FR3121551B1 - Procede de dissolution d’un materiau d’electrode positive - Google Patents

Procede de dissolution d’un materiau d’electrode positive Download PDF

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Publication number
FR3121551B1
FR3121551B1 FR2103264A FR2103264A FR3121551B1 FR 3121551 B1 FR3121551 B1 FR 3121551B1 FR 2103264 A FR2103264 A FR 2103264A FR 2103264 A FR2103264 A FR 2103264A FR 3121551 B1 FR3121551 B1 FR 3121551B1
Authority
FR
France
Prior art keywords
positive electrode
electrode material
dissolving
lithium
nickel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR2103264A
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English (en)
Other versions
FR3121551A1 (fr
Inventor
Emmanuel Billy
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Orano SA
Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
Original Assignee
Commissariat a lEnergie Atomique CEA
Orano SA
Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Commissariat a lEnergie Atomique CEA, Orano SA, Commissariat a lEnergie Atomique et aux Energies Alternatives CEA filed Critical Commissariat a lEnergie Atomique CEA
Priority to FR2103264A priority Critical patent/FR3121551B1/fr
Priority to JP2023559775A priority patent/JP2024512988A/ja
Priority to PCT/FR2022/050578 priority patent/WO2022208015A1/fr
Priority to CA3207772A priority patent/CA3207772A1/fr
Priority to KR1020237033069A priority patent/KR20230161987A/ko
Priority to EP22719315.8A priority patent/EP4314362A1/fr
Publication of FR3121551A1 publication Critical patent/FR3121551A1/fr
Application granted granted Critical
Publication of FR3121551B1 publication Critical patent/FR3121551B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/04Extraction of metal compounds from ores or concentrates by wet processes by leaching
    • C22B3/06Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic acid solutions, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions
    • C22B3/08Sulfuric acid, other sulfurated acids or salts thereof
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B23/00Obtaining nickel or cobalt
    • C22B23/04Obtaining nickel or cobalt by wet processes
    • C22B23/0453Treatment or purification of solutions, e.g. obtained by leaching
    • C22B23/0461Treatment or purification of solutions, e.g. obtained by leaching by chemical methods
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B26/00Obtaining alkali, alkaline earth metals or magnesium
    • C22B26/10Obtaining alkali metals
    • C22B26/12Obtaining lithium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/44Treatment or purification of solutions, e.g. obtained by leaching by chemical processes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/54Reclaiming serviceable parts of waste accumulators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/84Recycling of batteries or fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Inorganic Chemistry (AREA)
  • Electrochemistry (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)

Abstract

Procédé de dissolution d’un matériau d’électrode positive d’une batterie comportant une étape au cours de laquelle on plonge le matériau d’électrode positive, comportant du lithium et éventuellement du cobalt et/ou du nickel, dans une solution acide à un pH compris entre 0 et 4, la solution acide contenant soit des ions manganèse soit du peroxyde d’hydrogène, moyennant quoi on met en solution le lithium et éventuellement le cobalt et/ou le nickel et, le cas échéant, on fait précipiter sélectivement les ions manganèse sous forme d’oxyhydroxyde de manganèse. Figure pour l’abrégé : 1
FR2103264A 2021-03-30 2021-03-30 Procede de dissolution d’un materiau d’electrode positive Active FR3121551B1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
FR2103264A FR3121551B1 (fr) 2021-03-30 2021-03-30 Procede de dissolution d’un materiau d’electrode positive
JP2023559775A JP2024512988A (ja) 2021-03-30 2022-03-28 正極材料の溶解方法
PCT/FR2022/050578 WO2022208015A1 (fr) 2021-03-30 2022-03-28 Procede de dissolution d'un materiau d'electrode positive
CA3207772A CA3207772A1 (fr) 2021-03-30 2022-03-28 Procede de dissolution d'un materiau d'electrode positive
KR1020237033069A KR20230161987A (ko) 2021-03-30 2022-03-28 양극 재료를 용해시키기 위한 방법
EP22719315.8A EP4314362A1 (fr) 2021-03-30 2022-03-28 Procédé de dissolution d'un matériau d'electrode positive

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR2103264 2021-03-30
FR2103264A FR3121551B1 (fr) 2021-03-30 2021-03-30 Procede de dissolution d’un materiau d’electrode positive

Publications (2)

Publication Number Publication Date
FR3121551A1 FR3121551A1 (fr) 2022-10-07
FR3121551B1 true FR3121551B1 (fr) 2023-06-02

Family

ID=75954053

Family Applications (1)

Application Number Title Priority Date Filing Date
FR2103264A Active FR3121551B1 (fr) 2021-03-30 2021-03-30 Procede de dissolution d’un materiau d’electrode positive

Country Status (6)

Country Link
EP (1) EP4314362A1 (fr)
JP (1) JP2024512988A (fr)
KR (1) KR20230161987A (fr)
CA (1) CA3207772A1 (fr)
FR (1) FR3121551B1 (fr)
WO (1) WO2022208015A1 (fr)

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2868603B1 (fr) 2004-04-06 2006-07-14 Recupyl Sa Sa Procede de recyclage en melange de piles et batteries a base d'anode en lithium
FR2976295B1 (fr) 2011-06-07 2013-07-05 Sarp Ind Procede de separation de metaux a partir de batteries contenant du lithium
WO2016052568A1 (fr) * 2014-09-30 2016-04-07 Jx金属株式会社 Procédé de lixiviation pour déchet de batterie lithium-ion et procédé de récupération de métal à partir d'un déchet de batterie lithium-ion
FR3034104B1 (fr) 2015-03-26 2019-05-31 Commissariat A L'energie Atomique Et Aux Energies Alternatives Procede de dissolution d'un oxyde metallique en presence d'un metal reducteur.
CN108002408B (zh) 2016-10-31 2021-06-04 湖南金源新材料股份有限公司 电池废料制备硫酸镍、锰、锂、钴及四氧化三钴的方法

Also Published As

Publication number Publication date
KR20230161987A (ko) 2023-11-28
FR3121551A1 (fr) 2022-10-07
JP2024512988A (ja) 2024-03-21
EP4314362A1 (fr) 2024-02-07
WO2022208015A1 (fr) 2022-10-06
CA3207772A1 (fr) 2022-10-06

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