FR2214674A1 - Trifluoromethyl (oxy) aryl cpds prepn - by reacting chlorides of (thio) acids, or chlorothioformates with molybdenum hexafluorides - Google Patents
Trifluoromethyl (oxy) aryl cpds prepn - by reacting chlorides of (thio) acids, or chlorothioformates with molybdenum hexafluoridesInfo
- Publication number
- FR2214674A1 FR2214674A1 FR7301744A FR7301744A FR2214674A1 FR 2214674 A1 FR2214674 A1 FR 2214674A1 FR 7301744 A FR7301744 A FR 7301744A FR 7301744 A FR7301744 A FR 7301744A FR 2214674 A1 FR2214674 A1 FR 2214674A1
- Authority
- FR
- France
- Prior art keywords
- cpds
- aryl
- chlorothioformates
- hexafluorides
- prepn
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 150000001805 chlorine compounds Chemical class 0.000 title 1
- KTRFZWJCHOQHMN-UHFFFAOYSA-N chloromethanethioic s-acid Chemical class SC(Cl)=O KTRFZWJCHOQHMN-UHFFFAOYSA-N 0.000 title 1
- RLCOZMCCEKDUPY-UHFFFAOYSA-H molybdenum hexafluoride Chemical class F[Mo](F)(F)(F)(F)F RLCOZMCCEKDUPY-UHFFFAOYSA-H 0.000 title 1
- 125000000446 sulfanediyl group Chemical group *S* 0.000 title 1
- WSWMGHRLUYADNA-UHFFFAOYSA-N 7-nitro-1,2,3,4-tetrahydroquinoline Chemical compound C1CCNC2=CC([N+](=O)[O-])=CC=C21 WSWMGHRLUYADNA-UHFFFAOYSA-N 0.000 abstract 1
- 229910000831 Steel Inorganic materials 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 239000010959 steel Substances 0.000 abstract 1
- QHMQWEPBXSHHLH-UHFFFAOYSA-N sulfur tetrafluoride Chemical compound FS(F)(F)F QHMQWEPBXSHHLH-UHFFFAOYSA-N 0.000 abstract 1
- 231100000331 toxic Toxicity 0.000 abstract 1
- 230000002588 toxic effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B39/00—Halogenation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
Cpds. of formula ArCF3 or ArOCF3, where Ar is aryl, are prepd. by reacting molybdenum hexafluoride and the cpd. ArCOCl, ArCSCl or ArOCSCl. The reaction is pref. carried out in two stages, the first at -20 to -30 degrees C and the second between 20 degrees C and 190 degrees C. Other processes require the use of special steel autoclaves or use toxic sulphur tetrafluoride; the above requires normal temps and atmospheric pressure.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7301744A FR2214674A1 (en) | 1973-01-18 | 1973-01-18 | Trifluoromethyl (oxy) aryl cpds prepn - by reacting chlorides of (thio) acids, or chlorothioformates with molybdenum hexafluorides |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7301744A FR2214674A1 (en) | 1973-01-18 | 1973-01-18 | Trifluoromethyl (oxy) aryl cpds prepn - by reacting chlorides of (thio) acids, or chlorothioformates with molybdenum hexafluorides |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2214674A1 true FR2214674A1 (en) | 1974-08-19 |
FR2214674B1 FR2214674B1 (en) | 1975-10-31 |
Family
ID=9113486
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7301744A Granted FR2214674A1 (en) | 1973-01-18 | 1973-01-18 | Trifluoromethyl (oxy) aryl cpds prepn - by reacting chlorides of (thio) acids, or chlorothioformates with molybdenum hexafluorides |
Country Status (1)
Country | Link |
---|---|
FR (1) | FR2214674A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0563446A1 (en) * | 1992-04-01 | 1993-10-06 | PHARMPUR GmbH | Treating agent for ophthalmology and its use |
-
1973
- 1973-01-18 FR FR7301744A patent/FR2214674A1/en active Granted
Non-Patent Citations (1)
Title |
---|
NEANT * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0563446A1 (en) * | 1992-04-01 | 1993-10-06 | PHARMPUR GmbH | Treating agent for ophthalmology and its use |
US5441733A (en) * | 1992-04-01 | 1995-08-15 | Pharmpur Gmbh | Treatment agent for ophthalmology and use thereof |
Also Published As
Publication number | Publication date |
---|---|
FR2214674B1 (en) | 1975-10-31 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
DL | Decision of the director general to leave to make available licences of right | ||
ST | Notification of lapse |