FR3110168B1 - Procédé pour produire des polymères à base de fluorure de vinylidène thermiquement stables et hautement cristallins - Google Patents
Procédé pour produire des polymères à base de fluorure de vinylidène thermiquement stables et hautement cristallins Download PDFInfo
- Publication number
- FR3110168B1 FR3110168B1 FR2004832A FR2004832A FR3110168B1 FR 3110168 B1 FR3110168 B1 FR 3110168B1 FR 2004832 A FR2004832 A FR 2004832A FR 2004832 A FR2004832 A FR 2004832A FR 3110168 B1 FR3110168 B1 FR 3110168B1
- Authority
- FR
- France
- Prior art keywords
- vinylidene fluoride
- thermally stable
- highly crystalline
- fluoride polymers
- producing thermally
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000000034 method Methods 0.000 title abstract 3
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 title abstract 2
- 229920000642 polymer Polymers 0.000 title 1
- 150000001768 cations Chemical class 0.000 abstract 4
- 239000000178 monomer Substances 0.000 abstract 3
- 238000006116 polymerization reaction Methods 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 125000003709 fluoroalkyl group Chemical group 0.000 abstract 1
- 239000007800 oxidant agent Substances 0.000 abstract 1
- 239000003505 polymerization initiator Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/18—Monomers containing fluorine
- C08F14/22—Vinylidene fluoride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F114/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F114/18—Monomers containing fluorine
- C08F114/22—Vinylidene fluoride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/18—Monomers containing fluorine
- C08F14/28—Hexafluoropropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F16/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
- C08F16/12—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
- C08F16/14—Monomers containing only one unsaturated aliphatic radical
- C08F16/24—Monomers containing halogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
- C08F214/22—Vinylidene fluoride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
- C08F214/22—Vinylidene fluoride
- C08F214/222—Vinylidene fluoride with fluorinated vinyl ethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/46—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals
- C08F4/463—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals selected from sodium or potassium
Abstract
L'invention concerne un procédé de polymérisation d'au moins un monomère comprenant un monomère de fluorure de vinylidène, le procédé comprenant la mise en contact de l'au moins un monomère avec un amorceur de polymérisation et un agent oxydant, l'amorceur de polymérisation répondant à la formule (I) : (RfSO2 -)xMx + dans laquelle Rf est un groupement fluoroalkyle comprenant de 1 à 3 atomes de carbone ; et Mx+ est choisi parmi un cation monovalent, ou un cation divalent, ou un cation trivalent, ou un cation tétravalent. Figure pour l’abrégé : Fig. 1
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR2004832A FR3110168B1 (fr) | 2020-05-15 | 2020-05-15 | Procédé pour produire des polymères à base de fluorure de vinylidène thermiquement stables et hautement cristallins |
US17/998,797 US20230203213A1 (en) | 2020-05-15 | 2021-05-14 | Method for making highly crystalline and thermally stable vinylidene fluoride-based polymers |
CN202180035214.0A CN115605516A (zh) | 2020-05-15 | 2021-05-14 | 制备高结晶和热稳定的偏氟乙烯基聚合物的方法 |
JP2022569130A JP2023525157A (ja) | 2020-05-15 | 2021-05-14 | 高結晶性かつ熱安定性の高いフッ化ビニリデン系ポリマーの製造方法 |
PCT/EP2021/062887 WO2021229081A1 (fr) | 2020-05-15 | 2021-05-14 | Procédé de fabrication de polymères à base de fluorure de vinylidène hautement cristallins et thermiquement stables |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR2004832A FR3110168B1 (fr) | 2020-05-15 | 2020-05-15 | Procédé pour produire des polymères à base de fluorure de vinylidène thermiquement stables et hautement cristallins |
FR2004832 | 2020-05-15 |
Publications (2)
Publication Number | Publication Date |
---|---|
FR3110168A1 FR3110168A1 (fr) | 2021-11-19 |
FR3110168B1 true FR3110168B1 (fr) | 2022-08-26 |
Family
ID=71894990
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR2004832A Active FR3110168B1 (fr) | 2020-05-15 | 2020-05-15 | Procédé pour produire des polymères à base de fluorure de vinylidène thermiquement stables et hautement cristallins |
Country Status (5)
Country | Link |
---|---|
US (1) | US20230203213A1 (fr) |
JP (1) | JP2023525157A (fr) |
CN (1) | CN115605516A (fr) |
FR (1) | FR3110168B1 (fr) |
WO (1) | WO2021229081A1 (fr) |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5285002A (en) | 1993-03-23 | 1994-02-08 | Minnesota Mining And Manufacturing Company | Fluorine-containing polymers and preparation and use thereof |
DE69610099T2 (de) * | 1995-06-30 | 2001-05-10 | Du Pont | Verfahren zur herstellung von fluor-enthaltenden polymeren |
US5639837A (en) | 1996-06-04 | 1997-06-17 | E. I. Du Pont De Nemours And Company | Process for making fluoropolymers |
EP1392744B1 (fr) * | 2001-05-02 | 2008-07-09 | 3M Innovative Properties Company | Procede de polymerisation par emulsion aqueuse exempte d'emulsifiant permettant de produire des fluoropolymeres |
US7754810B2 (en) | 2007-11-09 | 2010-07-13 | Dupont Performance Elastomers | Process for producing fluoropolymers |
US20090124755A1 (en) | 2007-11-09 | 2009-05-14 | Dupont Performance Elastomers L.L.C. | Process for producing fluoropolymers |
JP5986102B2 (ja) | 2010-12-17 | 2016-09-06 | スリーエム イノベイティブ プロパティズ カンパニー | マイクロエマルジョン及びマイクロエマルジョンを用いて作製されたフルオロポリマー |
WO2012082551A2 (fr) * | 2010-12-17 | 2012-06-21 | 3M Innovative Properties Company | Monomères acides sulfiniques partiellement fluorés et leurs sels |
WO2012083107A2 (fr) | 2010-12-17 | 2012-06-21 | 3M Innovative Properties Company | Polymère fluoré comprenant une molécule contenant du sulfinate |
-
2020
- 2020-05-15 FR FR2004832A patent/FR3110168B1/fr active Active
-
2021
- 2021-05-14 JP JP2022569130A patent/JP2023525157A/ja active Pending
- 2021-05-14 US US17/998,797 patent/US20230203213A1/en active Pending
- 2021-05-14 WO PCT/EP2021/062887 patent/WO2021229081A1/fr active Application Filing
- 2021-05-14 CN CN202180035214.0A patent/CN115605516A/zh active Pending
Also Published As
Publication number | Publication date |
---|---|
CN115605516A (zh) | 2023-01-13 |
US20230203213A1 (en) | 2023-06-29 |
WO2021229081A1 (fr) | 2021-11-18 |
FR3110168A1 (fr) | 2021-11-19 |
JP2023525157A (ja) | 2023-06-14 |
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Legal Events
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PLFP | Fee payment |
Year of fee payment: 2 |
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PLSC | Publication of the preliminary search report |
Effective date: 20211119 |
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Year of fee payment: 5 |