FR3036398A1 - Compositions a base de 1,1,3,3-tetrachloropropene - Google Patents
Compositions a base de 1,1,3,3-tetrachloropropene Download PDFInfo
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- FR3036398A1 FR3036398A1 FR1554655A FR1554655A FR3036398A1 FR 3036398 A1 FR3036398 A1 FR 3036398A1 FR 1554655 A FR1554655 A FR 1554655A FR 1554655 A FR1554655 A FR 1554655A FR 3036398 A1 FR3036398 A1 FR 3036398A1
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- ppm
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- equal
- tetrachloropropene
- composition
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- 239000000203 mixture Substances 0.000 title claims abstract description 58
- XPIGFCKQOOBTLK-UHFFFAOYSA-N 1,1,3,3-tetrachloroprop-1-ene Chemical compound ClC(Cl)C=C(Cl)Cl XPIGFCKQOOBTLK-UHFFFAOYSA-N 0.000 title claims abstract description 14
- MSSNHSVIGIHOJA-UHFFFAOYSA-N pentafluoropropane Chemical compound FC(F)CC(F)(F)F MSSNHSVIGIHOJA-UHFFFAOYSA-N 0.000 claims abstract description 17
- 238000004519 manufacturing process Methods 0.000 claims abstract description 11
- LDTMPQQAWUMPKS-OWOJBTEDSA-N (e)-1-chloro-3,3,3-trifluoroprop-1-ene Chemical compound FC(F)(F)\C=C\Cl LDTMPQQAWUMPKS-OWOJBTEDSA-N 0.000 claims abstract description 8
- CDOOAUSHHFGWSA-OWOJBTEDSA-N (e)-1,3,3,3-tetrafluoroprop-1-ene Chemical compound F\C=C\C(F)(F)F CDOOAUSHHFGWSA-OWOJBTEDSA-N 0.000 claims abstract description 7
- GVVUPGXFVJLPDE-UHFFFAOYSA-N 1,3,3,3-tetrachloroprop-1-ene Chemical compound ClC=CC(Cl)(Cl)Cl GVVUPGXFVJLPDE-UHFFFAOYSA-N 0.000 claims abstract description 5
- 150000001875 compounds Chemical class 0.000 claims description 52
- 238000000034 method Methods 0.000 claims description 33
- 238000003682 fluorination reaction Methods 0.000 claims description 29
- 230000008569 process Effects 0.000 claims description 27
- 238000000926 separation method Methods 0.000 claims description 26
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 24
- 238000006243 chemical reaction Methods 0.000 claims description 21
- 239000007791 liquid phase Substances 0.000 claims description 18
- 238000004821 distillation Methods 0.000 claims description 17
- 239000010457 zeolite Substances 0.000 claims description 14
- 229910021536 Zeolite Inorganic materials 0.000 claims description 12
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 12
- 239000003054 catalyst Substances 0.000 claims description 11
- VFWCMGCRMGJXDK-UHFFFAOYSA-N 1-chlorobutane Chemical class CCCCCl VFWCMGCRMGJXDK-UHFFFAOYSA-N 0.000 claims description 10
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 claims description 10
- DUDKKPVINWLFBI-UHFFFAOYSA-N 1-chlorobut-1-ene Chemical class CCC=CCl DUDKKPVINWLFBI-UHFFFAOYSA-N 0.000 claims description 9
- 238000007033 dehydrochlorination reaction Methods 0.000 claims description 9
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 9
- VVWFZKBKXPXGBH-UHFFFAOYSA-N 1,1,1,3,3-pentachloropropane Chemical compound ClC(Cl)CC(Cl)(Cl)Cl VVWFZKBKXPXGBH-UHFFFAOYSA-N 0.000 claims description 8
- 239000012528 membrane Substances 0.000 claims description 8
- 239000002808 molecular sieve Substances 0.000 claims description 8
- 238000001179 sorption measurement Methods 0.000 claims description 8
- UMGQVBVEWTXECF-UHFFFAOYSA-N 1,1,2,3-tetrachloroprop-1-ene Chemical class ClCC(Cl)=C(Cl)Cl UMGQVBVEWTXECF-UHFFFAOYSA-N 0.000 claims description 7
- 239000012071 phase Substances 0.000 claims description 6
- FTCVHAQNWWBTIV-UHFFFAOYSA-N 1,1,1,2,2-pentachloropropane Chemical class CC(Cl)(Cl)C(Cl)(Cl)Cl FTCVHAQNWWBTIV-UHFFFAOYSA-N 0.000 claims description 4
- ZXPCCXXSNUIVNK-UHFFFAOYSA-N 1,1,1,2,3-pentachloropropane Chemical compound ClCC(Cl)C(Cl)(Cl)Cl ZXPCCXXSNUIVNK-UHFFFAOYSA-N 0.000 claims description 2
- UTACNSITJSJFHA-UHFFFAOYSA-N 1,1,1,3-tetrachloropropane Chemical compound ClCCC(Cl)(Cl)Cl UTACNSITJSJFHA-UHFFFAOYSA-N 0.000 claims description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- 239000005977 Ethylene Substances 0.000 claims description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- 238000005660 chlorination reaction Methods 0.000 claims description 2
- 230000000274 adsorptive effect Effects 0.000 claims 1
- 238000000605 extraction Methods 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- 239000012535 impurity Substances 0.000 description 24
- 150000002894 organic compounds Chemical class 0.000 description 13
- 239000012429 reaction media Substances 0.000 description 10
- 239000000047 product Substances 0.000 description 9
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 6
- 238000009835 boiling Methods 0.000 description 6
- SNMVRZFUUCLYTO-UHFFFAOYSA-N n-propyl chloride Chemical class CCCCl SNMVRZFUUCLYTO-UHFFFAOYSA-N 0.000 description 5
- 238000009826 distribution Methods 0.000 description 4
- 239000011148 porous material Substances 0.000 description 4
- OWXJKYNZGFSVRC-UHFFFAOYSA-N 1-chloroprop-1-ene Chemical class CC=CCl OWXJKYNZGFSVRC-UHFFFAOYSA-N 0.000 description 3
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 3
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 150000001299 aldehydes Chemical class 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 238000004334 fluoridation Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000010926 purge Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 238000011282 treatment Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- VKHSLYFRPGQIBB-UHFFFAOYSA-N 1,1,1-trichlorobut-2-ene Chemical compound CC=CC(Cl)(Cl)Cl VKHSLYFRPGQIBB-UHFFFAOYSA-N 0.000 description 2
- LSNLOFDRJFJKDX-UHFFFAOYSA-N 1,1,4-trichlorobut-2-ene Chemical compound ClCC=CC(Cl)Cl LSNLOFDRJFJKDX-UHFFFAOYSA-N 0.000 description 2
- IRBPMDVHUVGLFL-UHFFFAOYSA-N 1,2,3-trichlorobut-1-ene Chemical compound CC(Cl)C(Cl)=CCl IRBPMDVHUVGLFL-UHFFFAOYSA-N 0.000 description 2
- SXCATGXBSQWDDJ-UHFFFAOYSA-N 1,2,4-trichlorobut-2-ene Chemical compound ClCC=C(Cl)CCl SXCATGXBSQWDDJ-UHFFFAOYSA-N 0.000 description 2
- AKQZPPKQVZVYCC-UHFFFAOYSA-N 4,4,4-trichlorobut-1-ene Chemical class ClC(Cl)(Cl)CC=C AKQZPPKQVZVYCC-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 238000010924 continuous production Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000001627 detrimental effect Effects 0.000 description 2
- 238000000895 extractive distillation Methods 0.000 description 2
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- DAFIBNSJXIGBQB-UHFFFAOYSA-N perfluoroisobutene Chemical group FC(F)=C(C(F)(F)F)C(F)(F)F DAFIBNSJXIGBQB-UHFFFAOYSA-N 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- JUGQRTGGLWOBPG-UPHRSURJSA-N (z)-1,2,3,3-tetrachloroprop-1-ene Chemical compound Cl\C=C(/Cl)C(Cl)Cl JUGQRTGGLWOBPG-UPHRSURJSA-N 0.000 description 1
- ZQTIKDIHRRLSRV-UHFFFAOYSA-N 1,1,1,2,2,3,3,4,4-nonafluorobutane Chemical compound FC(F)C(F)(F)C(F)(F)C(F)(F)F ZQTIKDIHRRLSRV-UHFFFAOYSA-N 0.000 description 1
- DUAKCVSNUIDZMC-UHFFFAOYSA-N 1,1,1,2,2,3,3-heptafluorobutane Chemical compound CC(F)(F)C(F)(F)C(F)(F)F DUAKCVSNUIDZMC-UHFFFAOYSA-N 0.000 description 1
- VNCIRZZEHCGAQP-UHFFFAOYSA-N 1,1,1,3-tetrachlorobutane Chemical compound CC(Cl)CC(Cl)(Cl)Cl VNCIRZZEHCGAQP-UHFFFAOYSA-N 0.000 description 1
- VWCRVILSEXWIIL-UHFFFAOYSA-N 1,1,1,4,4-pentafluorobutane Chemical compound FC(F)CCC(F)(F)F VWCRVILSEXWIIL-UHFFFAOYSA-N 0.000 description 1
- ABSHBZODGOHLFR-UHFFFAOYSA-N 1,1,1-trichlorobutane Chemical class CCCC(Cl)(Cl)Cl ABSHBZODGOHLFR-UHFFFAOYSA-N 0.000 description 1
- LDRPULCXZDDSGE-UHFFFAOYSA-N 1,1,1-trifluorobutane Chemical compound CCCC(F)(F)F LDRPULCXZDDSGE-UHFFFAOYSA-N 0.000 description 1
- PANVCEBTPSTUEL-UHFFFAOYSA-N 1,1,2,3,3-pentachloropropane Chemical compound ClC(Cl)C(Cl)C(Cl)Cl PANVCEBTPSTUEL-UHFFFAOYSA-N 0.000 description 1
- FBSPLEKACMFIFU-UHFFFAOYSA-N 1,1,2,3-tetrachlorobut-1-ene Chemical class CC(Cl)C(Cl)=C(Cl)Cl FBSPLEKACMFIFU-UHFFFAOYSA-N 0.000 description 1
- MPQPMSJLSQSQQB-UHFFFAOYSA-N 1,1,2-trichlorobut-1-ene Chemical compound CCC(Cl)=C(Cl)Cl MPQPMSJLSQSQQB-UHFFFAOYSA-N 0.000 description 1
- GTLVCKJZOABDSQ-UHFFFAOYSA-N 1,1,2-trichlorobut-2-ene Chemical compound CC=C(Cl)C(Cl)Cl GTLVCKJZOABDSQ-UHFFFAOYSA-N 0.000 description 1
- HHRQYHKSSIGXJV-UHFFFAOYSA-N 1,1,2-trifluoropropane Chemical compound CC(F)C(F)F HHRQYHKSSIGXJV-UHFFFAOYSA-N 0.000 description 1
- IAHLQJBJZKIZIQ-UHFFFAOYSA-N 1,1,3,3-tetrachloro-1-fluoropropane Chemical compound FC(Cl)(Cl)CC(Cl)Cl IAHLQJBJZKIZIQ-UHFFFAOYSA-N 0.000 description 1
- NGAUWAOLBDDRKB-UHFFFAOYSA-N 1,1,3,3-tetrachlorobutane Chemical compound CC(Cl)(Cl)CC(Cl)Cl NGAUWAOLBDDRKB-UHFFFAOYSA-N 0.000 description 1
- GVFGURPOQVIHNM-UHFFFAOYSA-N 1,1,3-trichloro-2-methylprop-1-ene Chemical compound ClCC(C)=C(Cl)Cl GVFGURPOQVIHNM-UHFFFAOYSA-N 0.000 description 1
- DXLYBTCQQZDCQD-UHFFFAOYSA-N 1,1,3-trichlorobut-1-ene Chemical compound CC(Cl)C=C(Cl)Cl DXLYBTCQQZDCQD-UHFFFAOYSA-N 0.000 description 1
- SELHJAWKAFQYQR-UHFFFAOYSA-N 1,1,3-trichlorobut-2-ene Chemical compound CC(Cl)=CC(Cl)Cl SELHJAWKAFQYQR-UHFFFAOYSA-N 0.000 description 1
- IXFRXRYBVZIBDO-UHFFFAOYSA-N 1,1,4,4-tetrachlorobutane Chemical compound ClC(Cl)CCC(Cl)Cl IXFRXRYBVZIBDO-UHFFFAOYSA-N 0.000 description 1
- WZBFBGLQXCGMFG-UHFFFAOYSA-N 1,1-dichloro-3,3-difluoroprop-1-ene Chemical compound FC(F)C=C(Cl)Cl WZBFBGLQXCGMFG-UHFFFAOYSA-N 0.000 description 1
- UAZUEJTXWAXSMA-UHFFFAOYSA-N 1,1-dichlorobut-1-ene Chemical class CCC=C(Cl)Cl UAZUEJTXWAXSMA-UHFFFAOYSA-N 0.000 description 1
- IXZVKECRTHXEEW-UHFFFAOYSA-N 1,2,3,4-tetrachlorobutane Chemical compound ClCC(Cl)C(Cl)CCl IXZVKECRTHXEEW-UHFFFAOYSA-N 0.000 description 1
- OFHQVNFSKOBBGG-UHFFFAOYSA-N 1,2-difluoropropane Chemical compound CC(F)CF OFHQVNFSKOBBGG-UHFFFAOYSA-N 0.000 description 1
- FBKBJLKCZQXEQB-UHFFFAOYSA-N 1,3,3-trichlorobut-1-ene Chemical compound CC(Cl)(Cl)C=CCl FBKBJLKCZQXEQB-UHFFFAOYSA-N 0.000 description 1
- RQGXZVBGPDPESM-UHFFFAOYSA-N 1,3,4-trichlorobut-1-ene Chemical compound ClCC(Cl)C=CCl RQGXZVBGPDPESM-UHFFFAOYSA-N 0.000 description 1
- HPBWGILCMWDPPJ-UHFFFAOYSA-N 1,3-dichloro-2-(chloromethyl)prop-1-ene Chemical compound ClCC(CCl)=CCl HPBWGILCMWDPPJ-UHFFFAOYSA-N 0.000 description 1
- DYASWFAOCHPTRT-UHFFFAOYSA-N 1,3-dichloro-3,3-difluoroprop-1-ene Chemical compound FC(F)(Cl)C=CCl DYASWFAOCHPTRT-UHFFFAOYSA-N 0.000 description 1
- WSPZFVOCHITLIY-UHFFFAOYSA-N 2,2,3,3-tetrachlorobutane Chemical class CC(Cl)(Cl)C(C)(Cl)Cl WSPZFVOCHITLIY-UHFFFAOYSA-N 0.000 description 1
- AASDQMCRDOJFCP-UHFFFAOYSA-N 2,2,3,3-tetrafluorobutane Chemical compound CC(F)(F)C(C)(F)F AASDQMCRDOJFCP-UHFFFAOYSA-N 0.000 description 1
- PQUUGVDRLWLNGR-UHFFFAOYSA-N 2,3,3,3-tetrachloroprop-1-ene Chemical compound ClC(=C)C(Cl)(Cl)Cl PQUUGVDRLWLNGR-UHFFFAOYSA-N 0.000 description 1
- WZUZDBPJFHQVJC-UHFFFAOYSA-N 2,3,4-trichlorobut-1-ene Chemical compound ClCC(Cl)C(Cl)=C WZUZDBPJFHQVJC-UHFFFAOYSA-N 0.000 description 1
- RMISVOPUIFJTEO-UHFFFAOYSA-N 2,3-dichlorobutane Chemical class CC(Cl)C(C)Cl RMISVOPUIFJTEO-UHFFFAOYSA-N 0.000 description 1
- OQISUJXQFPPARX-UHFFFAOYSA-N 2-chloro-3,3,3-trifluoroprop-1-ene Chemical class FC(F)(F)C(Cl)=C OQISUJXQFPPARX-UHFFFAOYSA-N 0.000 description 1
- IRFIKENZBOBPCV-UHFFFAOYSA-N 3,3,4-trichlorobut-1-ene Chemical compound ClCC(Cl)(Cl)C=C IRFIKENZBOBPCV-UHFFFAOYSA-N 0.000 description 1
- BKSGSFFPKXGKBD-UHFFFAOYSA-N 3,3-dichloro-2-(chloromethyl)prop-1-ene Chemical compound ClCC(=C)C(Cl)Cl BKSGSFFPKXGKBD-UHFFFAOYSA-N 0.000 description 1
- VBNWUUIAAZFRAO-UHFFFAOYSA-N 3,4,4-trichlorobut-1-ene Chemical compound ClC(Cl)C(Cl)C=C VBNWUUIAAZFRAO-UHFFFAOYSA-N 0.000 description 1
- 101100421144 Danio rerio selenoo1 gene Proteins 0.000 description 1
- 101100202896 Mus musculus Selenoo gene Proteins 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- ZVQOOHYFBIDMTQ-UHFFFAOYSA-N [methyl(oxido){1-[6-(trifluoromethyl)pyridin-3-yl]ethyl}-lambda(6)-sulfanylidene]cyanamide Chemical compound N#CN=S(C)(=O)C(C)C1=CC=C(C(F)(F)F)N=C1 ZVQOOHYFBIDMTQ-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 238000010533 azeotropic distillation Methods 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000012295 chemical reaction liquid Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000012025 fluorinating agent Substances 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- VHHHONWQHHHLTI-UHFFFAOYSA-N hexachloroethane Chemical compound ClC(Cl)(Cl)C(Cl)(Cl)Cl VHHHONWQHHHLTI-UHFFFAOYSA-N 0.000 description 1
- 231100000086 high toxicity Toxicity 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- -1 oligomeric compounds Chemical class 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000008707 rearrangement Effects 0.000 description 1
- 239000003507 refrigerant Substances 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
- C07C17/202—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction
- C07C17/206—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction the other compound being HX
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/25—Preparation of halogenated hydrocarbons by splitting-off hydrogen halides from halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/26—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
- C07C17/263—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by condensation reactions
- C07C17/266—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by condensation reactions of hydrocarbons and halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/26—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
- C07C17/263—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by condensation reactions
- C07C17/269—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by condensation reactions of only halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/38—Separation; Purification; Stabilisation; Use of additives
- C07C17/383—Separation; Purification; Stabilisation; Use of additives by distillation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
- C09K5/041—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
- C09K5/044—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
- C09K5/041—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
- C09K5/044—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
- C09K5/045—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds containing only fluorine as halogen
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- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/10—Components
- C09K2205/12—Hydrocarbons
- C09K2205/126—Unsaturated fluorinated hydrocarbons
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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Abstract
Description
Claims (6)
- REVENDICATIONS1. Composition comprenant au moins 99,5% en poids de 1,1,3,3- tétrachloropropène (F-1230za), ou d'un mélange de 1,1,3,3- tétrachloropropène et de 1,3,3,3-tétrachloropropène (F-1230zd), et au moins un composé supplémentaire choisi parmi une liste de composés consistant en les pentachloropropanes, les tétrachloropropènes autres que le F-1230za et le F-1230zd, les chlorobutènes, les chlorobutanes et les composés oxygénés, ledit composé et/ou la totalité desdits composés étant présent(s) dans la composition en une teneur inférieure ou égale à 0,5% en poids.
- 2. Composition selon la revendication 1, dans laquelle ledit composé supplémentaire représente une teneur inférieure ou égale à 1000 ppm; ou inférieure ou égale à 500 ppm ; ou inférieure ou égale à 450 ppm ; ou inférieure ou égale à 400 ppm ; ou inférieure ou égale à 350 ppm ou inférieure ou égale à 300 ppm ; ou inférieure ou égale à 250 ppm ou inférieure ou égale à 200 ppm ; ou inférieure ou égale à 150 ppm ou inférieure ou égale à 100 ppm ; ou inférieure ou égale à 75 ppm ou inférieure ou égale à 50 ppm ; ou inférieure ou égale à 25 ppm ; ou inférieure ou égale à 10 ppm ; ou inférieure ou égale à 5 ppm, dans la composition.
- 3. Composition selon la revendication 2, dans laquelle ledit composé supplémentaire est ou sont choisis parmi le 1,1,1,3,3- pentachloropropane (F-240fa), le 1,1,1,2,3-pentachloropropane (F240db) et le 1,1,2,3-tétrachloropropène (F-1230xa).
- 4. Procédé de fabrication de la composition selon l'une quelconque les revendications 1 à 3 comprenant les étapes suivantes : la réaction d'un tétrachlorure de carbone avec du chlorure de vinyle pour produire du 1,1,1,3,3-pentachloropropane (F240fa) ; la déshydrochloration du F-240fa pour obtenir le 1,1,3,3- tétrachloropropène (F-1230za) une ou plusieurs étapes de séparation du F-1230za. 3036398 18
- 5. Procédé de fabrication de la composition selon l'une quelconque les revendications 1 à 3 comprenant les étapes suivantes : - la réaction du tétrachlorure de carbone avec de l'éthylène pour produire du 1,1,1,3-tetrachloropropane (F-250fb) ; la chloration du F-250fb pour fabriquer le 1,1,1,3,3- pentachloropropane (F-240fa); la déshydrochloration du F-240fa pour obtenir le 1,1,3,3- tétrachloropropène (F-1230za) une ou plusieurs étapes de séparation du F-1230za. Procédé selon la revendication 4 ou 5 dans lequel la séparation est effectuée par distillation ou extraction, et/ou par séparation physico-chimique sur tamis moléculaire, alumine ou charbon actif, et/ou par séparation membranaire, éventuellement en phase gazeuse. Procédé selon la revendication 6 dans lequel une première étape de séparation est effectuée par une ou plusieurs distillation(s) et une deuxième étape de séparation est effectuée par adsorption sur tamis moléculaire, sur charbon actif, ou sur un mélange de ceux-ci. Procédé selon la revendication 6 ou 7 dans lequel l'étape de séparation est effectuée par adsorption sur zéolite, de type tamis moléculaire 4A, 5A, 10X ou 13X, et éventuellement suivie d'une séparation membranaire en phase gazeuse. Procédé selon la revendication l'une quelconque les revendications 6, 7 ou 8 dans lequel l'étape de séparation par adsorption est mise en oeuvre à température comprise entre 0 et 120°C, de préférence entre 20 et 80°C. Utilisation de la composition selon l'une quelconque les revendications 1 à 5 dans la fabrication du 1-chloro-3,3,3-trifluoropropène (F-1233zd), du 1,3,3,3-tétrafluoropropène (F-1234ze) ou du 1,1,1,3,3- pentafluoropropane (F-245fa). Procédé de fabrication du 1-chloro-3,3,3-trifluoropropène (F-1233zd), et/ou du 1,3,3,3-tétrafluoropropène (F-1234ze) et/ou du 1,1,1,3,3- 5 10
- 6. 15 7 20 8. 25 9. 30 10. 35 11. 3036398 19 pentafluoropropane (F-245fa), par fluoration effectuée en phase liquide et en l'absence de catalyseur, comprenant l'étapes : - d'introduire dans un réacteur de fluoration un flux comprenant la composition selon l'une quelconque les revendications 1 à 3. 5 12. Procédé selon la revendication 11 pour former du trans-1-chloro-3,3,3- trifluoropropène (F-1233zdE) ou du trans-1,3,3,3-tétrafluoropropène (F-1234zeE). 10 13. Procédé selon la revendication 11 ou 12 suivi par une ou plusieurs étapes de séparation du 1-chloro-3,3,3-trifluoropropène (F-1233zd), et/ou du 1,3,3,3-tétrafluoropropène (F-1234ze) et/ou du 1,1,1,3,3- pentafluoropropane (F-245fa), du flux de produits. 15 20 25 30 35
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1554655A FR3036398B1 (fr) | 2015-05-22 | 2015-05-22 | Compositions a base de 1,1,3,3-tetrachloropropene |
CN201680029733.5A CN107646029A (zh) | 2015-05-22 | 2016-05-04 | 基于1,1,3,3‑四氯丙烯的组合物 |
EP16726920.8A EP3297981A1 (fr) | 2015-05-22 | 2016-05-04 | Compositions a base de 1,1,3,3-tetrachloropropène |
US15/575,980 US10427998B2 (en) | 2015-05-22 | 2016-05-04 | Compositions based on 1,1,3,3-tetrachloropropene |
PCT/FR2016/051054 WO2016189214A1 (fr) | 2015-05-22 | 2016-05-04 | Compositions a base de 1,1,3,3-tetrachloropropène |
JP2017560689A JP6959144B2 (ja) | 2015-05-22 | 2016-05-04 | 1,1,3,3−テトラクロロプロペンをベースとする組成物 |
US16/545,294 US20190375698A1 (en) | 2015-05-22 | 2019-08-20 | Compositions based on 1,1,3,3-tetrachloropropene |
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FR1554655A FR3036398B1 (fr) | 2015-05-22 | 2015-05-22 | Compositions a base de 1,1,3,3-tetrachloropropene |
FR1554655 | 2015-05-22 |
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FR3036398A1 true FR3036398A1 (fr) | 2016-11-25 |
FR3036398B1 FR3036398B1 (fr) | 2019-05-03 |
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US (2) | US10427998B2 (fr) |
EP (1) | EP3297981A1 (fr) |
JP (1) | JP6959144B2 (fr) |
CN (1) | CN107646029A (fr) |
FR (1) | FR3036398B1 (fr) |
WO (1) | WO2016189214A1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112645793A (zh) * | 2020-12-18 | 2021-04-13 | 西安近代化学研究所 | 一种生产反式-1-氯-3,3,3-三氟丙烯的工艺系统及方法 |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2937328B1 (fr) | 2008-10-16 | 2010-11-12 | Arkema France | Procede de transfert de chaleur |
FR3003566B1 (fr) | 2013-03-20 | 2018-07-06 | Arkema France | Composition comprenant hf et e-3,3,3-trifluoro-1-chloropropene |
US9255045B2 (en) | 2014-01-13 | 2016-02-09 | Arkema France | E-1-chloro-3,3,3-trifluoropropene production process from 1,1,3,3-tetrachloropropene |
FR3023286B1 (fr) | 2014-07-02 | 2018-02-16 | Arkema France | Procede de fabrication de tetrafluoropropene |
US9896400B2 (en) * | 2014-10-16 | 2018-02-20 | Spolek Pro Chemickou A Hutni Vyrobu A.S. | Process for producing a chlorinated C3-6 alkane |
KR20180041123A (ko) * | 2015-08-19 | 2018-04-23 | 스폴렉 프로 케미코우 어 허트니 비로부, 아크시오바 스폴렉노스트 | C3 염소화된 알칸 및 알켄 화합물을 생성하기 위한 프로세스 |
FR3056222B1 (fr) | 2016-09-19 | 2020-01-10 | Arkema France | Composition a base de 1-chloro-3,3,3-trifluoropropene |
EP3647301A4 (fr) * | 2017-06-30 | 2021-01-13 | Central Glass Company, Limited | Procédé de fabrication de ,3 dichloro difluoropropène |
FR3078698B1 (fr) | 2018-03-07 | 2020-02-21 | Arkema France | Procede de production du 2-chloro-3,3,3-trifluoropropene |
FR3078700B1 (fr) | 2018-03-07 | 2020-07-10 | Arkema France | Procede de production du 2,3,3,3-tetrafluoropropene |
FR3078699B1 (fr) | 2018-03-07 | 2020-02-21 | Arkema France | Procede de production du 2,3,3,3-tetrafluoropropene |
FR3081158B1 (fr) | 2018-05-16 | 2020-07-31 | Arkema France | Procede de production du 1-chloro-3,3,3-trifluoropropene. |
FR3083232B1 (fr) | 2018-06-27 | 2021-11-12 | Arkema France | Procede de production du 1-chloro-3,3,3-trifluoropropene |
FR3086287B1 (fr) | 2018-09-26 | 2020-09-18 | Arkema France | Stabilisation du 1-chloro-3,3,3-trifluoropropene |
CN111470937A (zh) * | 2020-05-19 | 2020-07-31 | 常州新东化工发展有限公司 | 一种吸附提纯1,1,2,3-四氯丙烯的方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5705779A (en) * | 1996-08-08 | 1998-01-06 | Alliedsignal Inc. | Preparation of 1,1,1,3,3-pentachloropropane by photochlorination of 1,1,1,3-tetrachloropropane |
WO2010059496A1 (fr) * | 2008-11-19 | 2010-05-27 | Arkema Inc. | Procédé de fabrication d'hydrochlorofluorooléfines |
US20120190902A1 (en) * | 2011-01-26 | 2012-07-26 | Nyberg Janice M | Stabilization of Chloropropenes |
WO2015175791A1 (fr) * | 2014-05-16 | 2015-11-19 | Occidental Chemical Corporation | Procédé de fabrication de 1,1,3,3-tétrachloropropène |
Family Cites Families (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5616819A (en) | 1995-08-28 | 1997-04-01 | Laroche Industries Inc. | Process for preparing fluorinated aliphatic compounds |
FR2768727A1 (fr) | 1997-09-23 | 1999-03-26 | Atochem Elf Sa | Synthese du 1,1,1,3,3-pentafluoropropane |
US5877359A (en) * | 1998-01-27 | 1999-03-02 | Elf Atochem North America, Inc. | Uncatalyzed liquid phase fluorination of 1230ZA |
US6013846A (en) | 1998-03-05 | 2000-01-11 | Elf Atochem North America, Inc. | Azeotrope of HF and 1233zd |
JP3804289B2 (ja) * | 1998-09-22 | 2006-08-02 | ダイキン工業株式会社 | 1,1,1,3,3−ペンタフルオロプロパン及び/又は1−クロロ−3,3,3−トリフルオロプロペンの製造方法 |
US6166274A (en) | 1999-12-15 | 2000-12-26 | Atofina Chemicals, Inc. | Catalyzed liquid phase fluorination of 1230za |
US20050177012A1 (en) * | 2001-07-20 | 2005-08-11 | Pcbu Services, Inc. | Halocarbon production processes, halocarbon separation processes, and halocarbon separation systems |
CN101687735B (zh) * | 2007-04-11 | 2014-07-09 | 西方化学股份有限公司 | 稳定氯丙烯 |
FR2916755B1 (fr) | 2007-05-31 | 2009-08-21 | Arkema France | Procede de preparation d'(hydro)(chloro)(fluoro)olefines |
FR2937328B1 (fr) | 2008-10-16 | 2010-11-12 | Arkema France | Procede de transfert de chaleur |
US8735636B2 (en) | 2009-03-24 | 2014-05-27 | Arkema Inc. | Separation of R-1233 from hydrogen fluoride |
WO2010150835A1 (fr) * | 2009-06-24 | 2010-12-29 | 株式会社トクヤマ | Procédé de fabrication d'un hydrocarbure chloré |
US9206097B2 (en) | 2009-11-16 | 2015-12-08 | Arkema Inc. | Method to purify and stabilize chloroolefins |
FR2955590B1 (fr) | 2010-01-22 | 2012-03-23 | Arkema France | Compositions de nettoyage a base d'hydrochlorofluoroolefine |
US9045386B2 (en) | 2010-02-18 | 2015-06-02 | Honeywell International Inc. | Integrated process and methods of producing (E)-1-chloro-3,3,3-trifluoropropene |
FR2957350B1 (fr) | 2010-03-09 | 2013-06-14 | Arkema France | Compositions d'agent d'expansion a base d'hydrochlorofluoroolefine |
US8426656B2 (en) | 2010-04-05 | 2013-04-23 | Honeywell International Inc. | Integrated process to co-produce trans-1-chloro-3,3,3-trifluoropropene and trans-1,3,3,3-tetrafluoropropene |
US8704017B2 (en) | 2010-09-03 | 2014-04-22 | Honeywell International Inc. | Continuous low-temperature process to produce trans-1-chloro-3,3,3-trifluoropropene |
US9156752B2 (en) * | 2011-01-04 | 2015-10-13 | Honeywell International Inc. | High purity E-1-chloro-3,3,3-trifluoropropene and methods of making the same |
US8404907B2 (en) | 2011-02-18 | 2013-03-26 | Honeywell International Inc. | Process for cis-1-chloro-3,3,3-trifluoropropene |
US8436217B2 (en) | 2011-04-25 | 2013-05-07 | Honeywell International Inc. | Integrated process to co-produce 1,1,1,3,3-pentafluoropropane, trans-1-chloro-3,3,3-trifluoropropene and trans-1,3,3,3-tetrafluoropropene |
US8921621B2 (en) | 2012-02-15 | 2014-12-30 | Honeywell International Inc. | Process for the production of HCFC-1233zd |
US8664456B2 (en) | 2012-03-28 | 2014-03-04 | Honeywell International Inc. | Integrated process for the co-production of trans-1-chloro-3,3,3-trifluoropropene, trans-1,3,3,3-tetrafluoropropene, and 1,1,1,3,3-pentafluoropropane |
US8889930B2 (en) * | 2013-01-22 | 2014-11-18 | Axiall Ohio, Inc. | Process for producing chlorinated hydrocarbons |
US8907146B2 (en) | 2013-02-04 | 2014-12-09 | Honeywell International Inc. | Process for the preparation of 1-chloro-3,3,3-trifluoropropene using a phase transfer catalyst |
US9334210B2 (en) * | 2013-03-13 | 2016-05-10 | Honeywell International Inc. | Azeotropic compositions of 1,1,3,3-tetrachloroprop-1-ene and hydrogen fluoride |
FR3003566B1 (fr) | 2013-03-20 | 2018-07-06 | Arkema France | Composition comprenant hf et e-3,3,3-trifluoro-1-chloropropene |
US9255045B2 (en) | 2014-01-13 | 2016-02-09 | Arkema France | E-1-chloro-3,3,3-trifluoropropene production process from 1,1,3,3-tetrachloropropene |
-
2015
- 2015-05-22 FR FR1554655A patent/FR3036398B1/fr active Active
-
2016
- 2016-05-04 CN CN201680029733.5A patent/CN107646029A/zh active Pending
- 2016-05-04 EP EP16726920.8A patent/EP3297981A1/fr not_active Withdrawn
- 2016-05-04 WO PCT/FR2016/051054 patent/WO2016189214A1/fr active Application Filing
- 2016-05-04 JP JP2017560689A patent/JP6959144B2/ja active Active
- 2016-05-04 US US15/575,980 patent/US10427998B2/en active Active
-
2019
- 2019-08-20 US US16/545,294 patent/US20190375698A1/en not_active Abandoned
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5705779A (en) * | 1996-08-08 | 1998-01-06 | Alliedsignal Inc. | Preparation of 1,1,1,3,3-pentachloropropane by photochlorination of 1,1,1,3-tetrachloropropane |
WO2010059496A1 (fr) * | 2008-11-19 | 2010-05-27 | Arkema Inc. | Procédé de fabrication d'hydrochlorofluorooléfines |
US20120190902A1 (en) * | 2011-01-26 | 2012-07-26 | Nyberg Janice M | Stabilization of Chloropropenes |
WO2015175791A1 (fr) * | 2014-05-16 | 2015-11-19 | Occidental Chemical Corporation | Procédé de fabrication de 1,1,3,3-tétrachloropropène |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112645793A (zh) * | 2020-12-18 | 2021-04-13 | 西安近代化学研究所 | 一种生产反式-1-氯-3,3,3-三氟丙烯的工艺系统及方法 |
CN112645793B (zh) * | 2020-12-18 | 2023-02-14 | 西安近代化学研究所 | 一种生产反式-1-氯-3,3,3-三氟丙烯的工艺系统及方法 |
Also Published As
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JP2018515568A (ja) | 2018-06-14 |
CN107646029A (zh) | 2018-01-30 |
US20180148394A1 (en) | 2018-05-31 |
WO2016189214A1 (fr) | 2016-12-01 |
EP3297981A1 (fr) | 2018-03-28 |
JP6959144B2 (ja) | 2021-11-02 |
US20190375698A1 (en) | 2019-12-12 |
US10427998B2 (en) | 2019-10-01 |
FR3036398B1 (fr) | 2019-05-03 |
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