FR3116107B1 - Installation et procédé de production d’hydrogène à température cryogénique - Google Patents

Installation et procédé de production d’hydrogène à température cryogénique Download PDF

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Publication number
FR3116107B1
FR3116107B1 FR2011491A FR2011491A FR3116107B1 FR 3116107 B1 FR3116107 B1 FR 3116107B1 FR 2011491 A FR2011491 A FR 2011491A FR 2011491 A FR2011491 A FR 2011491A FR 3116107 B1 FR3116107 B1 FR 3116107B1
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Prior art keywords
hydrogen
installation
flow
cooled
expansion
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FR2011491A
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FR3116107A1 (fr
Inventor
Pierre Barjhoux
Pierre Crespi
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Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Original Assignee
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
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Application filed by Air Liquide SA, LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude filed Critical Air Liquide SA
Priority to FR2011491A priority Critical patent/FR3116107B1/fr
Priority to KR1020237017377A priority patent/KR20230104898A/ko
Priority to US18/036,127 priority patent/US20230408189A1/en
Priority to EP21798334.5A priority patent/EP4241028A1/fr
Priority to JP2023521353A priority patent/JP2023548753A/ja
Priority to PCT/EP2021/079034 priority patent/WO2022096262A1/fr
Publication of FR3116107A1 publication Critical patent/FR3116107A1/fr
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/0002Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
    • F25J1/0005Light or noble gases
    • F25J1/001Hydrogen
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/02Hydrogen or oxygen
    • C25B1/04Hydrogen or oxygen by electrolysis of water
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/0002Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
    • F25J1/0012Primary atmospheric gases, e.g. air
    • F25J1/0017Oxygen
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    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/003Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
    • F25J1/0032Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
    • F25J1/0035Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by gas expansion with extraction of work
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    • F25J1/0047Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle
    • F25J1/005Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by expansion of a gaseous refrigerant stream with extraction of work
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    • F25J1/0072Nitrogen
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    • F25J2210/62Liquefied natural gas [LNG]; Natural gas liquids [NGL]; Liquefied petroleum gas [LPG]
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    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2230/00Processes or apparatus involving steps for increasing the pressure of gaseous process streams
    • F25J2230/08Cold compressor, i.e. suction of the gas at cryogenic temperature and generally without afterstage-cooler
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2230/00Processes or apparatus involving steps for increasing the pressure of gaseous process streams
    • F25J2230/20Integrated compressor and process expander; Gear box arrangement; Multiple compressors on a common shaft
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2230/00Processes or apparatus involving steps for increasing the pressure of gaseous process streams
    • F25J2230/30Compression of the feed stream
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00Refrigeration techniques used
    • F25J2270/14External refrigeration with work-producing gas expansion loop
    • F25J2270/16External refrigeration with work-producing gas expansion loop with mutliple gas expansion loops of the same refrigerant
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Emergency Medicine (AREA)
  • Health & Medical Sciences (AREA)
  • Separation By Low-Temperature Treatments (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

Installation de production d’hydrogène à température cryogénique, notamment d’hydrogène liquéfié, comprenant un électrolyseur (2) muni d’une sortie d’oxygène et d’une sortie d’hydrogène, un circuit (3) d’hydrogène à refroidir comprenant une extrémité amont reliée à la sortie d’hydrogène et une extrémité aval destinée à être reliée à un organe (23) de collecte de l’hydrogène refroidi et/ou liquéfié, l’installation (1) comprenant un ensemble d’échangeur(s) (4, 5, 6, 7, 8) de chaleur en échange thermique avec le circuit (3) d’hydrogène à refroidir, l’installation (1) comprenant au moins un dispositif (9, 10) de refroidissement en échange thermique avec au moins une partie de l’ensemble d’échangeur(s) (4, 5, 6, 7, 8) de chaleur, le circuit (3) d’hydrogène à refroidir comprenant un système (18) de détente du flux d’hydrogène et au moins un compresseur (19) de l’hydrogène en amont du système (18) de détente du flux d’hydrogène, le système (18) de détente du flux d’hydrogène comprenant au moins une turbine (18) de détente, caractérisé en ce que ladite au moins une turbine (18) de détente et ledit au moins un compresseur (19) sont accouplés à un même arbre (20) rotatif pour transférer du travail de détente du flux d’hydrogène sous pression au compresseur (19) pour comprimer le flux d’hydrogène en amont de la turbine Figure de l’abrégé : Fig. 1
FR2011491A 2020-11-09 2020-11-09 Installation et procédé de production d’hydrogène à température cryogénique Active FR3116107B1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
FR2011491A FR3116107B1 (fr) 2020-11-09 2020-11-09 Installation et procédé de production d’hydrogène à température cryogénique
KR1020237017377A KR20230104898A (ko) 2020-11-09 2021-10-20 극저온에서 수소를 생성하기 위한 설비 및 방법
US18/036,127 US20230408189A1 (en) 2020-11-09 2021-10-20 Plant and method for producing hydrogen at cryogenic temperature
EP21798334.5A EP4241028A1 (fr) 2020-11-09 2021-10-20 Installation et procédé de production d'hydrogène à température cryogénique
JP2023521353A JP2023548753A (ja) 2020-11-09 2021-10-20 極低温で水素を製造するためのプラント及び方法
PCT/EP2021/079034 WO2022096262A1 (fr) 2020-11-09 2021-10-20 Installation et procédé de production d'hydrogène à température cryogénique

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FR2011491 2020-11-09
FR2011491A FR3116107B1 (fr) 2020-11-09 2020-11-09 Installation et procédé de production d’hydrogène à température cryogénique

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FR3116107B1 true FR3116107B1 (fr) 2022-12-16

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EP (1) EP4241028A1 (fr)
JP (1) JP2023548753A (fr)
KR (1) KR20230104898A (fr)
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WO (1) WO2022096262A1 (fr)

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US20220205714A1 (en) * 2020-12-28 2022-06-30 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Method for efficient cold recovery in o2-h2 combustion turbine power generation system
FR3145032A1 (fr) * 2023-01-16 2024-07-19 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Installation et procédé de liquéfaction d'un flux de fluide

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GB2142423B (en) 1983-03-10 1986-08-06 Smith Dr Eric Murray Production of liquid hydrogen
FR2775512B1 (fr) * 1998-03-02 2000-04-14 Air Liquide Poste et procede de distribution d'un gaz detendu
JP2004210597A (ja) * 2003-01-06 2004-07-29 Toshiba Corp 排熱利用水素・酸素システムおよび液体水素の製造方法
JP2007205667A (ja) * 2006-02-03 2007-08-16 Mitsubishi Heavy Ind Ltd 液化水素製造装置
DE102014212718A1 (de) * 2014-07-01 2016-01-07 Siemens Aktiengesellschaft Verfahren zum Betreiben einer Elektrolyseanlage sowie Elektrolyseanlage
EP3162871A1 (fr) * 2015-10-27 2017-05-03 Linde Aktiengesellschaft Cycle de réfrigération pour mélange hydrogène-néon pour refroidissement et liquéfaction d'hydrogène à grande échelle
CN107014151B (zh) * 2017-06-01 2023-04-11 四川蜀道装备科技股份有限公司 一种氢气液化的装置及方法

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WO2022096262A1 (fr) 2022-05-12
FR3116107A1 (fr) 2022-05-13
EP4241028A1 (fr) 2023-09-13
JP2023548753A (ja) 2023-11-21
US20230408189A1 (en) 2023-12-21

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