GB1070942A - Improvements relating to phenyl tin compounds - Google Patents
Improvements relating to phenyl tin compoundsInfo
- Publication number
- GB1070942A GB1070942A GB3539/64A GB353964A GB1070942A GB 1070942 A GB1070942 A GB 1070942A GB 3539/64 A GB3539/64 A GB 3539/64A GB 353964 A GB353964 A GB 353964A GB 1070942 A GB1070942 A GB 1070942A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ph4sn
- phsnx3
- ph3snx
- snx4
- reacted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- ODOPKAJVFRHHGM-UHFFFAOYSA-N phenyltin Chemical class [Sn]C1=CC=CC=C1 ODOPKAJVFRHHGM-UHFFFAOYSA-N 0.000 title 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 abstract 2
- 239000003208 petroleum Substances 0.000 abstract 2
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 abstract 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- -1 phenyl alkali metal compound Chemical class 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/22—Tin compounds
- C07F7/2208—Compounds having tin linked only to carbon, hydrogen and/or halogen
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PhSnX3, wherein X is halogen is reacted with a phenyl alkali metal compound to give Ph4Sn, which is then reacted with SnX4 to give Ph3SnX and PhSnX3, the PhSnX3 being recycled. Example 1 describes the preparation of Ph4Sn by reacting Na with chlorobenzene, under N2, in petroleum ether, adding RhSnCl3 thereto and filtering off the Ph4Sn. Examples 1 and 3 describe the reaction of the Ph4Sn and SnX4 by heating them together under reduced pressure, e.g. 10 mm., at 120 DEG c. to distil off PhSnX3 and leaving a residue of Ph3SnX. Alternatively, the Ph4Sn and SnX4, may be heated together in a solvent, e.g. dibutyl ether, benzene, petroleum ether, from which Ph3SnX ppts. on cooling. Product Ph3SnCl may be hdrolysed with NaOH to form to the oxide and then reacted with CH3COOH to form the acetate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB3539/64A GB1070942A (en) | 1964-01-28 | 1964-01-28 | Improvements relating to phenyl tin compounds |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB3539/64A GB1070942A (en) | 1964-01-28 | 1964-01-28 | Improvements relating to phenyl tin compounds |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1070942A true GB1070942A (en) | 1967-06-07 |
Family
ID=9760231
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3539/64A Expired GB1070942A (en) | 1964-01-28 | 1964-01-28 | Improvements relating to phenyl tin compounds |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB1070942A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4222950A (en) * | 1978-08-10 | 1980-09-16 | M&T Chemicals Inc. | Method for preparing triorganotin halide |
| CN111584845A (en) * | 2020-05-20 | 2020-08-25 | 信阳师范学院 | Preparation method and application of N, S co-doped carbon/tin disulfide composite material |
-
1964
- 1964-01-28 GB GB3539/64A patent/GB1070942A/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4222950A (en) * | 1978-08-10 | 1980-09-16 | M&T Chemicals Inc. | Method for preparing triorganotin halide |
| CN111584845A (en) * | 2020-05-20 | 2020-08-25 | 信阳师范学院 | Preparation method and application of N, S co-doped carbon/tin disulfide composite material |
| CN111584845B (en) * | 2020-05-20 | 2022-04-29 | 信阳师范学院 | Preparation method and application of N, S co-doped carbon/tin disulfide composite material |
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