FR3078710B1 - Composition comprenant des copolymeres thermoassociatifs et echangeables - Google Patents

Composition comprenant des copolymeres thermoassociatifs et echangeables Download PDF

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Publication number
FR3078710B1
FR3078710B1 FR1851968A FR1851968A FR3078710B1 FR 3078710 B1 FR3078710 B1 FR 3078710B1 FR 1851968 A FR1851968 A FR 1851968A FR 1851968 A FR1851968 A FR 1851968A FR 3078710 B1 FR3078710 B1 FR 3078710B1
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France
Prior art keywords
composition
thermoassociative
composition including
polydiol
side chains
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FR1851968A
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English (en)
French (fr)
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FR3078710A1 (fr
Inventor
Gregory Descroix
Fanny Briand
Renaud Nicolay
Thibault Derouineau
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Centre National de la Recherche Scientifique CNRS
Ecole Superieure de Physique et Chimie Industrielles de Ville de Paris ESPCI
TotalEnergies Onetech SAS
Original Assignee
Centre National de la Recherche Scientifique CNRS
Ecole Superieure de Physique et Chimie Industrielles de Ville de Paris ESPCI
Total Marketing Services SA
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Filing date
Publication date
Priority to FR1851968A priority Critical patent/FR3078710B1/fr
Application filed by Centre National de la Recherche Scientifique CNRS, Ecole Superieure de Physique et Chimie Industrielles de Ville de Paris ESPCI, Total Marketing Services SA filed Critical Centre National de la Recherche Scientifique CNRS
Priority to JP2020546423A priority patent/JP2021517183A/ja
Priority to KR1020207028446A priority patent/KR20200139165A/ko
Priority to PCT/FR2019/050509 priority patent/WO2019171006A1/fr
Priority to EP19715163.2A priority patent/EP3762453B1/fr
Priority to US16/979,133 priority patent/US11840593B2/en
Priority to CN201980030837.1A priority patent/CN112088186B/zh
Publication of FR3078710A1 publication Critical patent/FR3078710A1/fr
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Publication of FR3078710B1 publication Critical patent/FR3078710B1/fr
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/06Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08CTREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00Chemical modification of rubber
    • C08C19/02Hydrogenation
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08CTREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00Chemical modification of rubber
    • C08C19/28Reaction with compounds containing carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08CTREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00Chemical modification of rubber
    • C08C19/30Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule
    • C08C19/34Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with oxygen or oxygen-containing groups
    • C08C19/38Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with oxygen or oxygen-containing groups with hydroxy radicals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02Monomers containing only one unsaturated aliphatic radical
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02Monomers containing only one unsaturated aliphatic radical
    • C08F212/04Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06Hydrocarbons
    • C08F212/12Monomers containing a branched unsaturated aliphatic radical or a ring substituted by an alkyl radical
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    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/16Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/16Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1812C12-(meth)acrylate, e.g. lauryl (meth)acrylate
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    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F289/00Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds not provided for in groups C08F251/00 - C08F287/00
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    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
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    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
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    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/12Hydrolysis
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    • C08F8/00Chemical modification by after-treatment
    • C08F8/42Introducing metal atoms or metal-containing groups
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/55Boron-containing compounds
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    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L43/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium or a metal; Compositions of derivatives of such polymers
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M155/00Lubricating compositions characterised by the additive being a macromolecular compound containing atoms of elements not provided for in groups C10M143/00 - C10M153/00
    • C10M155/04Monomer containing boron
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M157/00Lubricating compositions characterised by the additive being a mixture of two or more macromolecular compounds covered by more than one of the main groups C10M143/00 - C10M155/00, each of these compounds being essential
    • C10M157/10Lubricating compositions characterised by the additive being a mixture of two or more macromolecular compounds covered by more than one of the main groups C10M143/00 - C10M155/00, each of these compounds being essential at least one of them being a compound containing atoms of elements not provided for in groups C10M157/02 - C10M157/08
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M161/00Lubricating compositions characterised by the additive being a mixture of a macromolecular compound and a non-macromolecular compound, each of these compounds being essential
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F230/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
    • C08F230/04Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
    • C08F230/06Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing boron
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00Living radical polymerisation
    • C08F2438/01Atom Transfer Radical Polymerization [ATRP] or reverse ATRP
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    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00Living radical polymerisation
    • C08F2438/03Use of a di- or tri-thiocarbonylthio compound, e.g. di- or tri-thioester, di- or tri-thiocarbamate, or a xanthate as chain transfer agent, e.g . Reversible Addition Fragmentation chain Transfer [RAFT] or Macromolecular Design via Interchange of Xanthates [MADIX]
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    • C08F2810/00Chemical modification of a polymer
    • C08F2810/30Chemical modification of a polymer leading to the formation or introduction of aliphatic or alicyclic unsaturated groups
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    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/102Aliphatic fractions
    • C10M2203/1025Aliphatic fractions used as base material
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    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/084Acrylate; Methacrylate
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    • C10M2227/00Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/06Organic compounds derived from inorganic acids or metal salts
    • C10M2227/061Esters derived from boron
    • C10M2227/062Cyclic esters
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    • C10M2229/00Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/006Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions used as thickening agents
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01Physico-chemical properties
    • C10N2020/02Viscosity; Viscosity index
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    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/02Pour-point; Viscosity index

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Lubricants (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
FR1851968A 2018-03-07 2018-03-07 Composition comprenant des copolymeres thermoassociatifs et echangeables Active FR3078710B1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR1851968A FR3078710B1 (fr) 2018-03-07 2018-03-07 Composition comprenant des copolymeres thermoassociatifs et echangeables
KR1020207028446A KR20200139165A (ko) 2018-03-07 2019-03-07 열결합성 및 교환가능한 공중합체를 포함하는 조성물
PCT/FR2019/050509 WO2019171006A1 (fr) 2018-03-07 2019-03-07 Composition comprenant des copolymeres thermoassociatifs et echangeables
EP19715163.2A EP3762453B1 (fr) 2018-03-07 2019-03-07 Composition comprenant des copolymères thermoassociatifs et échangeables
JP2020546423A JP2021517183A (ja) 2018-03-07 2019-03-07 熱会合性で交換可能な共重合体を含む組成物
US16/979,133 US11840593B2 (en) 2018-03-07 2019-03-07 Composition comprising thermoassociative and exchangeable copolymers
CN201980030837.1A CN112088186B (zh) 2018-03-07 2019-03-07 包含热缔合的可交换共聚物的组合物

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1851968A FR3078710B1 (fr) 2018-03-07 2018-03-07 Composition comprenant des copolymeres thermoassociatifs et echangeables
FR1851968 2018-03-07

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FR3078710A1 FR3078710A1 (fr) 2019-09-13
FR3078710B1 true FR3078710B1 (fr) 2020-10-30

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US (1) US11840593B2 (https=)
EP (1) EP3762453B1 (https=)
JP (1) JP2021517183A (https=)
KR (1) KR20200139165A (https=)
CN (1) CN112088186B (https=)
FR (1) FR3078710B1 (https=)
WO (1) WO2019171006A1 (https=)

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FR3059005B1 (fr) * 2016-11-23 2018-12-07 Total Marketing Services Copolymeres thermoassociatifs et echangeables, composition les comprenant
FR3081465B1 (fr) * 2018-05-24 2020-06-12 Total Marketing Services Oligomeres associatifs et echangeables, composition les comprenant
FR3081466B1 (fr) * 2018-05-24 2020-06-12 Total Marketing Services Oligomeres associatifs et echangeables, composition les comprenant
FR3081464B1 (fr) * 2018-05-24 2020-09-18 Total Marketing Services Oligomeres associatifs et echangeables, composition les comprenant
JP7661665B2 (ja) 2018-09-28 2025-04-15 オーリス ヘルス インコーポレイテッド 医療器具をドッキングするためのシステム及び方法
WO2023099635A1 (en) 2021-12-03 2023-06-08 Totalenergies Onetech Lubricant compositions
WO2023099631A1 (en) 2021-12-03 2023-06-08 Evonik Operations Gmbh Boronic ester modified polyalkyl(meth)acrylate polymers
WO2023099637A1 (en) 2021-12-03 2023-06-08 Totalenergies Onetech Lubricant compositions
WO2023099632A1 (en) 2021-12-03 2023-06-08 Evonik Operations Gmbh Boronic ester modified polyalkyl(meth)acrylate polymers
WO2023099630A1 (en) 2021-12-03 2023-06-08 Evonik Operations Gmbh Boronic ester modified polyalkyl(meth)acrylate polymers
WO2023099634A1 (en) 2021-12-03 2023-06-08 Totalenergies Onetech Lubricant compositions
US12534682B2 (en) * 2021-12-24 2026-01-27 Idemitsu Kosan Co., Ltd. Viscosity index enhancer composition, additive composition for lubricating oil, and lubricating oil composition

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IT1258916B (it) * 1992-05-15 1996-03-01 Mini Ricerca Scient Tecnolog Additivo per olii lubrificanti contenente boro e procedimento per la sua preparazione
WO1998031643A1 (en) * 1997-01-21 1998-07-23 W.R. Grace & Co.-Conn. Emulsified comb polymer and defoaming agent composition and method of making same
DE19919776A1 (de) * 1999-04-30 2000-11-02 Beiersdorf Ag Kombination aus wasserlöslichen und/oder wasserdispergierbaren siliconmodifizierten Kammpolymeren und einer oder mehrere Substanzen gewählt aus der Gruppe der physiologisch verträglichen anionischen oder amphoteren Polymere
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JP6014540B2 (ja) * 2013-04-17 2016-10-25 コスモ石油ルブリカンツ株式会社 内燃機関用潤滑油組成物
FR3016887B1 (fr) * 2014-01-27 2016-02-05 Total Marketing Services Compositions lubrifiantes comprenant des copolymeres thermoassociatifs et echangeables
FR3016885B1 (fr) * 2014-01-27 2017-08-18 Total Marketing Services Copolymeres thermoassociatifs et echangeables, compositions les comprenant
FR3031744B1 (fr) * 2015-01-15 2017-02-10 Total Marketing Services Compositions d'additifs thermoassociatifs dont l'association est controlee et compositions lubrifiantes les contenant
FR3059005B1 (fr) 2016-11-23 2018-12-07 Total Marketing Services Copolymeres thermoassociatifs et echangeables, composition les comprenant

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CN112088186A (zh) 2020-12-15
US11840593B2 (en) 2023-12-12
WO2019171006A1 (fr) 2019-09-12
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FR3078710A1 (fr) 2019-09-13
EP3762453B1 (fr) 2025-01-15

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