GB1046464A - Process for clarifying suspensions - Google Patents
Process for clarifying suspensionsInfo
- Publication number
- GB1046464A GB1046464A GB1744263A GB1744263A GB1046464A GB 1046464 A GB1046464 A GB 1046464A GB 1744263 A GB1744263 A GB 1744263A GB 1744263 A GB1744263 A GB 1744263A GB 1046464 A GB1046464 A GB 1046464A
- Authority
- GB
- United Kingdom
- Prior art keywords
- aldehyde groups
- polymer
- cannizzaro
- reaction
- methacrolein
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/54—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
Abstract
A water-soluble polymer or derivatives thereof in which the polymer is made by treating a homo- or co-polymer of acrolein or methacrolein with a strong base to produce hydroxy carboxylic acids by Cannizzaro's reaction is used as a flocculating aid in sedimenting solids dispersed in liquids. The m.w. of the polymers is preferably 200,000 to 500,000.ALSO:Homopolymers of or copolymers of acrolein and methacrolein are subjected to strong bases in the Cannizzaro reaction to produce hydroxy carboxylic acids. The free aldehyde groups may be shielded to produce a desired acid. The aldehyde groups which are shielded may be changed to chlorides, amines, oximes, acetals, mercaptals hydrazones, hydrazides and Schiff bases before and after the Cannizzaro reaction. Other modifications may be made by hydrogenation, oxidation or esterification. Preferably 5 to 10% of the aldehyde groups undergo dismutation. Comonomers exemplified are maleric fumaric and acrylic acids, maleic anhydride vinyl chloride or acetate and methyl and ethyl acrylates. The bases used should be stronger than ammonium hydroxide.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEF36789A DE1299566B (en) | 1962-05-12 | 1962-05-12 | Procedure for clearing Trueben |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1046464A true GB1046464A (en) | 1966-10-26 |
Family
ID=7096607
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1744263A Expired GB1046464A (en) | 1962-05-12 | 1963-05-02 | Process for clarifying suspensions |
Country Status (2)
Country | Link |
---|---|
AT (1) | AT246067B (en) |
GB (1) | GB1046464A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4076913A (en) | 1973-07-31 | 1978-02-28 | Glaxo Laboratories Limited | Solid or gel polymers containing a plurality of free hydrazone groups |
EP0798269A1 (en) * | 1996-03-29 | 1997-10-01 | Yoshimasa Tahara | Apparatus for purifying water from organic halides contained therein |
-
1963
- 1963-05-02 GB GB1744263A patent/GB1046464A/en not_active Expired
- 1963-05-10 AT AT381763A patent/AT246067B/en active
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4076913A (en) | 1973-07-31 | 1978-02-28 | Glaxo Laboratories Limited | Solid or gel polymers containing a plurality of free hydrazone groups |
EP0798269A1 (en) * | 1996-03-29 | 1997-10-01 | Yoshimasa Tahara | Apparatus for purifying water from organic halides contained therein |
US5866009A (en) * | 1996-03-29 | 1999-02-02 | Tahara; Yoshimasa | Apparatus for purifying water from organic halides contained therein |
Also Published As
Publication number | Publication date |
---|---|
AT246067B (en) | 1966-03-25 |
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