GB1044397A - Process for the production of foamed cross-linked materials - Google Patents
Process for the production of foamed cross-linked materialsInfo
- Publication number
- GB1044397A GB1044397A GB36018/64A GB3601864A GB1044397A GB 1044397 A GB1044397 A GB 1044397A GB 36018/64 A GB36018/64 A GB 36018/64A GB 3601864 A GB3601864 A GB 3601864A GB 1044397 A GB1044397 A GB 1044397A
- Authority
- GB
- United Kingdom
- Prior art keywords
- formula
- alkyl radical
- diols
- inclusive
- integer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/013—Fillers, pigments or reinforcing additives
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
Compounds of the formula <FORM:1044397/C2/1> where A, A1, A11 are each -CH2-CH2-, -CH=CH-, or -C=C- radicals; R is a tertiary alkyl radical; R1 is a C1- 3 alkyl radical and n is an integer from 1 to 5 inclusive; are prepared by reacting a diol of the formula <FORM:1044397/C2/2> with excess of a dihydroperoxide of the formula <FORM:1044397/C2/3> to obtain a hydroperoxide of the formula <FORM:1044397/C2/4> The hydroperoxy groups of the product can then be reacted with a compound of the formula R-OH to obtain the desired peroxide. Suitable diols may be obtained by the reaction of acetylene, methylethylketone, or methyliso-propylketone in the presence of KOH, the product being hydrogenated if desired to the corresponding alkane and alkene diols. The diols may be oxidized to dihydroperoxides by hydrogen peroxide in sulphuric acid.ALSO:Polyolefin foaming compositions may include, with or without other peroxides, at least one compound of the formula <FORM:1044397/C3/1> where A, A1, and A11 are each one of the groups -CH2-CH2-, -CH = CH-, and -CC-; R is a tertiary alkyl radical; R1 is a C1- 3 alkyl radical and n is an integer from 1 to 5 inclusive. Specified polymers include low and high density polyethylene and a copolymer of ethylene and vinyl acetate. Exemplified blowing agents are dinitrosopentamethylene tetramine, azodicarbonamide and diphenyloxide-4,41-disulphohydrazide. Carbon black, graphite, and metal oxides, carbonates, silicates and phosphates may be used as fillers.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DED42388A DE1208488B (en) | 1963-09-02 | 1963-09-02 | Process for the production of crosslinked foams from polyolefins or ethylene copolymers |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1044397A true GB1044397A (en) | 1966-09-28 |
Family
ID=7046804
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB36018/64A Expired GB1044397A (en) | 1963-09-02 | 1964-09-02 | Process for the production of foamed cross-linked materials |
Country Status (4)
Country | Link |
---|---|
BE (1) | BE652539A (en) |
DE (1) | DE1208488B (en) |
GB (1) | GB1044397A (en) |
NL (1) | NL6410151A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0034201A1 (en) * | 1980-02-19 | 1981-08-26 | Argus Chemical Corporation | Method and composition for making foamed crosslinked polyethylene |
US4521541A (en) * | 1983-02-09 | 1985-06-04 | International Flavors & Fragrances Inc. | Process for forming functional fluid and solid-containing thermoplastic films, uses thereof and process for producing same |
US9150682B2 (en) | 2010-07-22 | 2015-10-06 | Borealis Ag | Modified polymer compositions, modification process and free radical generating agents for i.a. wire and cable applications |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE622380A (en) * | 1962-09-11 |
-
1963
- 1963-09-02 DE DED42388A patent/DE1208488B/en active Pending
-
1964
- 1964-09-01 NL NL6410151A patent/NL6410151A/xx unknown
- 1964-09-01 BE BE652539D patent/BE652539A/xx unknown
- 1964-09-02 GB GB36018/64A patent/GB1044397A/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0034201A1 (en) * | 1980-02-19 | 1981-08-26 | Argus Chemical Corporation | Method and composition for making foamed crosslinked polyethylene |
US4521541A (en) * | 1983-02-09 | 1985-06-04 | International Flavors & Fragrances Inc. | Process for forming functional fluid and solid-containing thermoplastic films, uses thereof and process for producing same |
US9150682B2 (en) | 2010-07-22 | 2015-10-06 | Borealis Ag | Modified polymer compositions, modification process and free radical generating agents for i.a. wire and cable applications |
Also Published As
Publication number | Publication date |
---|---|
NL6410151A (en) | 1965-03-03 |
BE652539A (en) | 1964-12-31 |
DE1208488B (en) | 1966-01-05 |
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