GB1028923A - Naphthalene-substituted heterocyclic compounds - Google Patents
Naphthalene-substituted heterocyclic compoundsInfo
- Publication number
- GB1028923A GB1028923A GB11031/62A GB1103162A GB1028923A GB 1028923 A GB1028923 A GB 1028923A GB 11031/62 A GB11031/62 A GB 11031/62A GB 1103162 A GB1103162 A GB 1103162A GB 1028923 A GB1028923 A GB 1028923A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alkoxy
- substituted
- aryloxy
- amino
- mercapto
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
- C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
- C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
- C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
- C07D239/30—Halogen atoms or nitro radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
- C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
- C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
- C07D251/14—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hydrogen or carbon atoms directly attached to at least one ring carbon atom
- C07D251/16—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hydrogen or carbon atoms directly attached to at least one ring carbon atom to only one ring carbon atom
- C07D251/20—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hydrogen or carbon atoms directly attached to at least one ring carbon atom to only one ring carbon atom with no nitrogen atoms directly attached to a ring carbon atom
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0041—Optical brightening agents, organic pigments
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/60—Optical bleaching or brightening
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/60—Optical bleaching or brightening
- D06L4/614—Optical bleaching or brightening in aqueous solvents
- D06L4/636—Optical bleaching or brightening in aqueous solvents with disperse brighteners
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/60—Optical bleaching or brightening
- D06L4/65—Optical bleaching or brightening with mixtures of optical brighteners
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Detergent Compositions (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Soaps or detergents are brightened by incorporating therein a compound of formula <FORM:1028923/C4-C5/1> where R and R1 are hydrogen, alkoxy, aralkoxy, aryloxy or acyloxy (not both being hydrogen), A is N, CH or CCl, and X and Y are halogen. amino, substituted amino, alkoxy, substituted alkoxy, aryloxy, mercapto or substituted mercapto (see Division C2).ALSO:The invention comprises the compounds of formula <FORM:1028923/C2/1> where R and R1 are hydrogen, alkoxy, aralkoxy, aryloxy or acyloxy (not both being hydrogen), A is N, CH or CCl, and X and Y are halogen, amino, substituted amino, alkoxy, substituted alkoxy, aryloxy, mercapto or substituted mercapto; the production of compounds in which X and Y are halogen by reacting a cyanuric halide or 2,4,6-trihalogenopyrimidine with an approximately equimolecular amount of a naphthalene having alkoxy, aralkoxy or aryloxy substituents in the 1 and/or 3 positions in the presence of a Friedel-Crafts catalyst; and the production of compounds in which X and/or Y is substituted amino, alkoxy, substituted alkoxy, aryloxy or substituted mercapto by reacting the compounds with X and Y as halogen with an amine, alcohol, phenol or mercaptan (or two in succession) in the presence of an acid binding agent. 2,4,5,6-Tetrachloropyrimidine may also be used as starting material. Other methods specified and/or exemplified are the alkylation or acylation of the products of Specification 1,028,922; heating the dichloro-compound with the sodium derivative of an alcohol; or with sodium phenate followed by heating the diphenoxy compound with excess of an alcohol and a catalytic amount of the corresponding sodium alkoxide; reacting the dichloro compound with NH3; acylating an amino compound; reacting the dichloro compound with H2S, and the product with dimethyl sulphate. Specified groups for R and R1 are methoxy, ethoxy, higher alkoxy, acetoxy, chloroacetoxy, higher acyloxy, benzyloxy and phenoxy; and for X and Y, chloro, bromo, amino, alkylamino, arylamino, dialkylamino, b -hydroxyethylamino, bis-(b -hydroxyethyl)-amino, alkoxy, b -hydroxyethoxy, aryloxy, 4-methoxyphenoxy, alkyl mercapto and arylmercapto. Water-soluble products are obtained by condensing the mono- or dichloro compound with an arylamine sulphonic acid such as sulphanilic, or with ethanolamine followed by sulphating or acetylating. The products of the invention are whitening agents (see Division D1).ALSO:Polymeric materials such as polyhexamethylene adipamide, polyethylene terephthalate, polyurethanes, polyacrylonitrile and hydrolysed polyacrylonitriles, polymethyl methacrylate, polystyrene, polyethylene, and polypropylene are brightened by incorporating into the molten or plasticized polymer a compound of formula <FORM:1028923/C3/1> where R and R1 are hydrogen, alkoxy, aralkoxy, aryloxy or acyloxy (not both being hydrogen), A is N, CH or CCl and X and Y are each halogen, amino, substituted amino, alkoxy, substituted alkoxy, aryloxy, mercapto or substituted mercapto (see Division C2).
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BE629911D BE629911A (en) | 1962-03-22 | ||
NL290482D NL290482A (en) | 1962-03-22 | ||
NL135936D NL135936C (en) | 1962-03-22 | ||
GB11031/62A GB1028923A (en) | 1962-03-22 | 1962-03-22 | Naphthalene-substituted heterocyclic compounds |
DE19631444019 DE1444019B1 (en) | 1962-03-22 | 1963-03-21 | 2,4-dichloro-6-naphthyl- (1) -1,3,5-triazines |
CH363363A CH420043A (en) | 1962-03-22 | 1963-03-22 | Process for the optical brightening of textile fibers with naphthalene derivatives |
FR928984A FR1359373A (en) | 1962-03-22 | 1963-03-22 | Production and application of new naphthalene compounds |
ES286305A ES286305A1 (en) | 1962-03-22 | 1963-03-22 | Procedure for obtaining naftalene compounds (Machine-translation by Google Translate, not legally binding) |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB11031/62A GB1028923A (en) | 1962-03-22 | 1962-03-22 | Naphthalene-substituted heterocyclic compounds |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1028923A true GB1028923A (en) | 1966-05-11 |
Family
ID=9978786
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB11031/62A Expired GB1028923A (en) | 1962-03-22 | 1962-03-22 | Naphthalene-substituted heterocyclic compounds |
Country Status (7)
Country | Link |
---|---|
BE (1) | BE629911A (en) |
CH (1) | CH420043A (en) |
DE (1) | DE1444019B1 (en) |
ES (1) | ES286305A1 (en) |
FR (1) | FR1359373A (en) |
GB (1) | GB1028923A (en) |
NL (2) | NL290482A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0623340A1 (en) * | 1993-05-03 | 1994-11-09 | L'oreal | Use of hydroxy or dihydroxynaphthalene in the preparation of a cosmetic or dermatological composition for skin whitening |
EP1310492A1 (en) * | 2001-11-09 | 2003-05-14 | Cytec Technology Corp. | Phenyl ether-substituted hydroxyphenyl triazine ultraviolet light absorbers |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1551095A (en) * | 1925-08-25 | of basel | ||
FR1281155A (en) * | 1961-02-23 | 1962-01-08 | Ciba Geigy | New triazine derivatives, their process for obtaining and dyes prepared with these derivatives |
-
0
- NL NL135936D patent/NL135936C/xx active
- NL NL290482D patent/NL290482A/xx unknown
- BE BE629911D patent/BE629911A/xx unknown
-
1962
- 1962-03-22 GB GB11031/62A patent/GB1028923A/en not_active Expired
-
1963
- 1963-03-21 DE DE19631444019 patent/DE1444019B1/en active Pending
- 1963-03-22 FR FR928984A patent/FR1359373A/en not_active Expired
- 1963-03-22 ES ES286305A patent/ES286305A1/en not_active Expired
- 1963-03-22 CH CH363363A patent/CH420043A/en unknown
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0623340A1 (en) * | 1993-05-03 | 1994-11-09 | L'oreal | Use of hydroxy or dihydroxynaphthalene in the preparation of a cosmetic or dermatological composition for skin whitening |
FR2704755A1 (en) * | 1993-05-03 | 1994-11-10 | Oreal | Use of hydroxy or dihydroxy naphthalenes in the preparation of a cosmetic or dermatological composition with depigmenting action. |
EP1310492A1 (en) * | 2001-11-09 | 2003-05-14 | Cytec Technology Corp. | Phenyl ether-substituted hydroxyphenyl triazine ultraviolet light absorbers |
US6855269B2 (en) | 2001-11-09 | 2005-02-15 | Cytec Technology Corp. | Phenyl ether-substituted hydroxyphenyl triazine ultraviolet light absorbers |
Also Published As
Publication number | Publication date |
---|---|
NL135936C (en) | |
BE629911A (en) | |
ES286305A1 (en) | 1963-11-16 |
FR1359373A (en) | 1964-04-24 |
CH420043A (en) | 1967-03-15 |
CH363363A4 (en) | 1966-03-15 |
DE1444019B1 (en) | 1972-05-04 |
NL290482A (en) |
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