GB1044610A - Improvements relating to the copolymerisation of vinyl acetate - Google Patents

Improvements relating to the copolymerisation of vinyl acetate

Info

Publication number
GB1044610A
GB1044610A GB37394/65A GB3739465A GB1044610A GB 1044610 A GB1044610 A GB 1044610A GB 37394/65 A GB37394/65 A GB 37394/65A GB 3739465 A GB3739465 A GB 3739465A GB 1044610 A GB1044610 A GB 1044610A
Authority
GB
United Kingdom
Prior art keywords
sodium
vinyl acetate
emulsifying agent
specified
persulphate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB37394/65A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WR Grace and Co
Original Assignee
WR Grace and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by WR Grace and Co filed Critical WR Grace and Co
Publication of GB1044610A publication Critical patent/GB1044610A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/02—Esters of monocarboxylic acids
    • C08F218/04—Vinyl esters
    • C08F218/08—Vinyl acetate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Paints Or Removers (AREA)

Abstract

In a modification of the process of the parent Specification, vinyl acetate is copolymerized with a fumaric, maleic or acrylic ester in water containing an anionic emulsifying agent and a peroxy catalyst wherein the total cation concentration exclusive of cations from the emulsifying agent is 15-40 millimoles/litre and the emulsifying agent concentration is 35-60 millimoles/litre. Specified ester comonomers are dibutyl maleate, 2-ethylhexyl acrylate, butyl acrylate and dibutyl fumarate. Specified catalysts are sodium persulphate, ammonium persulphate and alkali metal perborates. Specified emulsifiurs are sodium dodecylbenzene sulphonate and sodium lauryl sulphate. Buffers such as sodium bicarbonate, sodium acetate and sodium phosphate may be used. The monomers may be added during polymerization. In examples vinyl acetate and dibutyl maleate are copolymerized in the presence of potassium persulphate, sodium dodecylbenzene sulphonate and sodium bicarbonate.
GB37394/65A 1964-03-03 1965-09-01 Improvements relating to the copolymerisation of vinyl acetate Expired GB1044610A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US34918064A 1964-03-03 1964-03-03
US43198665A 1965-02-11 1965-02-11

Publications (1)

Publication Number Publication Date
GB1044610A true GB1044610A (en) 1966-10-05

Family

ID=26996064

Family Applications (2)

Application Number Title Priority Date Filing Date
GB8663/65A Expired GB1024607A (en) 1964-03-03 1965-03-01 Improvements relating to the polymerisation of vinyl acetate
GB37394/65A Expired GB1044610A (en) 1964-03-03 1965-09-01 Improvements relating to the copolymerisation of vinyl acetate

Family Applications Before (1)

Application Number Title Priority Date Filing Date
GB8663/65A Expired GB1024607A (en) 1964-03-03 1965-03-01 Improvements relating to the polymerisation of vinyl acetate

Country Status (3)

Country Link
DE (1) DE1570685A1 (en)
FR (1) FR1425831A (en)
GB (2) GB1024607A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
USRE31985E (en) * 1978-10-26 1985-09-17 Dai Nippon Toryo Co, Ltd. Aqueous dispersion type thermosetting coating composition
WO2003054041A1 (en) * 2001-12-21 2003-07-03 Clariant Gmbh Food coating substance containing a softener-free, aqueous copolymer poly(vinyl ester) dispersion, production and use thereof
US7491777B2 (en) 2003-12-02 2009-02-17 Celanese Emulsions Gmbh Polymer dispersions having improved water-vapor barrier action, their production and use for food coating

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115991813A (en) * 2021-10-20 2023-04-21 中国石油化工股份有限公司 Application of emulsifier in increasing molecular weight of ethylene-vinyl acetate copolymer emulsion

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
USRE31985E (en) * 1978-10-26 1985-09-17 Dai Nippon Toryo Co, Ltd. Aqueous dispersion type thermosetting coating composition
WO2003054041A1 (en) * 2001-12-21 2003-07-03 Clariant Gmbh Food coating substance containing a softener-free, aqueous copolymer poly(vinyl ester) dispersion, production and use thereof
US7312272B2 (en) 2001-12-21 2007-12-25 Celanese Emulsions Gmbh Food coating substance containing a softener-free aqueous copolymer poly(vinyl ester) dispersion, production and use thereof
US7491777B2 (en) 2003-12-02 2009-02-17 Celanese Emulsions Gmbh Polymer dispersions having improved water-vapor barrier action, their production and use for food coating

Also Published As

Publication number Publication date
GB1024607A (en) 1966-03-30
FR1425831A (en) 1966-01-24
DE1570685A1 (en) 1970-01-08

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