GB1058188A - Method for preparing highly siliceous zeolite-type materials and materials resulting therefrom - Google Patents
Method for preparing highly siliceous zeolite-type materials and materials resulting therefromInfo
- Publication number
- GB1058188A GB1058188A GB820564A GB820564A GB1058188A GB 1058188 A GB1058188 A GB 1058188A GB 820564 A GB820564 A GB 820564A GB 820564 A GB820564 A GB 820564A GB 1058188 A GB1058188 A GB 1058188A
- Authority
- GB
- United Kingdom
- Prior art keywords
- aluminosilicate
- aluminium
- ratio
- complexing agent
- ordination complex
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 11
- 229910000323 aluminium silicate Inorganic materials 0.000 abstract 10
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 6
- 229910052782 aluminium Inorganic materials 0.000 abstract 6
- 239000004411 aluminium Substances 0.000 abstract 6
- 239000008139 complexing agent Substances 0.000 abstract 5
- 239000013522 chelant Substances 0.000 abstract 3
- 239000013078 crystal Substances 0.000 abstract 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 3
- 230000007062 hydrolysis Effects 0.000 abstract 3
- 238000006460 hydrolysis reaction Methods 0.000 abstract 3
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 239000003957 anion exchange resin Substances 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000002738 chelating agent Substances 0.000 abstract 2
- 229960001484 edetic acid Drugs 0.000 abstract 2
- 230000000717 retained effect Effects 0.000 abstract 2
- 239000010457 zeolite Substances 0.000 abstract 2
- CHRJZRDFSQHIFI-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;styrene Chemical compound C=CC1=CC=CC=C1.C=CC1=CC=CC=C1C=C CHRJZRDFSQHIFI-UHFFFAOYSA-N 0.000 abstract 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical group [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 238000002441 X-ray diffraction Methods 0.000 abstract 1
- 229910021536 Zeolite Inorganic materials 0.000 abstract 1
- 230000002378 acidificating effect Effects 0.000 abstract 1
- LDDQLRUQCUTJBB-UHFFFAOYSA-N ammonium fluoride Chemical compound [NH4+].[F-] LDDQLRUQCUTJBB-UHFFFAOYSA-N 0.000 abstract 1
- 125000004429 atom Chemical group 0.000 abstract 1
- 230000009920 chelation Effects 0.000 abstract 1
- 230000002950 deficient Effects 0.000 abstract 1
- -1 ethylene diamino Chemical group 0.000 abstract 1
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract 1
- 239000011707 mineral Substances 0.000 abstract 1
- 150000002894 organic compounds Chemical class 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 239000012429 reaction media Substances 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
- 238000007873 sieving Methods 0.000 abstract 1
- 230000001131 transforming effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
- C10G11/04—Oxides
- C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/18—Synthetic zeolitic molecular sieves
- B01J20/186—Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/085—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
- B01J29/087—X-type faujasite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/085—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
- B01J29/088—Y-type faujasite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7007—Zeolite Beta
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
- C01B33/28—Base exchange silicates, e.g. zeolites
- C01B33/2807—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures
- C01B33/2869—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures of other types characterised by an X-ray spectrum and a definite composition
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/16—After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US26149463A | 1963-02-27 | 1963-02-27 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1058188A true GB1058188A (en) | 1967-02-08 |
Family
ID=22993554
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB820564A Expired GB1058188A (en) | 1963-02-27 | 1964-02-27 | Method for preparing highly siliceous zeolite-type materials and materials resulting therefrom |
Country Status (5)
| Country | Link |
|---|---|
| CH (1) | CH485598A (enrdf_load_stackoverflow) |
| GB (1) | GB1058188A (enrdf_load_stackoverflow) |
| NL (1) | NL6400999A (enrdf_load_stackoverflow) |
| NO (1) | NO125528B (enrdf_load_stackoverflow) |
| SE (1) | SE311638B (enrdf_load_stackoverflow) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2064521A1 (de) * | 1970-01-02 | 1971-07-08 | Standard Oil Co , Chicago, 111 (V St A ) | Katalysator, der ultrastabile Aluminosilicate umfasst, und Kohlenwas serstoffumwandlungsverfahren, die diese Katalysatoren verwenden |
| WO2005039755A1 (en) * | 2003-10-27 | 2005-05-06 | Council Of Scientific And Industrial Research | Process for the preparation of molecular sieve adsorbent for selective adsorption of oxygen from air |
| EP2522425A1 (en) | 2006-03-02 | 2012-11-14 | BASF Catalysts LLC | Hydrocracking catalyst comprising an in situ produced y-fauajasite and hydrocracking process |
| US8778171B2 (en) | 2011-07-27 | 2014-07-15 | Exxonmobil Research And Engineering Company | Hydrocracking catalysts containing stabilized aggregates of small crystallites of zeolite Y associated hydrocarbon conversion processes |
| US8778824B2 (en) | 2011-03-07 | 2014-07-15 | Exxonmobil Research And Engineering Company | Aggregates of small crystallites of zeolite Y |
| US8852326B2 (en) | 2011-03-07 | 2014-10-07 | Exxonmobil Research And Engineering Company | Aggregates of small particles of synthetic faujasite zeolite |
| US8882993B2 (en) | 2011-03-07 | 2014-11-11 | Exxonmobil Research And Engineering Company | Stabilized aggregates of small crystallites of zeolite Y |
| US10195593B2 (en) | 2014-03-28 | 2019-02-05 | Agency For Science, Technology And Research | Method for preparing a sodium faujasite catalyst and its use in producing acrylic acid |
| CN111250117A (zh) * | 2020-02-07 | 2020-06-09 | 新疆大学 | 一种负载型无汞催化剂及其制备方法和在催化乙炔氢氯化反应中的应用 |
| CN116328826A (zh) * | 2021-12-24 | 2023-06-27 | 中国石油化工股份有限公司 | 一种含钡的l分子筛及其制备方法与应用 |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4604373A (en) * | 1984-08-24 | 1986-08-05 | Union Oil Company Of California | Hydrocracking catalyst of improved activity |
-
1964
- 1964-02-06 NL NL6400999A patent/NL6400999A/xx unknown
- 1964-02-20 CH CH204164A patent/CH485598A/de not_active IP Right Cessation
- 1964-02-26 NO NO15217864A patent/NO125528B/no unknown
- 1964-02-26 SE SE236664A patent/SE311638B/xx unknown
- 1964-02-27 GB GB820564A patent/GB1058188A/en not_active Expired
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2064521A1 (de) * | 1970-01-02 | 1971-07-08 | Standard Oil Co , Chicago, 111 (V St A ) | Katalysator, der ultrastabile Aluminosilicate umfasst, und Kohlenwas serstoffumwandlungsverfahren, die diese Katalysatoren verwenden |
| WO2005039755A1 (en) * | 2003-10-27 | 2005-05-06 | Council Of Scientific And Industrial Research | Process for the preparation of molecular sieve adsorbent for selective adsorption of oxygen from air |
| US7319082B2 (en) | 2003-10-27 | 2008-01-15 | Council Of Scientific And Industrial Research | Process for the preparation of molecular sieve adsorbent for selective adsorption of oxygen from air |
| KR100803771B1 (ko) | 2003-10-27 | 2008-02-15 | 카운슬 오브 사이언티픽 앤드 인더스트리얼 리서치 | 공기로부터 산소의 선택적 흡착을 위한 분자체 흡착제의제조 공정 |
| EP2522425A1 (en) | 2006-03-02 | 2012-11-14 | BASF Catalysts LLC | Hydrocracking catalyst comprising an in situ produced y-fauajasite and hydrocracking process |
| US8778824B2 (en) | 2011-03-07 | 2014-07-15 | Exxonmobil Research And Engineering Company | Aggregates of small crystallites of zeolite Y |
| US8852326B2 (en) | 2011-03-07 | 2014-10-07 | Exxonmobil Research And Engineering Company | Aggregates of small particles of synthetic faujasite zeolite |
| US8882993B2 (en) | 2011-03-07 | 2014-11-11 | Exxonmobil Research And Engineering Company | Stabilized aggregates of small crystallites of zeolite Y |
| US8778171B2 (en) | 2011-07-27 | 2014-07-15 | Exxonmobil Research And Engineering Company | Hydrocracking catalysts containing stabilized aggregates of small crystallites of zeolite Y associated hydrocarbon conversion processes |
| US10195593B2 (en) | 2014-03-28 | 2019-02-05 | Agency For Science, Technology And Research | Method for preparing a sodium faujasite catalyst and its use in producing acrylic acid |
| CN111250117A (zh) * | 2020-02-07 | 2020-06-09 | 新疆大学 | 一种负载型无汞催化剂及其制备方法和在催化乙炔氢氯化反应中的应用 |
| CN116328826A (zh) * | 2021-12-24 | 2023-06-27 | 中国石油化工股份有限公司 | 一种含钡的l分子筛及其制备方法与应用 |
Also Published As
| Publication number | Publication date |
|---|---|
| SE311638B (enrdf_load_stackoverflow) | 1969-06-23 |
| NL6400999A (enrdf_load_stackoverflow) | 1964-08-28 |
| DE1467149B2 (de) | 1972-11-16 |
| DE1467149A1 (de) | 1970-04-30 |
| CH485598A (de) | 1970-02-15 |
| NO125528B (enrdf_load_stackoverflow) | 1972-09-25 |
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