GB1050231A - - Google Patents

Info

Publication number
GB1050231A
GB1050231A GB1050231DA GB1050231A GB 1050231 A GB1050231 A GB 1050231A GB 1050231D A GB1050231D A GB 1050231DA GB 1050231 A GB1050231 A GB 1050231A
Authority
GB
United Kingdom
Prior art keywords
composition
ammonium
copolymer
weight
article
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Publication of GB1050231A publication Critical patent/GB1050231A/en
Active legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/62Monocarboxylic acids having ten or more carbon atoms; Derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • C09D133/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/062Copolymers with monomers not covered by C09D133/06
    • C09D133/064Copolymers with monomers not covered by C09D133/06 containing anhydride, COOH or COOM groups, with M being metal or onium-cation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Paints Or Removers (AREA)

Abstract

1,050,231. Removable polymer coatings. PITTSBURGH PLATE GLASS CO. Jan. 28, 1964 [Jan. 30, 1963], No. 3515/64. Heading C3P. An article having a rigid, solid, non-porous surface, such as a glass, metal or lacquered metal article, is temporarily protected by applying thereto a water-resistant film of a composition consisting essentially of a copolymer of 10 to 20% by weight of an α,(#-ethylenically unsaturated monocarboxylic acid, and the balance by weight of at least one ester having the formula wherein R<SP>1</SP> is hydrogen or methyl and R is an alkyl group containing from 1 to 8 carbon atoms, optionally containing up to 23% by weight of the total of copolymerizod > C = CH 2 monomer, e.g. styrene or vinyl toluene, and optionally containing a pigment, or of an ammonium or amine salt of the composition, and the film is subsequently removed from the article by the use of a dilute alkaline solution. Acids specified are acrylic and crotonic acids and their alpha- C 1-4 -alkyl derivatives. The composition may be applied as an aqueous solution of the ammonium or amine salt (including hydrazine salt) of the copolymer or as a solution of the copolymer in an organic solvent, which may be an alcohol, alcohol-ether, ester, ketone or aromatic hydrocarbon. In the examples ethyl acrylate, methyl methacrylate and methacrylic acid are copolymerized in the presence of tertiary dodecyl mercaptan in aqueous dispersion using ammonium persulphate as the catalyst. Zinc ammonium acetate or strontium chromate are included in the composition in two of the examples. An alkaline medium for removing the composition is also disclosed.
GB1050231D 1963-01-30 Active GB1050231A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US25511863A 1963-01-30 1963-01-30

Publications (1)

Publication Number Publication Date
GB1050231A true GB1050231A (en)

Family

ID=22966906

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1050231D Active GB1050231A (en) 1963-01-30

Country Status (2)

Country Link
DE (1) DE1519288A1 (en)
GB (1) GB1050231A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2129823A (en) * 1982-11-05 1984-05-23 Building Adhesives Ltd Water-based sealers for protecting decorative building surfacing components

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3101892A1 (en) 1981-01-22 1982-08-26 Röhm GmbH, 6100 Darmstadt METHOD FOR PRODUCING AQUEOUS PLASTIC DISPERSIONS WITH A HIGH PIGMENT BINDING CAPACITY

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2129823A (en) * 1982-11-05 1984-05-23 Building Adhesives Ltd Water-based sealers for protecting decorative building surfacing components

Also Published As

Publication number Publication date
DE1519288A1 (en) 1970-07-02

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