GB2019845A - Catalytic epoxidation of olefines - Google Patents

Catalytic epoxidation of olefines

Info

Publication number
GB2019845A
GB2019845A GB7911480A GB7911480A GB2019845A GB 2019845 A GB2019845 A GB 2019845A GB 7911480 A GB7911480 A GB 7911480A GB 7911480 A GB7911480 A GB 7911480A GB 2019845 A GB2019845 A GB 2019845A
Authority
GB
United Kingdom
Prior art keywords
olefines
catalytic epoxidation
catalytic
boron
hydrogen peroxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB7911480A
Other versions
GB2019845B (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Produits Chimiques Ugine Kuhlmann
Ugine Kuhlmann SA
Original Assignee
Produits Chimiques Ugine Kuhlmann
Ugine Kuhlmann SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Produits Chimiques Ugine Kuhlmann, Ugine Kuhlmann SA filed Critical Produits Chimiques Ugine Kuhlmann
Publication of GB2019845A publication Critical patent/GB2019845A/en
Application granted granted Critical
Publication of GB2019845B publication Critical patent/GB2019845B/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Epoxy Compounds (AREA)

Abstract

A process for the catalytic epoxidation of olefines by means of hydrogen peroxide, in which an olefine and hydrogen peroxide are put in contact in a solvent in the presence of a catalytic quantity of boron or a mineral or organic derivative of boron or a mixture of the latter at a temperature between 120 DEG C and 200 DEG C.
GB7911480A 1978-04-28 1979-04-02 Catalytic expoxidation of olefines Expired GB2019845B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7812627A FR2424265A1 (en) 1978-04-28 1978-04-28 CATALYTIC EPOXIDATION OF OLEFINS IN THE PRESENCE OF BORON DERIVATIVES

Publications (2)

Publication Number Publication Date
GB2019845A true GB2019845A (en) 1979-11-07
GB2019845B GB2019845B (en) 1982-07-28

Family

ID=9207707

Family Applications (1)

Application Number Title Priority Date Filing Date
GB7911480A Expired GB2019845B (en) 1978-04-28 1979-04-02 Catalytic expoxidation of olefines

Country Status (10)

Country Link
JP (1) JPS54144305A (en)
BE (1) BE875484A (en)
CA (1) CA1115725A (en)
CH (1) CH637648A5 (en)
DE (1) DE2916834C2 (en)
ES (1) ES480050A1 (en)
FR (1) FR2424265A1 (en)
GB (1) GB2019845B (en)
IT (1) IT1118979B (en)
NL (1) NL7903373A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4849532A (en) * 1985-08-05 1989-07-18 Degussa Aktiengesellschaft Process for the preparation of a cycloaliphatic diepoxide
US4851556A (en) * 1985-08-05 1989-07-25 Degussa Aktiengesellschaft Process for the preparation of epoxidized polybutadienes
US4855465A (en) * 1985-08-05 1989-08-08 Degussa Aktiengesellschaft Process for the treatment of aliphatic epoxides

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2952755A1 (en) * 1979-12-29 1981-07-02 Bayer Ag, 5090 Leverkusen METHOD FOR PRODUCING OXIRANES
DE3528003A1 (en) * 1985-08-05 1987-02-05 Degussa METHOD FOR PRODUCING A CYCLOALIPHATIC DIEPOXID
DE3602254A1 (en) * 1986-01-25 1987-07-30 Basf Ag METHOD FOR THE PRODUCTION OF OXIRANYLCARBONIC ACID ESTERS

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1038182A (en) * 1962-06-29 1966-08-10 Monsanto Co Production of epoxides
GB1088810A (en) * 1965-09-07 1967-10-25 Shell Int Research Method of epoxidizing olefinic compounds
GB1105710A (en) * 1965-06-01 1968-03-13 Rhone Poulenc Sa Process for the manufacture of epoxy compounds
GB1517908A (en) * 1977-05-19 1978-07-19 Texaco Development Corp Boride catalyst for epoxidizing olefinic compounds

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE747316A (en) * 1969-03-14 1970-08-17 Sumitomo Chemical Co PROCESS FOR THE PRODUCTION OF EPOXIDE COMPOUNDS
US3993673A (en) * 1970-02-26 1976-11-23 Union Carbide Corporation Production of olefin oxides
FR2407209A2 (en) * 1977-10-28 1979-05-25 Ugine Kuhlmann Liquid phase epoxidation of olefin cpds. with hydrogen peroxide - using boron-based catalyst with continuous removal of water, for simplicity
BE863237A (en) * 1977-02-01 1978-07-24 Ugine Kuhlmann CATALYTIC EPOXIDATION PROCESS OF OLEFINS
JPS53137903A (en) * 1977-05-09 1978-12-01 Mitsubishi Gas Chem Co Inc Preparation of propylene oxide

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1038182A (en) * 1962-06-29 1966-08-10 Monsanto Co Production of epoxides
GB1105710A (en) * 1965-06-01 1968-03-13 Rhone Poulenc Sa Process for the manufacture of epoxy compounds
GB1088810A (en) * 1965-09-07 1967-10-25 Shell Int Research Method of epoxidizing olefinic compounds
GB1517908A (en) * 1977-05-19 1978-07-19 Texaco Development Corp Boride catalyst for epoxidizing olefinic compounds

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4849532A (en) * 1985-08-05 1989-07-18 Degussa Aktiengesellschaft Process for the preparation of a cycloaliphatic diepoxide
US4851556A (en) * 1985-08-05 1989-07-25 Degussa Aktiengesellschaft Process for the preparation of epoxidized polybutadienes
US4855465A (en) * 1985-08-05 1989-08-08 Degussa Aktiengesellschaft Process for the treatment of aliphatic epoxides

Also Published As

Publication number Publication date
FR2424265B1 (en) 1981-04-30
CH637648A5 (en) 1983-08-15
IT1118979B (en) 1986-03-03
ES480050A1 (en) 1980-04-01
FR2424265A1 (en) 1979-11-23
JPS54144305A (en) 1979-11-10
NL7903373A (en) 1979-10-30
DE2916834C2 (en) 1982-04-15
CA1115725A (en) 1982-01-05
BE875484A (en) 1979-10-11
IT7967899A0 (en) 1979-04-27
GB2019845B (en) 1982-07-28
DE2916834A1 (en) 1979-10-31

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Legal Events

Date Code Title Description
PCNP Patent ceased through non-payment of renewal fee

Effective date: 19950402