GB1001942A - Liquid hydrocarbons with increased electrical conductivity - Google Patents
Liquid hydrocarbons with increased electrical conductivityInfo
- Publication number
- GB1001942A GB1001942A GB4181161A GB4181161A GB1001942A GB 1001942 A GB1001942 A GB 1001942A GB 4181161 A GB4181161 A GB 4181161A GB 4181161 A GB4181161 A GB 4181161A GB 1001942 A GB1001942 A GB 1001942A
- Authority
- GB
- United Kingdom
- Prior art keywords
- amide
- prepared
- butyl
- butylmethacryl
- methacrylonitrile
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/20—Conductive material dispersed in non-conductive organic material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/52—Amides or imides
- C08F20/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/143—Organic compounds mixtures of organic macromolecular compounds with organic non-macromolecular compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
- D06L1/02—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using organic solvents
- D06L1/04—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using organic solvents combined with specific additives
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
- H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/188—Carboxylic acids; metal salts thereof
- C10L1/189—Carboxylic acids; metal salts thereof having at least one carboxyl group bound to an aromatic carbon atom
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/234—Macromolecular compounds
- C10L1/236—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derivatives thereof
- C10L1/2364—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derivatives thereof homo- or copolymers derived from unsaturated compounds containing amide and/or imide groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/24—Organic compounds containing sulfur, selenium and/or tellurium
- C10L1/2431—Organic compounds containing sulfur, selenium and/or tellurium sulfur bond to oxygen, e.g. sulfones, sulfoxides
- C10L1/2437—Sulfonic acids; Derivatives thereof, e.g. sulfonamides, sulfosuccinic acid esters
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Physics & Mathematics (AREA)
- Organic Chemistry (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Dispersion Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
An organic liquid composition comprises a major proportion of a liquid light petroleum fraction boiling in the gasoline and/or kerosine boiling range and with a dielectric constant of 8 or less, and minor proportions of (A) a salt of a polyvalent metal and a alkyl salicylic acid having at least one alkyl substituent with 8 or more carbon atoms, and (B) a polymer of formula <FORM:1001942/C4-C5/1> in which R1, R2 and R3 are hydrogen atoms or hydrocarbon groups, R4 is a hydrocarbon group, and n is an integer, at least one of R1 and R2 being a hydrocarbon group, and certain provisos being attached to the size of R4 in relation to R3. Typical (A) additives are chromium, ferric, nickel, manganese and cobalt C14-18 alkyl salicylates; and typical (B) additives are homopolymers of N - 1 - propylbutyl methacrylamide, N-1,1,3,3-tetramethylbutylacrylamide, N,N - n - butyl - sec.amylmethacrylamide, a ,b -dimethylacrylamide and a ,b - dibenzyl acrylamide, many others being mentioned. A third additive (C) which may be present comprises a salt of dioctyl- or didecyl-sulphosuccinic ester, the salt-forming metals being as specified for (A). In examples, solutions of additives (A), (B) and (C) in xylene or gasoline are added to kerosine, and in some examples C14-18 alkyl phenol is also present.ALSO:Polymers of the amides listed below are prepared by treating a xylene solution of the amide with ditertiary butyl peroxide in a nitrogen atmosphere. The amides are N-1,1-dimethylethylmethacryl amide; N - n - butylmethacryl amide; N - 1 - methylbutylmethacryl amide; N - 1 - ethylbutylmethacryl amide; N - 1 - propylbutylmethacryl amide; N - 1 - methylheptylmethacryl amide; N - 1,1,3,3 - tetramethylbutylmethacryl amide; N - 1,1,3,3 - tetramethylbutylacryl amide; N - 3,5,5 - trimethylhexylmethacryl amide; N - n - decylmethacryl amide; N - 1 - methylpentadecylmethacryl amide; N - n - octadecylmethacryl amide; N,N-N,N - di - n - butylmethacrylamide; N,N-diisobutylmethacryl amide; N,N - n - butyl - secamylmethacryl amide; N,N - di - n - amylmethacryl amide; N,N - di - n - tridecylmethacryl amide; and N,N - di - n - butylacryl amide. It is also stated that poly (unsaturated amides) may be prepared from the corresponding poly (unsaturated ester) and an amine. Specific examples are the reaction of polymethylmethacrylate and n-octylamine to give polymeric N-n-octylmethacryl amide; and the reaction of polymethylacrylate with di-n-octylamine to give polymeric N,N-di-n-octylacryl amide.ALSO:N - n - butylmethacryl amide; N - 3,5,5 -tri-methylhexylmethacryl amide; N-n-decylmethacryl amide; and N-n-octadecylmethacryl amide are prepared from methacrylyl chloride and the appropriate primary amine. N - 1,1 - dimethylethylmethacryl amide is prepared from tert.-butyl alcohol and methacrylonitrile. N - 1 - methylbutylmethacryl amide; N-1-ethyl-butylmethacryl amide; N-1-propylbutylmethacryl amide; and N-1-methylheptylmethacryl amide are prepared from methacrylonitrile and the appropriate secondary alcohol, i.e. pentanol-2, hexanol-3, heptanol-4, and octanol-2 respectively. N - 1,1,3,3 - tetramethylbutylmethacryl amide and N - 1,1,3,3 - tetramethylbutylacryl amide are prepared by the addition of diisobutene and water on to methacrylonitrile and acrylonitrile respectively. N - 1 - methylpentadecylmethacryl amide is prepared from cetene-1 (hexadecene-1), water and methacrylonitrile. N,N - di - n - butylmethacryl amide; N,N - di-isobutylmethacryl amide; N,N - n - butyl - sec. -amylmethacryl amide; N,N - di - n - amylmethacryl amide; and N,N - di - n - tridecylmethacryl amide are prepared from methacrylyl chloride and the appropriate secondary amine. N,N-di-n-butylacryl amide is prepared from acrylyl chloride and di-n-butylamine.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL258333 | 1960-11-24 | ||
NL263311 | 1961-04-07 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1001942A true GB1001942A (en) | 1965-08-18 |
Family
ID=26641748
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB4181161A Expired GB1001942A (en) | 1960-11-24 | 1961-11-22 | Liquid hydrocarbons with increased electrical conductivity |
Country Status (5)
Country | Link |
---|---|
BE (1) | BE610617A (en) |
DE (1) | DE1258534B (en) |
FR (1) | FR1310127A (en) |
GB (1) | GB1001942A (en) |
NL (2) | NL105483C (en) |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1050338B (en) * | 1952-12-30 |
-
0
- FR FR1310127D patent/FR1310127A/fr not_active Expired
- BE BE610617D patent/BE610617A/xx unknown
- NL NL258333D patent/NL258333A/xx unknown
- NL NL105483D patent/NL105483C/xx active
-
1961
- 1961-11-22 DE DE1961S0076800 patent/DE1258534B/en active Pending
- 1961-11-22 GB GB4181161A patent/GB1001942A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
DE1258534B (en) | 1968-01-11 |
FR1310127A (en) | 1963-03-06 |
NL258333A (en) | |
NL105483C (en) | |
BE610617A (en) |
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