GB1059117A - Polymeric quaternary ammonium salts - Google Patents

Polymeric quaternary ammonium salts

Info

Publication number
GB1059117A
GB1059117A GB83/65A GB8365A GB1059117A GB 1059117 A GB1059117 A GB 1059117A GB 83/65 A GB83/65 A GB 83/65A GB 8365 A GB8365 A GB 8365A GB 1059117 A GB1059117 A GB 1059117A
Authority
GB
United Kingdom
Prior art keywords
alkyl
polyepichlorhydrin
sodium
plus
amine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB83/65A
Inventor
George B Walker
Cushman M Cambre
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Publication of GB1059117A publication Critical patent/GB1059117A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707—Polyethers, e.g. polyalkyleneoxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32—Polymers modified by chemical after-treatment
    • C08G65/329—Polymers modified by chemical after-treatment with organic compounds
    • C08G65/333—Polymers modified by chemical after-treatment with organic compounds containing nitrogen
    • C08G65/33303—Polymers modified by chemical after-treatment with organic compounds containing nitrogen containing amino group
    • C08G65/33306—Polymers modified by chemical after-treatment with organic compounds containing nitrogen containing amino group acyclic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Detergent Compositions (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)

Abstract

Detergent compositions contain quaternary ammonium compounds of the general formula <FORM:1059117/C4-C5/1> wherein R is alkyl (1-24 C), R1 and R11 are alkyl (1-4 C), n is 1-50 (and the units may vary), m is 0-49, n + m is 2-50, and n + m plus the number of carbon atoms in R is greater than 12 (which have anti-bacterial activity) and inorganic alkaline builder salts such as sodium and potassium phosphates, silicates, carbonates, bicarbonates, borates and polyphosphates. The composition may also contain non-ionic detergents and diluents such as sodium sulphate.ALSO:New compounds of formula <FORM:1059117/C2/1> where R is alkyl (1-24 C) and R1 and R11 are where R is alkyl (1-24 C) and R1 and R11 are alkyl (1-4 C), n is 1-50 (and the units may vary), m is 0-49, n + m is 2-50, and n + m plus the number of carbon atoms in R is greater than 12, are prepared by (1) reacting polyepichlorhydrin and at least one amine RR1R11N at 60-300 DEG F. in presence of 0.1-6%, by weight of polyepichlorhydrin, of one or more of sodium or potassium bicarbonate or hydroxide, or (2) refluxing epichlorhydrin in a solvent of b.pt. 60-300 DEG F. with at least one amine RR1R11N.ALSO:New compounds of formula <FORM:1059117/C3/1> where R is alkyl (1-24 C) and R1 and R11 are alkyl (1-4 C), n is 1-50 (and the units may vary), m is 0-49, n+m is 2-50, and n+m plus the number of carbon atoms in R is greater than 12, are prepared by (1) reacting polyepichlorhydrin and at least one amine RR1R11 at 60-300 DEG F. in presence of 0.1-6%, by wt. of polyepichlorhydrin, of one or more of sodium or potassium bicarbonate or hydroxide, or (2) refluxing epichlorhydrin in a solvent of b.pt. 60-300 DEG F. with at least one amine RR1R11N.ALSO:Antibacterial compositions comprise the new polyepichlorhydrin quaternary ammonium derivatives of formula <FORM:1059117/A5-A6/1> where R is alkyl (1-24C), R1 and R11 are alkyl (1-4C), n is 1-50 (and the units may vary), m is 0-49, n+m is 2-50, n+m plus the number of carbon atoms in R is greater than 12, as in aqueous solutions or detergent compositions with inorganic alkaline builder salts: further ingredients mentioned are surfactants, nonionic detergents, sodium sulphate, sodium and potassium phosphates silicates, carbonates, bicarbonates, borates and polyphosphates.
GB83/65A 1964-01-03 1965-01-01 Polymeric quaternary ammonium salts Expired GB1059117A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US33565564A 1964-01-03 1964-01-03
US59972866A 1966-12-07 1966-12-07

Publications (1)

Publication Number Publication Date
GB1059117A true GB1059117A (en) 1967-02-15

Family

ID=26989825

Family Applications (1)

Application Number Title Priority Date Filing Date
GB83/65A Expired GB1059117A (en) 1964-01-03 1965-01-01 Polymeric quaternary ammonium salts

Country Status (2)

Country Link
US (2) US3428680A (en)
GB (1) GB1059117A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3539684A (en) * 1968-11-21 1970-11-10 Calgon C0Rp Bactericidal polymers

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4156775A (en) * 1976-01-26 1979-05-29 The Dow Chemical Company Quaternary ammonium salts of epihalohydrin polymers as additives for fibrous materials
US3885913A (en) * 1972-10-26 1975-05-27 Petrolite Corp Method of inhibiting the corrosion of metals in an acidic environment using quaternary ammonium salts of polyepihalohydrin
DE2601438A1 (en) * 1975-01-23 1976-07-29 Dow Chemical Co QUATERNIZED HALOGENIC ALKYLENE OXIDE COPOLYMERISATE
GB1553201A (en) * 1975-04-18 1979-09-26 Colgate Palmolive Co Method of cleaning glass or glazed articles
US4024311A (en) * 1975-10-30 1977-05-17 International Paper Company Electroconductive paper coating
US4198269A (en) * 1976-01-26 1980-04-15 The Dow Chemical Company Quaternary ammonium salts of epihalohydrin polymers as additives for fibrous cellulosic materials
LU75405A1 (en) * 1976-07-16 1978-02-08
US4377710A (en) * 1982-03-08 1983-03-22 Nalco Chemical Company Quaternized epichlorohydrin adducts of perfluoro substituted ethanols
US4664848A (en) * 1982-12-23 1987-05-12 The Procter & Gamble Company Detergent compositions containing cationic compounds having clay soil removal/anti-redeposition properties
US5326841A (en) * 1989-01-25 1994-07-05 Epitope, Inc. Germicidal barriers
DE69422081T2 (en) * 1993-04-19 2000-07-20 Reckitt & Colman Inc General purpose detergent composition
DE10137978A1 (en) * 2001-08-02 2003-02-13 Creavis Tech & Innovation Gmbh Antimicrobial cleaning or disinfecting agents for use e.g. by spraying in bathrooms contain antimicrobial polymers, especially those based on nitrogen- or phosphorus-containing monomers
CN102712752B (en) * 2009-12-29 2015-07-08 日本瑞翁株式会社 Polyether rubber, rubber composition, cross-linked rubber, and conductive member
GB202117816D0 (en) * 2021-12-09 2022-01-26 Reckitt Benckiser Finish Bv Granular additive

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE626245A (en) *
CH257759A (en) * 1947-04-10 1948-10-31 Genevoise Instr Physique Centering device for machine tools.
AT213383B (en) * 1955-01-22 1961-02-10 Hermann Leinfelder Process for the production of new, water-soluble poly-N-quaternary electrolytes
US2876217A (en) * 1956-12-31 1959-03-03 Corn Products Co Starch ethers containing nitrogen and process for making the same

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3539684A (en) * 1968-11-21 1970-11-10 Calgon C0Rp Bactericidal polymers

Also Published As

Publication number Publication date
US3428680A (en) 1969-02-18
US3496109A (en) 1970-02-17

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