FR3089979B1 - Polymères fluorés électroactifs comprenant des groupements polarisables - Google Patents
Polymères fluorés électroactifs comprenant des groupements polarisables Download PDFInfo
- Publication number
- FR3089979B1 FR3089979B1 FR1873054A FR1873054A FR3089979B1 FR 3089979 B1 FR3089979 B1 FR 3089979B1 FR 1873054 A FR1873054 A FR 1873054A FR 1873054 A FR1873054 A FR 1873054A FR 3089979 B1 FR3089979 B1 FR 3089979B1
- Authority
- FR
- France
- Prior art keywords
- copolymer
- group
- formula
- carbon atoms
- fluorinated polymers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 229920002313 fluoropolymer Polymers 0.000 title 1
- 229920001577 copolymer Polymers 0.000 abstract 5
- 125000004432 carbon atom Chemical group C* 0.000 abstract 3
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 230000004927 fusion Effects 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 125000004430 oxygen atom Chemical group O* 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 125000004434 sulfur atom Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
- C08F214/22—Vinylidene fluoride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
- C08F214/24—Trifluorochloroethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/26—Removing halogen atoms or halogen-containing groups from the molecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08L27/16—Homopolymers or copolymers or vinylidene fluoride
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/52—Electrically conductive inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C09D127/16—Homopolymers or copolymers of vinylidene fluoride
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K10/00—Organic devices specially adapted for rectifying, amplifying, oscillating or switching; Organic capacitors or resistors having potential barriers
- H10K10/40—Organic transistors
- H10K10/46—Field-effect transistors, e.g. organic thin-film transistors [OTFT]
- H10K10/462—Insulated gate field-effect transistors [IGFETs]
- H10K10/484—Insulated gate field-effect transistors [IGFETs] characterised by the channel regions
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/10—Organic polymers or oligomers
- H10K85/141—Organic polymers or oligomers comprising aliphatic or olefinic chains, e.g. poly N-vinylcarbazol, PVC or PTFE
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/10—Organic polymers or oligomers
- H10K85/151—Copolymers
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N30/00—Piezoelectric or electrostrictive devices
- H10N30/01—Manufacture or treatment
- H10N30/07—Forming of piezoelectric or electrostrictive parts or bodies on an electrical element or another base
- H10N30/074—Forming of piezoelectric or electrostrictive parts or bodies on an electrical element or another base by depositing piezoelectric or electrostrictive layers, e.g. aerosol or screen printing
- H10N30/077—Forming of piezoelectric or electrostrictive parts or bodies on an electrical element or another base by depositing piezoelectric or electrostrictive layers, e.g. aerosol or screen printing by liquid phase deposition
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N30/00—Piezoelectric or electrostrictive devices
- H10N30/80—Constructional details
- H10N30/85—Piezoelectric or electrostrictive active materials
- H10N30/857—Macromolecular compositions
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
- C08F214/182—Monomers containing fluorine not covered by the groups C08F214/20 - C08F214/28
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
- C08F2800/10—Copolymer characterised by the proportions of the comonomers expressed as molar percentages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2810/00—Chemical modification of a polymer
- C08F2810/50—Chemical modification of a polymer wherein the polymer is a copolymer and the modification is taking place only on one or more of the monomers present in minority
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Manufacturing & Machinery (AREA)
- General Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Paints Or Removers (AREA)
Abstract
La présente invention concerne un copolymère comprenant des unités fluorées de formule (I) : (I) -CX1X2-CX3X4- dans laquelle chacun des X1, X2, X3 et X4 est indépendamment choisi parmi H, F et des groupements alkyles comprenant de 1 à 3 atomes de carbone qui sont optionnellement partiellement ou complétement fluorés ; des unités de formule (III) : (III) -CXAXB-CXCZ- dans laquelle chacun des XA, XB et XC est indépendamment choisi parmi H, F et des groupements alkyles comprenant de 1 à 3 atomes de carbone qui sont optionnellement partiellement ou complétement fluorés, et Z étant un groupement polarisable de formule -Y-Ar-R ; Y représentant un atome O, ou un atome S, ou un groupement NH, Ar représentant un groupement aryle, de préférence un groupement phényle, et R étant un groupement monodenté ou bidenté comprenant de 1 à 30 atomes de carbone ;et le copolymère ayant une enthalpie de fusion supérieure ou égale à 5 J/g. La présente invention concerne également un procédé de préparation de ce copolymère, une composition comprenant ce copolymère, ainsi qu’une encre et un film obtenus à partir dudit copolymère. Figure pour l’abrégé : Fig. 4.
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1873054A FR3089979B1 (fr) | 2018-12-17 | 2018-12-17 | Polymères fluorés électroactifs comprenant des groupements polarisables |
KR1020217022420A KR20210103531A (ko) | 2018-12-17 | 2019-12-16 | 분극성 기를 포함하는 전기활성 플루오르화된 폴리머 |
EP19845702.0A EP3900067A1 (fr) | 2018-12-17 | 2019-12-16 | Polymères fluorés électroactifs comprenant des groupements polarisables |
TW108146031A TW202035476A (zh) | 2018-12-17 | 2019-12-16 | 包含可極化基團的電活性氟聚合物 |
US17/414,459 US20220073663A1 (en) | 2018-12-17 | 2019-12-16 | Electroactive fluoropolymers comprising polarizable groups |
PCT/FR2019/053075 WO2020128266A1 (fr) | 2018-12-17 | 2019-12-16 | Polymères fluorés électroactifs comprenant des groupements polarisables |
JP2021534696A JP2022514267A (ja) | 2018-12-17 | 2019-12-16 | 分極性基を含む電気活性フルオロポリマー |
CN201980091721.9A CN113412545A (zh) | 2018-12-17 | 2019-12-16 | 包含可极化基团的电活性氟化聚合物 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1873054A FR3089979B1 (fr) | 2018-12-17 | 2018-12-17 | Polymères fluorés électroactifs comprenant des groupements polarisables |
Publications (2)
Publication Number | Publication Date |
---|---|
FR3089979A1 FR3089979A1 (fr) | 2020-06-19 |
FR3089979B1 true FR3089979B1 (fr) | 2021-11-05 |
Family
ID=66286498
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR1873054A Active FR3089979B1 (fr) | 2018-12-17 | 2018-12-17 | Polymères fluorés électroactifs comprenant des groupements polarisables |
Country Status (8)
Country | Link |
---|---|
US (1) | US20220073663A1 (fr) |
EP (1) | EP3900067A1 (fr) |
JP (1) | JP2022514267A (fr) |
KR (1) | KR20210103531A (fr) |
CN (1) | CN113412545A (fr) |
FR (1) | FR3089979B1 (fr) |
TW (1) | TW202035476A (fr) |
WO (1) | WO2020128266A1 (fr) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114621382B (zh) * | 2022-02-14 | 2022-11-29 | 上海交通大学 | 电卡制冷用高熵绝缘聚合物及其制备方法 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2843398B1 (fr) * | 2002-08-09 | 2007-04-27 | Commissariat Energie Atomique | Polymeres fluores, membranes preparees a partir de ceux-ci et dispositif de pile a combustible comprenant ces membranes |
JP4506166B2 (ja) * | 2003-12-12 | 2010-07-21 | コニカミノルタホールディングス株式会社 | 有機エレクトロルミネッセンス素子用単量体、有機エレクトロルミネッセンス素子用重合体、有機エレクトロルミネッセンス素子、表示装置及び照明装置 |
US7402264B2 (en) | 2004-03-09 | 2008-07-22 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Sensing/actuating materials made from carbon nanotube polymer composites and methods for making same |
FR2896250B1 (fr) | 2006-01-13 | 2012-08-17 | Arkema | Agent d'extrusion a base de pvdf |
EP2065409B1 (fr) * | 2006-09-28 | 2015-04-01 | Asahi Glass Company, Limited | Nouveau polymère fluoré |
FR2944285B1 (fr) | 2009-04-09 | 2011-11-25 | Francois Bauer | Procede de fabrication de terpolymeres a base de vdf, trfe et cfe ou ctfe |
FR3004718B1 (fr) | 2013-04-18 | 2016-05-06 | Inst Nat Sciences Appliquees Lyon | Procede de fabrication de materiau composite polarisable sous l'action d'un faible champ electrique |
FR3031519B1 (fr) * | 2015-01-14 | 2016-12-30 | Arkema France | Composition a base de terpolymere electroactif |
WO2017021783A2 (fr) * | 2015-08-05 | 2017-02-09 | Thin Film Electronics Asa | Copolymère de pvdf-trfe ayant des propriétes ferroélectriques améliorées, procédés de fabrication d'un copolymère de pvdf-trfe ayant des propriétes ferroélectriques améliorées et procédés de changement du groupe terminal d'un copolymère de pvdf-trfe |
-
2018
- 2018-12-17 FR FR1873054A patent/FR3089979B1/fr active Active
-
2019
- 2019-12-16 WO PCT/FR2019/053075 patent/WO2020128266A1/fr unknown
- 2019-12-16 EP EP19845702.0A patent/EP3900067A1/fr active Pending
- 2019-12-16 US US17/414,459 patent/US20220073663A1/en active Pending
- 2019-12-16 TW TW108146031A patent/TW202035476A/zh unknown
- 2019-12-16 KR KR1020217022420A patent/KR20210103531A/ko active Search and Examination
- 2019-12-16 CN CN201980091721.9A patent/CN113412545A/zh active Pending
- 2019-12-16 JP JP2021534696A patent/JP2022514267A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
US20220073663A1 (en) | 2022-03-10 |
JP2022514267A (ja) | 2022-02-10 |
TW202035476A (zh) | 2020-10-01 |
WO2020128266A1 (fr) | 2020-06-25 |
KR20210103531A (ko) | 2021-08-23 |
CN113412545A (zh) | 2021-09-17 |
FR3089979A1 (fr) | 2020-06-19 |
EP3900067A1 (fr) | 2021-10-27 |
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