GB1057829A - Flame retardant composition and process - Google Patents

Flame retardant composition and process

Info

Publication number
GB1057829A
GB1057829A GB48180/64A GB4818064A GB1057829A GB 1057829 A GB1057829 A GB 1057829A GB 48180/64 A GB48180/64 A GB 48180/64A GB 4818064 A GB4818064 A GB 4818064A GB 1057829 A GB1057829 A GB 1057829A
Authority
GB
United Kingdom
Prior art keywords
halide
hydroxy
chloride
hydroxyorgano
composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB48180/64A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hooker Chemical Corp
Original Assignee
Hooker Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hooker Chemical Corp filed Critical Hooker Chemical Corp
Publication of GB1057829A publication Critical patent/GB1057829A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H5/00—Special paper or cardboard not otherwise provided for
    • D21H5/0002—Flame-resistant papers; (complex) compositions rendering paper fire-resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
    • C08G12/40—Chemically modified polycondensates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G79/00—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
    • C08G79/02—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G79/00—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
    • C08G79/02—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing phosphorus
    • C08G79/06—Phosphorus linked to carbon only
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C08L61/32—Modified amine-aldehyde condensates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
    • D06M15/423—Amino-aldehyde resins
    • D06M15/43—Amino-aldehyde resins modified by phosphorus compounds
    • D06M15/431—Amino-aldehyde resins modified by phosphorus compounds by phosphines or phosphine oxides; by oxides or salts of the phosphonium radical
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/71—Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes
    • D21H17/72—Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes of organic material
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/34—Ignifugeants
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L85/00—Compositions of macromolecular compounds obtained by reactions forming a linkage in the main chain of the macromolecule containing atoms other than silicon, sulfur, nitrogen, oxygen and carbon; Compositions of derivatives of such polymers
    • C08L85/02—Compositions of macromolecular compounds obtained by reactions forming a linkage in the main chain of the macromolecule containing atoms other than silicon, sulfur, nitrogen, oxygen and carbon; Compositions of derivatives of such polymers containing phosphorus

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Paper (AREA)

Abstract

A flame-proofing composition for impregnating paper comprises an aqueous polyvinyl chloride or fluoride latex; antimony oxide; a resin precondensate derived from tetrakis (hydroxyorgano) phosphonium halide, urea and formaldehyde; and optionally isopropanol. The hydroxyorgano radical may be hydroxy methyl (when halide is bromide); or hydroxychloromethyl, a -hydroxypropyl, a -hydroxyallyl, a -hydroxybenzyl, a -hydroxy-p-chlorobenzyl, a -hydroxymethylcyclohexyl, a - hydroxymethyl-4 - chlorocyclohexyl, a - hydroxypropionyl, a - hydroxybutanyl, or a -hydroxy - 4 - chlorobutanyl (when halide is chloride). Polyvinyl chloride may be in the form of a copolymer with vinyl acetate or vinylidene chloride. The composition may also comprise citric acid (curing catalyst), polyvinyl alcohol or hydroxy methyl or ethyl cellulose (protective colloid), oxyethylated alkyl phenol (wetting agent), and a silicone or wax (water repellent). The impregnated paper may be dried and cured in an oven at 200-400 DEG F. for 1-10 minutes.ALSO:A flame-proofing composition for impregnating paper comprises an aqueous polyvinyl chloride or fluoride latex; antimony oxide; a resin precondensate derived from tetrakis (hydroxyorgano) phophonium halide, urea and formaldehyde; and optionally isopropanol. The hydroxyorgano radical may be hydroxy methyl (when halide is bromide); or hydroxychloromethyl, a -hydroxypropyl, a -hydroxyallyl, a -hydroxybenzyl, a -hydroxy-p-chlorobenzyl, a -hydroxymethylcyclohexyl, a -hydroxymethyl-4-chlorocyclohexyl, a -hydroxypropionyl, a -hydroxybutanyl, or a -hydroxy-4-chlorobutanyl (when halide is chloride). Polyvinyl chloride may be in the form of a copolymer with vinyl acetate or vinylidene chloride. The composition may also comprise citric acid (curing catalyst), polyvinyl alcohol or hydroxy methyl or ethyl cellulose (protective colloid), oxyethylated alkyl phenol (wetting agent), and a silicone or wax (water repellent). The impregnated paper may be dried and cured in an oven at 200-400 DEG F. for 1-10 mins.
GB48180/64A 1962-03-21 1964-11-26 Flame retardant composition and process Expired GB1057829A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US18145662A 1962-03-21 1962-03-21
US327062A US3243391A (en) 1962-03-21 1963-11-29 Composition and process for treating cellulosic materials to make them flame-retardant

Publications (1)

Publication Number Publication Date
GB1057829A true GB1057829A (en) 1967-02-08

Family

ID=31996626

Family Applications (1)

Application Number Title Priority Date Filing Date
GB48180/64A Expired GB1057829A (en) 1962-03-21 1964-11-26 Flame retardant composition and process

Country Status (6)

Country Link
US (1) US3243391A (en)
BE (1) BE690875A (en)
DE (1) DE1546372B2 (en)
FR (1) FR87266E (en)
GB (1) GB1057829A (en)
NL (1) NL6413907A (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3294632A (en) * 1964-08-31 1966-12-27 Hooker Chemical Corp Controlling bacteria on textile materials with reaction products of tetrakis (alpha-hydroxyorgano) phosphonium halides combined with formaldehyde source materials
US3488140A (en) * 1965-04-29 1970-01-06 Us Agriculture Phosphorylation of cotton with inorganic phosphates
US3915915A (en) * 1971-05-07 1975-10-28 Us Agriculture Flame proofing textile treating composition of tris(hydroxymethyl) phosphine-urea adduct and polyvinylbromide
US3949108A (en) * 1973-06-01 1976-04-06 The United States Of America As Represented By The Secretary Of Agriculture Process for producing fire resistant organic textile materials
US3900666A (en) * 1974-06-04 1975-08-19 Us Agriculture Flame retardant textiles by use of nitrogenous type resin and antimony oxide
US4888136A (en) * 1988-05-02 1989-12-19 Witco Corporation New flame retardant compositions of matter and cellulosic products containing same

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2549060A (en) * 1948-12-09 1951-04-17 American Cyanamid Co Method of treating fibrous cellulosic materials to impart flame resistance thereto, composition therefor, and products thereof
US2868741A (en) * 1952-01-30 1959-01-13 Dick Co Ab Water base stencil duplicating ink
US2809941A (en) * 1952-04-22 1957-10-15 Wilson A Reeves Producing phosphorus containing amino resins and flameproofing organic textiles
NL177766B (en) * 1952-04-22 Mechanical Res Corp PNEUMATIC IMPACT TOOL.
US2825708A (en) * 1953-05-04 1958-03-04 Geigy Ag J R Process in making oil-in-water resin emulsion pigment printing colors
US3087836A (en) * 1959-10-12 1963-04-30 Hooker Chemical Corp Flameproof paper and process of making same
NL271608A (en) * 1960-11-21 1900-01-01

Also Published As

Publication number Publication date
DE1546372A1 (en) 1972-03-09
BE690875A (en) 1967-06-08
NL6413907A (en) 1965-07-26
US3243391A (en) 1966-03-29
FR87266E (en) 1966-07-08
DE1546372B2 (en) 1976-05-06

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