GB1022875A - Cis, cis-cyclodecadiene-(1.6) and its manufacture - Google Patents

Cis, cis-cyclodecadiene-(1.6) and its manufacture

Info

Publication number
GB1022875A
GB1022875A GB14467/62A GB1446762A GB1022875A GB 1022875 A GB1022875 A GB 1022875A GB 14467/62 A GB14467/62 A GB 14467/62A GB 1446762 A GB1446762 A GB 1446762A GB 1022875 A GB1022875 A GB 1022875A
Authority
GB
United Kingdom
Prior art keywords
cis
metal
cyclodecadiene
isomerization
platinum
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB14467/62A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Studiengesellschaft Kohle gGmbH
Original Assignee
Studiengesellschaft Kohle gGmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Studiengesellschaft Kohle gGmbH filed Critical Studiengesellschaft Kohle gGmbH
Publication of GB1022875A publication Critical patent/GB1022875A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/40—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals
    • C07C15/42—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic
    • C07C15/44—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic the hydrocarbon substituent containing a carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/21—Alkatrienes; Alkatetraenes; Other alkapolyenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/02—Monocyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/271—Monocyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with a nine- to ten- membered ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/23—Rearrangement of carbon-to-carbon unsaturated bonds
    • C07C5/25—Migration of carbon-to-carbon double bonds
    • C07C5/2506—Catalytic processes
    • C07C5/2556—Catalytic processes with metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/18—Systems containing only non-condensed rings with a ring being at least seven-membered
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/18—Systems containing only non-condensed rings with a ring being at least seven-membered
    • C07C2601/20—Systems containing only non-condensed rings with a ring being at least seven-membered the ring being twelve-membered

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

The new compound cis, cis-cyclodecadiene-1,6 is prepared by isomerization of trans,cis-cyclodecadiene-1,5 in the presence of a metal of Group VIII. Isomerization is effected at 0-100 DEG C. using a Raney metal or platinum or palladium prepared under hydrogenating conditions, e.g. by reducing a compound of the metal with a hydride or an organometallic compound of a metal of the main Groups I-III or the metal itself or by decomposing a labile olefin- or acetylene-p -complex of platinum or palladium or nickel by heat or reduction. A solvent such as hexane, cyclohexane, benzene, ether or alcohol where Raney metals are employed. The preparation of the starting material is described in Specification 977,108.
GB14467/62A 1963-04-10 1964-04-10 Cis, cis-cyclodecadiene-(1.6) and its manufacture Expired GB1022875A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEST20502A DE1230023B (en) 1963-04-10 1963-04-10 Process for the preparation of cis, cis-cyclodecadiene- (1, 6)

Publications (1)

Publication Number Publication Date
GB1022875A true GB1022875A (en) 1966-03-16

Family

ID=7458598

Family Applications (1)

Application Number Title Priority Date Filing Date
GB14467/62A Expired GB1022875A (en) 1963-04-10 1964-04-10 Cis, cis-cyclodecadiene-(1.6) and its manufacture

Country Status (6)

Country Link
US (1) US3317620A (en)
BE (1) BE646244A (en)
CH (1) CH446312A (en)
DE (2) DE1230023B (en)
GB (1) GB1022875A (en)
NL (1) NL139294B (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1142744A (en) * 1965-09-13 1969-02-12 Montedison Spa Process for the preparation of cyclododecadienes
US5076460A (en) * 1991-02-13 1991-12-31 Hussell Donald E Three ball snap hinge box
JP5661647B2 (en) 2009-01-28 2015-01-28 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ Production of pure cyclododecanone
WO2010086313A1 (en) 2009-01-28 2010-08-05 Basf Se Method for isolating dodecatrienal and use thereof as a flavouring
DE102014212602A1 (en) 2013-07-02 2015-01-08 Basf Se Process for the preparation of a ketone from an olefin

Also Published As

Publication number Publication date
DE1230023B (en) 1966-12-08
NL6403826A (en) 1964-10-12
CH446312A (en) 1967-11-15
DE1288087B (en) 1969-01-30
BE646244A (en) 1900-01-01
US3317620A (en) 1967-05-02
NL139294B (en) 1973-07-16

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