GB1002643A - New organic peroxides - Google Patents
New organic peroxidesInfo
- Publication number
- GB1002643A GB1002643A GB4052461A GB4052461A GB1002643A GB 1002643 A GB1002643 A GB 1002643A GB 4052461 A GB4052461 A GB 4052461A GB 4052461 A GB4052461 A GB 4052461A GB 1002643 A GB1002643 A GB 1002643A
- Authority
- GB
- United Kingdom
- Prior art keywords
- hydrogen atoms
- halogens
- substituted
- bis
- general formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C409/00—Peroxy compounds
- C07C409/16—Peroxy compounds the —O—O— group being bound between two carbon atoms not further substituted by oxygen atoms, i.e. peroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
A vulcanizable composition comprises a peroxide of the general formula <FORM:1002643/C3/1> in which R2 to R7 are alkyl groups containing from 1 to 6 carbon atoms, partially substituted or not with halogens, R1 is an alkyl group containing from 1 to 6 carbon atoms whose hydrogen atoms may be partially substituted with halogens or an aromatic group whose hydrogen atoms may be substituted or not with alkyl, aryl or cycloalkyl groups or with halogens, and A is an arylene group whose hydrogen atoms may be substituted or not as above, and a copolymer of ethylene and an alpha-olefin. Preferred copolymers contain ethylene in an amount of 5 to 70% by weight with propylene or butene-1. The concentration of peroxide is usually from 0.002 to 0.02 mols. per 100 g. of copolymer. Auxiliary substance such as sulphur, quinone compounds, vinyl monomers or dimaleimide may be present. The vulcanization may be carried out at from 110 DEG to 230 DEG C., preferably from 150 DEG to 200 DEG C. Auxiliary substances included in examples in addition to those specified above are carbon black, clay, silica, magnesium dioxide, diphenyl guanidine, diethylene glycol, liquid polybutadiene, divinylbenzene, p-quinonedioxime-dibenzoate.ALSO:The invention comprises a peroxide of the general formula <FORM:1002643/C2/1> in which R2 to R7 are aralkyl groups containing from 1 to 6 carbon atoms, partially substituted or not with halogens, R1 is an alkyl group containing from 1 to 6 carbon atoms whose hydrogen atoms may be partially substituted with halogens or an aromatic group containing from 6 to 20 carbon atoms whose hydrogen atoms may be substituted or not with alkyl, aryl or cycloalkyl groups or with halogens, and -A-is an arylene group whose hydrogen atoms may be substituted or not as above, particularly a ,a 1-bis(tert.-butylperoxy) - 1,4 - diisopropylbenzene; a ,a 1 - bis(cumyl peroxy) - diisopropylbenzene; di - tert. - butylperoxy - diisopropyldiphenyl; bis(tert.-butylperoxy) - 2,5 - diisopropyl naphthalene; and a mixture of meta and para a ,a 1- bis(tert. - butyl - peroxy) - diisopropyl - benzene. The novel peroxides are made by heating a mixture of an aromatic hydrocarbon having two mobile hydrogen atoms of the general formula <FORM:1002643/C2/2> and a catalyst consisting of a salt of copper, manganese or cobalt to 40 DEG C., or preferably 60-120 DEG C., with agitation and gradually adding an hydroperoxide of the general formula <FORM:1002643/C2/3> in an amount such as to provide a slight excess of hydroperoxide with respect to the hydrocarbon, and separating the diperoxide formed from the reaction mixture by evaporation under vacuum or by fractional crystallization. Alternatively, an alcohol of the general formula <FORM:1002643/C2/4> is reacted with the above hydroperoxide. The reaction is carried out in an alcohol, ketone or organic acid and an acid condensing agent, such as perchloric, sulphuric, or benzenesulphonic acid, or bromine trifluoride, is added to the solution or suspension while agitating at temperatures from room temperature to 120 DEG C. Examples describe the preparation of the above-mentioned specific peroxides and also a ,a 1-bis (cumyl peroxy)-diisopropyl-diphenyl.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT2194960 | 1960-12-22 | ||
IT1735861 | 1961-09-27 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1002643A true GB1002643A (en) | 1965-08-25 |
Family
ID=26326931
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB4052461A Expired GB1002643A (en) | 1960-12-22 | 1961-11-23 | New organic peroxides |
Country Status (8)
Country | Link |
---|---|
BE (1) | BE611834A (en) |
CH (1) | CH446325A (en) |
DE (1) | DE1569149C3 (en) |
DK (2) | DK130789B (en) |
GB (1) | GB1002643A (en) |
LU (1) | LU40997A1 (en) |
NL (2) | NL272390A (en) |
SE (1) | SE368711B (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2165741A1 (en) * | 1970-12-30 | 1972-07-20 | Asahi Glass Co Ltd | Process for the preparation of a crosslinked copolymer from tetrafluoroethylene and propylene |
CN103102472A (en) * | 2013-01-09 | 2013-05-15 | 河北科技大学 | Synthesis and application of copolymer of 1% of DVB crosslinking skeleton of chloromethylate polystyrene resin and 1,4-naphthoquinone |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL120227C (en) * | 1962-10-12 | 1965-03-15 | ||
DE3342309A1 (en) * | 1983-11-23 | 1985-05-30 | Bayer Ag, 5090 Leverkusen | METHOD FOR PRODUCING A NETWORKED NITRILE RUBBER |
-
0
- NL NL134335D patent/NL134335C/xx active
- NL NL272390D patent/NL272390A/xx unknown
- BE BE611834D patent/BE611834A/xx unknown
-
1961
- 1961-11-23 GB GB4052461A patent/GB1002643A/en not_active Expired
- 1961-12-19 DE DE19611569149 patent/DE1569149C3/en not_active Expired
- 1961-12-21 SE SE51870A patent/SE368711B/xx unknown
- 1961-12-21 CH CH1475161A patent/CH446325A/en unknown
- 1961-12-22 DK DK517561A patent/DK130789B/en unknown
- 1961-12-22 LU LU40997D patent/LU40997A1/xx unknown
-
1965
- 1965-09-23 DK DK488565A patent/DK114864B/en unknown
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2165741A1 (en) * | 1970-12-30 | 1972-07-20 | Asahi Glass Co Ltd | Process for the preparation of a crosslinked copolymer from tetrafluoroethylene and propylene |
CN103102472A (en) * | 2013-01-09 | 2013-05-15 | 河北科技大学 | Synthesis and application of copolymer of 1% of DVB crosslinking skeleton of chloromethylate polystyrene resin and 1,4-naphthoquinone |
CN103102472B (en) * | 2013-01-09 | 2015-05-20 | 河北科技大学 | Synthesis and application of copolymer of 1% of DVB crosslinking skeleton of chloromethylate polystyrene resin and 1,4-naphthoquinone |
Also Published As
Publication number | Publication date |
---|---|
DE1569149C3 (en) | 1974-02-14 |
NL272390A (en) | |
CH446325A (en) | 1967-11-15 |
DE1569149B2 (en) | 1973-07-12 |
LU40997A1 (en) | 1962-12-22 |
DK114864B (en) | 1969-08-11 |
DE1569149A1 (en) | 1969-12-18 |
DK130789B (en) | 1975-04-14 |
BE611834A (en) | |
SE368711B (en) | 1974-07-15 |
DK130789C (en) | 1975-09-15 |
NL134335C (en) |
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