GB1038182A - Production of epoxides - Google Patents
Production of epoxidesInfo
- Publication number
- GB1038182A GB1038182A GB2585063A GB2585063A GB1038182A GB 1038182 A GB1038182 A GB 1038182A GB 2585063 A GB2585063 A GB 2585063A GB 2585063 A GB2585063 A GB 2585063A GB 1038182 A GB1038182 A GB 1038182A
- Authority
- GB
- United Kingdom
- Prior art keywords
- esters
- haloalkyl
- straight
- chain alkyl
- carbon atom
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/06—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the liquid phase
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/38—Compounds containing oxirane rings with hydrocarbon radicals, substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D303/40—Compounds containing oxirane rings with hydrocarbon radicals, substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals by ester radicals
- C07D303/42—Acyclic compounds having a chain of seven or more carbon atoms, e.g. epoxidised fats
Abstract
Epoxides are obtained by oxidizing an olefinically unsaturated compound with molecular oxygen in a liquid reaction medium comprising at least 25% by weight of at least one of: (i) acetone; (ii) acetic esters CH3COOCR3; (iii) boric esters <FORM:1038182/C2/1> (iv) carbonic esters R3CO.COOCR3 or <FORM:1038182/C2/2> and (v) benzoic esters PhCOOCR13, where each R is hydrogen, straight-chain alkyl or haloalkyl of 1-3 C, or straight-chain alkyl or haloalkyl of 2 or 3 C substituted on a non-terminal carbon atom by one or more alkyl or haloalkyl of 1-3 C [provided that the carbon atom to which the R's are attached bears not more than one CH2 group (not counting CH3)], and each R1 is hydrogen, straight-chain alkyl or haloalkyl of 1-4 C, or straight-chain alkyl or haloalkyl of 2-4 C substituted on a non-terminal carbon atom by at least one straight- or branched-chain alkyl or haloalkyl of 1-4 C. Many individual solvents are specified. Metal-containing catalysts may be present, as well as inert diluents. Examples epoxidize propylene, ethylene, 2-methyl-2-butene, styrene, butadiene, cyclohexene, propylene trimer, vinyl cyclohexene, isobutylene and soybean oil. Other starting materials are listed, including polymers, hydrocarbons, halohydrocarbons, alcohols, ethers, ketones, acids, esters, amides, imides, nitriles and phosphorus esters. Boric esters above may be prepared by reacting boric acid with appropriate alcohols or glycols.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US20616062A | 1962-06-29 | 1962-06-29 | |
US21696662A | 1962-08-15 | 1962-08-15 | |
US21696762A | 1962-08-15 | 1962-08-15 | |
US21696562A | 1962-08-15 | 1962-08-15 | |
US21811362A | 1962-08-20 | 1962-08-20 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1038182A true GB1038182A (en) | 1966-08-10 |
Family
ID=27539533
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2585063A Expired GB1038182A (en) | 1962-06-29 | 1963-06-28 | Production of epoxides |
Country Status (2)
Country | Link |
---|---|
DE (1) | DE1468270A1 (en) |
GB (1) | GB1038182A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2019845A (en) * | 1978-04-28 | 1979-11-07 | Ugine Kuhlmann | Catalytic epoxidation of olefines |
-
1963
- 1963-06-28 GB GB2585063A patent/GB1038182A/en not_active Expired
- 1963-06-29 DE DE19631468270 patent/DE1468270A1/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2019845A (en) * | 1978-04-28 | 1979-11-07 | Ugine Kuhlmann | Catalytic epoxidation of olefines |
Also Published As
Publication number | Publication date |
---|---|
DE1468270A1 (en) | 1969-01-09 |
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