FR3080851B1 - Procede de synthese de molecules aromatiques fluorees en presence d'un photocatalyseur - Google Patents
Procede de synthese de molecules aromatiques fluorees en presence d'un photocatalyseur Download PDFInfo
- Publication number
- FR3080851B1 FR3080851B1 FR1853883A FR1853883A FR3080851B1 FR 3080851 B1 FR3080851 B1 FR 3080851B1 FR 1853883 A FR1853883 A FR 1853883A FR 1853883 A FR1853883 A FR 1853883A FR 3080851 B1 FR3080851 B1 FR 3080851B1
- Authority
- FR
- France
- Prior art keywords
- synthesis
- photocatalyst
- fluorinated aromatic
- aromatic molecules
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C391/00—Compounds containing selenium
- C07C391/02—Compounds containing selenium having selenium atoms bound to carbon atoms of six-membered aromatic rings
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B39/00—Halogenation
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
- C07C319/14—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D215/00—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems
- C07D215/02—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen atoms or carbon atoms directly attached to the ring nitrogen atom
- C07D215/16—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen atoms or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
- C07D333/02—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
- C07D333/04—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
- C07D333/26—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D333/30—Hetero atoms other than halogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
- C07D333/02—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
- C07D333/04—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
- C07D333/26—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D333/38—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
L'invention a pour objet un procédé de synthèse de molécules aromatiques fluorées de formule (I) Ar2-A-B (I) dans laquelle Ar2 représente un (hétéro)aryle; A représente un atome du 16ème groupe du tableau périodique ; B représente un groupement (C1-C6)fluoroalkyle comprenant la réaction d'un sel de diazonium de formule (II) : Ar2-NΞN+ X- avec un composé de formule (III) en présence d'un photocatalyseur activé par de la lumière.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1853883A FR3080851B1 (fr) | 2018-05-04 | 2018-05-04 | Procede de synthese de molecules aromatiques fluorees en presence d'un photocatalyseur |
PCT/FR2019/051018 WO2019211568A1 (fr) | 2018-05-04 | 2019-05-03 | Procede de synthese de molecules aromatiques fluorees en presence d'un photocatalyseur |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1853883 | 2018-05-04 | ||
FR1853883A FR3080851B1 (fr) | 2018-05-04 | 2018-05-04 | Procede de synthese de molecules aromatiques fluorees en presence d'un photocatalyseur |
Publications (2)
Publication Number | Publication Date |
---|---|
FR3080851A1 FR3080851A1 (fr) | 2019-11-08 |
FR3080851B1 true FR3080851B1 (fr) | 2020-05-29 |
Family
ID=63557566
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR1853883A Active FR3080851B1 (fr) | 2018-05-04 | 2018-05-04 | Procede de synthese de molecules aromatiques fluorees en presence d'un photocatalyseur |
Country Status (2)
Country | Link |
---|---|
FR (1) | FR3080851B1 (fr) |
WO (1) | WO2019211568A1 (fr) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114605299B (zh) * | 2022-03-17 | 2023-08-25 | 浙江师范大学 | 一种亲电三氟甲硒基试剂、制备方法及其应用 |
CN115806516A (zh) * | 2022-12-16 | 2023-03-17 | 南京理工大学 | 苄位五氟乙硒基化合物及其制备方法 |
-
2018
- 2018-05-04 FR FR1853883A patent/FR3080851B1/fr active Active
-
2019
- 2019-05-03 WO PCT/FR2019/051018 patent/WO2019211568A1/fr active Application Filing
Also Published As
Publication number | Publication date |
---|---|
FR3080851A1 (fr) | 2019-11-08 |
WO2019211568A1 (fr) | 2019-11-07 |
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Effective date: 20191108 |
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