FR2973661A1 - METHOD FOR TREATING HAIR - Google Patents

Abstract

The present invention relates to a method of treating hair, comprising the steps of; applying to the hair a composition comprising one or more active agents chosen from: hair conditioners, reducing agents, organic or mineral bases, hair dyes, abrasive solid particles or moisturizing agents, - combing the hair by means of a motorized combing device (10) comprising pawls animated with an oscillating movement

Description

The present invention relates to methods and devices for treating hair. Tools for cleaning or massaging the hair are known US 6,283,930 B, 2002-363039 A, JP 2005-046190 A, CN 201 4658 11070019 A. The application EP 1 825 8A1 discloses a massage device deRinéà massage the scalp during the washing of the hair for example, and provides the joint use of a shampoo. The application US 2009/0182249 A1 discloses a scalp massage device comprising a reservoir that can accommodate a liquid such as a shampoo or a good stimulation of hair pop. Various scalp massage devices are further disclosed in EP 1 972 317 A1, EP 1 964 537 A1 and EP 2 080 500 A1. There is a need to benefit from a method and a treatment package which permits to get better efficiency of hair treatment assets. According to one of its aspects, the subject of the invention is a cosmetic hair treatment method comprising the steps of: applying to the hair a composition comprising one or more active agents chosen from: hair conditioning agents, reducing agents, organic or inorganic bases, hair dyes, abrasive solid particles or moisturizing agents, combing the hair by means of a motorized combing device comprising oscillating pikes, Combing the hair using the motorized device can be performed after application of the composition according to the invention to the hair, preferably in the presence of it on the hair. The combing of the hair using the motorized device can be carried out before application of the composition according to the invention to the hair, in particular after moistening the hair or after the application of a composition comprising no active ingredient according to the invention. invention. The combing may be carried out for example less than 60 minutes before the application of the composition containing the active agent according to the invention. The application of the method to curly or curly hair in combination with the composition containing the active shows a very clear effect of decreasing volume, apparent weight, better disentangling and a smoother feel, preferably characterized by the fact that it comprises a flexible membrane carrying the pins and a drive mechanism for periodically deforming the membrane to generate a displacement of the pins. The mechanism preferably comprises an oscillatingly movable rod connected at one end to a rotatably driven member by an electric motor and connected directly or indirectly to the other end with the diaphragm. in a central region of it. The oscillation frequency of the membrane is preferably between 0.5 and 200 Hz and preferably between 1 and 20 Hz, including bnes. The envelope surface defined by the free ends of the pins may be an outwardly concave surface, of which: curvature radius varies according to the deformations of the membrane. During oscillations of the membrane, at least! some dots rub on the hair. The increased performances are obtained by friction of the pins on the hair combined with the use of the composition. The invention makes it possible to obtain an effect superior to that obtained by the method. Preferably, the pins are made of a thermoplastic material. The invention further relates, in another aspect, to a motorized combing device 25 for mine of the above process. The invention also relates to a motorized combing device comprising a flexible membrane bearing the pins adapted to contact the hair, and an entablature mechanism for periodically deforming the membrane to generate the movement of pista in contact with the hair and a reservoir containing a composition to be applied as a pre-filled removable cartridge.

Assets The composition according to the invention applied to the hair may contain at least one of the following active ingredients. The active ingredient (s) may be applied alone or in combination with other ingredients. According to this latter embodiment, the active ingredient may represent up to 50% by weight of the total composition weight, preferably up to 20% by weight of the total weight of the composition. The asset or assets can represent more than 0.001%, better than 0A%, even better! 0.2% and more particularly more than 0.5% by weight relative to the total weight of the composition. Capillary dye means, for the purpose of the present invention, synthetic direct dyes, natural dyes and dye precursors.

oxidation. These hair dyes may be nonionic or ionic, in particular cationic or anionic. The oxidation dye precursor (s) present in the composition of the present invention may be chosen from oxidation bases and couplers conventionally used for oxidation dyeing. The oxidation base (s) may be chosen from among the para lenediames, the blyg n laen iam £ gm, pal + am {#op ns, his-paraaminophenols, oRh samin henob, the 0rtho phenene s, heterocyclic bases and their addition salts. Among the phenethylamines, there may be mentioned, by way of example, para-phenylamine, peraminamine, 2-chloro per phenylene in 2,3-dimethylpyridine è edi ^ m, the dim +! pU + phenylene, 2,6-diethyl parphenylamine, and the para-phenylamine, N, imethrap n eeam / nc, N, p2 + 2hen7J! friend # A N, N-diethyl 3-methyl N, N-is- (xt) by phenylene diamine, 4-N N-is- ( (2-methyl aniline), N-hydroxyalkylamino) aniline, 2-methylparaphenylamine, 2-methylbenzylamine, 2-methylaniline, phenyl (acmamene, N (omex! opue) pg + ph n èn Grnia% la 2 iy oxy 66 @ 2 + 2hényiè iami "% N, -diméth3'm & hyl pg + Çhén ènediami, N, / Ah3 () -hm xycth) for phenol iami5%. N /), y-diih d xyp p) - para p nenaminin N- (ninhénx) para p1én enamie, the N hem! paraphe diamine, the 2d-hydo + xy pa has phen ned the mile !, the 23rd. "Aminoethyloxyparamethoxyphenylamine" (N-phenylthyl) para phenylenediamine, 4-aminophenylpyridinylphenylamine, 2-hydroxyethylamino-5-amino-toluene, 3-hydroxyoxy-1,4-amam £ # hen yJ ine and their salts of addition.

Among the phenamines mentioned above, para-phenyl amine, para-amido iamit-2 sopro, initialed !! ethanol, 2-hydroxyethoxy 2-phenylamine, 2-yl xylethoxy by + 5% diphenylamine, 6% triethylamine, 6% perchloramine, 3% para-ammethylamine, (2) para-phenyl S amine 2-acetylamino-6-oxy-para-phenylene diamine, and their addition salts are particularly preferred. Among the examples which may be mentioned are, for example, N, N-hydroxy-N, N- (N-) aminopropanol, N, N-oxyne), Eblw (N-phenyl) ethylenediamine, N, N'-bis- (4-aminophenyl) -trimethylamino, N, N-N-oxyethyl N, S bis (-N-E-phenyl) ## EQU1 ## ## EQU1 ## ## where ## STR1 ## is the N, sbis (Et) N, (Emino, 3 'methyl) ethylenediamine, 1,8-bis- (2,5) diamino phenoxy) -3,6-dioxaoctane, and their addition salts. Among the para-amines, para 2 -phen, 4-methylphenol, 4-fluoro-phenol, 4-aminodiphenol, 4-methylphenol, 4-methylphenol 4 amio 2 methphenol, the 4 amino 2 h 2 methylamino, the 4 amine 2 methox ma6 phenol, the 4 aminon aminon ethphenol, the 4 amino> drox aminomethyl) phenol, the 4 ammo 2 fluorophenol, and their addition salts.

Examples include 2-amino phenol, 2-methyl-phenol, 2-amino-6-phenol, 5-acam-2, and the like. ino phenol, and their addition salts.

Among the heterocyclic bases, mention may be made, by way of example, of pyridine derivatives. derivatives perir and pyrazole derivatives. Among the pyridine derivatives, mention may be made of the compounds described for example in patents GB10269 and GB11531 196, co-diaminopyridi, la2 (4 m as #yphenl) amino 3-ami no pyridine, 2,3-diamino6 methoxy pyridine, 1-methoxy-3-amino-6-methoxy pyridine, 3-pyridine, and their addition salts. Other pyridinic oxidation bases in the present invention are the 3-amino pyrazolo [1,5-a] pyridine oxidation bases or their addition salts described, for example, in US Pat. No. 2,801,308. By way of example, mention may be made of pyrazolylamine, 2-aminopyrazolo [l] quinolamine; 2 lpyrazGo morplin, 5-jpyri clin-3 lamine; 3-amino-azo-5-alpylidin-2-carboxylic acid x; R 6 oxoxy-1Hazol, p dinamino; (3-Aminopyrazolo [1,5-aididin-7-yl] -methariol; 2α, 5α-diisopropylamine, ethanol, 5α-diol, 2-aminopropylbenzylamine, 2-aminopropylbenzylamine, 2-aminopropylbenzylamine, 2-aminopropylbenzylamine, 2-aminopropylbenzylamine, 2-aminopropylbenzylamine, 2-aminopropylbenzylamine, 2-aminopropylbenzylamine, 2-aminopropylbenzylamine, 1-aminopropylbenzylamino-2 Yridine, 3-diamine pylazo, pyridine, pyrazine, pyridine 3, 6min, 7 m orptin, 4-pazolazole, p-amine, p-aminopropylamine; 3,5-amine, 5-morphol-2-ylmethylamine, 24 (3 min pyrazol, 1.5 micromethyl) -ammonium-1-amine, 2-mole pyro, 3-Aminoazo [a] amino-3-aminopropyl-3-amino-3-amino-3-aminopropyl-3-amino-3-amino-3-aminopropyl-3-aminopropyl-3-aminopropyl-3-aminopropyl-3-aminopropyl-3-aminopropyl-3-aminobenzylamine. Examples of the compounds which may be mentioned include, for example, the compounds described in patents DE 23 59 399. Or Patent Application WO 96/15765, as described in US Pat. No. 5,709,475, or Patent Application WO 96/15765, as described in US Pat. 6- + miramine, 4 Æt / droxy 5,6-diamin yrimidine, 5,6 iamiop rimidine, and derivatives pyrazo 7yri ESQ s such as those mentioned in the d patent application FR A 2,750,048 and among which we may mention the Ta o, -a] y3m! -3, diamine, 1,5-di-kthpyrazol [1-a] -pyridine, diamine, 1- [1,5a-pyrimidin-3,5-diamine; 7dime l p az, 5-a] -pyrrolidine e-3,5-diamine; 3-anilyl, 5-pyridyl; 3-amino pazo, 5a-imidin-5-ol; 2 (3 mils o pyrazo, p-pyrazolaminoamino), 2α-amino pyrazolo- [1,5-a] -pidimidin-3-ylamino) ethanol, [(3-amin-pyrazo)); -a] pyf; e / di) - h / dxxet6) -ino a, 2 / 7am / n-pyrazo / -a} m in-3 ydr0) th) -no] kt, the 56dimeth pJazo,] - pyim ine3, -diGml. + $ dimethp / Iazolo [1,] -pyri 1 -3, - amine, 2,5, NN 7a # amethiopro /, 5yyimidin-3, -diam /, la3-a nino 5m hy Propylamine, p-azo, -pyrimene and their addition salts and tautomeric forms, when tautomeric equilibrium exists. Among the pyrogenic derivatives, mention may be made of the compounds described in DE 38 43 892, DE 41 33 957 patent applications WO 94/08969, WO 94/08970, FR A 733 749 and DE 195 43 988 as the 4 5-diamino-1- (p-hydroxyethyl) pyrazole, 4,5-diamino-1-methyl pyrazole, 3,4-iodo pyrazole, 4,5-diamino ) 4,5-diamino-3-methyl-4,5-diamino-3-methyl-5-dimethyl-5-dimethyl-5-dimethyl-5-dimethyl-5-dimethyl-5-dimethyl-5-dimethyl-5-dimethyl-5-dimethyl-5-dimethyl-5-dimethyl-5-dimethyl-4-dimethyl-5-dimethyl-5-dimethyl-5-dimethyl-5-dimethyl-5-dimethyl-5-dimethyl-5-dimethyl-4 pyrazole, 4,5-diamino-3-methyl-pyrazole, 5-amino-3-tert-butyl-methyltriazole, 4,5-diamino-1- (tripthanol); 3-methylpyrazine, 5-diaminol) 2drox 2f) 3-methylhexyl, 5-anainol 3-methpyfaze, 4,5-diamino-1-ene (4m (A np) pyrazole, 4 5-diamino and 3-yl pyrazole, 4,5-diamino-3-ylmethylmethyl-meth-3-aze, 5-diarnino-3-ylmethyl-1-isopropyl pyrazole, 5-amino-3-methylpolaze, 4 amineoct), 1,3,5-amino-pyrazole, 1-methyl-3,4-methylamino pyrazole, 3,4-diamino-1-methylmethylamaze, 1-3,5-diamino 4 -hk th) amino-1-methylpyrazole, 3-amino-6,7-dihydroxybenzylamine and their addition salts. The coupler (s) present in the composition according to the present invention may be selected from the group consisting of mk + nhé Æ £ £ 2 2 #,,, mA + Æphén s, naphthalenic couplers, heterocyclic couplers and their salts. addition. By way of examples, mention may be made of 3-aminophenol, 2-methoxyphenol, 2-methyl-5-aminoethyl phenol, 2-chloro-3-amino phenol, 1,3-yl oxy. benzene, 1,3-methoxybenzene, 1,3-aminobenzene, 4-amino-3-hydroxybenzene, 2-amino-4,4-hydroxyethylamino), and 1,4-aminobenzene; > 3-bα2, - diamino-henox propane, 3-uro-Andeanine, 3-ure-I-dimethylamino benzene, sesamol, ydro & yethamino l / -m ~ £ è iox cnzéne, / na h Æ the 2m ¥ thy- 1H, 6-hydyl, 4-hydroxyl, 4-hydroxy-N-methyl-indole, 2-amino-3-oxy-pyridine, 6-hydroxy-6-methylamine, and 6-hydroxyethylamine. Jine, the lN <6 th, 6) friend "o 3, -A ¨ thè e dioxy enzi, the 6 bis \ hydroxyether am no) t ue e! and their addition salts. In general, the addition salts of the oxidation bases and couplers that can be used in the context of the invention are especially chosen from acid addition salts such as hydrochlorides, hydrobromides, sulphates and citrates. , saccharides, tartrates, lactates, (C 1 -C 4) alkylsulphonates, and

acetates and addition salts with a base such as sodium hydroxide, potassium hydroxide, ammonia, amines or alanolamines.

By natural lovants, o,! means any dye or dye precursor having a natural occurrence and produced either by extraction (and optionally purification) from a vegetative matrix: or by chemical synthesis. By contrast, synthetic dyes are understood to mean any dye that does not have a natural occurrence.

As examples of suitable synthetic direct dyes, mention may be made of azo direct dyes; methine; carbonyls; mimicry; nitrates Aer are; t1 / ho (f) ary methanes; seou in mixtures. More particularly, azo dyes have a function whose two nitrogen atoms are not simultaneously engaged in a ring. However, it is not excluded that one of the two nitrogen atoms of the sequence -Nt-M. be engaged in a cycle. The dyes of the methine family are! more particularly compounds comprising at least one sequence chosen from> C = C <and -N = C <, the two atoms are not simultaneously engaged in a ring. However, it is specified that one of the nitrogen or carbon atoms of the chains can be engaged in a cycle. More particularly, the dyes of this family are derived methine-type compounds true (comprising one or more -C-C-chains above); azomethine comprising at least one or more sequences (N) with, for example, azanyanine and their isomers, diazacarbocyanines and their isomers, G2aazAalkyans; mono- and di-acetylated amines (or diphenylamine); indophenols; With regard to the dyes of the carbonyl family, mention may be made, for example, of the dyes chosen from acridone, benzoquinone, anthrinin, nap toq! Li o, bey anron e, a 62a thne, pr ehon e, py azan62 e, inoantbrone rim, At anthro, idanthr0, flavone, (iSo) violanthr0, isoi ino, nzi £! azo. quinone anthrapyridone, pyrazoloquinazolone, perinone, naphthalene, phenyl, indie, toin, naphthalimide, antinebridine, dicem / pyrrole coumarin. Conèernan (the dyes of the family of aziniques, one can quote in particular the mines, xa tea, thioxanthène, gia, 6! #E, (di) oxazine, (di) thiazine, py m £, the dyes Aera aroma are more particularly nitro benzene or nitro pyridinic direct dyes. Concerning the porphyrin-type dyes or yanit> can be used cationic or non-cationic compounds, optionally comprising one or more metals or metallics, as for example, alkali and alkaline earth metals, zinc and silicon, Examples of particularly suitable direct dyes are nitro dyes of the benzene series, azo direct dyes, and especially azomethine dyes; diazacarbocyanines and their isomers and tetraazacarbocyanines (t6 # aaza lek ines), quinone direct dyes and in particular anthrylic dyes, na htoqui niquesSou be oquinonie; direct azic ants; trarylene; in am ni es; i di es; phtalo ani setporphyrins; in mixtures. Preferably, the direct dyes are chosen from nitro dyes and the benzene series; azo; azamines to diazacarbocyanines and their isomers; 2aaza ar oocyanines (! 6 # aaza e5 {m "Ahi s); direct anthraquinone dyes 30; the direct corang triarylmethaniq5; only Ouen mixes. Even more preferably, these direct dyes are chosen from nitro dyes of the benzene series; the azo direct corats azomethi azornethines with the diazaearboeyanines and their isomers, the 2aacg) yaines (tetraazapentamethines) alone or in mixture. Among the nitrobenzene direct dyes that may be used according to the invention, the following compounds may be mentioned in a nonlimiting manner: ## STR2 ## bis) ydmxyeth / aminoyonz§2C 1 / -Bis (yd oxyethylamine or-1-ydroxyctharnin nitrbly (P-hyoxycthami = s cnzé # c IO 4 -P 7droxycthamino tr4 amino ene e G-0 2droxyet friends ## EQU0000 ## 15-1-amino-2-pyridinium-5-bromo-5-bromo-1-methyl-5-naphtholamine 5-aminobenzon 1-hydroxybenzoyl 4-hydroxybenzoyl 4-Hydroxy-3-nitro-4-hydroxy-2-amino-4-nitro-4-nitro-4-yloxy-2-hydroxy-2-hydroxy-2 Q-Mehox hydroxyeA amines5-ni! fobenzenamine I -p 2droxyethox -mémino 4 n12obenzène 25 1 dihy oxyppox -methamino 4 nitrobenzene Q-P ydroxyethi o-d! Nitrogen-4-methyl-4-methyl-4-methyl-4-methyl-4-methyl-4-methyl-4-methyl-4-phenyl-4-phenyl-4-benzoyl-4-benzoyl-4-methyl-3-methyl-benzoyl amino 5 methoxy 2 ni 2 o) C nze Q-dok 2-c oI eth lamines nl 20 nzéLe "1 d \" chlor-l-4-ni ee G- dr0k 6-bà / hy oxyét / amig 3-610 nzéSe -1 -0 ydr0 & ycthamino 2 nitrenzé§e -I -H / drox x thamino 3 iI! enzène. Among the azo, azomethine and methine direct dyes that may be used according to the invention, mention may be made of the cationic dyes described above. in the patent applications WO 95/15144, WO 95/01772 and EP 7 149 54; No. 2,189,006, EP 2 285 851, FR 2 140 205, EP 1 378 544 and EP 1 674 073. For example, the synthetic direct peptide (s) can be chosen by cationic direct dyes mochrom d§ S of types azo; MeTHF # es; Azomates with diazacarbocyanines and their isomers, tetraazacarbocyanines; anqu noniq s; alone or in mixture. Thus, mention may be made, in particular, of the cationic direct dyes corresponding to the following formulas: sulfate acetate, 2973661 R, A-D '= D in which; D represents a nitrogen atony or the group -CH, RI and R2, identical or different, represent a hydrogen atom; a C1-C4 alkyl radical which may be substituted with u. radical -CN, -OH or -NH2 or form a carbon atom of the benzene ring optionally oxygenated or nitrogen heterocycle, which may be substituted by one or more C1-C4 alkyl radicals; a 4'-aminopheryl radical, R3 and R'3, which may be identical or different, represent a hydrogen or halogen atom chosen from chlorine, bromine, iodine and fluorine; C4 or acetyloxy, X - represents an anion preferably selected from the chloride, mail It A reesete grouping chosen by the following structures: R4.Ne, W

e '. / R4 t. In which R4 represents a C 1 -C 4 alkyl radical which may be substituted with a hydroxyl radical; in which: R5 represents a 62droge atom, a C1-C4 alkoxy radical, a halogen atom, and bromine, chlorine, iodine or fluorine R6 represents a hydrogen atom or a C1-C4 alkyl radical; or form with a carbon atom of the benzene ring a heterocyclic ring optionally oxygenated and / or substituted by one or more C1 -C4 alkyl groups, R7 represents a halogen atom, such as bromine, chlorine or iodine; or fluorine, D1 D2, identical identical, represent a nitrogen atom or the group -CH, m = 0o = \ X - represents an anion sot it quem 1 acceptable and preferably chosen pue \ chloride, methsr / " and acetate E represents a group chosen by the following structures: embedded image in which R represents a C 1 -C 4 alkyl radical; when i = 0 and D1 represents a nitrogen atom, then E can also designate a group of following structure: X -

in which R 'represents a C 1 -C 4 alkyl radical. Among the abovementioned compounds, the following compounds (A2) CH 2 are used in particular. 3 N CH3 x -NN) 01-13 N ---- -NH, X --- N CH3 CH3, -N (/ NH, Y- (A3) (A5) CH, CH3 (M) X representing an anion or a mixture of cosmetically acceptable anions As other dyes that may be used according to the invention, mention may also be made, among the azo direct dyes, of the following dyes, described in the COLOR INDEX INTERNATIONAL 3rd edition: -Disperse Red 17 15 -Disperse Red 13-Basic Red 22 -Basic Red 76-Basic Yellow 57 -Base Brown 16 -Basic Brown 17 -Disperse Green 9 -Disperse Black 9. -Solvent Black 3 -Disperse Blue 148 -Disperse Violet 63 -Solvent Orange 7th We can also quote 1- (4a-a (1-ethylhexyl) -2-ethyl-p-hydroxyethyl) aminoberene (Non [NCI: HC Yellow 7] Among the quinone direct dyes, the following dyes may be mentioned: Disperse Red 15 -Solvent Violet 13 -So1 Wind Blue 14 -Disperse Violet 1 -Disperse Violet 4 -Disperse Blue 1 -Disperse Violet 8 -Disperse Blue 3 -Disperse Red 1 -Disperse Blue 7 -Disperse Blue 14 -Low ic Elne 22 -Disperse Violet 15 disperse Blue 377 -Disperse Blue 60 -Basic Blue 99 as well as the following compounds: 1-Etlylmorphol i-propyla-4-hydroxyanthraquinone -1 -Aminopropyl-4-methylaminoant aquinone -1-Aminopropyla inoanthraquinone -5-3 Example 2-Aminoocthamisoan # 2 uinone Q / -86 / -d & 1 aminanui-60-1-hydroxyethyl-1-ethylcarbamoyl 2-Aminocthamisoan # 2 Another example is coumarin Disperse Yellow 82. The following are the following compounds: Basic Blue 17 -Base Red 2 -Solvent Orange 15. Among the triarylmetharasic dyes that can be used according to the invention, mention may be made of the following compounds: 10 -Basic Green 1 -Basic Violet 3 -Basic Violet 14 -Basic Blue 7 -Basic Blue 26 Among the indoamine dyes which can be used according to the invention, mention may be made of the following compounds: ## STR5 ## 4Eamin anit -I / enzoq ino 20 GN% Chl4 'ydro & p £ 62 -acetllaminm Aboli I, 4 enzoquino imine 3-N '-C -AAh Phenibur3l mib m + h bI, enzoqui imine -' - / ett Agam meta "ino] -p1 £ -ur6d me abI, 4 benzoquinone imine. Preferably, the cationic direct dyes are chosen from azo direct dyes; m Ahl s; azomethines with the diazacarbocyanines and their isomers, "#aaz arbocyani es étraazentamahlnes); anthraqui # mcques, alone or in mixture Among the direct mimic dyes can be mentioned especially those described Jase COLOUR INDEX INTERNATIONAL 3rd i2misous ap / ttaion ACID "in particular: -Disperse Red 17 -AGJYelw9 -Acid Black 1G / Yellow 36 6J Orange 7 -Mid Red 33 -Mid Red 35 -Acid YÜ w23 -Acid Orange 24 -Acid Violet 43 -Aeid Blue 62 -Acid 9 -Mid Violet 49 -Aeid Blue 7.

The particular natural dye (s) which are suitable for the implementation of the invention are preferably chosen from the laws of the United States, Alizarin, Purpurin and Acidic Acidic Acid. Acacia, parpu o fine, Canüragall, protocatéchaldéhyde, indigo, garaine, curcumine, spinusoline, chlorophylls, loroph liges, cephalogyme, hdmatoxie, braziline, braziline, dyes of safflower (such as, for example, carthamine)> flavonoids (with, for example, fine, eniÆ1, sandalwood), anthocyanins (of the bath type, carotenoids, tannins, sorghum) and the cochineal carmine or mixtures thereof The extracts or decoctions containing these natural dyes, and in particular the extracts with tentai base, may also be used. Preferably, the natural dye (s) are chosen from lawsone, ju o, 2 / yzarinGlapurpuin Acetic acid, acetic acid, acetic acid, lacuric acid, urea, allergy, ateca kde, di, isatin, curcu, ie, apigenidine, ch, rophy fine, sorghum, orceins, cochineal bath, hem + G, themato in brazine and azie and mixtures thereof. corats can optionally be used in the presence of mordants (eg salts of zinc, manganese, aluminum, iron,. Reducing agents. Eacomposition can contain at least! a reducing agent capable of reducing the bonds (bisulfides of the hair, it is possible to use an alkaline phosphine reducing agent or an sulphite or a bisulphite). Advantageously, a thiolated reducer is used. Preferably, the thiol or thiols used as reducing agents in the reducing composition are chosen from aminothiols such as eysteb and its derivatives, such as Nucleic acid, stearl and its derivatives, preferably its C1-C4 acyl derivatives. such as N ty! cysteamine and N-pion cysteamine, and non-amino thiols such as t-1-tiq acid and its esters, such as the glycerol moiety actea e, thioglycolic acid and its esters, such as glycerol monothioglycolate or When the thiol has at least one carboxylic acid function, it is possible, if appropriate, to use said thiol in the form of one or more of its salts, such as the alkali metal or ammonium salts. It is thus possible to use ammonium thioglycolate as thiol. If an amino group is used, it may optionally be used in the form of one or more of its salts, such as aminothiol halides. . As aminothiols used in the reductive composition used according to the invention, mention may also be made of N-αOca or alkylamines of sugars, such as N ~ (mero 2 6thlunam e, pa f / Aæe, N (ercaptoalk) 6 / Examples of these are those described in Patent Application No. PA 54,835 and the N mono- or N, ikm 2, and 4-hutyramides, such as those described in patent application PA 68,763, US Pat. Such as those described in patent application A. 32 000 and alkylaminomercaptoalkylamides such as those described in the application and PA 14 282. Among the non-amino thiols used in the invention may also be mentioned the thioglycolate hyd ox mixture 2 propyl (2/3) and thioglycolate of 2-oxoethyl (67/33) described in application and FR A 679 448, 13-mercaptopropionic acid and its derivatives, and thiomalic acid. It is possible to use a reducing agent, in particular thioglycolic acid and cysteine.

Base if! 5 ml ml ales. For defecation, deforts such as alkali or alkaline earth metal hydroxides, transition metals and organic hydroxides can also be used. Examples of hydroxide compounds that may be mentioned are sodium hydroxide, lithium hydroxide, calcium hydroxide, magnesium hydroxide, barium hydroxide, strontium hydroxide and manganese hydroxide. Zinc hydroxide, guanine hydroxide, and preferred hydroxyl compounds are sodium hydroxide, calcium hydroxide, lithium hydroxide, and gua-inium hydroxide. The packaging agent may be chosen from the group comprising non-silicone cationic polymers, non-silicone cationic surfactants, silicones, especially organosiloxanes, linear or branched C8-C30 hydrocarbons, linear fatty alcohols or branched e !! C8 C30, C8-C30 fatty acid esters and C30-C30 polyol monoalcohols, including C8-C30 fatty acid esters and C8-C30 fatty alcohols, C1 + acid or C1-diacid salts; -C7 and fatty alcohol in

The term "non-siculated cationic polymer" means a polymer which does not have any at least one silicon in its structure, positively charged when it is contained in the composition according to the invention. This polymer may carry one or more positive permanent charges or contain one or more cationizable functions within the composition according to the invention. The cationic polymer or polymers which may be used as conditioning agents according to the present invention are preferably chosen from polymers containing primary, secondary, tertiary and / or quaternary amine groups which are part of the polymer chain or which are directly connected thereto, and which have a molecular weight of from 500 to about 5,000,000 and preferably from 1,000 to 3,000,000. When the conditioning agent is a cationic polymer, it is preferably selected from those containing units having primary, secondary amine groups, Tertiary and / or quaternary may either be part of the polymeric backbone or may be carried by a side substituent directly connected thereto. Among the cationic polymers, mention may be made more particularly of the polyamine, polyaminoamide and p6 / quaternary ammonium type polymers. These are known products. They are for example described! in French patents Nos. 2,505,348 and 2,542,997. Among these polymers, mention may be made of: (1) homopolymers or copolymers derived from acrylic or methacrylic esters or amides and comprising at least one of the following units of formulas: Wherein R3 and R4, which may be identical or different, are as follows: ## STR2 ## wherein R3 and R4, which may be identical or different, represent hydrogen or an alkyl group having 1 to 6 carbon atoms and preferably methyl or ethyl; R5, which may be identical or different, denote an identical or different hydrogen atom or a radical, represents a linear or branched alkyl group, 1 to 6 carbon atoms, preferably 2 or 3 carbon atoms, or a drox3 / k group of 1 to 4 carbon atoms; neatline; R 7, R 8, which may be identical or different, represent an alkyl group having to 18 carbon atoms or a benzyl radical preferably a 1 to 6 carbon alkyl group; X denotes an anion derived from a mineral or organic acid such as a methosulphate anion or a halide such as chloride or bromide. The copolymers of the family (1) may contain in addition to one or more moieties derived from moieties which may be selected from the family of r lam, mechales, acetamides acrylamides, acrylamides and methaerylamides substituted on the nitrogen by lower alkyls (C1-C), acrylic or methacrylic acids or their esters, vinyllactams such as pyrrolidone or vinyl acetate, and among these copolymers of the family (1), mention may be made of: dimethylaminoethyl methacrylate copolymers which are dimethyl sulphate or with a dimethyl hologenide, such as that sold by the company HERCULES under the name FIERCOFLOC, the copolymers of alkali metal chloride and methacrylate chloride. described for example in the patent application EP-A-080976 and sold under the name BINA QUAT P 100 by the company CIBA GG - the copolymer of ace and m 6 sulfagi m # 6 lo oxytthtri 6thÆmmoni v DETAILED RETEN by the company HERCULES, the copolymers vin on / acrylate or methacrylate of 6K! aminokk q + r or not, such as the products sold under the name "GAFQUAT" by the company t as for example "GAFQUAT 734" or "GAFQU 755" or the products referred to as "COPOLYMER 845, 958 and 937". These polymers are described in detail in French Pat. Nos. 2,077,077 and 2,393,573; dimethylaminoethyl methacrylate / water-ae1am2 / viyrr EJO such as the product sold under the name GAFFIX VC 713 by the company P the copolymers, for example, under the name STYLEZE CC 10 by ISP, are preferably used under the name STYLEZE CC 10. and quaternized copolymers such as the product sold under the name "GAFQUAT HS 100" by the company ISP, and the crosslinked polymers of AA6acroxyalkyl-C trialkyl-C salts. Ammonium such as the polymers obtained by homopolymerization of dimethylaminoethyl methacrylate quaternized with methyl chloride, or by copolymerization of amylamid with methylamine methyl methacrylate quaternized by methyl chloride, 267 ° or the copolymerization being followed by crosslinking by an unsaturated compound, especially methylenebisacrylamide. It is more particularly possible to use a crosslinked acrylamide / methylene chloride / trimethylammonium chloride copolymer (20/80 by weight) in the form of a dispersion containing 50% by weight of said copolymer in mineral oil. This dispersion is marketed under the name "S LC AREA SC 92" by CIBA. It is also possible to use a crosslinked monomer of acrylamide trifluorethylammonium chloride, for example dispersed in mineral oil or in a liquid ester. These dispersions are sold under the names "SALCARE + SC 95" and "SA CRE®". SC96 "by the company CIBAa (2) polymers consisting of patterns p! Either straight or branched chain divalent radicals, optionally interrupted by oxygen, sulfur, nitrogen or aromatic or heterocyclic rings, as well as oxidation products and or quaternization of these polymers. Such polymers are especially described in French patents 2,162,025 and 2,280,361 (3) the water-soluble pyamines prepared especially by polycondensation of an acidic compound with a polyamine; these polyaminoamides can be crosslinked by an epihalohydrin, a diepoxide, a dianhydride, an unsaturated dianhydride> a bis-unsaturated derivative, a bis-haline, a bis-az + ini, a bis-acamami, a bis-halide or by an oligomer resulting from the reaction of a bis-halogenide-reactive bis-halogen compound of a bis (azidinium), a bis (2-yl) diamine or a bis-halide. alkyl, halo, ydrin, di oxide or bis-unsaturated derivative; the stabilizing agent being used in proportions ranging from 025 to 35 mol per amine group p62m amine; spi 7aminoam will be expected to be ak és or if they include one or more f tertiary amines functions, quater isées. Such polymers are described in French brets 2252 840 and 2,368,508; (4) The polyamino derivatives resulting from the condensation of polyamines with polycarboxylic acids followed by alkylation with bifunctional agents. For example, the adipipediacoylaminohydroxyalkyldialoylene triamine polymers in which the alkyl radical comprises to 4 carbon atoms and preferably denotes methyl, ethyl, propyl. Such polymers are described in particular in French Patent L583,363. These derivatives include, in particular, the adimethamino-p-p-trimeric acid polymers sold under the name Cartaretine F, F4 or F8 by the company Sandoz. (5) polymers obtained by reaction of a polyamine having two primary amine groups and a secondary amine group with a dicarboxylic acid selected from diglycolic acid and saturated aliphatic dicarboxylic acids having from 3 to 8 carbon atoms. The molar ratio between the pyalkene p monamine and dicarboxylic is between 8: 1 and 1,4: the resulting polyaminoamide being reacted with epic ydrin in molar ratio ic016 \ dine compared to secondary amine group p yami amecompris between 0.5: let 1.8: 1. Such polymers are especially described in! US Pat. Nos. 3,227,615 and 2,961,347. Polymers of this type are especially marketed under the name "Hercosett 57" by Hercules Inc.. or under the name "PD 170" or "Delsette 101" in Hercules in the case of the adipic acid / epoxypropyl-diethylenetramine copolymer. (6) cyclic diallyl amine or diallyl ammonium cyclopolymers, such as homopolymers or copolymers comprising, as the main constituent of the chain, units corresponding to formulas (V) or (VI): (CH 2) CH 2) - CR 22 C (Rq / CH1 ~ 1 CH2 CH2 (V) N N ÷ R! Formulas in.le2mket t are equal to o or 1, sum k + equal to 1; R12 denotes a hydrogen atom or a methyl radical; RIO and k! independently of each other, denote an alkyl group having 1 to 6 carbon atoms, a hydroxyalkyl group in which the alkyl group preferably has 1 to 5 carbon atoms, a lower amidoalkyl group (C1-C4). or RIO and RI 1 may together with the nitrogen atom to which they are attached> designate heterocyclic groups such as piperidinyl or mo ph in; Y- is an anion such as bromide, chloride, acetate, borate, citrate, tartrate, bisulfate, bisulphite, sulfate, phosphate, polymers are especially described in the patent 2,080,759 and in its certificate of addition 2,190,406. RIO and RI 1, independently of 1%, preferably denote an alkyl group having carbon datomas and more particularly 1. Among the polymers defined above, there may be mentioned more particularly the chloride chloride dimethe Æ / lan mniul sold under the name "Melk at 100" by the company N LCU (and its low weight average molecular weight counterparts) and the copolymers of diazo-ammonium chloride and ammonia sold under the trade name "RQUAT 550". (7) the quaternary diammonium polymer containing repeating units having the formula: / (CH 2) k

CR22 (R12-CH2 CH2 / CH2) ## STR4 ## wherein R13, R14 and the like are the same or different; are aliphatic, alicyclic, or aryl radicals containing 1 to 20 carbon atoms or lower hydroxyl radicals, although heterocycles optionally containing a second heteroatom other than nitrogen or R13, R1, R15 and R16 represent a substituted linear or branched C1-C6 alkyl radical

By a nitrilo ester group, acyl amide o-CO-O-RI D or -CO.NG-R17 D RI 7 is an ak / Grc / D a quaternary ammonium group;

Al and B represent pymethenic groups containing 2 carbon atoms which may be linear or branched, saturated or unsaturated, and may contain, bound to or intercalated in the main chain, one or more aromatic rings, or one or more atoms of oxygen, sulfur or o, sulfo, disulfide, amino, alkylamino, hydroxyl, quaternary ammonium, ureido, bitter ester groups, and X denotes an anion derived from a mineral or organic acid;

Al, RI3 and R15 can form with the two nitrogen atoms to which they are attached a piperazine ring; furthermore, if Al denotes a linear or branched, saturated or unsaturated radical or a linear or branched hydroxyalkylene, B 1 can also denote a group (Cl n CO D-OC (CH 2) n) and p es of its nesenates ranging from 2 to approximately 20 in which D denotes: a radical of glycol glycol: -O- - O 2 where Z denotes a linear or branched hydrocarbon radical or a group corresponding to one of the following formulas: (CH 2 CH 2 O) x CH 2 H 2

s G -C s0j CG CH "3 \ o !! x and y denote an integer I to represent a defined and unique polymerization degree or any number of I to 4 representing a mean degree of polymerization a diamine bis second remainder such as a pipélazill e derivative; a bis-primary diamine residue; wherein Y denotes a linear or branched hydrocarbon radical, or the bivalent radical - »C} S-C» C »; a ureylene group of formula: -NH-CO-NH-; Preferably, X is an anion such as chloride or bromide.

These polymers have a number average molecular weight generally between 1000 and 100,000. Polymers of the type are described, in particular, in French patents 2,320,330, 2,270,84, 2,316,271, 2,336,434 and 2,441,907 and US Patents 2,273,780, 2.3. 853, 2,388,614, 2,454,543,206,462, 2261.00, 2271,378, 3,874,870, 4,1.15, 3,929,990, 4,025,627, 4.0653, 4,026,945 and 4,027,020. Polymers which consist of repeating units having the formula: ## STR2 ## in which R18, R19, R20 and 1121 can be used more particularly. , identical or different, denote an alkyl or hydroalkyl radical having from 1 to about 4 carbon atoms, r and s are integers ranging from 2 to about 20 and X is an anion derivative derived from mineral or organic acid. 2, particularly preferred is that for which R 18, R 19, R 20 and R 21, represent a methyl radical "f = 3, s = 6 and X = Cl, referred to as G 1 6 chloride according to the 1NCI nomenclature (CTFA). quaternary polyamino polymers consisting of units of formula (IX): ## STR2 ## ## STR2 ## ## STR2 ## ## STR2 ## formula in which:

R22, R23, R24 and R25, which may be identical or different, represent a hydrogen atom or a methyl, ethyl, propyl, 0-hydroxyethyl or OHCH OCH2CH pOH radical;

wherein p is 0 or integer from 1 to 6 with the proviso that R2R2R24 and R25 are not simultaneously hydrogen;

t and u, identical or different, are integers between 1 and 6,

# is 0 to an integer from 1 to 34, such as a halogenide, A denotes a radical, a dihalide or is preferably -CS CG Ü-CH CG.

Such compounds are in particular described in patent application EPA422324,

For example, there may be mentioned among the products "Mirapol® A 15," Mira! In ADIn, n A AZI and "Mira pole 175" sold by the company Miranol,

(9) Quaternary pyrrol and vinylimidazole polymers such as, for example, the products sold under the names Uviguat® FC 905, FC 550 and PC 370 by the company BSA SY.

(1) Cationic polysaccharides, in particular cationic celluloses and cationic galactomarman gums,

Among the cationic polysaccharides, mention may be made more particularly of cellulose ether derivatives comprising quaternary ammonium groups, cationic cellulose copolymers or cellulose derivatives grafted with a monomer.

Water-soluble quaternary ammonium and cationic galaetornannan gums,

The cellulose ether derivatives containing quaternary ammonium groups described in French Patent 1,492,597. These polymers are also defined in the CTFA dictionary as quaternary ammonium compounds that have reacted with an epoxide substituted with a #imethammonium group. Cationic cellulose copolymers or cellulose derivatives grafted with a water-soluble quaternary ammonium monomer, are described in particular in US Pat. No. 4,131,576, such as hydroxyalkyl celluloses, such as hydroxyethyl or hydroxypropyl grafted celluloses, such as Methyl ethyl phosphate salt, methacrylate for methyl methamphetyl chloride The cationic galactoma gums are described more particularly in US Pat. Nos. 3,589,578 and 4,031,307, in particular guar gums containing tr Cationic groups. / lammonium. For example, salt-modified guar gums (eg, chloride) of epoxypmp tria (tham ni) are used. Other cationic polymers which can be used in the context of the invention are cationic proteins or cationic protein hydrolysates, polyalkyleneimines, especially polymers containing vinylpyridine or vinyvinyl units, condensates of polyamines and quaternary polymers and chitin derivatives. The cationic proteins or hydrolysates of cationic proteins are in particular chemically modified polypeptides carrying a chain end, or grafted thereto, quaternary ammonium groups, their molecular mass may vary for example from 1500 to 10 000, and in particular from 2000 to 2000. About 5,000 of these include, but are not limited to: Preferably, these polypeptides are of vegetable origin, and include: 25 hydrolysates of wheat protein, soy protein or rice modified with cocodimonium hydroxypropyl groups. wheat, soy, jojoba, oat or rice modified hydrolysates. hydroxypropyl trirnonium groups. 3 hydrolysates protein wheat, soy or jojoba modified with laurdimonium hydroxypropyl groups. the hydrolysates of jojoba, soy or rice protein modified with hydroxypropyl steardimonium groups. Among the products which may be mentioned as examples are the product offered by the company COGNIS, GLUADIN WQ, by the company C RODA under the names HYDROT. CUM WQ PE or CROQUAT SOYA. Of all the cationic polymers which may be used in the context of the present invention, it is preferred to use cationic eyelopolymers, in particular the dimethyldiallylammonium chloride copolymers or copolymers, sold under the names "MERQUAT 100%". M MERQUAT 550 "e" MERQUAT S "by the company N LCO, quaternary polymers vin pr one and vinylimidazole, cationic polysaccharides and mixtures thereof.

Non-silicone cationic surfactants The conditioning agent (s) that may be used according to the invention may be chosen from non-silicone cationic surfactants. The term "non-silicone cationic surfactant", a surfactant having no silicon atoms in its structure and positively charged when it is contained in the composition according to the invention. This surfactant may carry one or more positive permanent charges or contain one or more cationizable functions within the composition according to the invention. . The cationic surfactant (s) that can be used as conditioning agents according to the present invention are preferably chosen from primary, secondary or tertiary fatty amines, optionally polyoxyalkylenated, or their salts, quaternary ammonium salts, and mixtures thereof. Fatty amines include e,! in general, at least one C8-C30 hydrocarbon chain. The fatty amines which can be used according to the invention include, for example, stearyl amine and distearyl amine.

As quaternary ammonium salts, there may be mentioned, for example: - those having the following general formula "XII) = + [kG w: k1E N X Z k (£! (XII)

in which the radicals R8 to k1, which may be identical or different, represent a linear or branched aliphatic radical containing 1 to 30 carbon atoms, or an aromatic radical such as aryl or alkylaryl, at least one of the radicals R8 to RII. designating uradical having 8 to 30 carbon atoms, preferably 12 to 24 carbon atoms. The aliphatic radicals can comprise heteroatoms such as Sman in oxygen, nitrogen, sulfur and halogens. The aliphatic radicals are, for example, chosen from C 1 -C 30 alkyl radicals, C 1 alkoxyalkylene radicals (C2- C6), C1-30alkylamide, C12alkylcarbonyl, C12alkylcarbonyl and C 1 -C 30 alkaniline, and X is an anion selected from the group of halides, phosphates, acetates, lactates, Embedded image Among the quaternary ammonium salts of Fe (e), it is preferred, on the one hand, to give 2-aminam chlorides such as, for example, The chlorides comprise about 12 to 22 carbon atoms, in particular the chlorines of beimethammethyl, distearyl dimethylammonium, this kimmoniummonium, benzylmethylstearylammonium or, on the other hand, glymyl ammonium chloride or stearamidopropyldimethyl (rnyristyl acetate) chloride. ammonium sold under the name C2RAPGY 70 to 70 by VAN DYK. the quaternary ammonium salts of imidazoline, for instance those of the following formula: ## STR2 ## in which RI 2 represents an alkenic radical or alkyl having from 8 to 30 carbon atoms, for example derived from tallow acids, R13 represents a hydrogen atom, a C1-C4 alkyl radical or an alkenyl or alkyl + X25 radical containing from 8 to 30 carbon atoms; a C 1 -C 4 alkyl radical; R 15 represents a hydrogen atom; a C 1 -C 4 alkyl radical; X is an anion chosen from the group of halides, phosphates, acetates, lactates, alkyl sulphates, all or alkyl sulphates; + & i. Preferably, R12 and R13 denote a mixture of alkenyl or alkyl radicals containing from 12 to 21 carbon atoms, for example fatty acid derivatives of tallow, R14 denotes a methyl radical, and k15 denotes a hydrogen atom. Such a product is an example. sold under the name REWOQUAT® W 75 by the company RE O; the di or quaternary ammonium salts, in particular of the formula ## STR2 ## of carbon optionally hydroxylated and / or interrupted by one or more oxygen atoms, R17 is chosen from hydrogen, an alkyl radical containing from 1 to 4 carbon atoms or a group (R16a (17a (R18a N) R 1, R 17a, R 12 R 11, R 20 and R 21, which are identical or different, are chosen from hydrogen or an alkyl radical containing 1 to 4 carbon atoms, and X is an anion chosen from the group of halides, acetates and phosphates, Such compounds are, for example, the Finquat CT-P proposed by the company FINETEX (Cua + rium 89), the FITTCTCT proposed by the company "INTEGRITY" and the like. ,

quaternary ammonium salts containing at least one ester function, such as those of the following formula (XV): ## STR2 ## wherein

R22 is selected from C1-C6 alkyl radicals and hydroxy radicals or C1-C6 alkyl radicals; R23 is selected from: Ü

the radical R 26 -C = - the radicals R 27 which are linear or branched, saturated or unsaturated C 1 -C 22 hydrocarbon radicals,

- the hydrogen atom, R25 is chosen psi: O. || G radical R29 radicals which are hydrocarbon radicals C 1 -C 6, linear or branched. saturated or unsaturated,

the hydrogen atom, R24, R26 and R28, which are identical or different, are chosen from linear or branched, saturated or unsaturated C 7 -C 21 hydrocarbon radicals;

rsett, identical mldifferent, are integers worth 2 to 6; y is an entivda t 1 to 10;

x and z, which are identical or different, are integers ranging from 0 to 10; X- is a simple or complex anion, organic yes ,! inorganic;

provided that x + y z is from I to 15, that when x is 0

then R23 denotes R27 and that is when R25déJgneR2R

The alkyl radicals R22 may be linear or branched and more particularly linear. Preferably, R22 desires a methyl, ethyl, hydroxylethyl or dihydryl radical, and more particularly a methyl or ethyl radical.

Advantageously, the man x + y + zvaut dc1 to 10.

When R 23 is a hydrocarbon R 27 radical, it may be long and have 12 to 22 carbon atoms, or short and have 1 to 3 carbon atoms.

When R 25 is a hydrocarbon R 29 radical, it has preference! at 3 atoms one, Advantageously, R24> R26 and R28, which are identical or different, are chosen from linear or branched C11-C2 1 hydrocarbon radicals> saturated or unsaturated, and more particularly from the radicals / k le and alkenyl en Cil 21, linear or branched, saturated or unsaturated. Preferably, x and z, identical or different, are 0 or 1, advantageously, y is equal to 1. Preferably, r, s "identical or different, are equal to 2 or 3, and even more

The anion X- is preferably a halide (chloride, bromide or iodide) or a more particularly melamine. However, it is possible to use methanmulphonate phosphate, nitrate, tosylate, an anion derived from an organic acid such as acetate or lactate or any other ammonium compatible anion.

Ester. X- is even more particularly chloride or naethylsulfate. More particularly, in the composition according to the invention, the salts of formula (XV) in which: R 22 denotes a methyl or ethyl radical, 20 - and y are equal to 1; z is 0 or 1; - r, set t are equal to 2; - R23 is chosen pmoi: 0 -1 radical R§6 - C

Methyl, ethyl or C14-C22 hydrocarbon radicals; .R25and selected from: / -the radical R £ -C-

- the hydrogen atom; - R2R26 and R28, which are identical or different, are chosen from linear or branched, saturated or unsaturated C13-CIE hydrocarbon radicals, and preferably from linear or branched, branched or unsaturated C 1 -C 18 -alkyl and alkenyl radicals.

Advantageously, the hydrocarbon radicals are linear. Examples which may be mentioned are compounds of formula (XV), such as the salts (especially chloride or methylsulfate) of dlacoxyetimethylammonium dioxythymethylammonium, monoacyloxyethyl-dihydroxyethylmethylammonium, triacox th -methammonium. my & yethy- hy ox A6y -dimethammoniu and yu s m + years. Most preferably, 14 to 18 carbon atoms are derived from a vegetable oil such as palm oil or sunflower oil. When the compound contains more than one acyl radical, the latter may be identical or different. These products are obtained, for example, by direct esterification of triethanolamine, tri-amine, γ-kkyldiet amine or U / SOS opanamine, optionally oxyalkylenated on C30-C30 fatty acids or C10 fatty acid mixtures. C30 of vetal or animal origin, or by talesesté! They contain their methyl esters. This esterification is followed by a gating agent with an alkaion agent such as alkyl halide (preferably methyl or ethyl), and 2-sulphate (preferably methyl or ethyl), ethyl acetate, ethyl acetate, chlorohydric glycol or glycerol. Such compounds are, for example, sold under the names DEHYQUART®pa by the company NKE and EPANQUATÆpA by the company STEPAN, NÜXAMIUM® by the company CECA, RE OQUAT® WE 18 by the company REWÜ. W CO. The composition according to the invention may contain, for example, a mixture of magnesium, di- and triethyl ester / quaternary ammonium salts with a majority of the ammonium salts. It is also possible to use the ammonium salts containing at least one ester function described in patents US-A-4874554 and US-A-4137180. The cationic surfactants or surfactants that are particularly preferred and usable according to the invention are chosen from compounds of formula (XII) or of formula (XV). Among all the cationic surfactants that may be present in the composition according to the invention, it is preferred to choose the cetyl trimethyl ammonium, trimethylammonium, dipalmitoylethyl hydroxyethyl methyl salts.

C1-C10 C2-amoethyl-azazon, stearyl op-formamine, selimidopimethylammonium salt, and mixtures thereof Silicones Among the silicones that can be used as conditioning agents in accordance with the present invention, it is not limited to the following: The volatile silicones: These have a boiling point between 60 ° C. and 260 ° C. Among this type of silicone, mention is made of: (j) cyclic silicones having 3 to 7 silicon atoms, and preferably 4 to 5 This is, for example, a product sold under the name "VOLATILE SILICONE 72070" by the company UNION CARBIDE or "SJLBIONE 70045 V20" by the company RHONE POULENC, the decamé y / cn ilo sold under the name "VOLATILE SILICONE 71580" by the company UNION CARBIDE, "SILBIONE 70045 V50" by SRHONE POULENC, as well as their blends Also mention the QOpolymers of the type filed yb20 & aemeth d \ soxa e, te q the "SILICONE VOLATILE FZ 31?" Sold by the UNION CARBIDE Company, which i is a cyclocopolymer dimeth soxae / A @t \ 2oxa e; (fi) linear volatile silicones having 2 to 9 silicon atoms and having a viscosity inA / ÆEe or equal to 5.10-6 m 2 / s at 25 ° C. This is, for example, hexamethyldisiloxane sold under the name "SILBIONE 70041 V0,650" by RIIONE POULENC. This type of product is described in the article TODD & BYERS "Volatile Silicone Fluids for Cosmetics", Cmt and Toiletries, Vol. 91, Jan 76, pages 27 32. J. Nonvolatile silicones They consist mainly of polyalkylsiloxanes, py # ryxa, p / kk aryls kanes and organomodified p ysiloamines, as well as their mixtures. They can be in the form of oils, gums and resins.

Among the polyalkylsiloxanes, mention may be made of linear polydimethylsiloxanes having a viscosity of greater than 5 × 10 -6 m 2 / s, and preferably less than 2 moles, ie: with terminal groups, such as, for example, and without limitation, L-olione ® "70047 series marketed by the company 10 RHONE POULE wacker oil Bels! DM 60000 WACKER or certain "VI CASÎ O" of the company ELEC RIC, - with terminal groups ti drox lyl, such as the oils of the series "48 VO" of the company RHONE POULENC '. In this class of polyalkylsiloxanes, mention may also be made of the polyalkylsiloxanes sold by the company GOLDSCHMIDT under the names "ABILWAX 98000" and "ABILWAX 98010", which are p / kk (CIE, S0, Pa and the polyalkylarylsiloxanes, mention may be made of the linear and / or branched polydimethyldiphenylsiloxane polymers, viscosity 2 m 2, of the RHONE POULENC series, the oils "LBIONEO" the series 70641 of RHONE POULENC, such as the oils "£ SION £ 70641 V300" and "SILBIONE 70641 V2000", - the product "DC 5560" C m llcG muidd DOW CORNIN- BAYER PK series silicones, such as the "PK200", 25-series P series silicones PH of BAYER> as the "PN 10000" and "PH 10000", - certain oils of the SF GENERAL ELECTRIC series, such as the "SF 12502" SF 12650 "," SE 11540 "," SF 10230 ". In accordance with the present invention, silicone compounds are high molecular weight omprise between 200,000 and 1,000,000, used alone or mix in u !! a solvent selected from volatile silicones, polydimethylsiloxane oils (PDMS), methylsixphenyl oils (PPMS), isoparaffins, methylene chloride, pentane, dodecane, tridecane, tetradecane or their mixtures. For example, compounds having the following structures are given: ## STR1 ## ## STR2 ## ## STR2 ## ## STR2 ## )], gomm ± Sp mmeth / Q xan / (p1méthysi xanen gums po imkSi and Xlphén si ae) / (methvin s oxanq We can cite the gum Mirasil DM 300 000 from the company Rhoclia. , without limitation, the following mixtures: 1) mixtures formed from an end-hydroxylated hydroxylated po1 dimA6 (DIMETHICONOL according to the CITA nomenclature), and a cyclic polydimeth YCEOMET / ICONE according to CTFA nomenclature ), Such as the "Q2 14010" or Dow Corning 1501 Fluid products sold by the Dow Corning Company; the mixtures formed from a polydimethylsiloxane gum with a cyclic silicone, + 1 the product "S 1214 SILICONE GUIDA" from GENERAL ELEC RI, which is a gum "SE 30®" PM 500.000 (- & n)! solubilized in "SF 20 1202 SILICONE TDI UID0 ecamkthcyc pe # Usoxane; 3) blends of two PDMS of different viscosities, including a 2DM S gum and a PDMS oil, such as plod products" St 1236® " and "CF 12410" GENERAL ELECTRONIC IC.The product "S {1 60" is a mixture of a "SE 300" gum defined above with a viscosity of 20 nl and an oil SF 96® "d 5.106 m 2 / s (1 g of "SE 300" and 85% of "SF 960" oil). The product "12410" is the mixture "SE 300" (33%) and a PDS ( 13m viscosity The resins used in this invention are crosslinked alkoxidic systems containing the units: R 2 SiO RSiO 3/2 and SiO 2 in which R represents a hydrocarbon group having 1 to 6 carbon atoms. These products are particularly preferred in those where k denotes a lower alkyl radical or a phenyl radical. r the product sold under the name "DOW CÜRNING 5930" or those sold under the names "SILICONE FLUID 5 SS 4Æ" "" SILICONE £ LUIDSS 4267 "by SGENERAL ELECTRIC and which are dimethyltrimide / B / o & ans. The organomodified silicones, in accordance with the present invention, are silicones as previously defined, comprising in their general structure, an o! several groups / years unction ls directly attached to the siloxane chain 10 or fixed via a hydrocarbon radical. Mention may be made, for example, of silicones comprising: ## STR1 ## for example, those sold by GE RAI, EL ÉCTR C under the names F150 FLUOROSILICONE® ID® or by SHIN ETSU under the names "X-22-819 E," X-22-820 "," X2 821® "" X-22-8220 "; for example, those described in the patent application EP 0 342 834 and in particular the silicone sold by the company 1) WO CORNING under the name "Q2-84130"; thiol groups as in silicones "X 2-83600" DOW CORNI Gou Company "GP 72A0" and "Gf71®" GENESEE; non-q + amino groups, such as in GENESEE's "G # 4 SILICONE FLUID®" GENESEE, G`GP 71007 ", DOW CORNINp" Q2 82200 "," AFL 40® "of UNION CARBIDE or silicone called "Amodimethicone" in the CTFA dictionary, the carboxylate groups, such as the products described in EP 186 507 of CFIISSO CORPORATION, groups x 61, such as C2 C18 hydroxyalkyl polyhydroxy ss, described for example in patent application In particular, the product marketed by Dow Coming under the name DC 190, especially alkoxylated groups such as Silicone Copte ymer 50 SWS SILICONES and the products at B WAX 24223 WA 24340, k8 WAX 24400 "SGÜ GOLDSCH IDT; acyloxy (C 8 -C 22) alkyl (C 2 -C 18) groups, such as, for example, pyoranopoxa described in patent application 888433, quaternary ammonium groups, as in 2X2 products. 080 and 2 81 092 the product-ABC K 32700 "of the company GOLDSCHMIDT j) amphoteric or betaine groups, such as in the product sold by the company GOLDSCHMIDT under the name" ABI B 99500 ", bisulfite groups, fels that in the products sold by GOLDSCHMIDT under the names B 5201® and "SI S255®". »2 yethen groups x polypropyleneoxy cab optionally comprising C6 C24 alkyl groups such as the products referred to as diméfico py marketed by the company Dow Corning under the name DC 1248 or the oils SILWET L 792, £ 7500, L 77, E 711 of the company UNION CARBIDE and f / k 1 retholy copolyol marketed by the company Dow Corning under the name Q2 5200; According to the invention, one can also utl s! and silicones comprising the polysiloxane portion and a portion consisting of a non-silicified organic chain, one of the two portions constituting the main chain of the polymer / other being grafted onto said main chain. These polymers are for example de! in patent applications to 12,704, EP A 12,707, A 40,105 and WO 95/00578, EP-A-582,152 and WO 93/23009 and US Patents 4,693,935, US 4,728,571 and US 4,972,037. These polymers are preferably anionic or nonionic.

Such polymers are, for example, copolymers which can be obtained by radical polymerization from the monomer mixture consisting of from 3 to 50 to 90% by weight of teat acrylate; 0 to 40% by weight of acrylic acid; 5 to 40% by weight of silicone macromer of formula: ## STR3 ## H2-CCC-O (CH2) ## STR3 ## where f is a number ranging from 5 to 700, the percentages by weight being calculated relative to the total weight of the monomers D Other examples of grafted silicone polymers are, in particular, DM-imaged pimples, on which are grafted, via a thiopropylene-type connecting link, mixed polymer units of the po mA atr Eq acid type and of the py mech acrlate / k type. G and p imethsoxa es (PDMS) on which are grafted, via a thiopropylene-type connecting member, polymethylenetributyl-type polymer units. According to the invention, all the silicones can also be used. The polyorganosiloxanes which are particularly preferred according to the invention are: - non-volatile silicones chosen from the family of end-grouped end groups, such as oils having a viscosity of from 5 to 10 carbon atoms; iscosity of between 0.2 and 2.5 m at 25 ° C. such that the DOW CORNING series DC200, in particular that with a viscosity of 60 000 Cst, the SILBIONE 70047 series and more particularly the 70 047 V 500 000 oil marketed by the RHODIA CHIMIE company> the pyÆ & kai xanesà dimethylsilanol terminal groups such as limé 2 no! or the arsenic po such as SILBIONE 70641 V 200 oil marketed by RHODIA CHIMIE; aminated po / S / O kane such as amodimethicones or trlmahs amodimethi; The viscosities of the silicones may in particular be determined by the ASTM D445-97 standard (VQ A6tri.) CH2Si - (CH3) 3 - CH3 | CH3 3 Hydrocarbons When the conditioning agent the composition according to the invention is a hydrocarbon This is a hydrocarbon, linear or branched C.sub.8 C.sub.300. Among the drocarburiquiquids at ambient temperature which correspond to this definition, mention may in particular be made of decanation of hexane and its isomers (such as 2, 6H, 6H, isoeicosane, etestracosa e, the isomers of said compounds, n deca, pane, p ae, pd cana, p pe mdecanæ, vaseline oil and mixtures of these hydrocarbons. According to the invention, preference is given to liquid petroleum jelly, o-oxide or one of its isomers Fatty alcohols When the conditioning agent is a fatty alcohol, it is of the linear or branched, saturated or unsaturated type. , C8 C30 Amongst these, for example, are alcohol, alcohol, alcohol, alcohol oleic alcohol, isocetyl alcohol, isostearyl alcohol, behenyl alcohol, stearyl alcohol, alcohol and mixtures thereof, fatty ester. When the conditioning agent is a fatty ester, it may be either ester of a C 8 -C 30 fatty acid and monohydric alcohols or polyols C 30 of which the fatty acid esters e! C8 C30 and C8-C30 fatty alcohols is an ester of a C1 -C7 acid or diacid and a C8-C30 fatty alcohol. Among these esters, mention may be made, for example, of ethyl, isopropyl, ethyl-2 and 2-octyl palmitate, of isopropyl, butyl, cetyl and titanium stearate and butyl stearate. hexyl, hexyl ytail and 2 x dec. 36, such as dioctyl dity malate, myristyl myristate, stearyl myristate, palmitate and myristyl stearate, stearyl stearate. this stearate and their mixtures. Mention may also be made of natural or synthetic triglycerides and in particular vegetable oils + R that rapeseed oil, avocado oil, olive oil, / sunflower oil, oil and oil. of grape seeds.

Ceramides Ceramides or ceramide analogues, such as glycoceramides which can be used as conditioning agents in the compositions according to the invention, are known per se and are natural or synthetic molecules which can be used according to the following general formula (XIX): R 3 CHOH -CH-CH2OR2 (XIX) wherein: - R1 denotes a linear or branched, saturated or unsaturated alkyl radical derived from fatty acids e! C14-C30, which radical may be substituted by a hydroxyl group in the alpha position, or an omega-hydroxyl group esterified with a saturated or unsaturated C16-C30 fatty acid; R 2 denotes a hydrogen atom or a (glycosyl) radical n, (gd tole) sulphite ctos e, in which n is an integer varying from 1 to 4 and m is an integer ranging from 1 to 8; R 3 denotes a saturated or unsaturated C 5 -C 26 hydrocarbon-based radical, this radical possibly being substituted with one or more alkyl radicals;

CI-C14; it being understood that in the case of natural ceramides or glycoceramides, R3 may also denote a C15-C26 alpha ydrok / kkaG radical, the hydroxyl group optionally being esterified with a C16-C30 alpha-hydroxy acid. Preferred ceramides in the context of the present invention are those described by DOWNING in Arch. Dermatol, Vol, 13, 13814384, 1987, or those described in French Patent FR 2,673,179. The ceramide or ceramides more particularly preferred according to the invention are the compounds for which R 1 denotes saturated or unsaturated alkyl derived from C16-C22 fatty acids; R2 denotes a hydrogen atom; and R 3 denotes a C 15 saturated linear radical. Such compounds are, for example: N-amino-6-fluorosine-N-hydroxyphosphonate, N-hydrofluoromethylphosphine, N-eno dih roll b "si, or mixtures of these compounds. Even more preferentially, the ceramides for which R1 denotes a saturated or unsaturated alkyl radical / ace fatty are used; R2 denotes a yd toslyousulf / kactoQ / + R3 radical denoting a group -CHCSÇCH I2 CS% A 6 # e of example, there may be mentioned the product consisting of a mixture of these compounds, sold under the trademark GLYCOCER by the company WATT KIINTERNKTIONAL RIOS £ & C £ Abrasive solid particles Abrasive solid particles are understood to mean particles having a hardness greater than or equal to that of the hair. For example, the abrasive solid particles may have a hardness greater than or equal to 3 on the Mohs scale, or even greater than or equal to, for example, greater than or equal to 5 on the Mohs scale. The solid particles may be chosen from natural materials, in particular of mineral origin, or synthetic materials. The abrasive solid particles may, for example, be chosen from the following materials, this list not being limiting: inorganic metal particles such as boron nitride, in cubic form UIazo # aluminosilicate, zircon, mixed oxides Aluminum such as emery, zinc oxide, aluminum oxides such as aluminas or corundum, titanium oxide, mica-titanium oxide, carbides, especially silicon carbide ( carborundum), or other metal oxides, metals and metal alloys such as iron shot, steel, especially pe15 +; silicates such as glass, quartz or sand, calcium carbonate (for example, bora bora sand or Brignoles rose) magnesium carbonate, sodium chloride, pumice, amorphous silica, the diamond, the ceramics, the organic particles such as the fruit core, in particular apricot, for example the SGubamis apricot, the wood cellulose, for example ground bamboo stem, the coconut shell, for example Coconut t exf 6+; polyamides, especially nylon-6 sugars; pyétlenes; lespG @@openes, and - the mixed particles combining organic and inorganic compounds, and the particles coated with the compounds described above "The solid particles may have a flattened, spherical, elongated, irregular polyhedral shape" solid particles may come for example from pumice powder grains, diamond powder, cores test powder powder cor nuts, for example mQfoils of alumina, glass, polyamide, especially Nylon-6, or fibers, especially polyamide fibers, hardwood cellulose fibers. The moisturizing agents are preferably selected from mash, urea derivatives such as hydroxy, polyols such as glycerol, pnspylene glycol, sorbitol, polyethylene glycols, preferably the composition of the invention comprises at least one of the following: conditioning agent or at least one reducing agent or at least one organic or inorganic base, at least one hair dye. Still more preferably, the composition of the invention comprises at least one hair conditioning agent. The hair cosmetic composition used according to the invention. "# 60" may also contain other usual compounds in the hair cosmetic field such as vitamins and pro-vitamins whose pa t en, sunscreens, mineral or organic pigments, colored o! u! non-colored, pearlescent and opacifying agents, sequestering agents, plasticizing agents, solubilising agents, antioxidants, hydroxy-perfumes, perfumes, nonionic, anionic, cationic or amphoteric surfactants, nonionic, cationic anionic polymers or amphoteric, short chain alkanes such as ethanol or isopropanol, acidifying agents, and preserving agents. The compositions of the invention may be aqueous or anhydrous, they may be in the form of powders, liquids, gels, milks, creams and solids no! n powdery. They can optionally be sprayed on the hair via an aerosol or a pump bottle. The process according to the invention can be carried out according to several variants. In a first variant, the combing of the hair using the motorized device is carried out after application of the composition according to the invention to the hair, the composition may be present on the hair. In a second variant, the combing of the hair with the aid of the motorized device is carried out before applying the composition according to the invention to the hair. In this variant, the combing is carried out after moistening the hair follicle or after the application of the hair. a composition not comprising active agents according to the invention. The first variant is preferred. The method of this variant may also comprise a subsequent step of applying a composition with or without active agents according to the invention.

The treatment may or may not be followed by rinsing. In the end the hair is dried or left to dry. The process of the invention can be repeated several times. In general, the process of the invention is applied one or two times. The invention is particularly suitable for curly or curly hair.

The invention will be better understood on reading the description which follows, examples of non-limiting implementation of arec! on examining the appended drawing, in which: FIG. represents an example of combing device according to the invention, = Figure 2 shows, in schematic section, the device of Figure 1, Figure 3 schematically illustrates the membrane def! mat on during operation of the device, figure 4 illustrates the use of the device, FIG. 5 schematically shows in perspective a variant embodiment of the combing device, and FIGS. 6A and 613 show a hair with sides treated respectively according to the invention and FIG. conventional way. The motorized combing device shown in FIGS. 1 and 2 comprises a handpiece 10 which can receive a removable membrane 20 carrying pins 21 i The combing device can be proposed to the user with a gectic charger 30 for recharging an accumulator 18 contained in the handpiece 10. In the example illustrated, the device is similar to those sold under the name NEO or FLEX by the company TWINBIRD and that described IO in particular in the patent application US 2009/0182249: 1 a cut is reproduced in Figure 2. It is seen in this figure that the handpiece comprises tua electric motor 11 reduced leading el! rotation a drive member 12 on which is articulated a connecting rod 13 connected to the membrane 20 for example with a hook 15 which engages in relief 22 provided on the inner face of the membrane 20. The latter can be attached to its periphery on a flange 16 of the hand-held housing 10. In FIG., it can be seen that a block 23 of a porous, rectangular forming material forming a reserve formation can be arranged on the side of the inner face of the membrane, but in a variant this material is absent openings 25 may allow a communication between the outside of the membrane 20, between the pins 21 and the block 23. The handpiece may comprise, cmesus #% u switch 17 to turn on the electric motor 1 1, the latter being fed by the accumulator 18. The pins 21 may have different heights, being generally shorter in the central region of the membrane and longer periphery, for donation to the surfaenveloppe which leans on the free ends of the pins 21 a generally concave shape.

The pins 21 may, as illustrated, divide between two groups, namely a premigne 21a disposed in central region, the pins are oriented parallel to X axis x displacement drelief, and a second group 21b of pins disposed around the first, whose respective longitudinal axes extend obliquely with respect to the X axis, towards the outside. The pins 21 may be arranged in concentric rows up to the periphery of the membrane. Thus, the pins 21 are non-aligned and when the combing device is moved along a hair lock in a direction perpendicular or oblique to its major axis, the hair passing between the pins 21 follow a non-rectilinear path. During the operation of the device, rod 13 is driven oscillatingly from top to bottom in FIG. 2, which causes a periodic deformation lamembrane 20, the periphery of the membrane 20 remaining fixed relative to the handpiece 10 while its central region oscillates along the X axis with a maximum amplitude. The oscillations of the membrane 20 generate, as illustrated in FIG. 3, a friction action of the pins 21 on the hair, which, combined with the use of the composition according to invention, makes it possible to obtain results superior to the use of the composition alone. or combing device alone To use combing device, the user can, as illustrated in Figure 4, apply the composition on wet hair, and comb the hair, for example by passing several times the base to the tips. EXAMPLE The protocol is as follows: Application of a Composition A Comprising 1% of Active Ingredients of a Methyl Oxa or B Comprising 03% of Trimethylammonium Chloride Active Ingredients on Wet Hair, for example African or Caucasian types,

Distribution of the composition with hand drawing with the hand or with a comb of a machine and with NE0 device of the TWINBIRD company the other side of the head, pendanminutes, q Rinse, Drying The application of the process especially on hair curly or curly in association with the compositions A or B containing the active shows as illustrated in Figures 6A and 6B a better individualization of the hair which is reflected by very clear effect of volume reduction, the apparent mass compared hand massage . We also observe a better disentangling and a smoother touch. This effect is residual to several shampoos. It is also possible to repeat steps a) and after the step and then finish with steps 10 and d). It is possible to use, without departing from the scope of the present invention, a combing device comprising, as illustrated in FIG. 5, a removable reservoir 40 containing the composition to be applied during the use of the combing device. The reservoir 40 is, for example, pre-filled with a composition being supplied to the operator under the fuse of a cartridge to be diosed in the handpiece 10. The distribution of composition from the reservoir is effected for example by means of a pump powered by the same motor as the one that deforms the membrane. The expression "comprising at least one" must be understood as being equivalent to "containing one or more

Claims (15)

REVENDICATIONS1. A method of treating hair, comprising the steps of: applying to the hair a composition comprising one or more active agents chosen from: o hair conditioners, o reducing agents, o organic or mineral bases, o hair dyes, O the abrasive solid particles o the moisturizing agents, - combing the hair using a motorized combing device (10, 20) comprising pins (21) animated with an oscillating movement. 2. Method according to claim 1, the combing of the hair with the aid of the motorized device is carried out after application of the composition according to the invention to the hair. 3. Method according to claim 1, combing the hair using the motorized device is performed before applying the composition according to the invention on the hair. 20 4. Method according to claims 1 to 3, the combing device comprising a flexible membrane (20) carrying the pins adapted to contact the hair, and a drive mechanism (11, 12, 13, 15) for periodically deforming the membrane to generate a displacement of the pins in contact with the hair. 5. Method according to claim 4, the oscillation frequency of the membrane being between 0.5 and 200 Hz, better still between 1 and 20 Hz inclusive. 6. Method according to claims 4 or 5, the envelope surface defined by the free ends of the pins being an outwardly concave surface, the radius of curvature of which varies according to the deformations of the membrane. 7. Method according to any one of claims 1 to 6, the pins (21) 30 being made of a thermoplastic material. 8. Process according to any one of claims 1 to 7, the composition comprising at least one hair dye chosen from synthetic direct dyes, natural dyes and oxidation dye precursors. 9. Process according to any one of Claims 1 to 8, the composition comprising at least one reducing agent chosen from alkaline phosphines or sulphites or bisulphites or thiols. 10. Process according to any one of claims 1 to 9, the composition comprising at least one organic or inorganic base selected from alkali metal or alkaline earth metal hydroxides, transition metals and organic hydroxides. 10 11. Process according to any one of Claims 1 to 10, the composition comprising at least one conditioning agent chosen from non-silicone cationic polymers, non-silicone cationic surfactants, silicones, in particular organosiloxanes, and linear or branched hydrocarbons. C8-C30, linear or branched C8-C30 fatty alcohols, C8-C30 fatty acid esters and C1-C30 monohydric or polyhydric alcohols including C8-C30 fatty acid esters and C8-C30 fatty acids; C 8 -C 30 fatty alcohol, esters of C 1 -C 7 acid or diacid and C 8 -C 30 fatty alcohols, wet or ceramide analogues. 12. Process according to any one of Claims 1 to 11, the composition comprising at least abrasive solid particles chosen from natural materials, in particular of mineral or vegetable origin, or synthetic materials. 13. Process according to any one of Claims 1 to 12, the composition comprising at least one moisturizing agent chosen from urea, urea derivatives such as hydroxyethylurea, polyols such as glycerin, propylene glycol, sorbitol, polyethylene glycols. 25 14. Method according to any one of claims 1 to 13, the combing of the hair being carried out for a duration ranging from 1 to 5 min. 15. Process according to any one of claims 1 to 14, wherein the active agent (s) representing more than 0.001%, better still more than 0.1%, even more preferably more than 0.2% and more particularly more than 0.5% by weight relative to the total weight of the composition being applied alone or with other ingredients, in which case the active ingredient preferably represents up to 50% by total weight of the composition, more preferably up to 20% by weight total of the composition.