FR2977890B1 - Procede de metathese des olefines utilisant un catalyseur a base d'un materiau spherique comprenant des particules metalliques oxydes piegees dans une matrice mesostructuree - Google Patents

Procede de metathese des olefines utilisant un catalyseur a base d'un materiau spherique comprenant des particules metalliques oxydes piegees dans une matrice mesostructuree

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Publication number
FR2977890B1
FR2977890B1 FR1102221A FR1102221A FR2977890B1 FR 2977890 B1 FR2977890 B1 FR 2977890B1 FR 1102221 A FR1102221 A FR 1102221A FR 1102221 A FR1102221 A FR 1102221A FR 2977890 B1 FR2977890 B1 FR 2977890B1
Authority
FR
France
Prior art keywords
piegeed
metathesis
olefins
metal particles
catalyst based
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR1102221A
Other languages
English (en)
Other versions
FR2977890A1 (fr
Inventor
Damien Debecker
Justin Frederic Colbeau
Clement Sanchez
Alexandra Chaumonnot
Mikael Berthod
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Universite Catholique de Louvain UCL
Centre National de la Recherche Scientifique CNRS
Universite Pierre et Marie Curie Paris 6
IFP Energies Nouvelles IFPEN
Original Assignee
Universite Catholique de Louvain UCL
Centre National de la Recherche Scientifique CNRS
Universite Pierre et Marie Curie Paris 6
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Universite Catholique de Louvain UCL, Centre National de la Recherche Scientifique CNRS, Universite Pierre et Marie Curie Paris 6, IFP Energies Nouvelles IFPEN filed Critical Universite Catholique de Louvain UCL
Priority to FR1102221A priority Critical patent/FR2977890B1/fr
Priority to CN201280035137.XA priority patent/CN103857647B/zh
Priority to CA2840530A priority patent/CA2840530A1/fr
Priority to EP12748729.6A priority patent/EP2739594A1/fr
Priority to US14/232,313 priority patent/US20140179973A1/en
Priority to PCT/FR2012/000285 priority patent/WO2013011209A1/fr
Publication of FR2977890A1 publication Critical patent/FR2977890A1/fr
Application granted granted Critical
Publication of FR2977890B1 publication Critical patent/FR2977890B1/fr
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/041—Mesoporous materials having base exchange properties, e.g. Si/Al-MCM-41
    • B01J29/045—Mesoporous materials having base exchange properties, e.g. Si/Al-MCM-41 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B01J37/033—Using Hydrolysis
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/12—Silica and alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/14—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of germanium, tin or lead
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/28—Molybdenum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/30—Tungsten
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/32—Manganese, technetium or rhenium
    • C07C2523/36—Rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46—Ruthenium, rhodium, osmium or iridium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/745—Iron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/75—Cobalt
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
FR1102221A 2011-07-15 2011-07-15 Procede de metathese des olefines utilisant un catalyseur a base d'un materiau spherique comprenant des particules metalliques oxydes piegees dans une matrice mesostructuree Expired - Fee Related FR2977890B1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
FR1102221A FR2977890B1 (fr) 2011-07-15 2011-07-15 Procede de metathese des olefines utilisant un catalyseur a base d'un materiau spherique comprenant des particules metalliques oxydes piegees dans une matrice mesostructuree
CN201280035137.XA CN103857647B (zh) 2011-07-15 2012-07-11 使用基于包含捕集在介观结构化基质中的金属氧化物粒子的球形材料的催化剂的烯烃复分解方法
CA2840530A CA2840530A1 (fr) 2011-07-15 2012-07-11 Procede de metathese des olefines utilisant un catalyseur a base d'un materiau spherique comprenant des particules metalliques oxydes piegees dans une matrice mesostructuree
EP12748729.6A EP2739594A1 (fr) 2011-07-15 2012-07-11 Procédé de métathèse des oléfines utilisant un catalyseur a base d'un matériau sphérique comprenant des particules métalliques oxydes piégées dans une matrice mésostructurée
US14/232,313 US20140179973A1 (en) 2011-07-15 2012-07-11 Method of olefin metathesis using a catalyst based on a spherical material comprising oxidised metal particles trapped in a mesostructured matrix
PCT/FR2012/000285 WO2013011209A1 (fr) 2011-07-15 2012-07-11 Procédé de métathèse des oléfines utilisant un catalyseur a base d'un matériau sphérique comprenant des particules métalliques oxydes piégées dans une matrice mésostructurée

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1102221A FR2977890B1 (fr) 2011-07-15 2011-07-15 Procede de metathese des olefines utilisant un catalyseur a base d'un materiau spherique comprenant des particules metalliques oxydes piegees dans une matrice mesostructuree

Publications (2)

Publication Number Publication Date
FR2977890A1 FR2977890A1 (fr) 2013-01-18
FR2977890B1 true FR2977890B1 (fr) 2013-07-19

Family

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FR1102221A Expired - Fee Related FR2977890B1 (fr) 2011-07-15 2011-07-15 Procede de metathese des olefines utilisant un catalyseur a base d'un materiau spherique comprenant des particules metalliques oxydes piegees dans une matrice mesostructuree

Country Status (6)

Country Link
US (1) US20140179973A1 (fr)
EP (1) EP2739594A1 (fr)
CN (1) CN103857647B (fr)
CA (1) CA2840530A1 (fr)
FR (1) FR2977890B1 (fr)
WO (1) WO2013011209A1 (fr)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3007029B1 (fr) * 2013-06-17 2015-07-24 IFP Energies Nouvelles Procede de metathese des olefines utilisant un catalyseur a base d'un materiau spherique a porosite hierarchisee comprenant des particules metalliques oxydes piegees dans une matrice comprenant de l'oxyde de silicium
CN104557398B (zh) * 2013-10-28 2017-08-11 中国石油化工股份有限公司 碳五生产丙烯的方法
CN104557399B (zh) * 2013-10-28 2017-07-14 中国石油化工股份有限公司 戊烯与乙烯歧化制丙烯的方法
EP3238819B1 (fr) * 2015-03-20 2020-11-04 SMH Co., Ltd. Procédé pour la métathèse d'oléfines
FR3039544B1 (fr) * 2015-07-31 2020-02-28 IFP Energies Nouvelles Procede de metathese des olefines utilisant un catalyseur contenant du silicium et du molybdene incorpores au moyen d'au moins deux precurseurs
FR3039545B1 (fr) * 2015-07-31 2020-02-28 IFP Energies Nouvelles Procede de metathese des olefines utilisant un catalyseur contenant de l'aluminium et du molybdene
FR3039546B1 (fr) * 2015-07-31 2017-08-11 Ifp Energies Now Procede de metathese des olefines utilisant un catalyseur contenant du silicium et du molybdene
FR3039543B1 (fr) * 2015-07-31 2019-04-12 IFP Energies Nouvelles Procede de metathese des olefines utilisant un catalyseur contenant de l'aluminium et du molybdene incorpores au moyen d'au moins deux precurseurs
US10125062B2 (en) * 2015-11-06 2018-11-13 Lyondell Chemical Technology, L.P. Propylene production processes and catalyst systems for use therein
FR3044005B1 (fr) 2015-11-23 2017-12-15 Ifp Energies Now Procede de synthese d'hydrocarbures a partir de gaz de synthese en presence d'un catalyseur a base de cobalt piege dans une matrice oxyde mesoporeuse et obtenu a partir d'au moins un precurseur monomerique
EP3700668A1 (fr) * 2017-10-24 2020-09-02 Saudi Arabian Oil Company Procédés de fabrication par séchage par pulvérisation de catalyseurs par métathèse, et ses utilisations
US11446635B2 (en) 2017-12-27 2022-09-20 Sekisui Chemical Co., Ltd. Catalyst and method for producing same, and method for producing diene compound using said catalyst
US10981151B2 (en) * 2018-06-29 2021-04-20 Uop Llc Poorly crystalline transition metal molybdotungstate

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DE19805716A1 (de) 1998-02-12 1999-08-19 Basf Ag Verfahren zur Herstellung von Propen und gegebenenfalls 1-Buten
FR2843050B1 (fr) * 2002-08-01 2005-04-15 Inst Francais Du Petrole Catalyseur a base de metaux du groupe vi et du groupe viii presents au moins en partie sous la forme d'heteropolyanions dans le precurseur oxyde
US7214841B2 (en) 2003-07-15 2007-05-08 Abb Lummus Global Inc. Processing C4 olefin streams for the maximum production of propylene
US7220886B2 (en) * 2004-10-27 2007-05-22 Catalytic Distillation Technologies Olefin metathesis
FR2880018B1 (fr) 2004-12-27 2007-02-23 Inst Francais Du Petrole Production de propylene mettant en oeuvre la dimerisation de l'ethylene en butene-1, l'hydro-isomerisation en butene-2 et la metathese par l'ethylene
FR2886636B1 (fr) * 2005-06-02 2007-08-03 Inst Francais Du Petrole Materiau inorganique presentant des nanoparticules metalliques piegees dans une matrice mesostructuree
FR2904243B1 (fr) * 2006-07-31 2008-10-31 Inst Francais Du Petrole Catalyseur a base d'un support hybride organique - inorganique et son utilisation en hydroraffinage et hydroconversion
DE102006039904A1 (de) 2006-08-25 2008-02-28 Linde Ag Verfahren zur Propenerzeugung in einer Anlage zur Dampfspaltung von Olefinen
FR2929264B1 (fr) * 2008-03-31 2010-03-19 Inst Francais Du Petrole Materiau inorganique forme de particules spheriques de taille specifique et presentant des nanoparticules metalliques piegees dans une matrice mesostructuree
FR2931705B1 (fr) * 2008-05-28 2010-09-03 Inst Francais Du Petrole Catalyseur a base d'un materiau amorphe comprenant du silicium a porosite hierarchisee et organisee et procede ameliore de traitement de charges hydrocarbonees
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US8704028B2 (en) * 2010-03-30 2014-04-22 Uop Llc Conversion of acyclic symmetrical olefins to higher and lower carbon number olefin products

Also Published As

Publication number Publication date
CN103857647B (zh) 2015-09-23
FR2977890A1 (fr) 2013-01-18
US20140179973A1 (en) 2014-06-26
EP2739594A1 (fr) 2014-06-11
CN103857647A (zh) 2014-06-11
CA2840530A1 (fr) 2013-01-24
WO2013011209A1 (fr) 2013-01-24

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