ES332250A1 - Procedure for preparing polyoxyliocohylene eter dolls. (Machine-translation by Google Translate, not legally binding) - Google Patents

Procedure for preparing polyoxyliocohylene eter dolls. (Machine-translation by Google Translate, not legally binding)

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Publication number
ES332250A1
ES332250A1 ES0332250A ES332250A ES332250A1 ES 332250 A1 ES332250 A1 ES 332250A1 ES 0332250 A ES0332250 A ES 0332250A ES 332250 A ES332250 A ES 332250A ES 332250 A1 ES332250 A1 ES 332250A1
Authority
ES
Spain
Prior art keywords
iii
group
integer
carbon atoms
oxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES0332250A
Other languages
Spanish (es)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Aerojet Rocketdyne Holdings Inc
Original Assignee
General Tire and Rubber Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US496721A external-priority patent/US3404109A/en
Application filed by General Tire and Rubber Co filed Critical General Tire and Rubber Co
Publication of ES332250A1 publication Critical patent/ES332250A1/en
Expired legal-status Critical Current

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  • Polyethers (AREA)

Abstract

Process for preparing polyoxyalkylene ether diols, wherein the hydroxyl groups are substantially terminal hydroxyl groups, comprising mixing at least one polymerizable organic cyclic monomer, having a ring of 2 to 3 carbon atoms and an oxygen atom, and up to total of 18 carbon atoms, said oxide being chosen from the group consisting of epoxides, oxetanes, 3-substituted oxetanes and 3,3-disubstituted oxetanes, with water being present in an amount of about 0.0001 to 5% by weight, based on in the polymerizable oxide, in the presence of a catalyst in an amount of about 0.0001 to 15% by weight on said monomer, said catalyst comprising a double metal cyanide complex compound having the general formula Ma (Z) c. (H2O) ) d. (R) e, where Z is chosen from the group consisting of M '(CN) by M' [(CN) r (X) t] b where M is at least one metal selected from the group consisting of Zn (II), Fe (II), Fe (III), Co (II), Ni (II), Mo (IV), M or (VI), Al (III), V (IV), V (V), Sr (II), W (IV), W (VI), Mn (II) and Cr (III) M 'is a selected metal of the group consisting of Fe (II), Fe (II) Co (II), Co (III) Cr (ll), Cr (III), Mn (II), Mn (III), V (IV) and V ( V), X is an elected member of the group consisting of (see formula), R is an organic compound of low molecular weight that has up to 18 carbon atoms and is selected from the group consisting of alcohols, aldehydes, ketones, ethers, esters and amides, nitriles and sulfides, being a, b and c numbers whose values are a function of the valences and coordination indices of M and M ', with the total positive net charge of M, multiplied by a, essentially equal to the total negative net charge of Z multiplied by c, R is an integer, T is an integer, where R is greater than T, d is equal to 0 or an integer, and e is an integer; maintaining said mixture at a temperature at which said water and cyclic oxide will react to produce said polyoxyalkylene ether diols. (Machine-translation by Google Translate, not legally binding)
ES0332250A 1965-10-15 1966-10-14 Procedure for preparing polyoxyliocohylene eter dolls. (Machine-translation by Google Translate, not legally binding) Expired ES332250A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US496721A US3404109A (en) 1963-02-14 1965-10-15 Production of polyether diols using water as a telogen

Publications (1)

Publication Number Publication Date
ES332250A1 true ES332250A1 (en) 1967-07-16

Family

ID=41533525

Family Applications (1)

Application Number Title Priority Date Filing Date
ES0332250A Expired ES332250A1 (en) 1965-10-15 1966-10-14 Procedure for preparing polyoxyliocohylene eter dolls. (Machine-translation by Google Translate, not legally binding)

Country Status (2)

Country Link
JP (1) JPS4627250B1 (en)
ES (1) ES332250A1 (en)

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Also Published As

Publication number Publication date
JPS4627250B1 (en) 1971-08-07

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