GB1070383A - Improvements in or relating to metal protecting preparations - Google Patents
Improvements in or relating to metal protecting preparationsInfo
- Publication number
- GB1070383A GB1070383A GB25235/63A GB2523563A GB1070383A GB 1070383 A GB1070383 A GB 1070383A GB 25235/63 A GB25235/63 A GB 25235/63A GB 2523563 A GB2523563 A GB 2523563A GB 1070383 A GB1070383 A GB 1070383A
- Authority
- GB
- United Kingdom
- Prior art keywords
- stearyl
- phosphoric acid
- ester
- alcohol
- thioglycollate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002184 metal Substances 0.000 title 1
- 238000002360 preparation method Methods 0.000 title 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 abstract 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 abstract 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 3
- 150000002148 esters Chemical class 0.000 abstract 3
- -1 iso-octyl thioglycollate Chemical compound 0.000 abstract 3
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- HDFRDWFLWVCOGP-UHFFFAOYSA-N carbonothioic O,S-acid Chemical compound OC(S)=O HDFRDWFLWVCOGP-UHFFFAOYSA-N 0.000 abstract 2
- 229910052802 copper Inorganic materials 0.000 abstract 2
- 239000010949 copper Substances 0.000 abstract 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 abstract 2
- 235000019441 ethanol Nutrition 0.000 abstract 2
- 229910052759 nickel Inorganic materials 0.000 abstract 2
- LFHBOSSJYCHNBJ-UHFFFAOYSA-N octadecyl 2-sulfanylpropanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C(C)S LFHBOSSJYCHNBJ-UHFFFAOYSA-N 0.000 abstract 2
- 239000000843 powder Substances 0.000 abstract 2
- 229910052709 silver Inorganic materials 0.000 abstract 2
- 239000004332 silver Substances 0.000 abstract 2
- 238000005494 tarnishing Methods 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 abstract 1
- 239000005909 Kieselgur Substances 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000000440 bentonite Substances 0.000 abstract 1
- 229910000278 bentonite Inorganic materials 0.000 abstract 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 abstract 1
- 238000005282 brightening Methods 0.000 abstract 1
- 238000005530 etching Methods 0.000 abstract 1
- 239000004744 fabric Substances 0.000 abstract 1
- 150000002191 fatty alcohols Chemical class 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 238000005554 pickling Methods 0.000 abstract 1
- 238000005498 polishing Methods 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09G—POLISHING COMPOSITIONS; SKI WAXES
- C09G1/00—Polishing compositions
- C09G1/02—Polishing compositions containing abrasives or grinding agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/3472—Organic compounds containing sulfur additionally containing -COOH groups or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
- C23F11/16—Sulfur-containing compounds
- C23F11/161—Mercaptans
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/10—Other heavy metals
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/3427—Organic compounds containing sulfur containing thiol, mercapto or sulfide groups, e.g. thioethers or mercaptales
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Metallurgy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Detergent Compositions (AREA)
Abstract
An ester of a mercapto carboxylic acid derived from an alcohol having at least 12 carbon atoms, e.g. stearyl mercaptopropionate and stearyl, lauryl or iso-octyl thioglycollate, is used to prevent tarnishing of copper, silver or nickel. In an example, a liquid polish consists of (by weight) polishing powder (diatomaceous earth) 20%, ethyl alcohol 20%, stearyl glycollate 2.5%, phosphoric acid 0.2%, water up to 100%. Bentonite (2 to 4%) may be added and acetic or hydrochloric acid may be used instead of phosphoric acid. The polish may also be in the form of a paste, powder, block or impregnated fabric.ALSO:An ester of a mercapto carboxylic acid derived from an aliphatic alcohol having at least 12 carbon atoms, e.g. stearyl, lauryl or iso octyl thioglycollate and stearyl mercaptopropionate is used to prevent tarnishing of silver, nickel or copper. The ester may be added to a pickling, detarnishing, brightening, de-scaling or etching bath. In an example, the solution contains (by weight) 3 stearyl thioglycollate, 3 ethoxylated fatty alcohol, 0.2 phosphoric acid, 94 water. Acetic or hydrochloric acid may be used instead of phosphoric acid as a stabilizer.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB25235/63A GB1070383A (en) | 1963-06-25 | 1963-06-25 | Improvements in or relating to metal protecting preparations |
| US377391A US3518098A (en) | 1963-06-25 | 1964-06-23 | Metal protecting preparations |
| DE19641519159 DE1519159A1 (en) | 1963-06-25 | 1964-06-25 | Cleaning and polishing agents for metal surfaces |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB25235/63A GB1070383A (en) | 1963-06-25 | 1963-06-25 | Improvements in or relating to metal protecting preparations |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1070383A true GB1070383A (en) | 1967-06-01 |
Family
ID=10224398
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB25235/63A Expired GB1070383A (en) | 1963-06-25 | 1963-06-25 | Improvements in or relating to metal protecting preparations |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US3518098A (en) |
| DE (1) | DE1519159A1 (en) |
| GB (1) | GB1070383A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005095675A1 (en) * | 2004-03-30 | 2005-10-13 | Middlesex Silver Co. Limited | Water-based metal treatment composition |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4305779A (en) * | 1980-05-28 | 1981-12-15 | The United States Of America As Represented By The United States Department Of Energy | Method of polishing nickel-base alloys and stainless steels |
| US4459158A (en) * | 1982-09-29 | 1984-07-10 | Phillips Petroleum Company | Sulfur based metal cleaners |
| US4640713A (en) * | 1984-11-19 | 1987-02-03 | S. C. Johnson & Son, Inc. | Tarnish remover/metal polish formulation comprising a metal iodide, an acid, and water |
| US5487792A (en) * | 1994-06-13 | 1996-01-30 | Midwest Research Institute | Molecular assemblies as protective barriers and adhesion promotion interlayer |
| TW387926B (en) * | 1998-05-15 | 2000-04-21 | Nippon Dacro Shamrock Co | Surface treatment agent for metals, surface treatment method for metals, and pre-coated steel plate |
| GB0307290D0 (en) * | 2003-03-31 | 2003-05-07 | Cole Paul G | Enhancing silver tarnish-resistance |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2947599A (en) * | 1955-07-05 | 1960-08-02 | Little Inc A | Corrosion inhibitors |
| US2841501A (en) * | 1957-04-17 | 1958-07-01 | James G Murphy | Silver polish |
| NL283747A (en) * | 1961-09-28 |
-
1963
- 1963-06-25 GB GB25235/63A patent/GB1070383A/en not_active Expired
-
1964
- 1964-06-23 US US377391A patent/US3518098A/en not_active Expired - Lifetime
- 1964-06-25 DE DE19641519159 patent/DE1519159A1/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005095675A1 (en) * | 2004-03-30 | 2005-10-13 | Middlesex Silver Co. Limited | Water-based metal treatment composition |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1519159A1 (en) | 1969-06-12 |
| US3518098A (en) | 1970-06-30 |
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