FR3047735A1 - Composition de caoutchouc comprenant une silice essentiellement spherique et peu structuree - Google Patents
Composition de caoutchouc comprenant une silice essentiellement spherique et peu structuree Download PDFInfo
- Publication number
- FR3047735A1 FR3047735A1 FR1651141A FR1651141A FR3047735A1 FR 3047735 A1 FR3047735 A1 FR 3047735A1 FR 1651141 A FR1651141 A FR 1651141A FR 1651141 A FR1651141 A FR 1651141A FR 3047735 A1 FR3047735 A1 FR 3047735A1
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- FR
- France
- Prior art keywords
- silica
- composition
- composition according
- reinforcing filler
- spherical nanoparticles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 268
- 239000000203 mixture Substances 0.000 title claims abstract description 187
- 239000000377 silicon dioxide Substances 0.000 title claims abstract description 118
- 229920001971 elastomer Polymers 0.000 title claims abstract description 83
- 239000005060 rubber Substances 0.000 title claims abstract description 48
- 239000002105 nanoparticle Substances 0.000 claims abstract description 71
- 239000012763 reinforcing filler Substances 0.000 claims abstract description 59
- 229920003244 diene elastomer Polymers 0.000 claims abstract description 46
- 239000007822 coupling agent Substances 0.000 claims abstract description 26
- 238000004519 manufacturing process Methods 0.000 claims abstract description 20
- 238000010382 chemical cross-linking Methods 0.000 claims abstract description 7
- 229920001577 copolymer Polymers 0.000 claims description 40
- 239000004014 plasticizer Substances 0.000 claims description 37
- 239000000806 elastomer Substances 0.000 claims description 36
- 239000011347 resin Substances 0.000 claims description 33
- 229920005989 resin Polymers 0.000 claims description 33
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 26
- 238000000034 method Methods 0.000 claims description 23
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Natural products CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 17
- 239000006229 carbon black Substances 0.000 claims description 16
- 239000007788 liquid Substances 0.000 claims description 16
- 239000005350 fused silica glass Substances 0.000 claims description 14
- 239000003795 chemical substances by application Substances 0.000 claims description 11
- 230000009477 glass transition Effects 0.000 claims description 10
- 125000005372 silanol group Chemical group 0.000 claims description 10
- 238000004132 cross linking Methods 0.000 claims description 8
- 229920002857 polybutadiene Polymers 0.000 claims description 5
- 229920003051 synthetic elastomer Polymers 0.000 claims description 5
- 244000043261 Hevea brasiliensis Species 0.000 claims description 3
- 229920003052 natural elastomer Polymers 0.000 claims description 3
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- 238000004898 kneading Methods 0.000 claims description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 36
- 229920006026 co-polymeric resin Polymers 0.000 description 35
- -1 s Chemical class 0.000 description 28
- 239000003921 oil Substances 0.000 description 25
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- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 20
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- 150000001875 compounds Chemical class 0.000 description 17
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- 235000019241 carbon black Nutrition 0.000 description 15
- 229910003475 inorganic filler Inorganic materials 0.000 description 15
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- 239000000126 substance Substances 0.000 description 11
- HECLRDQVFMWTQS-UHFFFAOYSA-N Dicyclopentadiene Chemical compound C1C2C3CC=CC3C1C=C2 HECLRDQVFMWTQS-UHFFFAOYSA-N 0.000 description 10
- 239000006185 dispersion Substances 0.000 description 10
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- 125000003118 aryl group Chemical group 0.000 description 8
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- 101150117627 bpl1 gene Proteins 0.000 description 7
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- 229910052799 carbon Inorganic materials 0.000 description 6
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- 150000003505 terpenes Chemical class 0.000 description 6
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- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 5
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 5
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 5
- 239000005642 Oleic acid Substances 0.000 description 5
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 238000012512 characterization method Methods 0.000 description 5
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 5
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- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 5
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 4
- OWRCNXZUPFZXOS-UHFFFAOYSA-N 1,3-diphenylguanidine Chemical compound C=1C=CC=CC=1NC(=N)NC1=CC=CC=C1 OWRCNXZUPFZXOS-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- 238000010411 cooking Methods 0.000 description 4
- 230000008878 coupling Effects 0.000 description 4
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- 125000002897 diene group Chemical group 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
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- 238000010304 firing Methods 0.000 description 4
- 125000000524 functional group Chemical group 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 4
- 239000003208 petroleum Substances 0.000 description 4
- 238000001556 precipitation Methods 0.000 description 4
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- 229910052717 sulfur Inorganic materials 0.000 description 4
- 239000011593 sulfur Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 3
- 239000004606 Fillers/Extenders Substances 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 3
- 235000006708 antioxidants Nutrition 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000005520 cutting process Methods 0.000 description 3
- 239000003085 diluting agent Substances 0.000 description 3
- 238000010891 electric arc Methods 0.000 description 3
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- 238000005259 measurement Methods 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
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- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 3
- DEQZTKGFXNUBJL-UHFFFAOYSA-N n-(1,3-benzothiazol-2-ylsulfanyl)cyclohexanamine Chemical compound C1CCCCC1NSC1=NC2=CC=CC=C2S1 DEQZTKGFXNUBJL-UHFFFAOYSA-N 0.000 description 3
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- XMGQYMWWDOXHJM-JTQLQIEISA-N (+)-α-limonene Chemical compound CC(=C)[C@@H]1CCC(C)=CC1 XMGQYMWWDOXHJM-JTQLQIEISA-N 0.000 description 2
- XMGQYMWWDOXHJM-SNVBAGLBSA-N (-)-α-limonene Chemical compound CC(=C)[C@H]1CCC(C)=CC1 XMGQYMWWDOXHJM-SNVBAGLBSA-N 0.000 description 2
- QEDJMOONZLUIMC-UHFFFAOYSA-N 1-tert-butyl-4-ethenylbenzene Chemical compound CC(C)(C)C1=CC=C(C=C)C=C1 QEDJMOONZLUIMC-UHFFFAOYSA-N 0.000 description 2
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 2
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 2
- SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical class ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 2
- PDELBHCVXBSVPJ-UHFFFAOYSA-N 2-ethenyl-1,3,5-trimethylbenzene Chemical group CC1=CC(C)=C(C=C)C(C)=C1 PDELBHCVXBSVPJ-UHFFFAOYSA-N 0.000 description 2
- CTHJQRHPNQEPAB-UHFFFAOYSA-N 2-methoxyethenylbenzene Chemical class COC=CC1=CC=CC=C1 CTHJQRHPNQEPAB-UHFFFAOYSA-N 0.000 description 2
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 2
- ZZMVLMVFYMGSMY-UHFFFAOYSA-N 4-n-(4-methylpentan-2-yl)-1-n-phenylbenzene-1,4-diamine Chemical compound C1=CC(NC(C)CC(C)C)=CC=C1NC1=CC=CC=C1 ZZMVLMVFYMGSMY-UHFFFAOYSA-N 0.000 description 2
- 239000002028 Biomass Substances 0.000 description 2
- 244000020551 Helianthus annuus Species 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- 235000019486 Sunflower oil Nutrition 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical group [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
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- 125000003545 alkoxy group Chemical group 0.000 description 2
- 235000010210 aluminium Nutrition 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
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- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
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- QEQBMZQFDDDTPN-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy benzenecarboperoxoate Chemical compound CC(C)(C)OOOC(=O)C1=CC=CC=C1 QEQBMZQFDDDTPN-UHFFFAOYSA-N 0.000 description 1
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- RBORURQQJIQWBS-QVRNUERCSA-N (4ar,6r,7r,7as)-6-(6-amino-8-bromopurin-9-yl)-2-hydroxy-2-sulfanylidene-4a,6,7,7a-tetrahydro-4h-furo[3,2-d][1,3,2]dioxaphosphinin-7-ol Chemical compound C([C@H]1O2)OP(O)(=S)O[C@H]1[C@@H](O)[C@@H]2N1C(N=CN=C2N)=C2N=C1Br RBORURQQJIQWBS-QVRNUERCSA-N 0.000 description 1
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- UQSXEMVUGMPGLS-UHFFFAOYSA-N 2-tert-butylperoxycarbonylbenzoic acid Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1C(O)=O UQSXEMVUGMPGLS-UHFFFAOYSA-N 0.000 description 1
- OAOZZYBUAWEDRA-UHFFFAOYSA-N 3,4-dimethylidenehexane Chemical compound CCC(=C)C(=C)CC OAOZZYBUAWEDRA-UHFFFAOYSA-N 0.000 description 1
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- HBAQYPYDRFILMT-UHFFFAOYSA-N 8-[3-(1-cyclopropylpyrazol-4-yl)-1H-pyrazolo[4,3-d]pyrimidin-5-yl]-3-methyl-3,8-diazabicyclo[3.2.1]octan-2-one Chemical class C1(CC1)N1N=CC(=C1)C1=NNC2=C1N=C(N=C2)N1C2C(N(CC1CC2)C)=O HBAQYPYDRFILMT-UHFFFAOYSA-N 0.000 description 1
- 241001133760 Acoelorraphe Species 0.000 description 1
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-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/016—Additives defined by their aspect ratio
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Tires In General (AREA)
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1651141A FR3047735A1 (fr) | 2016-02-12 | 2016-02-12 | Composition de caoutchouc comprenant une silice essentiellement spherique et peu structuree |
| EP17709143.6A EP3414284B1 (fr) | 2016-02-12 | 2017-02-10 | Composition de caoutchouc comprenant une silice essentiellement sphérique et peu structurée |
| PCT/FR2017/050312 WO2017137711A1 (fr) | 2016-02-12 | 2017-02-10 | Composition de caoutchouc comprenant une silice essentiellement sphérique et peu structurée |
| US16/070,167 US10737531B2 (en) | 2016-02-12 | 2017-02-10 | Rubber composition comprising an essentially spherical, relatively unstructured silica |
| CN201780009174.6A CN108602981B (zh) | 2016-02-12 | 2017-02-10 | 包含基本上为球形的相对非结构化的二氧化硅的橡胶组合物 |
| JP2018542168A JP6924200B2 (ja) | 2016-02-12 | 2017-02-10 | 実質的に球状の比較的構造化されていないシリカを含むゴム組成物 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1651141A FR3047735A1 (fr) | 2016-02-12 | 2016-02-12 | Composition de caoutchouc comprenant une silice essentiellement spherique et peu structuree |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| FR3047735A1 true FR3047735A1 (fr) | 2017-08-18 |
Family
ID=55650569
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR1651141A Withdrawn FR3047735A1 (fr) | 2016-02-12 | 2016-02-12 | Composition de caoutchouc comprenant une silice essentiellement spherique et peu structuree |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US10737531B2 (OSRAM) |
| EP (1) | EP3414284B1 (OSRAM) |
| JP (1) | JP6924200B2 (OSRAM) |
| CN (1) | CN108602981B (OSRAM) |
| FR (1) | FR3047735A1 (OSRAM) |
| WO (1) | WO2017137711A1 (OSRAM) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20220001695A1 (en) * | 2018-10-31 | 2022-01-06 | Compagnie Generale Des Etablissements Michelin | Non-rubber masterbatches of nanoparticles |
| US20210102047A1 (en) * | 2019-10-04 | 2021-04-08 | The Goodyear Tire & Rubber Company | Pneumatic tire |
| FR3115541B1 (fr) * | 2020-10-23 | 2023-10-20 | Michelin & Cie | Produit renforcé à base d’au moins un élément de renfort métallique et d’une composition de caoutchouc. |
| JP7747500B2 (ja) * | 2021-11-25 | 2025-10-01 | Ｔｏｙｏ Ｔｉｒｅ株式会社 | ゴム組成物及びタイヤ |
| EP4438323A1 (en) | 2023-03-31 | 2024-10-02 | Bridgestone Europe NV/SA | Rubber composition for pneumatic tyre and pneumatic tyre produced therefrom |
| CN119101316B (zh) * | 2024-09-26 | 2025-05-06 | 上海芯密科技股份有限公司 | 一种含氟弹性体组合物及其制备方法和应用 |
Citations (3)
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|---|---|---|---|---|
| US20050004297A1 (en) * | 2001-08-13 | 2005-01-06 | Michelin Recherche Et Technique Paccot S.A. | Diene rubber composition for tire comprising a specific silica as reinforcing filler |
| US20110152434A1 (en) * | 2009-12-18 | 2011-06-23 | Claude Schweitzer | Tire with component containing combined high structure silica and low structure silica |
| WO2015097195A1 (fr) * | 2013-12-23 | 2015-07-02 | Compagnie Generale Des Etablissements Michelin | Composition de caoutchouc comprenant une charge non renforçante et une charge renforçante |
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| FR2740778A1 (fr) | 1995-11-07 | 1997-05-09 | Michelin & Cie | Composition de caoutchouc a base de silice et de polymere dienique fonctionalise ayant une fonction silanol terminale |
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| FR2749313A1 (fr) | 1996-05-28 | 1997-12-05 | Michelin & Cie | Composition de caoutchouc dienique a base d'alumine en tant que charge renforcante et son utilisation pour la fabrication d'enveloppes de pneumatiques |
| FR2765882B1 (fr) | 1997-07-11 | 1999-09-03 | Michelin & Cie | Composition de caoutchouc a base de noir de carbone ayant de la silice fixee a sa surface et de polymere dienique fonctionnalise alcoxysilane |
| EP1679315A1 (en) | 1997-08-21 | 2006-07-12 | General Electric Company | Blocked mercaptosilane coupling agents for filled rubbers |
| PT1537908E (pt) | 1997-09-30 | 2012-04-24 | Cabot Corp | Misturas de compósitos de elastómeros e métodos para a sua produção |
| DE69841286D1 (de) | 1997-11-28 | 2009-12-24 | Michelin & Cie | Aluminiumhaltiger, verstärkender Füllstoff und diesen enthaltende Kautschukzusammensetzung |
| JP4991063B2 (ja) | 1999-05-28 | 2012-08-01 | ソシエテ ド テクノロジー ミシュラン | ジエンエラストマー及び強化酸化チタンに基づくタイヤ用ゴム組成物 |
| EP1127909B1 (fr) | 2000-02-24 | 2005-03-09 | Société de Technologie Michelin | Composition de caoutchouc vulcanisable, utilisable pour fabriquer un pneumatique, et pneumatique comprenant cette composition |
| JP5462428B2 (ja) | 2000-05-26 | 2014-04-02 | コンパニー ゼネラール デ エタブリッスマン ミシュラン | タイヤトレッドとして使用可能なゴム組成物 |
| JP5357371B2 (ja) | 2000-07-31 | 2013-12-04 | コンパニー ゼネラール デ エタブリッスマン ミシュラン | タイヤ用トレッド |
| EP1326871B1 (fr) | 2000-10-13 | 2006-02-01 | Société de Technologie Michelin | Organosilane polyfonctionnel utilisable comme agent de couplage et son procede d'obtention |
| WO2002031041A1 (fr) | 2000-10-13 | 2002-04-18 | Societe De Technologie Michelin | Composition de caoutchouc comportant a titre d'agent de couplage un organosilane polyfonctionnel |
| JP4820530B2 (ja) | 2001-01-02 | 2011-11-24 | ソシエテ ド テクノロジー ミシュラン | ジエンエラストマーと補強炭化ケイ素をベースとしたゴム組成物 |
| CN1271131C (zh) | 2001-03-12 | 2006-08-23 | 米其林技术公司 | 轮胎胎面用橡胶组合物 |
| FR2823215B1 (fr) | 2001-04-10 | 2005-04-08 | Michelin Soc Tech | Pneumatique et bande de roulement de pneumatique comportant a titre d'agent de couplage un tetrasulfure de bis-alkoxysilane |
| JP4536374B2 (ja) * | 2001-06-28 | 2010-09-01 | ソシエテ ド テクノロジー ミシュラン | 低い比表面積のシリカで強化されたタイヤトレッド |
| WO2003002649A1 (fr) | 2001-06-28 | 2003-01-09 | Societe De Technologie Michelin | Bande de roulement pour pneumatique renforcee d'une silice a tres basse surface specifique |
| ES2254847T3 (es) | 2001-08-06 | 2006-06-16 | Degussa Ag | Compuestos de organosilicio. |
| SE519792C2 (sv) | 2001-08-17 | 2003-04-08 | Volvo Lastvagnar Ab | Metod för estimering av massan hos ett fordon vilket framförs på en väg med en varierande lutning samt metod för estimering av lutningen av den väg där ett fordon framförs |
| WO2003031511A1 (en) * | 2001-10-09 | 2003-04-17 | The Yokohama Rubber Co., Ltd. | Rubber composition |
| US20030114571A1 (en) * | 2001-10-10 | 2003-06-19 | Xiao-Dong Pan | Wet traction in tire treads compounded with surface modified siliceous and oxidic fillers |
| FR2841560B1 (fr) | 2002-07-01 | 2006-02-03 | Michelin Soc Tech | Composition de caoutchouc a base d'elastomere dienique et d'un nitrure de silicium renforcant |
| JP4633471B2 (ja) | 2002-12-19 | 2011-02-16 | ソシエテ ド テクノロジー ミシュラン | 補強アルミノシリケートに基づくタイヤゴム組成物 |
| FR2854404B1 (fr) | 2003-04-29 | 2005-07-01 | Michelin Soc Tech | Procede d'obtention d'un elastomere greffe a groupes fonctionnels le long de la chaine et compositions de caoutchouc |
| US7928258B2 (en) | 2004-08-20 | 2011-04-19 | Momentive Performance Materials Inc. | Cyclic diol-derived blocked mercaptofunctional silane compositions |
| FR2880349B1 (fr) | 2004-12-31 | 2009-03-06 | Michelin Soc Tech | Nanoparticules de polyvinylaromatique fonctionnalise |
| FR2880354B1 (fr) | 2004-12-31 | 2007-03-02 | Michelin Soc Tech | Composition elastomerique renforcee d'une charge de polyvinylaromatique fonctionnalise |
| FR2886305B1 (fr) | 2005-05-26 | 2007-08-10 | Michelin Soc Tech | Composition de caoutchouc pour pneumatique comportant un agent de couplage organosilicique et un agent de recouvrement de charge inorganique |
| FR2886304B1 (fr) | 2005-05-26 | 2007-08-10 | Michelin Soc Tech | Composition de caoutchouc pour pneumatique comportant un systeme de couplage organosilicique |
| FR2886306B1 (fr) | 2005-05-26 | 2007-07-06 | Michelin Soc Tech | Composition de caoutchouc pour pneumatique comportant un agent de couplage organosiloxane |
| US7510670B2 (en) | 2006-02-21 | 2009-03-31 | Momentive Performance Materials Inc. | Free flowing filler composition based on organofunctional silane |
| FR2903411B1 (fr) | 2006-07-06 | 2012-11-02 | Soc Tech Michelin | Nanoparticules de polymere vinylique fonctionnalise |
| FR2903416B1 (fr) | 2006-07-06 | 2008-09-05 | Michelin Soc Tech | Composition elastomerique renforcee d'une charge de polymere vinylique non aromatique fonctionnalise |
| FR2915202B1 (fr) | 2007-04-18 | 2009-07-17 | Michelin Soc Tech | Elastomere dienique couple monomodal possedant une fonction silanol en milieu de chaine, son procede d'obtention et composition de caoutchouc le contenant. |
| FR2918065B1 (fr) | 2007-06-28 | 2011-04-15 | Michelin Soc Tech | Procede de preparation d'un copolymere dienique a bloc polyether, composition de caoutchouc renforcee et enveloppe de pneumatique. |
| FR2918064B1 (fr) | 2007-06-28 | 2010-11-05 | Michelin Soc Tech | Procede de preparation d'un copolymere dienique a bloc polyether, composition de caoutchouc renforcee et enveloppe de pneumatique. |
| JP5612243B2 (ja) * | 2007-07-25 | 2014-10-22 | 住友ゴム工業株式会社 | タイヤ用ゴム組成物および空気入りタイヤ |
| FR2928374B1 (fr) * | 2008-03-10 | 2011-10-07 | Michelin Soc Tech | Composition de caoutchouc dienique pour pneumatique comprenant une silice en tant que charge renforcante |
| FR2940294B1 (fr) | 2008-12-23 | 2011-02-18 | Michelin Soc Tech | Nouveau systeme d'amorcage pour polymerisation anionique de dienes conjugues, procede de preparation d'elastomeres dieniques. |
| FR2951178B1 (fr) | 2009-10-08 | 2012-08-17 | Michelin Soc Tech | Elastomere dienique fonctionnalise et composition de caoutchouc le contenant. |
| JP5545102B2 (ja) * | 2010-07-30 | 2014-07-09 | 戸田工業株式会社 | 疎水性シリカ粒子粉末及びその製造法並びに該疎水性シリカ粒子粉末を用いたゴム組成物 |
| FR2968307B1 (fr) | 2010-11-26 | 2018-04-06 | Societe De Technologie Michelin | Bande de roulement de pneumatique |
| JP5840971B2 (ja) * | 2012-02-15 | 2016-01-06 | 住友ゴム工業株式会社 | タイヤ用ゴム組成物及び空気入りタイヤ |
-
2016
- 2016-02-12 FR FR1651141A patent/FR3047735A1/fr not_active Withdrawn
-
2017
- 2017-02-10 EP EP17709143.6A patent/EP3414284B1/fr active Active
- 2017-02-10 US US16/070,167 patent/US10737531B2/en active Active
- 2017-02-10 CN CN201780009174.6A patent/CN108602981B/zh active Active
- 2017-02-10 JP JP2018542168A patent/JP6924200B2/ja active Active
- 2017-02-10 WO PCT/FR2017/050312 patent/WO2017137711A1/fr not_active Ceased
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050004297A1 (en) * | 2001-08-13 | 2005-01-06 | Michelin Recherche Et Technique Paccot S.A. | Diene rubber composition for tire comprising a specific silica as reinforcing filler |
| US20110152434A1 (en) * | 2009-12-18 | 2011-06-23 | Claude Schweitzer | Tire with component containing combined high structure silica and low structure silica |
| WO2015097195A1 (fr) * | 2013-12-23 | 2015-07-02 | Compagnie Generale Des Etablissements Michelin | Composition de caoutchouc comprenant une charge non renforçante et une charge renforçante |
Non-Patent Citations (2)
| Title |
|---|
| SCOTTI ROBERTO ET AL: "Shape controlled spherical (0D) and rod-like (1D) silica nanoparticles in silica/styrene butadiene rubber nanocomposites: Role of the particle morphology on the filler reinforcing effect", POLYMER, vol. 55, no. 6, 31 January 2014 (2014-01-31), pages 1497 - 1506, XP028630350, ISSN: 0032-3861, DOI: 10.1016/J.POLYMER.2014.01.025 * |
| TADIELLO L; D'ARIENZO M; DI CREDICO B; HANEL T; MATEJKA L; MAURI M; MORAZZONI F; SIMONUTTI R; SPIRKOVA M; SCOTTI R: "The filler-rubber interface in styrene butadiene nanocomposites with anisotropic silica particles: Morphology and dynamic properties", SOFT MATTER, vol. 11, no. 20, 28 May 2015 (2015-05-28), pages 4022 - 4033, XP002761141 * |
Also Published As
| Publication number | Publication date |
|---|---|
| EP3414284B1 (fr) | 2020-11-18 |
| EP3414284A1 (fr) | 2018-12-19 |
| US20190030953A1 (en) | 2019-01-31 |
| CN108602981A (zh) | 2018-09-28 |
| JP2019506508A (ja) | 2019-03-07 |
| US10737531B2 (en) | 2020-08-11 |
| CN108602981B (zh) | 2020-08-21 |
| WO2017137711A1 (fr) | 2017-08-17 |
| JP6924200B2 (ja) | 2021-08-25 |
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