GB1010695A - Process for the production of alpha, beta unsaturated carbonyl compounds - Google Patents
Process for the production of alpha, beta unsaturated carbonyl compoundsInfo
- Publication number
- GB1010695A GB1010695A GB4209762A GB4209762A GB1010695A GB 1010695 A GB1010695 A GB 1010695A GB 4209762 A GB4209762 A GB 4209762A GB 4209762 A GB4209762 A GB 4209762A GB 1010695 A GB1010695 A GB 1010695A
- Authority
- GB
- United Kingdom
- Prior art keywords
- elevated temperature
- calcining
- zinc oxide
- drying
- hours
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title abstract 3
- 150000001728 carbonyl compounds Chemical class 0.000 title abstract 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract 14
- 239000011787 zinc oxide Substances 0.000 abstract 7
- 238000001354 calcination Methods 0.000 abstract 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 5
- 239000003054 catalyst Substances 0.000 abstract 5
- 238000001035 drying Methods 0.000 abstract 5
- 150000001875 compounds Chemical class 0.000 abstract 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 3
- 239000000395 magnesium oxide Substances 0.000 abstract 3
- 229910052751 metal Inorganic materials 0.000 abstract 3
- 239000002184 metal Substances 0.000 abstract 3
- 150000002739 metals Chemical class 0.000 abstract 3
- -1 C20 aldehyde Chemical class 0.000 abstract 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 abstract 2
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 abstract 2
- 235000018660 ammonium molybdate Nutrition 0.000 abstract 2
- 239000011609 ammonium molybdate Substances 0.000 abstract 2
- 229940010552 ammonium molybdate Drugs 0.000 abstract 2
- 238000007580 dry-mixing Methods 0.000 abstract 2
- 150000002576 ketones Chemical class 0.000 abstract 2
- 229910052749 magnesium Inorganic materials 0.000 abstract 2
- 239000011777 magnesium Substances 0.000 abstract 2
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- 229910052750 molybdenum Inorganic materials 0.000 abstract 2
- 239000011733 molybdenum Substances 0.000 abstract 2
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 abstract 2
- 239000006187 pill Substances 0.000 abstract 2
- 239000000843 powder Substances 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 abstract 2
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 abstract 1
- 230000004048 modification Effects 0.000 abstract 1
- 238000012986 modification Methods 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 229910052596 spinel Inorganic materials 0.000 abstract 1
- 239000011029 spinel Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
- C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
- C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
- C07C45/74—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups combined with dehydration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/28—Molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/32—Manganese, technetium or rhenium
- B01J23/34—Manganese
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
- C07C49/20—Unsaturated compounds containing keto groups bound to acyclic carbon atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US16163061A | 1961-12-22 | 1961-12-22 | |
US161723A US3248428A (en) | 1961-12-22 | 1961-12-22 | Aldolization process |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1010695A true GB1010695A (en) | 1965-11-24 |
Family
ID=26857983
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB4209762A Expired GB1010695A (en) | 1961-12-22 | 1962-11-07 | Process for the production of alpha, beta unsaturated carbonyl compounds |
Country Status (3)
Country | Link |
---|---|
DE (1) | DE1203243B (enrdf_load_stackoverflow) |
GB (1) | GB1010695A (enrdf_load_stackoverflow) |
SE (1) | SE300815B (enrdf_load_stackoverflow) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3542878A (en) * | 1967-11-22 | 1970-11-24 | Gulf Research Development Co | Aldol condensation process |
US4005147A (en) * | 1971-10-13 | 1977-01-25 | Badische Anilin- & Soda-Fabrik Aktiengesellschaft | Production of α,β-unsaturated ketones |
US4535187A (en) * | 1983-12-21 | 1985-08-13 | Union Carbide Corporation | Preparation of isophorone and mesityl oxide from acetone |
WO1993020034A1 (en) * | 1992-04-07 | 1993-10-14 | Davy Mckee (London) Limited | Aldolisation-dehydration process |
US6960694B2 (en) | 2003-07-01 | 2005-11-01 | Eastman Chemical Company | Processes for preparing β-hydroxy-ketones and α,β-unsaturated ketones |
US7071361B2 (en) | 2004-06-25 | 2006-07-04 | Fastman Chemical Company | Processes for the preparation of high molecular weight saturated ketones |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4169109A (en) | 1978-08-10 | 1979-09-25 | International Flavors & Fragrances Inc. | Process for preparing ketones using zinc acetate condensation catalysts, products produced thereby and organoleptic uses of same |
DE4020838A1 (de) * | 1990-06-29 | 1992-01-02 | Henkel Kgaa | Verfahren zur aldolisierung von verbindungen mit aktiven wasserstoffatomen |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE836346C (de) * | 1950-05-20 | 1952-04-10 | Ruhrchemie Ag | Verfahren zur Gewinnung von substituierten Acroleinen |
DE1051838B (de) * | 1951-04-25 | 1959-03-05 | Melle Usines Sa | Verfahren zur Herstellung ungesaettigter hoehermolekularer aliphatischer Aldehyde |
US2852563A (en) * | 1955-10-17 | 1958-09-16 | Eastman Kodak Co | Condensation of isoaldehydes with lower aliphatic aldehydes |
DE1084711B (de) * | 1956-05-07 | 1960-07-07 | Armour & Co | Verfahren zur Herstellung von ª,ª-ungesaettigten Aldehyden mit hohem Molekulargewicht |
US2921089A (en) * | 1957-11-27 | 1960-01-12 | Eastman Kodak Co | 2-propylheptanol and its esters |
FR1224715A (fr) * | 1958-05-27 | 1960-06-27 | Eastman Kodak Co | Procédé de préparation d'aldéhydes aliphatiques non saturés |
-
1962
- 1962-11-07 GB GB4209762A patent/GB1010695A/en not_active Expired
- 1962-11-20 SE SE1243162A patent/SE300815B/xx unknown
- 1962-12-19 DE DEE24050A patent/DE1203243B/de active Pending
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3542878A (en) * | 1967-11-22 | 1970-11-24 | Gulf Research Development Co | Aldol condensation process |
US4005147A (en) * | 1971-10-13 | 1977-01-25 | Badische Anilin- & Soda-Fabrik Aktiengesellschaft | Production of α,β-unsaturated ketones |
US4535187A (en) * | 1983-12-21 | 1985-08-13 | Union Carbide Corporation | Preparation of isophorone and mesityl oxide from acetone |
WO1993020034A1 (en) * | 1992-04-07 | 1993-10-14 | Davy Mckee (London) Limited | Aldolisation-dehydration process |
AU659554B2 (en) * | 1992-04-07 | 1995-05-18 | Davy Process Technology Limited | Aldolisation-dehydration process |
US5434313A (en) * | 1992-04-07 | 1995-07-18 | Davy Mckee (London) Limited | Aldolisation-dehydration process |
EP0751109A1 (en) * | 1992-04-07 | 1997-01-02 | Davy Process Technology Limited | Adolisation-dehydration process |
CN1058697C (zh) * | 1992-04-07 | 2000-11-22 | 戴维加工技术有限公司 | 取代丙烯醛的生产方法 |
US6960694B2 (en) | 2003-07-01 | 2005-11-01 | Eastman Chemical Company | Processes for preparing β-hydroxy-ketones and α,β-unsaturated ketones |
US7071361B2 (en) | 2004-06-25 | 2006-07-04 | Fastman Chemical Company | Processes for the preparation of high molecular weight saturated ketones |
Also Published As
Publication number | Publication date |
---|---|
DE1203243B (de) | 1965-10-21 |
SE300815B (enrdf_load_stackoverflow) | 1968-05-13 |
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