GB1026912A - Novel copolymers of methyl methacrylate - Google Patents
Novel copolymers of methyl methacrylateInfo
- Publication number
- GB1026912A GB1026912A GB1537563A GB1537563A GB1026912A GB 1026912 A GB1026912 A GB 1026912A GB 1537563 A GB1537563 A GB 1537563A GB 1537563 A GB1537563 A GB 1537563A GB 1026912 A GB1026912 A GB 1026912A
- Authority
- GB
- United Kingdom
- Prior art keywords
- copolymers
- vinyl
- rubbery
- methyl methacrylate
- styrene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F22/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
- C08F22/36—Amides or imides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Novel copolymers are prepared by polymerizing a monomer mixture comprising 1 to 99% by weight of methyl methacrylate, 99 to 1% by weight of one or more N-aryl maleimides and 0 to 15% by weight of a copolymerizable ethylenically unsaturated compound. Suitable maleimides include N-phenyl maleimide optioally substituted by one or more halogen atoms or nitro, nitrile, aryl, aryloxy, aralkyl, aralkoxy, aryloxyalkyl, C1-4 alkyl or C1-4 alkoxy groups, and N-a -naphthyl maleimide and derivatives thereof. As optional copolymerizable compound there may be used vinyl esters, e.g. vinyl acetate, esters of acrylic or methacrylic acid, e.g. methyl acrylate, ethyl acrylate, n-butyl methacrylate and 2-ethylhexyl methacrylate, vinyl chloride, vinylidene chloride, acrylonitrile, methacrylonitrile, styrene, a -methyl-styrene, halogenated styrenes, vinyl and isopropenyl ethers, e.g. vinyl isobutyl ether, dienes, e.g. 1,3-butadiene, glycol dimethacrylate and di-vinyl-benzene. The polymerization may be effected in bulk, solution, aqueous emulsion or aqueous suspension, using a catalyst such as azo-bis isobutyronitrile, azo-dicyclohexane-carbonitrile, a peroxy compound, e.g. benzoyl peroxide or lauroyl peroxide, or potassium persulphate and, if desired, a chain transfer agent, e.g. lauryl mercaptan. The monomers may be partially polymerized to form a syrup which is then polymerized in a cell to form a sheet. Continuous polymerization can be effected by the process described in Specification 875,853. The copolymers may be combined with rubbery polymeric materials, e.g. copolymers of butadiene with styrene, methyl methacrylate or acrylonitrile; polyethyl acrylate; rubbery copolymers of C1-4 alkyl acrylates; rubbery copolymers of ethylene with e.g. vinyl acetate or methyl methacrylate. The rubbery polymers can be cross-linked, e.g. by masticating or incorporating therein a cross-linking monomer. The rubbery polymer may simply be mixed with the copolymer of the invention, or the monomeric components of one of these polymers may be polymerized in the presence of the other preformed polymer. Other ancillary ingredients may be added during or after the preparation of the novel copolymers; such substances include fillers, e.g. glass fibres, pigments, e.g. aluminium sulphate, heat and light stabilizers, plasticizers, lubricants, flame retardants and mould release agents.
Priority Applications (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL133553D NL133553C (en) | 1963-04-18 | ||
GB1537563A GB1026912A (en) | 1963-04-18 | 1963-04-18 | Novel copolymers of methyl methacrylate |
SE4766/64A SE318715B (en) | 1963-04-18 | 1964-04-17 | |
DE19641520147 DE1520147C3 (en) | 1963-04-18 | 1964-04-17 | Process for the preparation of copolymers of methyl methacrylate and N aryl maleimides |
BE646738A BE646738A (en) | 1963-04-18 | 1964-04-17 | |
DK190364A DK108271C (en) | 1963-04-18 | 1964-04-17 | High softening plastic based on a methyl methacrylate copolymer. |
FR971362A FR1394424A (en) | 1963-04-18 | 1964-04-17 | Copolymers of a naked-substituted maleimide and methyl methacrylate and process for their preparation |
NL6404196A NL6404196A (en) | 1963-04-18 | 1964-04-17 | |
CH502564A CH433759A (en) | 1963-04-18 | 1964-04-18 | Process for the preparation of new copolymers |
AT345464A AT251872B (en) | 1963-04-18 | 1964-04-20 | Process for the production of new copolymers |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1537563A GB1026912A (en) | 1963-04-18 | 1963-04-18 | Novel copolymers of methyl methacrylate |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1026912A true GB1026912A (en) | 1966-04-20 |
Family
ID=10058060
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1537563A Expired GB1026912A (en) | 1963-04-18 | 1963-04-18 | Novel copolymers of methyl methacrylate |
Country Status (7)
Country | Link |
---|---|
AT (1) | AT251872B (en) |
BE (1) | BE646738A (en) |
CH (1) | CH433759A (en) |
DE (1) | DE1520147C3 (en) |
DK (1) | DK108271C (en) |
GB (1) | GB1026912A (en) |
NL (2) | NL6404196A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61162543A (en) * | 1985-01-10 | 1986-07-23 | Nippon Shokubai Kagaku Kogyo Co Ltd | Thermoplastic resin composition |
EP0548839A1 (en) * | 1991-12-27 | 1993-06-30 | Bromine Compounds Ltd. | Flame retarded methyl methacrylates |
-
0
- NL NL133553D patent/NL133553C/xx active
-
1963
- 1963-04-18 GB GB1537563A patent/GB1026912A/en not_active Expired
-
1964
- 1964-04-17 DK DK190364A patent/DK108271C/en active
- 1964-04-17 DE DE19641520147 patent/DE1520147C3/en not_active Expired
- 1964-04-17 NL NL6404196A patent/NL6404196A/xx unknown
- 1964-04-17 BE BE646738A patent/BE646738A/xx unknown
- 1964-04-18 CH CH502564A patent/CH433759A/en unknown
- 1964-04-20 AT AT345464A patent/AT251872B/en active
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61162543A (en) * | 1985-01-10 | 1986-07-23 | Nippon Shokubai Kagaku Kogyo Co Ltd | Thermoplastic resin composition |
JPS6357460B2 (en) * | 1985-01-10 | 1988-11-11 | Nippon Shokubai Kagaku Kogyo Kk | |
EP0548839A1 (en) * | 1991-12-27 | 1993-06-30 | Bromine Compounds Ltd. | Flame retarded methyl methacrylates |
Also Published As
Publication number | Publication date |
---|---|
NL6404196A (en) | 1964-10-19 |
CH433759A (en) | 1967-04-15 |
NL133553C (en) | |
DE1520147B2 (en) | 1973-04-26 |
DK108271C (en) | 1967-10-30 |
DE1520147A1 (en) | 1970-10-08 |
AT251872B (en) | 1967-01-25 |
BE646738A (en) | 1964-10-19 |
DE1520147C3 (en) | 1973-12-13 |
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