GB1029461A - Catalytic purification of exhaust gases - Google Patents

Catalytic purification of exhaust gases

Info

Publication number
GB1029461A
GB1029461A GB17422/64A GB1742264A GB1029461A GB 1029461 A GB1029461 A GB 1029461A GB 17422/64 A GB17422/64 A GB 17422/64A GB 1742264 A GB1742264 A GB 1742264A GB 1029461 A GB1029461 A GB 1029461A
Authority
GB
United Kingdom
Prior art keywords
sio2
al2o3
mgo
exhaust gases
catalytic purification
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB17422/64A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WR Grace and Co
Original Assignee
WR Grace and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by WR Grace and Co filed Critical WR Grace and Co
Publication of GB1029461A publication Critical patent/GB1029461A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16—Clays or other mineral silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/944—Simultaneously removing carbon monoxide, hydrocarbons or carbon making use of oxidation catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8993—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Combustion & Propulsion (AREA)
  • Dispersion Chemistry (AREA)
  • Catalysts (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)

Abstract

Oxidation catalysts comprise 2-12% copper oxide, 1-10% chromium oxide and 0.0025-04% Pd on a support, the catalyst having a surface area greater than 100 sq. in/gm. a pane volume of 0.4-0.9 cc./gm. and at least 20% of the pane volume having a diameter of 600-2000\rA. The support may be silicon gel, SiO2-Al2O3, SiO2-MgO, SiO2-ZrO2, Al2O3-B2O3, SiO2-Al2O3-MgO, Al Pl4-gel, MgO, activated clay or bauxite. Other oxidizing components listed are MnO2, CoO, MoO3, Fe2O3, Fe2O3, NiO, V2O5, Pt and mixtures thereof.
GB17422/64A 1963-07-29 1964-04-27 Catalytic purification of exhaust gases Expired GB1029461A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US29816463A 1963-07-29 1963-07-29

Publications (1)

Publication Number Publication Date
GB1029461A true GB1029461A (en) 1966-05-11

Family

ID=23149335

Family Applications (1)

Application Number Title Priority Date Filing Date
GB17422/64A Expired GB1029461A (en) 1963-07-29 1964-04-27 Catalytic purification of exhaust gases

Country Status (3)

Country Link
DE (1) DE1259644B (en)
FR (1) FR1396861A (en)
GB (1) GB1029461A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018110604A1 (en) * 2016-12-15 2018-06-21 三菱日立パワーシステムズ株式会社 CATALYST AND METHOD FOR REMOVING NOx FROM COMBUSTION EXHAUST GAS
CN114100621A (en) * 2021-11-08 2022-03-01 荆楚理工学院 Catalyst for catalytic oxidation treatment of explosive hydrogen-containing waste gas, preparation method and application thereof

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5252193A (en) * 1975-10-23 1977-04-26 Toyota Motor Corp Catalyst for purifying exhaust gas from cars

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1074325B (en) * 1960-01-28 Ford-Werke Aktiengesellschaft, Köln-Niehl Process for the catalytic oxidation of exhaust gases from internal combustion engines
US2973330A (en) * 1957-12-23 1961-02-28 Exxon Research Engineering Co Hydroforming catalyst
GB950235A (en) * 1960-12-21 1964-02-19 Monsanto Chemicals Novel catalysts and uses therefor

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018110604A1 (en) * 2016-12-15 2018-06-21 三菱日立パワーシステムズ株式会社 CATALYST AND METHOD FOR REMOVING NOx FROM COMBUSTION EXHAUST GAS
US11376566B2 (en) 2016-12-15 2022-07-05 Mitsubishi Heavy Industries, Ltd. Catalyst and method for removing NOX from combustion exhaust gas
CN114100621A (en) * 2021-11-08 2022-03-01 荆楚理工学院 Catalyst for catalytic oxidation treatment of explosive hydrogen-containing waste gas, preparation method and application thereof

Also Published As

Publication number Publication date
FR1396861A (en) 1965-04-23
DE1259644B (en) 1968-01-25

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