GB0725140D0 - Catalytic Reactor - Google Patents

Catalytic Reactor

Info

Publication number
GB0725140D0
GB0725140D0 GBGB0725140.8A GB0725140A GB0725140D0 GB 0725140 D0 GB0725140 D0 GB 0725140D0 GB 0725140 A GB0725140 A GB 0725140A GB 0725140 D0 GB0725140 D0 GB 0725140D0
Authority
GB
United Kingdom
Prior art keywords
catalytic reactor
catalytic
reactor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
GBGB0725140.8A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CompactGTL PLC
Original Assignee
CompactGTL PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by CompactGTL PLC filed Critical CompactGTL PLC
Priority to GBGB0725140.8A priority Critical patent/GB0725140D0/en
Publication of GB0725140D0 publication Critical patent/GB0725140D0/en
Priority to MYPI2010002898A priority patent/MY157456A/en
Priority to EP08806671.7A priority patent/EP2227325B1/en
Priority to JP2010540174A priority patent/JP5571573B2/ja
Priority to CA2708821A priority patent/CA2708821C/en
Priority to BRPI0821525A priority patent/BRPI0821525A8/pt
Priority to KR1020107016437A priority patent/KR20100101158A/ko
Priority to PCT/GB2008/050855 priority patent/WO2009081175A1/en
Priority to US12/810,128 priority patent/US8444939B2/en
Priority to AU2008339634A priority patent/AU2008339634B2/en
Priority to EA201070797A priority patent/EA019964B1/ru
Priority to CN200880123322.8A priority patent/CN101932379B/zh
Priority to DK08806671.7T priority patent/DK2227325T3/da
Priority to ZA2010/04401A priority patent/ZA201004401B/en
Ceased legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/248—Reactors comprising multiple separated flow channels
    • B01J19/249—Plate-type reactors
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/34—Apparatus, reactors
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/34—Apparatus, reactors
    • C10G2/341—Apparatus, reactors with stationary catalyst bed
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00018—Construction aspects
    • B01J2219/0002—Plants assembled from modules joined together
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/18—Details relating to the spatial orientation of the reactor
    • B01J2219/185—Details relating to the spatial orientation of the reactor vertical
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2451—Geometry of the reactor
    • B01J2219/2453—Plates arranged in parallel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2451—Geometry of the reactor
    • B01J2219/2456—Geometry of the plates
    • B01J2219/2458—Flat plates, i.e. plates which are not corrugated or otherwise structured, e.g. plates with cylindrical shape
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2451—Geometry of the reactor
    • B01J2219/2456—Geometry of the plates
    • B01J2219/2459—Corrugated plates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2461—Heat exchange aspects
    • B01J2219/2462—Heat exchange aspects the reactants being in indirect heat exchange with a non reacting heat exchange medium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2476—Construction materials
    • B01J2219/2477—Construction materials of the catalysts
    • B01J2219/2479—Catalysts coated on the surface of plates or inserts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2476—Construction materials
    • B01J2219/2483—Construction materials of the plates
    • B01J2219/2485—Metals or alloys
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2476—Construction materials
    • B01J2219/2483—Construction materials of the plates
    • B01J2219/2485—Metals or alloys
    • B01J2219/2486—Steel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2491—Other constructional details
    • B01J2219/2497—Size aspects, i.e. concrete sizes are being mentioned in the classified document
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2491—Other constructional details
    • B01J2219/2498—Additional structures inserted in the channels, e.g. plates, catalyst holding meshes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
GBGB0725140.8A 2007-12-24 2007-12-24 Catalytic Reactor Ceased GB0725140D0 (en)

Priority Applications (14)

Application Number Priority Date Filing Date Title
GBGB0725140.8A GB0725140D0 (en) 2007-12-24 2007-12-24 Catalytic Reactor
DK08806671.7T DK2227325T3 (da) 2007-12-24 2008-09-24 Katalytisk reaktor
KR1020107016437A KR20100101158A (ko) 2007-12-24 2008-09-24 촉매 반응기
US12/810,128 US8444939B2 (en) 2007-12-24 2008-09-24 Catalytic reactor
JP2010540174A JP5571573B2 (ja) 2007-12-24 2008-09-24 触媒反応器
CA2708821A CA2708821C (en) 2007-12-24 2008-09-24 Catalytic reactor
BRPI0821525A BRPI0821525A8 (pt) 2007-12-24 2008-09-24 Módulo de reator para síntese de fischer-tropsch, planta para processamento de gás natural para produzir hidrocarbonetos de cadeia mais longa, e, processo para realizar a síntese de fischer-tropsch
MYPI2010002898A MY157456A (en) 2007-12-24 2008-09-24 Catalytic reactor
PCT/GB2008/050855 WO2009081175A1 (en) 2007-12-24 2008-09-24 Catalytic reactor
EP08806671.7A EP2227325B1 (en) 2007-12-24 2008-09-24 Catalytic reactor
AU2008339634A AU2008339634B2 (en) 2007-12-24 2008-09-24 Catalytic reactor
EA201070797A EA019964B1 (ru) 2007-12-24 2008-09-24 Каталитический реактор
CN200880123322.8A CN101932379B (zh) 2007-12-24 2008-09-24 催化反应器
ZA2010/04401A ZA201004401B (en) 2007-12-24 2010-06-22 Catalytic reactor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GBGB0725140.8A GB0725140D0 (en) 2007-12-24 2007-12-24 Catalytic Reactor

Publications (1)

Publication Number Publication Date
GB0725140D0 true GB0725140D0 (en) 2008-01-30

Family

ID=39048685

Family Applications (1)

Application Number Title Priority Date Filing Date
GBGB0725140.8A Ceased GB0725140D0 (en) 2007-12-24 2007-12-24 Catalytic Reactor

Country Status (14)

Country Link
US (1) US8444939B2 (enExample)
EP (1) EP2227325B1 (enExample)
JP (1) JP5571573B2 (enExample)
KR (1) KR20100101158A (enExample)
CN (1) CN101932379B (enExample)
AU (1) AU2008339634B2 (enExample)
BR (1) BRPI0821525A8 (enExample)
CA (1) CA2708821C (enExample)
DK (1) DK2227325T3 (enExample)
EA (1) EA019964B1 (enExample)
GB (1) GB0725140D0 (enExample)
MY (1) MY157456A (enExample)
WO (1) WO2009081175A1 (enExample)
ZA (1) ZA201004401B (enExample)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2002349143A1 (en) * 2001-12-05 2003-06-17 GTL Mircosystems AG Process an apparatus for steam-methane reforming
EP2197572A1 (en) * 2007-10-02 2010-06-23 CompactGTL plc Gas-to-liquid plant using parallel units
GB0915036D0 (en) * 2009-08-28 2009-09-30 Compactgtl Plc Catalytic reaction module
JP5581028B2 (ja) 2009-09-16 2014-08-27 住友精密工業株式会社 触媒反応器
KR101031886B1 (ko) 2009-10-07 2011-05-02 한국에너지기술연구원 Ｆｔ 슬러리 기포탑 반응기의 반응열 제거용 혼합형 냉각장치
GB0918738D0 (en) * 2009-10-26 2009-12-09 Compactgtl Plc Reactor with channels
KR101297597B1 (ko) * 2011-04-19 2013-08-19 한국화학연구원 합성가스로부터 탄화수소를 제조하기 위한 반응장치
GB201107070D0 (en) * 2011-04-27 2011-06-08 Davy Process Techn Ltd FT process using can reactor
GB201112028D0 (en) * 2011-07-13 2011-08-31 Gas2 Ltd Fixed bed fischer tropsch reactor
CA2862527C (en) 2012-02-06 2021-06-29 Helbio Societe Anonyme Hydrogen And Energy Production Systems Heat integrated reformer with catalytic combustion for hydrogen production
US11607657B2 (en) 2012-02-06 2023-03-21 Helbio S.A. Heat integrated reformer with catalytic combustion for hydrogen production
CA2864532A1 (en) 2012-02-17 2013-08-22 Ceramatec, Inc. Advanced fischer tropsch system
US9162935B2 (en) 2012-02-21 2015-10-20 Ceramatec, Inc. Compact FT combined with micro-fibrous supported nano-catalyst
WO2013126341A1 (en) 2012-02-21 2013-08-29 Ceramatec, Inc. Compact fischer tropsch system with integrated primary and secondary bed temperature control
US10960372B2 (en) 2012-03-08 2021-03-30 Helbio S.A. Catalytically heated fuel processor with replaceable structured supports bearing catalyst for fuel cell
US9255746B2 (en) 2012-10-26 2016-02-09 Modine Manufacturing Company Reactor core for use in a chemical reactor, and method of making the same
GB201302301D0 (en) * 2013-02-08 2013-03-27 Process Systems Entpr Ltd Reactor and reaction method
US9676623B2 (en) 2013-03-14 2017-06-13 Velocys, Inc. Process and apparatus for conducting simultaneous endothermic and exothermic reactions
JP6376131B2 (ja) 2013-09-13 2018-08-22 株式会社Ihi リアクタ
CN106457186B (zh) * 2014-05-12 2019-12-03 尤尼威蒂恩技术有限责任公司 使用具有堆叠气流间隙的插入组件的系统和方法
KR102003429B1 (ko) * 2016-10-19 2019-07-24 주식회사 포스코건설 합성석유 제조장치 및 제조방법
US10543470B2 (en) 2017-04-28 2020-01-28 Intramicron, Inc. Reactors and methods for processes involving partial oxidation reactions
US10544371B2 (en) 2018-05-11 2020-01-28 Intramicron, Inc. Channel reactors
JP7271865B2 (ja) * 2018-05-17 2023-05-12 株式会社Ihi 反応装置
EP3599075A1 (de) 2018-07-27 2020-01-29 Siemens Aktiengesellschaft Reaktor zur durchführung einer chemischen gleichgewichtsreaktion
CN112221439A (zh) * 2020-09-09 2021-01-15 中石化宁波工程有限公司 用于微通道反应器的分布板及具有其的微通道反应器
CN113345611B (zh) * 2021-05-11 2022-12-13 哈尔滨工程大学 一种板型燃料元件多矩形流道均匀释热模拟试验装置
CN116272686B (zh) * 2023-01-03 2024-09-27 东方电气集团东方锅炉股份有限公司 一种混合流列管式固定床反应器

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1116345A (en) * 1964-06-16 1968-06-06 Marston Excelsior Ltd Improvements in or relating to chemical catalytic reactors and like process vessels in which fluids are contacted with solid materials
ZA782775B (en) * 1977-06-27 1979-05-30 Minnesota Mining & Mfg Catalytic reactor for isothermal reactions
GB2223237B (en) * 1988-07-21 1992-09-16 Shell Int Research Shut-down process for a fischer-tropsch reactor, and said reactor
GB0116894D0 (en) * 2001-07-11 2001-09-05 Accentus Plc Catalytic reactor
GB0124999D0 (en) 2001-10-18 2001-12-05 Accentus Plc Catalytic reactor
AU2002349143A1 (en) * 2001-12-05 2003-06-17 GTL Mircosystems AG Process an apparatus for steam-methane reforming
DE60307885T3 (de) * 2002-12-02 2010-12-16 Compactgtl Plc, Abingdon Katalytisches verfahren
GB0413400D0 (en) * 2004-06-16 2004-07-21 Accentus Plc Catalytic plant and process
GB0501731D0 (en) 2005-01-31 2005-03-02 Accentus Plc Catalytic reactor
GB0504622D0 (en) * 2005-03-05 2005-04-13 Accentus Plc Catalytic reactors
MY147151A (en) * 2006-05-08 2012-11-14 Compactgtl Ltd Catalyst reactor comprising first and second catalyst

Also Published As

Publication number Publication date
BRPI0821525A8 (pt) 2016-03-22
CN101932379A (zh) 2010-12-29
EP2227325A1 (en) 2010-09-15
JP5571573B2 (ja) 2014-08-13
CN101932379B (zh) 2014-06-04
ZA201004401B (en) 2011-08-31
KR20100101158A (ko) 2010-09-16
BRPI0821525A2 (pt) 2015-06-16
EA019964B1 (ru) 2014-07-30
JP2011508043A (ja) 2011-03-10
CA2708821A1 (en) 2009-07-02
MY157456A (en) 2016-06-15
US20100324158A1 (en) 2010-12-23
WO2009081175A1 (en) 2009-07-02
AU2008339634B2 (en) 2012-12-06
DK2227325T3 (da) 2014-06-30
CA2708821C (en) 2015-12-29
EP2227325B1 (en) 2015-01-07
AU2008339634A1 (en) 2009-07-02
US8444939B2 (en) 2013-05-21
EA201070797A1 (ru) 2010-12-30

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Legal Events

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AT Applications terminated before publication under section 16(1)