GB1061173A - Process for the production of catalysts containing titanium - Google Patents
Process for the production of catalysts containing titaniumInfo
- Publication number
- GB1061173A GB1061173A GB7176/64A GB717664A GB1061173A GB 1061173 A GB1061173 A GB 1061173A GB 7176/64 A GB7176/64 A GB 7176/64A GB 717664 A GB717664 A GB 717664A GB 1061173 A GB1061173 A GB 1061173A
- Authority
- GB
- United Kingdom
- Prior art keywords
- titanium
- peroxy
- hydrogen peroxide
- salts
- compounds
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000010936 titanium Substances 0.000 title abstract 6
- 229910052719 titanium Inorganic materials 0.000 title abstract 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 title abstract 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 8
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- 150000003839 salts Chemical class 0.000 abstract 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 150000004965 peroxy acids Chemical class 0.000 abstract 2
- -1 titanium halides Chemical class 0.000 abstract 2
- 239000004342 Benzoyl peroxide Substances 0.000 abstract 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 abstract 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 abstract 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 235000019400 benzoyl peroxide Nutrition 0.000 abstract 1
- 230000032050 esterification Effects 0.000 abstract 1
- 238000005886 esterification reaction Methods 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000007800 oxidant agent Substances 0.000 abstract 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical class OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 abstract 1
- KHIWWQKSHDUIBK-UHFFFAOYSA-N periodic acid Chemical class OI(=O)(=O)=O KHIWWQKSHDUIBK-UHFFFAOYSA-N 0.000 abstract 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/063—Titanium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
- B01J31/0212—Alkoxylates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/04—Metal peroxides or peroxyhydrates thereof; Metal superoxides; Metal ozonides; Peroxyhydrates thereof
- C01B15/047—Metal peroxides or peroxyhydrates thereof; Metal superoxides; Metal ozonides; Peroxyhydrates thereof of heavy metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Titanium peroxy compounds suitable for use as esterification catalysts are prepared by reacting titanium halides and/or alkoxy-titanium halides with water in the presence of hydrogen peroxide or materials "capable of reacting like hydrogen peroxide." By this is meant salts of hydrogen peroxide, organic peroxy-compounds such as benzoyl peroxide, ozone, atomic oxygen, salts of peroxy-acids such as persulphates and percarbonates, salts of per-acids such as perchlorates and periodates and other oxidizing agents which have potentials, at a given pH, greater than those of the titanium peroxo-compounds to be produced. A solution of the titanium halide, or alkoxytitanium halide in dilute acid or methanol may be reacted with ammonium or alkali metal hydroxide solution in the presence of hydrogen peroxide to form an ammonium or alkali metal peroxy-titanate which may then be hydrolysed to a hydrated titanium peroxide or peroxytitanic acid.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DER0036031 | 1963-09-03 | ||
| DER36029A DE1185611B (en) | 1963-09-03 | 1963-09-03 | Process for the preparation of carboxylic acid esters |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1061173A true GB1061173A (en) | 1967-03-08 |
Family
ID=25991698
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB7175/64A Expired GB1061172A (en) | 1963-09-03 | 1964-02-20 | Process for the production of carboxylic acid esters |
| GB7176/64A Expired GB1061173A (en) | 1963-09-03 | 1964-02-20 | Process for the production of catalysts containing titanium |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB7175/64A Expired GB1061172A (en) | 1963-09-03 | 1964-02-20 | Process for the production of carboxylic acid esters |
Country Status (3)
| Country | Link |
|---|---|
| CH (1) | CH435238A (en) |
| DE (1) | DE1185611B (en) |
| GB (2) | GB1061172A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0282612A1 (en) * | 1987-03-17 | 1988-09-21 | Stauffer Chemical Company | Preparation of insoluble metal alkoxides |
| US7385075B2 (en) | 2000-11-13 | 2008-06-10 | Basf Aktiengesellschaft | Method for producing esters of multibasic acids |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59157058A (en) * | 1983-02-28 | 1984-09-06 | Ueno Seiyaku Oyo Kenkyusho:Kk | Preparation of aromatic hydrocarboxylic acid benzyl esters |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1103335B (en) * | 1955-10-13 | 1961-03-30 | Goodrich Co B F | Process for the production of carboxylic acid esters |
-
1963
- 1963-09-03 DE DER36029A patent/DE1185611B/en active Pending
-
1964
- 1964-02-20 GB GB7175/64A patent/GB1061172A/en not_active Expired
- 1964-02-20 GB GB7176/64A patent/GB1061173A/en not_active Expired
- 1964-06-26 CH CH858764A patent/CH435238A/en unknown
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0282612A1 (en) * | 1987-03-17 | 1988-09-21 | Stauffer Chemical Company | Preparation of insoluble metal alkoxides |
| US7385075B2 (en) | 2000-11-13 | 2008-06-10 | Basf Aktiengesellschaft | Method for producing esters of multibasic acids |
Also Published As
| Publication number | Publication date |
|---|---|
| CH435238A (en) | 1967-05-15 |
| DE1185611B (en) | 1965-01-21 |
| GB1061172A (en) | 1967-03-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| PT822920E (en) | Process for the preparation of a disinfection solution containing chlorine dioxide for water treatment | |
| KR890008027A (en) | How to prepare powdered barium titanate | |
| GB1041822A (en) | Process of treating waste gas containing sulphur oxide | |
| GB1061173A (en) | Process for the production of catalysts containing titanium | |
| ATE10948T1 (en) | PRODUCTION OF 2-KETO-D-GLUCONIC ACID AND HYDROGEN SPEROXIDE. | |
| GB834514A (en) | Improvements in or relating to the preparation of potassium monopersulphate | |
| ES417100A1 (en) | Treatment of aqueous effluents containing sulphurous impurities | |
| GB1418158A (en) | Curable compositions | |
| ES316250A1 (en) | Production of chlorine dioxide | |
| GB1015835A (en) | A method of producing a highly porous, light and flowable sodium perborate | |
| GB891094A (en) | Improvements in and relating to per-compounds | |
| JPS57150681A (en) | Manufacture of stable epsilon-caprolactone solution | |
| GB1040163A (en) | Derivatives of benzophenone and benzhydrol | |
| GB873614A (en) | Improvements in or relating to the production of substituted cyclohexanone peroxides | |
| GB1278519A (en) | Production of sodium perborate | |
| GB912061A (en) | Improvements in or relating to the manufacture of ketone peroxides | |
| GB931577A (en) | Improvements in or relating to the manufacture of steroids | |
| GB1173578A (en) | Process for the Manufacture of Ethylene Chlorohydrin. | |
| ES343251A1 (en) | Direct production of solid calcium bromite | |
| DE705909C (en) | Water-soluble, durable mixtures containing per-compounds | |
| GB890622A (en) | Therapeutically active product | |
| ES305710A3 (en) | A procedure for the bleaching, especially of organic substances, in aqueous solutions of acids of clorites. (Machine-translation by Google Translate, not legally binding) | |
| GB190205360A (en) | Improvements in Antiseptic Compounds and Methods of Producing the same. | |
| GB399367A (en) | Processes for the production of porous masses and objects | |
| GB736386A (en) | Process for recovering iodine from iodine-containing aqueous glycol solutions |