigmented polystyrene
polymerized
polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3703264A
Inventor
Thomas Ivor Jones
Allan King
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Geigy Co Ltd
Original Assignee
Geigy Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to NL126909D priority Critical patent/NL126909C/xx
Application filed by Geigy Co Ltd filed Critical Geigy Co Ltd
Priority to GB3703264A priority patent/GB1072983A/en
Priority to CH1241765A priority patent/CH459578A/en
Priority to BE669399D priority patent/BE669399A/xx
Priority to NL6511787A priority patent/NL6511787A/xx
Priority to DE19651570687 priority patent/DE1570687A1/en
Priority to FR30900A priority patent/FR1446685A/en
Publication of GB1072983A publication Critical patent/GB1072983A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/006—Preparation of organic pigments
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/06—Hydrocarbons
    • C08F12/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F257/00—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00
    • C08F257/02—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00 on to polymers of styrene or alkyl-substituted styrenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/16—Making expandable particles
    • C08J9/18—Making expandable particles by impregnating polymer particles with the blowing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/16—Making expandable particles
    • C08J9/20—Making expandable particles by suspension polymerisation in the presence of the blowing agent

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymerisation Methods In General (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

Pigmented polystyrene is produced by mixing an aqueous mass of a highly dispersed pigment paste with a copolymer of styrene and a C1- 12 alkyl acrylate or methacrylate prepared by emulsion polymerization as described in Specification 1,063,897, coagulating the mixture, removing the aqueous phase from the coagulum, drying and optionally pulverizing the resintreated pigment which is then incorporated into styrene monomer which is then polymerized in the presence of a polymerization catalyst to produce beads of pigmented polystyrene. 0.01-10% of pigment, e.g. a phthalocyanine blue, or carbon black (a number of proprietary pigments are exemplified) may be used in the monomer and the pigment may be dispersed with the aid of cetyl pyridinium bromide, sodium dinaphthyl methane sulphonate or an alkyl phenol ethylene oxide condesate. The polymerization catalys may be bisazo-isobutyronitile or benzoyl peroxide and the styrene may be polymerized in aqueou suspension in the presence of polyvinyl alcohol. The pigmented polystyrene beads may be expanded, e.g. by soaking in n-pentane and then steam treated.
GB3703264A 1964-09-10 1964-09-10 Pigmented polystyrene Expired GB1072983A (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
NL126909D NL126909C (en) 1964-09-10
GB3703264A GB1072983A (en) 1964-09-10 1964-09-10 Pigmented polystyrene
CH1241765A CH459578A (en) 1964-09-10 1965-09-07 Process for the production of strongly colored, homogeneously core-pigmented, expandable polystyrene beads
BE669399D BE669399A (en) 1964-09-10 1965-09-09
NL6511787A NL6511787A (en) 1964-09-10 1965-09-09
DE19651570687 DE1570687A1 (en) 1964-09-10 1965-09-09 Process for the production of core-pigmented, expandable polystyrene spheres
FR30900A FR1446685A (en) 1964-09-10 1965-09-09 Core pigmented polystyrene beads, convertible into foam

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3703264A GB1072983A (en) 1964-09-10 1964-09-10 Pigmented polystyrene

Publications (1)

Publication Number Publication Date
GB1072983A true GB1072983A (en) 1967-06-21

Family

ID=10393188

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3703264A Expired GB1072983A (en) 1964-09-10 1964-09-10 Pigmented polystyrene

Country Status (5)

Country Link
BE (1) BE669399A (en)
CH (1) CH459578A (en)
DE (1) DE1570687A1 (en)
GB (1) GB1072983A (en)
NL (2) NL6511787A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4105464A (en) 1974-07-12 1978-08-08 Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler Process for the production of pigment-synthetic resin concentrates
DE2600211C2 (en) 1975-01-08 1987-04-23 Ciba-Geigy Ag, Basel Pigment compositions and processes for their preparation
WO2008061678A3 (en) * 2006-11-23 2008-10-30 Polimeri Europa Spa Expandable vinyl aromatic polymers with enhanced heat insulation and process for the preparation thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4105464A (en) 1974-07-12 1978-08-08 Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler Process for the production of pigment-synthetic resin concentrates
DE2600211C2 (en) 1975-01-08 1987-04-23 Ciba-Geigy Ag, Basel Pigment compositions and processes for their preparation
WO2008061678A3 (en) * 2006-11-23 2008-10-30 Polimeri Europa Spa Expandable vinyl aromatic polymers with enhanced heat insulation and process for the preparation thereof
CN101646721B (en) * 2006-11-23 2014-06-18 波利玛利欧洲股份公司 Expandable vinyl aromatic polymers with enhanced heat insulation and process for the preparation thereof

Also Published As

Publication number Publication date
CH459578A (en) 1968-07-15
NL126909C (en)
DE1570687A1 (en) 1970-03-12
NL6511787A (en) 1966-03-11
BE669399A (en) 1966-03-09

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