FR3086946B1 - Procede ameliore pour la fabrication de polyamides transparents - Google Patents
Procede ameliore pour la fabrication de polyamides transparents Download PDFInfo
- Publication number
- FR3086946B1 FR3086946B1 FR1859173A FR1859173A FR3086946B1 FR 3086946 B1 FR3086946 B1 FR 3086946B1 FR 1859173 A FR1859173 A FR 1859173A FR 1859173 A FR1859173 A FR 1859173A FR 3086946 B1 FR3086946 B1 FR 3086946B1
- Authority
- FR
- France
- Prior art keywords
- isomers
- fractions
- cycloaliphatic diamine
- manufacture
- diamine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000004952 Polyamide Substances 0.000 title abstract 5
- 229920002647 polyamide Polymers 0.000 title abstract 5
- 238000004519 manufacturing process Methods 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- 150000004985 diamines Chemical class 0.000 abstract 5
- 239000000203 mixture Substances 0.000 abstract 3
- SYSQUGFVNFXIIT-UHFFFAOYSA-N n-[4-(1,3-benzoxazol-2-yl)phenyl]-4-nitrobenzenesulfonamide Chemical class C1=CC([N+](=O)[O-])=CC=C1S(=O)(=O)NC1=CC=C(C=2OC3=CC=CC=C3N=2)C=C1 SYSQUGFVNFXIIT-UHFFFAOYSA-N 0.000 abstract 3
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 238000009472 formulation Methods 0.000 abstract 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000002947 alkylene group Chemical group 0.000 abstract 1
- 125000003277 amino group Chemical group 0.000 abstract 1
- 238000004458 analytical method Methods 0.000 abstract 1
- 238000010828 elution Methods 0.000 abstract 1
- 238000004817 gas chromatography Methods 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 238000006068 polycondensation reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
- C08G69/265—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids from at least two different diamines or at least two different dicarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/36—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino acids, polyamines and polycarboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Proteomics, Peptides & Aminoacids (AREA)
- Polyamides (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
L'invention concerne principalement un procédé de fabrication d'un polyamide transparent comprenant une étape de polycondensation d'un mélange de monomères comprenant au moins un diacide carboxylique et au moins une diamine cycloaliphatique, dans lequel la diamine cycloaliphatique comporte deux cycles reliés par un groupe alkylène comportant 1 à 6 atomes de carbone, chaque cycle étant substitué par un groupe amine et au moins un groupe alkyle pouvant être identique ou différent, comportant 1 à 6 atomes de carbone, caractérisé en ce que la diamine se décompose en six fractions d'isomères lorsqu'elle est soumise à une analyse par chromatographie gazeuse sur une colonne non polaire et que, lorsque lesdites fractions d'isomères sont nommées fractions d'isomères I à VI dans leur ordre d'élution, la teneur massique Fi en fraction I de ladite diamine cycloaliphatique n'excède pas 35%. Elle concerne par ailleurs aussi l'utilisation d'une telle diamine cycloaliphatique pour la fabrication d'un polyamide transparent. Elle concerne enfin un polyamide transparent ainsi qu'une formulation, susceptibles d'être obtenus par ledit procédé et des articles obtenus à partir d'un tel polyamide ou d'une telle formulation.
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1859173A FR3086946B1 (fr) | 2018-10-03 | 2018-10-03 | Procede ameliore pour la fabrication de polyamides transparents |
US17/282,067 US20220267519A1 (en) | 2018-10-03 | 2019-10-02 | Improved method for the production of transparent polyamides |
EP19802241.0A EP3861053A1 (fr) | 2018-10-03 | 2019-10-02 | Procede ameliore pour la fabrication de polyamides transparents |
PCT/FR2019/052334 WO2020070446A1 (fr) | 2018-10-03 | 2019-10-02 | Procede ameliore pour la fabrication de polyamides transparents |
KR1020217012820A KR20210068505A (ko) | 2018-10-03 | 2019-10-02 | 투명 폴리아미드의 개선된 제조 방법 |
JP2021518627A JP7554740B2 (ja) | 2018-10-03 | 2019-10-02 | 透明ポリアミドの製造方法の改良 |
CN201980074852.6A CN113015759B (zh) | 2018-10-03 | 2019-10-02 | 用于生产透明聚酰胺的改进方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1859173A FR3086946B1 (fr) | 2018-10-03 | 2018-10-03 | Procede ameliore pour la fabrication de polyamides transparents |
Publications (2)
Publication Number | Publication Date |
---|---|
FR3086946A1 FR3086946A1 (fr) | 2020-04-10 |
FR3086946B1 true FR3086946B1 (fr) | 2021-06-25 |
Family
ID=65685549
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR1859173A Active FR3086946B1 (fr) | 2018-10-03 | 2018-10-03 | Procede ameliore pour la fabrication de polyamides transparents |
Country Status (7)
Country | Link |
---|---|
US (1) | US20220267519A1 (fr) |
EP (1) | EP3861053A1 (fr) |
JP (1) | JP7554740B2 (fr) |
KR (1) | KR20210068505A (fr) |
CN (1) | CN113015759B (fr) |
FR (1) | FR3086946B1 (fr) |
WO (1) | WO2020070446A1 (fr) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115725069B (zh) * | 2021-08-30 | 2024-06-04 | 上海凯赛生物技术股份有限公司 | 生物基透明聚酰胺及其制备方法 |
CN116063686B (zh) * | 2023-01-04 | 2024-06-25 | 万华化学集团股份有限公司 | 一种耐醇擦透明尼龙及其制备方法 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1541384A (fr) | 1966-10-18 | 1968-10-04 | Basf Ag | Procédé de fabrication de polyamides transparents |
DE2732928A1 (de) * | 1977-07-21 | 1979-02-01 | Bayer Ag | Transparente polyamide |
US4268661A (en) * | 1978-12-18 | 1981-05-19 | Inventa Ag Fur Forschung Und Patentverwertung, Zurich | Method for the manufacture of glass clear transparent polyamide |
CH667462A5 (de) * | 1985-01-07 | 1988-10-14 | Inventa Ag | Transparente copolyamide, verfahren zu deren herstellung und deren verwendung zur herstellung von formkoerpern. |
FR2622197B1 (fr) * | 1987-10-21 | 1990-03-09 | Atochem | Polyamides transparents, leur procede de fabrication |
JP5114431B2 (ja) | 2006-01-31 | 2013-01-09 | エーエムエス−ヒェミー・アクチェンゲゼルシャフト | ポリアミド成形配合物および透明かつ熱蒸気殺菌性成形物品または押出物を製造するためのその使用。 |
FR2932808B1 (fr) * | 2008-06-20 | 2010-08-13 | Arkema France | Copolyamide, composition comprenant un tel copolyamide et leurs utilisations. |
EP2290004B1 (fr) * | 2009-07-31 | 2016-08-31 | Ems-Patent Ag | Matériau de moulage à base d'un mélange de polyamides |
JP2021143211A (ja) | 2018-05-23 | 2021-09-24 | 宇部興産株式会社 | ポリアミド樹脂及びその製造方法 |
-
2018
- 2018-10-03 FR FR1859173A patent/FR3086946B1/fr active Active
-
2019
- 2019-10-02 CN CN201980074852.6A patent/CN113015759B/zh active Active
- 2019-10-02 WO PCT/FR2019/052334 patent/WO2020070446A1/fr unknown
- 2019-10-02 KR KR1020217012820A patent/KR20210068505A/ko unknown
- 2019-10-02 JP JP2021518627A patent/JP7554740B2/ja active Active
- 2019-10-02 EP EP19802241.0A patent/EP3861053A1/fr active Pending
- 2019-10-02 US US17/282,067 patent/US20220267519A1/en active Pending
Also Published As
Publication number | Publication date |
---|---|
KR20210068505A (ko) | 2021-06-09 |
JP7554740B2 (ja) | 2024-09-20 |
JP2022504278A (ja) | 2022-01-13 |
WO2020070446A1 (fr) | 2020-04-09 |
EP3861053A1 (fr) | 2021-08-11 |
US20220267519A1 (en) | 2022-08-25 |
CN113015759A (zh) | 2021-06-22 |
CN113015759B (zh) | 2024-04-19 |
FR3086946A1 (fr) | 2020-04-10 |
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