GB1067439A - Emulsion polymerization process - Google Patents
Emulsion polymerization processInfo
- Publication number
- GB1067439A GB1067439A GB4955763A GB4955763A GB1067439A GB 1067439 A GB1067439 A GB 1067439A GB 4955763 A GB4955763 A GB 4955763A GB 4955763 A GB4955763 A GB 4955763A GB 1067439 A GB1067439 A GB 1067439A
- Authority
- GB
- United Kingdom
- Prior art keywords
- mole
- vinyl
- reaction product
- compounds
- moles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000007720 emulsion polymerization reaction Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 239000007795 chemical reaction product Substances 0.000 abstract 4
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 abstract 4
- 150000001875 compounds Chemical class 0.000 abstract 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical class C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 abstract 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 abstract 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 2
- 125000002947 alkylene group Chemical group 0.000 abstract 2
- 150000001408 amides Chemical class 0.000 abstract 2
- 229910052799 carbon Inorganic materials 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000000084 colloidal system Substances 0.000 abstract 2
- 239000000839 emulsion Substances 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- 238000006116 polymerization reaction Methods 0.000 abstract 2
- 230000001681 protective effect Effects 0.000 abstract 2
- -1 vinyl heterocyclic compounds Chemical class 0.000 abstract 2
- 229920002554 vinyl polymer Polymers 0.000 abstract 2
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical class C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 abstract 1
- GELKGHVAFRCJNA-UHFFFAOYSA-N 2,2-Dimethyloxirane Chemical compound CC1(C)CO1 GELKGHVAFRCJNA-UHFFFAOYSA-N 0.000 abstract 1
- WQMWHMMJVJNCAL-UHFFFAOYSA-N 2,4-dimethylpenta-1,4-dien-3-one Chemical class CC(=C)C(=O)C(C)=C WQMWHMMJVJNCAL-UHFFFAOYSA-N 0.000 abstract 1
- 241000416162 Astragalus gummifer Species 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 abstract 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 abstract 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 1
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Natural products OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 abstract 1
- 239000001828 Gelatine Substances 0.000 abstract 1
- 229920000084 Gum arabic Polymers 0.000 abstract 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 abstract 1
- 239000004372 Polyvinyl alcohol Substances 0.000 abstract 1
- 239000004159 Potassium persulphate Substances 0.000 abstract 1
- 241000978776 Senegalia senegal Species 0.000 abstract 1
- 229920001615 Tragacanth Polymers 0.000 abstract 1
- 239000000205 acacia gum Substances 0.000 abstract 1
- 235000010489 acacia gum Nutrition 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical class C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- 150000001253 acrylic acids Chemical class 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 235000010443 alginic acid Nutrition 0.000 abstract 1
- 229920000615 alginic acid Polymers 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- WFYPICNXBKQZGB-UHFFFAOYSA-N butenyne Chemical group C=CC#C WFYPICNXBKQZGB-UHFFFAOYSA-N 0.000 abstract 1
- 239000001768 carboxy methyl cellulose Substances 0.000 abstract 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 abstract 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 abstract 1
- 239000003638 chemical reducing agent Substances 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 239000003995 emulsifying agent Substances 0.000 abstract 1
- 150000002170 ethers Chemical class 0.000 abstract 1
- 239000001530 fumaric acid Substances 0.000 abstract 1
- 229920000159 gelatin Polymers 0.000 abstract 1
- 235000019322 gelatine Nutrition 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 abstract 1
- 229920000609 methyl cellulose Polymers 0.000 abstract 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 abstract 1
- 239000001923 methylcellulose Substances 0.000 abstract 1
- 235000010981 methylcellulose Nutrition 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 150000002825 nitriles Chemical class 0.000 abstract 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 125000000864 peroxy group Chemical group O(O*)* 0.000 abstract 1
- 150000002989 phenols Chemical class 0.000 abstract 1
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 abstract 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 abstract 1
- 235000019394 potassium persulphate Nutrition 0.000 abstract 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
- 150000003440 styrenes Chemical class 0.000 abstract 1
- 150000003573 thiols Chemical class 0.000 abstract 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Polymerization Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US24732162A | 1962-12-26 | 1962-12-26 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1067439A true GB1067439A (en) | 1967-05-03 |
Family
ID=22934468
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4955763A Expired GB1067439A (en) | 1962-12-26 | 1963-12-16 | Emulsion polymerization process |
Country Status (3)
| Country | Link |
|---|---|
| BE (1) | BE641739A (enExample) |
| DE (1) | DE1221800B (enExample) |
| GB (1) | GB1067439A (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2325663A1 (fr) * | 1975-09-25 | 1977-04-22 | Synres Internationaal Nv | Procede de preparation d'emulsions aqueuses stables de polymeres et copolymere d'addition |
| FR2325662A1 (fr) * | 1975-09-25 | 1977-04-22 | Synres Internationaal Nv | Procede de preparation d'emulsions aqueuses de polymeres d'addition avec emulsifiant incorpore |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE954009C (de) * | 1953-12-30 | 1956-12-13 | Huels Chemische Werke Ag | Verwendung von Phosphorsaeureestern als Emulgatoren fuer die Emulsionspolymerisationvon polymerisierbaren chlorhaltigen organischen Verbindungen |
-
1963
- 1963-12-16 GB GB4955763A patent/GB1067439A/en not_active Expired
- 1963-12-24 DE DEG39473A patent/DE1221800B/de active Pending
- 1963-12-24 BE BE641739A patent/BE641739A/fr unknown
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2325663A1 (fr) * | 1975-09-25 | 1977-04-22 | Synres Internationaal Nv | Procede de preparation d'emulsions aqueuses stables de polymeres et copolymere d'addition |
| FR2325662A1 (fr) * | 1975-09-25 | 1977-04-22 | Synres Internationaal Nv | Procede de preparation d'emulsions aqueuses de polymeres d'addition avec emulsifiant incorpore |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1221800B (de) | 1966-07-28 |
| BE641739A (enExample) | 1964-04-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ES447427A1 (es) | Mejoras introducidas en un procedimiento para la preparacionde una composicion detergente liquida acuosa reforzada. | |
| GB727727A (en) | Improvements in or relating to polymerization process and catalyst | |
| GB1437855A (en) | Detergent film | |
| GB738683A (en) | Improvements in colour photography | |
| GB1030306A (en) | Process for the catalytic hydrogenation of polymers of dienes | |
| GB1132010A (en) | A process for the preparation of phenols containing unsaturated groups | |
| GB834904A (en) | Olefin polymerization process | |
| GB1067438A (en) | Emulsion polymerization process | |
| GB1091607A (en) | Azo compounds | |
| GB835674A (en) | Improvements in catalysts for aqueous emulsion polymerizations | |
| ES339492A1 (es) | Un procedimiento para la preparacion de una dispersion a- cuosa estable de un copolimero de un ester vinilico de un a-cido organico y etileno. | |
| GB582890A (en) | Dialkyl peroxide as catalysts for ethylene polymerisation | |
| GB826292A (enExample) | ||
| GB693496A (en) | Improvements in or relating to the production of aqueous dispersions of vinylidene chloride copolymers and of moistureproof sheet wrapping material produced therefrom | |
| GB976570A (en) | Amphoteric ion exchange resins | |
| GB807112A (en) | Process for the production of ethylene copolymers | |
| GB956800A (en) | Process for the manufacture of co-polymer dispersions | |
| GB1074327A (en) | Process for the preparation of stable cation-active polymer dispersions and substances suitable for use in the process | |
| GB760104A (en) | Improved polymerization process and products | |
| JP4157125B2 (ja) | 乳化重合用乳化剤、ポリマーエマルションの製造方法及びポリマーエマルション | |
| GB1094087A (en) | New hydrolysed copolymers of ethene and alkenyl esters and a process for the preparation thereof | |
| GB1042801A (en) | Process for regulating the molecular weight of polydiolefines | |
| GB954643A (en) | Method of preparing blotter-type polyvinyl halide resins | |
| GB952973A (en) | A process for the production of unsaturated esters and alcohols | |
| GB643045A (en) | Improvements in or relating to polymerization processes and the products obtained thereby |