GB1057723A - Polymeric thickening agents - Google Patents
Polymeric thickening agentsInfo
- Publication number
- GB1057723A GB1057723A GB772663A GB772663A GB1057723A GB 1057723 A GB1057723 A GB 1057723A GB 772663 A GB772663 A GB 772663A GB 772663 A GB772663 A GB 772663A GB 1057723 A GB1057723 A GB 1057723A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- butyl
- ammonium
- copolymer
- compositions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/52—Amides or imides
- C08F20/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
- C08F20/58—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide containing oxygen in addition to the carbonamido oxygen, e.g. N-methylolacrylamide, N-acryloylmorpholine
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Novel water-soluble copolymer salts are prepared by polymerizing in aqueous emulsion an N-alkoxyalkyl or N-cycloalkoxyalkyl derivative of an ethylenically unsaturated amide and an a ,b -ethylenically unsaturated carboxylic acid, and reacting the product with a basic substance, e.g. an alkali metal or ammonium hydroxide, or an organic base, e.g. diethylamine, morpholine, hydrazine or dimethylaminoethanol. The amide monomer is suitably a compound of the formula <FORM:1057723/C3/1> in which R is an alkyl or cycloalkyl radical having up to twelve carbon atoms and R1 is hydrogen, chlorine or a cyano or alkyl radical. Acid comonomers specified are acrylic acid, methacrylic acid, itaconic acid, maleic acid and fumaric acid; derivatives of suitable polycarboxylic acids, e.g. partial esters, having at least one free carboxylic acid group may also be used. Other monomers may additionally be used, e.g. styrene, vinyl toluene, methyl methacrylate, ethyl acrylate, di-n-butyl itaconate, di-n-butyl maleate, di-n-octyl maleate, acrylonitrile, 2-hydroxyethyl methacrylate, 2-hydroxy propyl methacrylate, divinylbenzene, glycol dimethacrylate and methylene-bis-acrylamide. In examples, N-n-butoxy methylacrylamide, ethyl acrylate, methyl methacrylate and methacrylic acid are emulsion polymerized using ammonium persulphate catalyst, sodium N-methyl-N-oleoyl-taurate emulsifier and lauryl mercaptan modifier, part of the components being added during the course of polymerization, and the product is neutralized with ammonia or dimethylamino-ethanol. The water-soluble copolymer salts can be rendered insoluble by curing and are suitable as thickening agents in coating compositions and textile-treating compositions. In the examples, such compositions include the following ingredients: red iron oxide, barytes, talc, tri-n-butyl phosphate, ethylene glycol mono-n-butyl ether, titanium dioxide, isophorone, calcium carbonate, methyl cellulose, polyacrylic acid (Trade Mark Primal ), polyvinyl acetate, ammonium chloride and a styrene-n-butyl acrylate - N - cyclohexyloxymethyl - acrylamide copolymer. Reference has been directed by the Comptroller to Specification 792,874.ALSO:Compositions suitable for coating steel, aluminium and asbestos (e.g. priming and lacquer compositions) and for application to textiles, e.g. cotton fabric, comprise as thickener a water-soluble inorganic (e.g. alkali metal or ammonium) or organic base salt of a copolymer comprising as essential components units of an N-alkoxy alkyl or N-cyclo-alkoxy alkyl deravative of an ethylenically unsaturated amide and units of an a , b -ethylenically unsaturated carboxylic acid. The thickener can be cured to a water-insoluble form. Exemplified thickeners are the ammonium and dimethyl-aminoethanol salts of a copolymer of N-n-butoxymethylacrylamide, ethyl acrylate, methyl methacrylate and methacrylic acid. Other ingredients included in the coating compositions illustrated are red iron oxide, barytes, talc, tri-n-butyl phosphate, ethylene glycol mono-n-butyl ether, titanium dioxide, isophorone, calcium carbonate, methylcellulose, polyacrylic acid (Trade Mark "Primal"), polyvinyl acetate, ammonium chloride and a styrene-n-butyl acrylate-N-cyclohexyloxymethyl-acrylamide copolymer. Reference has been directed by the Comptroller to Specification 792,874.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB772663A GB1057723A (en) | 1963-02-26 | 1963-02-26 | Polymeric thickening agents |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB772663A GB1057723A (en) | 1963-02-26 | 1963-02-26 | Polymeric thickening agents |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1057723A true GB1057723A (en) | 1967-02-08 |
Family
ID=9838575
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB772663A Expired GB1057723A (en) | 1963-02-26 | 1963-02-26 | Polymeric thickening agents |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB1057723A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004045755A2 (en) * | 2002-11-20 | 2004-06-03 | Efka Additives B.V. | Aqueous emulsion polymer as dispersant |
-
1963
- 1963-02-26 GB GB772663A patent/GB1057723A/en not_active Expired
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004045755A2 (en) * | 2002-11-20 | 2004-06-03 | Efka Additives B.V. | Aqueous emulsion polymer as dispersant |
WO2004045755A3 (en) * | 2002-11-20 | 2004-07-29 | Efka Additives B V | Aqueous emulsion polymer as dispersant |
CN100364649C (en) * | 2002-11-20 | 2008-01-30 | 埃弗卡添加剂股份有限公司 | Aqueous emulsion polymer as dispersant |
US8822592B2 (en) | 2002-11-20 | 2014-09-02 | Basf Se | Aqueous emulsion polymer as dispersant |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
GB1514494A (en) | Polymers | |
GB1181742A (en) | Alkyl Acrylate Polymer Latices | |
GB1408363A (en) | Resin dispersions | |
GB776503A (en) | N-tert-alkylaminoalkyl esters | |
GB961043A (en) | Aqueous dispersion polymer compositions | |
GB1411103A (en) | Oil-and-water-repellent compositions | |
GB846019A (en) | Thickening, suspending and emulsifying agents for water-base paints and coating compositions | |
US3649581A (en) | Stable polymeric latices of high carboxyl content | |
GB1144755A (en) | Self adhesive tapes | |
GB1069848A (en) | Process for the polymerisation of vinyl chloride | |
GB1057723A (en) | Polymeric thickening agents | |
GB944266A (en) | Process for the production of acrylonitrile copolymers | |
GB864311A (en) | New compolymers and their manufacture and use | |
GB1089500A (en) | Crosslinking agents for polymers | |
GB919324A (en) | New synthetic resins | |
GB1350407A (en) | Latexes of vinyl cyclohexanecarboxylate polymers | |
GB1014227A (en) | Polymer latexes and coating compositions containing the same | |
GB818715A (en) | Polymerization products, and the production thereof | |
GB1042010A (en) | Production of aqueous dispersions of curable plastics having improved film-forming properties | |
GB1079757A (en) | Textile adhesive compositions | |
ES346775A1 (en) | Emulsion polymerization of n-alkyl amic acid and alkyl acrylates or alkyl methacrylates | |
GB1339074A (en) | Process for the manufacture of speck-free dispersions of copolymers | |
GB1355709A (en) | Deodourizing aqueous dispersions of polymers of alkyl esters of alpha,beta-olefinically unsaturated carboxylic acids | |
GB1017932A (en) | Improvements in or relating to the production of synthetic resins | |
GB989932A (en) | Sulpho-containing ethyl methacrylate and polymers thereof |