GB1063526A - Double metal cyanide complex compositions and methods for making the same - Google Patents

Double metal cyanide complex compositions and methods for making the same

Info

Publication number
GB1063526A
GB1063526A GB41572/66A GB4157266A GB1063526A GB 1063526 A GB1063526 A GB 1063526A GB 41572/66 A GB41572/66 A GB 41572/66A GB 4157266 A GB4157266 A GB 4157266A GB 1063526 A GB1063526 A GB 1063526A
Authority
GB
United Kingdom
Prior art keywords
iii
metal
zncl2
compositions
complex
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB41572/66A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Aerojet Rocketdyne Holdings Inc
Original Assignee
General Tire and Rubber Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US258530A external-priority patent/US3278457A/en
Priority claimed from US258595A external-priority patent/US3278458A/en
Priority claimed from US258603A external-priority patent/US3278459A/en
Application filed by General Tire and Rubber Co filed Critical General Tire and Rubber Co
Priority claimed from GB4241/64A external-priority patent/GB1063525A/en
Publication of GB1063526A publication Critical patent/GB1063526A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/24—Nitrogen compounds
    • B01J27/26—Cyanides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2213—At least two complexing oxygen atoms present in an at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B60C1/0016—Compositions of the tread
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B60C1/0025—Compositions of the sidewalls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C11/00—Tyre tread bands; Tread patterns; Anti-skid inserts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645—Metals or compounds thereof, e.g. salts
    • C08G65/2663—Metal cyanide catalysts, i.e. DMC's
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0202—Polynuclearity
    • B01J2531/0205—Bi- or polynuclear complexes, i.e. comprising two or more metal coordination centres, without metal-metal bonds, e.g. Cp(Lx)Zr-imidazole-Zr(Lx)Cp
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
    • B01J2531/24—Strontium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
    • B01J2531/26—Zinc
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/50—Complexes comprising metals of Group V (VA or VB) as the central metal
    • B01J2531/56—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
    • B01J2531/72—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron

Abstract

The invention comprises compositions comprising a double metal cyanide complex compound, wherein the first metal is capable of forming a stronger metal-oxygen bond than the co-ordinate bond it forms with the CN nitrogen atom and wherein the second metal (which may be the same as the first) is a transition metal having more than one stable valence form and forms a relatively strong covalent bond with the CN carbon atom, and wherein at least the majority of the bridging groups between said first and second metals are CN-groups, said complex compound containing, in an amount sufficient to increase the activity of said complex for the polymerization of oxirans and oxetans, at least one organic material selected from alcohols, aldehydes, ketones, esters, ethers, amides, nitriles and sulphides. The compositions are made by treating the complex cyanides with the organic materials or a mixture of water and organic material and may have the rational formula <FORM:1063526/C2/1> where M is Zn (II), Fe (II), Fe (III), Co. (II), Ni (II), Mo (IV), Mo (VI), Al (III), V (IV), V (V), Sr (II), W (IV), W (VI), Mn (II), or Cr (III); M1 is Fe (II), Fe (III), Co (II), Co (III), Cr (II), Cr (III), Mn (II), Mn (III), V (IV) or V (V); X is F-, Cl-, Br-, I-, OH-, NO, O2-, CO, H2O, NO2-, C2O42-, SO42-, CNO-, CNS-, NCO- or NCS-; R is the organic material; a and c are numbers, r is a number greater than , t is a number or zero and the values of a, c, r and t are such that the valences and co-ordination numbers of M and M1 are satisfied, the total net positive charge on M times a being equal to the total net positive charge or (M1(CN)r(X)t times c; d is zero or a number and e is a number. The compositions may be polymeric in form and may be dried in vacuo or in a stream of gas up to 200 DEG C., or azeotropically.ALSO:Double metal complex cyanides are prepared as follows: Examples (1), (2) (13) and (14), Zn3[Fe(CN)6]2 by reacting ZnCl2, ZnBr2, Zn(C2H3O2)2 or Zn(NO3)2 with K3Fe(CN)6, a mixture of K3Fe(CN)6 and K4Fe(CN)6 or CaFe(CN)6; Example (7), iron hexacyano-ferrate by reacting FeCl3 with K4Fe(CN)6; Example (9), ZnFe(CN)5NO from ZnCl2 and Na2Fe(CN)5NO; Examples (10), (12) and (15), Zn3[Co(CN)6]2 from ZnCl2 and K3Co(CN)6, Ca3[Co(CN)6]2, Na3Co(CN)6 or Li3Co(CN)6; Example (11) Ni3[Fe(CN)6]2, aqueous media being used in each case.
GB41572/66A 1963-02-14 1964-01-31 Double metal cyanide complex compositions and methods for making the same Expired GB1063526A (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US258530A US3278457A (en) 1963-02-14 1963-02-14 Method of making a polyether using a double metal cyanide complex compound
US258595A US3278458A (en) 1963-02-14 1963-02-14 Method of making a polyether using a double metal cyanide complex compound
US258603A US3278459A (en) 1963-02-14 1963-02-14 Method of making a polyether using a double metal cyanide complex compound
GB4241/64A GB1063525A (en) 1963-02-14 1964-01-31 Organic cyclic oxide polymers, their preparation and tires prepared therefrom
US496721A US3404109A (en) 1963-02-14 1965-10-15 Production of polyether diols using water as a telogen

Publications (1)

Publication Number Publication Date
GB1063526A true GB1063526A (en) 1967-03-30

Family

ID=27515744

Family Applications (1)

Application Number Title Priority Date Filing Date
GB41572/66A Expired GB1063526A (en) 1963-02-14 1964-01-31 Double metal cyanide complex compositions and methods for making the same

Country Status (1)

Country Link
GB (1) GB1063526A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001089688A1 (en) * 2000-05-19 2001-11-29 Enichem S.P.A. Catalytic system based on bimetallic cyanides and their use in the synthesis of polyether-polyols
CN112973796A (en) * 2019-12-18 2021-06-18 湖北工业大学 Catalyst for quickly and efficiently degrading methylene blue wastewater and preparation method and application thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001089688A1 (en) * 2000-05-19 2001-11-29 Enichem S.P.A. Catalytic system based on bimetallic cyanides and their use in the synthesis of polyether-polyols
CN112973796A (en) * 2019-12-18 2021-06-18 湖北工业大学 Catalyst for quickly and efficiently degrading methylene blue wastewater and preparation method and application thereof

Similar Documents

Publication Publication Date Title
ES332250A1 (en) Procedure for preparing polyoxyliocohylene eter dolls. (Machine-translation by Google Translate, not legally binding)
Shriver et al. Ligand field strength of the nitrogen end of cyanide and structures of cubic cyanide polymers
GB1377228A (en) Hydrocyanation of unsaturated organic compounds
GB1149726A (en) Production of polyether diols using water as a telogen
ES399471A1 (en) Process for the manufacture of acrylonitrile and methacrylonitrile
GB1291323A (en) Manufacture of catalysts of the iron molybdate type for use particularly in the catalytic oxidation of alcohols to aldehydes
GB1063526A (en) Double metal cyanide complex compositions and methods for making the same
JPS5638402A (en) High density sintered magnetic body and its manufacture
JPS5481118A (en) Nonmagnetic steel excellent in mechanical properties
GB2016526A (en) Production of magnetic powder
GB1025417A (en)
GB1319190A (en) Process for the manufacture of acrylonitrile and methacrylonitrile
ES8206211A1 (en) Process for the preparation of catalysts based on oxides of molybdenum and/or tungsten and on oxides of other metals.
ES8207441A1 (en) Catalysts preparation process based on molybden and/or tungsten oxides and oxides of other metals.
JPS5655503A (en) Production of metal magnetic powder of superior corrosion resistance
GB1296922A (en)
GB1138696A (en) Process for preparing nitriles
ES8302030A1 (en) Oxygen-curable mercapto-functional organic compound compositions catalyzed by metal carbonyl compounds and method of forming higher molecular weight products therefrom.
JPS55134159A (en) Vortex combustion chamber member for diesel engine and mouthpiece material thereof
Ito et al. A Chelate Ring Size Effect on Spin States of Iron (III) Complexes with Hexadentate Ligands Derived from Salicylaldehyde and 4, 8-Diazaundecane-1, 11-diamine (3, 3, 3-tet) or 4, 7-Diazadecane-1, 10-diamine (3, 2, 3-tet), and their X-Ray Structures
SE7408807L (en)
ES8303478A1 (en) Oxygen-curable mercaptoorganosiloxane compositions containing both redox and iron carbonyl compounds and method of forming higher molecular weight products therefrom.
Aggarwal et al. Nicotinoyl hydrazide complexes of some first row transition metal ions
Tarafder et al. Nickel complexes of S-benzyl-β-N-(furyl) methylenedithiocarbazate
SU378969A1 (en) Ferritic material