GB1046464A - Process for clarifying suspensions - Google Patents

Process for clarifying suspensions

Info

Publication number
GB1046464A
GB1046464A GB1744263A GB1744263A GB1046464A GB 1046464 A GB1046464 A GB 1046464A GB 1744263 A GB1744263 A GB 1744263A GB 1744263 A GB1744263 A GB 1744263A GB 1046464 A GB1046464 A GB 1046464A
Authority
GB
United Kingdom
Prior art keywords
aldehyde groups
polymer
cannizzaro
reaction
methacrolein
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1744263A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Farbwerke Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DEF36789A external-priority patent/DE1299566B/en
Application filed by Hoechst AG, Farbwerke Hoechst AG filed Critical Hoechst AG
Publication of GB1046464A publication Critical patent/GB1046464A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/54Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material

Abstract

A water-soluble polymer or derivatives thereof in which the polymer is made by treating a homo- or co-polymer of acrolein or methacrolein with a strong base to produce hydroxy carboxylic acids by Cannizzaro's reaction is used as a flocculating aid in sedimenting solids dispersed in liquids. The m.w. of the polymers is preferably 200,000 to 500,000.ALSO:Homopolymers of or copolymers of acrolein and methacrolein are subjected to strong bases in the Cannizzaro reaction to produce hydroxy carboxylic acids. The free aldehyde groups may be shielded to produce a desired acid. The aldehyde groups which are shielded may be changed to chlorides, amines, oximes, acetals, mercaptals hydrazones, hydrazides and Schiff bases before and after the Cannizzaro reaction. Other modifications may be made by hydrogenation, oxidation or esterification. Preferably 5 to 10% of the aldehyde groups undergo dismutation. Comonomers exemplified are maleric fumaric and acrylic acids, maleic anhydride vinyl chloride or acetate and methyl and ethyl acrylates. The bases used should be stronger than ammonium hydroxide.
GB1744263A 1962-05-12 1963-05-02 Process for clarifying suspensions Expired GB1046464A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEF36789A DE1299566B (en) 1962-05-12 1962-05-12 Procedure for clearing Trueben

Publications (1)

Publication Number Publication Date
GB1046464A true GB1046464A (en) 1966-10-26

Family

ID=7096607

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1744263A Expired GB1046464A (en) 1962-05-12 1963-05-02 Process for clarifying suspensions

Country Status (2)

Country Link
AT (1) AT246067B (en)
GB (1) GB1046464A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4076913A (en) 1973-07-31 1978-02-28 Glaxo Laboratories Limited Solid or gel polymers containing a plurality of free hydrazone groups
EP0798269A1 (en) * 1996-03-29 1997-10-01 Yoshimasa Tahara Apparatus for purifying water from organic halides contained therein

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4076913A (en) 1973-07-31 1978-02-28 Glaxo Laboratories Limited Solid or gel polymers containing a plurality of free hydrazone groups
EP0798269A1 (en) * 1996-03-29 1997-10-01 Yoshimasa Tahara Apparatus for purifying water from organic halides contained therein
US5866009A (en) * 1996-03-29 1999-02-02 Tahara; Yoshimasa Apparatus for purifying water from organic halides contained therein

Also Published As

Publication number Publication date
AT246067B (en) 1966-03-25

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