FR3127557B1 - Procédé de givrage du dioxyde de carbone contenu dans du méthane liquide - Google Patents

Procédé de givrage du dioxyde de carbone contenu dans du méthane liquide Download PDF

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Publication number
FR3127557B1
FR3127557B1 FR2110231A FR2110231A FR3127557B1 FR 3127557 B1 FR3127557 B1 FR 3127557B1 FR 2110231 A FR2110231 A FR 2110231A FR 2110231 A FR2110231 A FR 2110231A FR 3127557 B1 FR3127557 B1 FR 3127557B1
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Prior art keywords
carbon dioxide
phase
liquid methane
methane
liquid
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FR2110231A
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FR3127557A1 (fr
Inventor
Denis Clodic
Joseph Toubassy
Mauro Riva
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Cryo Pur SAS
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Cryo Pur SAS
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Priority to FR2110231A priority Critical patent/FR3127557B1/fr
Priority to PCT/IB2022/059164 priority patent/WO2023052983A1/fr
Publication of FR3127557A1 publication Critical patent/FR3127557A1/fr
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/06Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation
    • F25J3/0605Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the feed stream
    • F25J3/061Natural gas or substitute natural gas
    • F25J3/0615Liquefied natural gas
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/06Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation
    • F25J3/063Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the separated product stream
    • F25J3/0635Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the separated product stream separation of CnHm with 1 carbon atom or more
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/06Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation
    • F25J3/063Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the separated product stream
    • F25J3/067Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the separated product stream separation of carbon dioxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/12Special parameters characterising the filtering material
    • B01D2239/1208Porosity
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/12Special parameters characterising the filtering material
    • B01D2239/1216Pore size
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00Processes or apparatus using other separation and/or other processing means
    • F25J2205/20Processes or apparatus using other separation and/or other processing means using solidification of components
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00Processes or apparatus using other separation and/or other processing means
    • F25J2205/24Processes or apparatus using other separation and/or other processing means using regenerators, cold accumulators or reversible heat exchangers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00Processes or apparatus using other separation and/or other processing means
    • F25J2205/40Processes or apparatus using other separation and/or other processing means using hybrid system, i.e. combining cryogenic and non-cryogenic separation techniques
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00Processes or apparatus using other separation and/or other processing means
    • F25J2205/84Processes or apparatus using other separation and/or other processing means using filter
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2210/00Processes characterised by the type or other details of the feed stream
    • F25J2210/66Landfill or fermentation off-gas, e.g. "Bio-gas"
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2220/00Processes or apparatus involving steps for the removal of impurities
    • F25J2220/60Separating impurities from natural gas, e.g. mercury, cyclic hydrocarbons
    • F25J2220/66Separating acid gases, e.g. CO2, SO2, H2S or RSH
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2235/00Processes or apparatus involving steps for increasing the pressure or for conveying of liquid process streams
    • F25J2235/60Processes or apparatus involving steps for increasing the pressure or for conveying of liquid process streams the fluid being (a mixture of) hydrocarbons

Abstract

Procédé d’extraction du dioxyde de carbone contenu dans du méthane liquide, comprenant : - une étape de détente d’un méthane liquide dont la teneur en dioxyde de carbone est supérieure à 280 parts par million en volume, la détente étant effectuée d’une pression supérieure à 6 bars jusqu’à une pression de 1 bar, la température du méthane liquide ainsi détendu étant de -161,5°C environ, - une étape de passage de la phase gaz de méthane et de la phase solide de dioxyde de carbone dans un premier séparateur (20) liquide-solide-gaz, avec extraction du dioxyde de carbone solide par filtration, et séparation du méthane gazeux, pour obtenir une première phase de méthane liquide, partiellement décarbonée, - une étape de transfert de cette première phase de méthane liquide vers un deuxième séparateur solide-liquide, la première phase de méthane liquide étant à une température de -161°C, le deuxième séparateur étant un échangeur dont la température est inférieure à -170°C, du dioxyde de carbone se déposant dans le deuxième échangeur, pour former une deuxième phase de méthane liquide, la concentration en dioxyde de carbone dans cette deuxième phase de méthane liquide à -170°C étant inférieure à 200 ppmv. Figure 1
FR2110231A 2021-09-28 2021-09-28 Procédé de givrage du dioxyde de carbone contenu dans du méthane liquide Active FR3127557B1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
FR2110231A FR3127557B1 (fr) 2021-09-28 2021-09-28 Procédé de givrage du dioxyde de carbone contenu dans du méthane liquide
PCT/IB2022/059164 WO2023052983A1 (fr) 2021-09-28 2022-09-27 Procédé de givrage du dioxyde de carbone contenu dans du méthane liquide

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR2110231A FR3127557B1 (fr) 2021-09-28 2021-09-28 Procédé de givrage du dioxyde de carbone contenu dans du méthane liquide
FR2110231 2021-09-28

Publications (2)

Publication Number Publication Date
FR3127557A1 FR3127557A1 (fr) 2023-03-31
FR3127557B1 true FR3127557B1 (fr) 2024-01-26

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FR2110231A Active FR3127557B1 (fr) 2021-09-28 2021-09-28 Procédé de givrage du dioxyde de carbone contenu dans du méthane liquide

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WO (1) WO2023052983A1 (fr)

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL291145A (fr) 1962-04-05
GB0015123D0 (en) * 2000-06-20 2000-08-09 Air Prod & Chem Process and apparatus for removal of volatile compounds from process gases
US6581409B2 (en) * 2001-05-04 2003-06-24 Bechtel Bwxt Idaho, Llc Apparatus for the liquefaction of natural gas and methods related to same
EP2475943A4 (fr) 2009-09-09 2013-04-03 Exxonmobil Upstream Res Co Système cryogénique pour éliminer des gaz acides d'un courant gazeux d'hydrocarbures
US20160109177A1 (en) * 2014-10-16 2016-04-21 General Electric Company System and method for natural gas liquefaction
US10551120B2 (en) * 2017-02-06 2020-02-04 Hall Labs Llc Method for condensing a CO2 vapor stream beyond the frost point

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FR3127557A1 (fr) 2023-03-31
WO2023052983A1 (fr) 2023-04-06

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