FR3080851B1 - Procede de synthese de molecules aromatiques fluorees en presence d'un photocatalyseur - Google Patents

Procede de synthese de molecules aromatiques fluorees en presence d'un photocatalyseur Download PDF

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Publication number
FR3080851B1
FR3080851B1 FR1853883A FR1853883A FR3080851B1 FR 3080851 B1 FR3080851 B1 FR 3080851B1 FR 1853883 A FR1853883 A FR 1853883A FR 1853883 A FR1853883 A FR 1853883A FR 3080851 B1 FR3080851 B1 FR 3080851B1
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FR
France
Prior art keywords
synthesis
photocatalyst
fluorinated aromatic
aromatic molecules
formula
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Active
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FR1853883A
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English (en)
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FR3080851A1 (fr
Inventor
Anis Tlili
Thierry Billard
Clement Ghiazza
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Centre National de la Recherche Scientifique CNRS
Universite Claude Bernard Lyon 1 UCBL
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Centre National de la Recherche Scientifique CNRS
Universite Claude Bernard Lyon 1 UCBL
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Priority to FR1853883A priority Critical patent/FR3080851B1/fr
Priority to PCT/FR2019/051018 priority patent/WO2019211568A1/fr
Publication of FR3080851A1 publication Critical patent/FR3080851A1/fr
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C391/00—Compounds containing selenium
    • C07C391/02—Compounds containing selenium having selenium atoms bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B39/00—Halogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/14—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D215/00—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems
    • C07D215/02—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen atoms or carbon atoms directly attached to the ring nitrogen atom
    • C07D215/16—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen atoms or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/02—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
    • C07D333/04—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
    • C07D333/26—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D333/30—Hetero atoms other than halogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/02—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
    • C07D333/04—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
    • C07D333/26—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D333/38—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

L'invention a pour objet un procédé de synthèse de molécules aromatiques fluorées de formule (I) Ar2-A-B (I) dans laquelle Ar2 représente un (hétéro)aryle; A représente un atome du 16ème groupe du tableau périodique ; B représente un groupement (C1-C6)fluoroalkyle comprenant la réaction d'un sel de diazonium de formule (II) : Ar2-NΞN+ X- avec un composé de formule (III) en présence d'un photocatalyseur activé par de la lumière.
FR1853883A 2018-05-04 2018-05-04 Procede de synthese de molecules aromatiques fluorees en presence d'un photocatalyseur Active FR3080851B1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
FR1853883A FR3080851B1 (fr) 2018-05-04 2018-05-04 Procede de synthese de molecules aromatiques fluorees en presence d'un photocatalyseur
PCT/FR2019/051018 WO2019211568A1 (fr) 2018-05-04 2019-05-03 Procede de synthese de molecules aromatiques fluorees en presence d'un photocatalyseur

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1853883 2018-05-04
FR1853883A FR3080851B1 (fr) 2018-05-04 2018-05-04 Procede de synthese de molecules aromatiques fluorees en presence d'un photocatalyseur

Publications (2)

Publication Number Publication Date
FR3080851A1 FR3080851A1 (fr) 2019-11-08
FR3080851B1 true FR3080851B1 (fr) 2020-05-29

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
FR1853883A Active FR3080851B1 (fr) 2018-05-04 2018-05-04 Procede de synthese de molecules aromatiques fluorees en presence d'un photocatalyseur

Country Status (2)

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FR (1) FR3080851B1 (fr)
WO (1) WO2019211568A1 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114605299B (zh) * 2022-03-17 2023-08-25 浙江师范大学 一种亲电三氟甲硒基试剂、制备方法及其应用
CN115806516A (zh) * 2022-12-16 2023-03-17 南京理工大学 苄位五氟乙硒基化合物及其制备方法

Also Published As

Publication number Publication date
WO2019211568A1 (fr) 2019-11-07
FR3080851A1 (fr) 2019-11-08

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