GB1034676A - Purification of ethylenically unsaturated monomers - Google Patents
Purification of ethylenically unsaturated monomersInfo
- Publication number
- GB1034676A GB1034676A GB19960/63A GB1996063A GB1034676A GB 1034676 A GB1034676 A GB 1034676A GB 19960/63 A GB19960/63 A GB 19960/63A GB 1996063 A GB1996063 A GB 1996063A GB 1034676 A GB1034676 A GB 1034676A
- Authority
- GB
- United Kingdom
- Prior art keywords
- resin
- anion exchange
- styrene
- exchange resin
- vinyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000178 monomer Substances 0.000 title abstract 11
- 238000000746 purification Methods 0.000 title 1
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 abstract 8
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 8
- 239000003112 inhibitor Substances 0.000 abstract 8
- 239000011347 resin Substances 0.000 abstract 8
- 229920005989 resin Polymers 0.000 abstract 8
- 239000003957 anion exchange resin Substances 0.000 abstract 6
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 abstract 4
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 abstract 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 4
- 238000006116 polymerization reaction Methods 0.000 abstract 4
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 abstract 3
- 238000000034 method Methods 0.000 abstract 3
- WVAFEFUPWRPQSY-UHFFFAOYSA-N 1,2,3-tris(ethenyl)benzene Chemical compound C=CC1=CC=CC(C=C)=C1C=C WVAFEFUPWRPQSY-UHFFFAOYSA-N 0.000 abstract 2
- JIGUICYYOYEXFS-UHFFFAOYSA-N 3-tert-butylbenzene-1,2-diol Chemical compound CC(C)(C)C1=CC=CC(O)=C1O JIGUICYYOYEXFS-UHFFFAOYSA-N 0.000 abstract 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 abstract 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 abstract 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 2
- 229910002651 NO3 Inorganic materials 0.000 abstract 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 abstract 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 abstract 2
- 150000001412 amines Chemical class 0.000 abstract 2
- MPMBRWOOISTHJV-UHFFFAOYSA-N but-1-enylbenzene Chemical compound CCC=CC1=CC=CC=C1 MPMBRWOOISTHJV-UHFFFAOYSA-N 0.000 abstract 2
- 229910052757 nitrogen Inorganic materials 0.000 abstract 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 abstract 2
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 abstract 2
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 abstract 2
- 125000001453 quaternary ammonium group Chemical group 0.000 abstract 2
- 150000003839 salts Chemical group 0.000 abstract 2
- 238000001179 sorption measurement Methods 0.000 abstract 2
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 2
- 150000003512 tertiary amines Chemical class 0.000 abstract 2
- -1 vinyl napthalene Chemical compound 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 abstract 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 abstract 1
- 238000004438 BET method Methods 0.000 abstract 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- AFSIMBWBBOJPJG-UHFFFAOYSA-N ethenyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC=C AFSIMBWBBOJPJG-UHFFFAOYSA-N 0.000 abstract 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/12—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/04—Processes using organic exchangers
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/47—Separation; Purification; Stabilisation; Use of additives by solid-liquid treatment; by chemisorption
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/48—Separation; Purification; Stabilisation; Use of additives
- C07C67/56—Separation; Purification; Stabilisation; Use of additives by solid-liquid treatment; by chemisorption
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/18—Introducing halogen atoms or halogen-containing groups
- C08F8/24—Haloalkylation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/44—Preparation of metal salts or ammonium salts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
- C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Water Supply & Treatment (AREA)
- Analytical Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US19876062A | 1962-05-31 | 1962-05-31 | |
| US215769A US3247242A (en) | 1962-05-31 | 1962-08-09 | Removal of inhibitors from ethylenically unsaturated monomers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1034676A true GB1034676A (en) | 1966-06-29 |
Family
ID=26894128
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB19960/63A Expired GB1034676A (en) | 1962-05-31 | 1963-05-20 | Purification of ethylenically unsaturated monomers |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US3247242A (enEXAMPLES) |
| JP (1) | JPS4815281B1 (enEXAMPLES) |
| BE (1) | BE632901A (enEXAMPLES) |
| CH (1) | CH432847A (enEXAMPLES) |
| DE (1) | DE1468543B2 (enEXAMPLES) |
| DK (1) | DK129335B (enEXAMPLES) |
| FR (1) | FR1370647A (enEXAMPLES) |
| GB (1) | GB1034676A (enEXAMPLES) |
| NL (2) | NL126244C (enEXAMPLES) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3415870A (en) * | 1965-03-03 | 1968-12-10 | Dow Chemical Co | Purification of ethylenically unsaturated sulfonated monomers |
| DE1595341B1 (de) * | 1966-09-06 | 1970-06-25 | Basf Ag | Verfahren zur Herstellung von Vinylchlorid-Polymerisaten |
| US4267055A (en) * | 1979-09-04 | 1981-05-12 | Rohm And Haas Company | Separation of more planar molecules from less planar molecules |
| US4387264A (en) * | 1981-05-04 | 1983-06-07 | Atlantic Richfield Company | Diolefin monomer purification process for anionic polymerization |
| US4717785A (en) * | 1986-12-10 | 1988-01-05 | Shell Oil Company | Removal of phosphine impurities from higher olefins |
| US4885413A (en) * | 1987-05-20 | 1989-12-05 | Borg-Warner Chemicals, Inc. | Process and composition for stabilization of ar-brominated styrenic monmer against premature stabilization |
| US4997990A (en) * | 1989-03-23 | 1991-03-05 | General Electric Company | Process and composition for stabilization of ar-brominated styrenic monomer |
| US6046357A (en) * | 1998-10-02 | 2000-04-04 | Celanese International Corporation | Stabilization and transport of α,β-unsaturated carboxylic acid and removal of stabilizer |
| US6100439A (en) | 1998-12-14 | 2000-08-08 | Betzdearborn Inc. | Styrene caustic wash extraction aid |
| JP5126929B2 (ja) * | 2006-01-26 | 2013-01-23 | 積水化成品工業株式会社 | 光拡散樹脂粒子及びその製造方法 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2888494A (en) * | 1954-10-21 | 1959-05-26 | Columbia Southern Chem Corp | Purification of trichloroethylene |
| US3022259A (en) * | 1955-05-06 | 1962-02-20 | John W Pearce | Process for purifying acid-containing compositions |
| BE576052A (enEXAMPLES) * | 1958-03-03 | |||
| BE590370A (enEXAMPLES) * | 1959-04-29 | 1900-01-01 |
-
0
- NL NL293216D patent/NL293216A/xx unknown
- NL NL126244D patent/NL126244C/xx active
- BE BE632901D patent/BE632901A/xx unknown
-
1962
- 1962-08-09 US US215769A patent/US3247242A/en not_active Expired - Lifetime
- 1962-11-30 JP JP37052718A patent/JPS4815281B1/ja active Pending
-
1963
- 1963-05-20 GB GB19960/63A patent/GB1034676A/en not_active Expired
- 1963-05-24 DK DK247963AA patent/DK129335B/da unknown
- 1963-05-28 CH CH667063A patent/CH432847A/fr unknown
- 1963-05-30 DE DE1468543A patent/DE1468543B2/de active Pending
- 1963-05-31 FR FR936818A patent/FR1370647A/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DE1468543B2 (de) | 1975-04-10 |
| DK129335B (da) | 1974-09-30 |
| CH432847A (fr) | 1967-03-31 |
| DE1468543A1 (de) | 1969-02-20 |
| DK129335C (enEXAMPLES) | 1975-02-17 |
| BE632901A (enEXAMPLES) | |
| JPS4815281B1 (enEXAMPLES) | 1973-05-14 |
| NL293216A (enEXAMPLES) | |
| FR1370647A (fr) | 1964-08-28 |
| NL126244C (enEXAMPLES) | |
| US3247242A (en) | 1966-04-19 |
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