GB1030303A - Improvements in or relating to polymeric sulphur compounds - Google Patents

Improvements in or relating to polymeric sulphur compounds

Info

Publication number
GB1030303A
GB1030303A GB719662A GB719662A GB1030303A GB 1030303 A GB1030303 A GB 1030303A GB 719662 A GB719662 A GB 719662A GB 719662 A GB719662 A GB 719662A GB 1030303 A GB1030303 A GB 1030303A
Authority
GB
United Kingdom
Prior art keywords
sulphur
thiocarbonate
relating
prepared
sulphur compounds
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB719662A
Inventor
Max Schmidt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SULPHUR INST
Original Assignee
SULPHUR INST
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SULPHUR INST filed Critical SULPHUR INST
Priority to GB719662A priority Critical patent/GB1030303A/en
Publication of GB1030303A publication Critical patent/GB1030303A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/28Polythiocarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/14Polysulfides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)

Abstract

Polymeric sulphur compounds containing the recurring group <FORM:1030303/C1/1> are prepared from the reaction of an alkali or alkaline earth metal thiocarbonate and a sulphur SxCl2, where x is 2-20, at less than 25 DEG C., preferably 2-4 DEG C., until either free sulphur chloride disappears when thiocarbonate is added to it or, in the reverse order of procedure, until free sulphur chloride appears. Initially, sodium thiocarbonate Na2CSy, for example, may be prepared from sodium sulphide and carbon disulphide with the addition of free sulphur to the solution if y is to be greater than 3. The polymer may be purified by consecutive washing with water-methanol and carbon disulphide.
GB719662A 1962-02-23 1962-02-23 Improvements in or relating to polymeric sulphur compounds Expired GB1030303A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB719662A GB1030303A (en) 1962-02-23 1962-02-23 Improvements in or relating to polymeric sulphur compounds

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB719662A GB1030303A (en) 1962-02-23 1962-02-23 Improvements in or relating to polymeric sulphur compounds

Publications (1)

Publication Number Publication Date
GB1030303A true GB1030303A (en) 1966-05-18

Family

ID=9828444

Family Applications (1)

Application Number Title Priority Date Filing Date
GB719662A Expired GB1030303A (en) 1962-02-23 1962-02-23 Improvements in or relating to polymeric sulphur compounds

Country Status (1)

Country Link
GB (1) GB1030303A (en)

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