FR2960429A1 - Composition, useful e.g. for making up and/or caring for the skin, comprises, in medium, supramolecular polymer based on functionalized polyalkene and silicone filler comprising e.g. organopolysiloxane powders coated with silicone resin - Google Patents

Abstract

Composition (I) comprises, in a medium, at least one supramolecular polymer based on functionalized polyalkene (a) and at least one silicone filler comprising organopolysiloxane powders coated with silicone resin and polymethylsilsesquioxane powders. Composition (I) comprises, in a medium, at least one supramolecular polymer based on functionalized polyalkene of formula (HO-P1-OH) (a) and at least one silicone filler comprising organopolysiloxane powders coated with silicone resin and polymethylsilsesquioxane powders. P1 : a homopolymer or a copolymer that may be obtained by polymerization of one or more linear, cyclic and/or branched polyunsaturated 2-10C, preferably 2-4C alkenes, which may be derived from the reaction, preferably the condensation, of the functionalized polyalkene polymer with at least one junction group functionalized with at least one reactive group capable of reacting with the reactive group(s) of the functionalized polyalkene polymer, where the junction group is capable of forming at least 3 hydrogen bonds, preferably 4 hydrogen-bonds.

Description

The present invention mainly relates to a cosmetic composition and in particular a composition for makeup and / or care of the skin and / or lips comprising at least one supramolecular polymer and a silicone filler. In general, when women use a makeup product, especially of the foundation or lipstick type, they wish that this product has, after application, a good hold on the skin or the lips, and in particular that he does not transfer. In view of this expectation, it is commonly introduced in this type of compositions one or more polymers specifically dedicated to provide these improved properties withstanding time. As an illustration of these polymers, silicone resins, polyacrylates and latices may be particularly mentioned. However, the abovementioned polymers which are advantageous in terms of holding properties, and in particular of non-transfer, are unfortunately likely to generate a feeling of discomfort, during application (difficult spreading, stickiness) and / or after application (tightness, mask effect), of the cosmetic product containing them. Supramolecular polymers such as those described in applications EP 2189151 and FR 2938758 are, however, known to allow obtaining on the skin a deposit which is both comfortable and with good holding properties. There remains, however, a feeling of "sticky" for the user during the application and drying, on the skin and / or the lips, products incorporating these supramolecular polymers. Unexpectedly, the inventors have found that it is possible to overcome this disadvantage subject to using such supramolecular polymers in combination with a silicone filler. The present invention therefore aims to overcome this drawback and to provide a cosmetic composition, on the one hand, to obtain good cosmetic properties such as good adhesion to the support (skin or hair) and therefore good performance the composition, where appropriate, a good gloss, and secondly, capable of forming a deposit that is not or slightly tacky and particularly resistant to external aggression by fatty substances (oil, meals, sebum) and friction , resulting in less wear of the deposit. Thus, according to one of its aspects, the invention relates to a composition for makeup and / or care of the skin and / or the lips comprising in a physiologically acceptable medium at least one functionalized polyalkene-based supramolecular polymer of formula HO-P -OH wherein P represents a homo- or a copolymer obtainable by polymerization of one or more linear, cyclic and / or branched, polyunsaturated C 2 -C 10, preferably C 2 -C 4, alkenes capable of result from the reaction, in particular condensation, of said functionalized polyalkene polymer with at least one linking group functionalized by at least one reactive group capable of reacting with the reactive group or groups of the functionalized polyalkene polymer, said joining group being capable of forming at least 3 H (hydrogen) bonds, preferably at least 4 H bonds, preferably 4 H bonds, relative to its total weight and at least 4 a silicone charge. For the purposes of the present invention, the term "physiologically acceptable medium" means a medium that is suitable for applying a composition to the skin and / or the lips, in particular the lips. As can be seen from the examples which follow, the combination considered according to the invention is particularly effective in providing a composition which simultaneously has an improved behavior over time, in particular the holding of the color of the deposit (no embrittlement or fragmentation of the deposit which remains homogeneous) and satisfactory comfort properties, both the application (including slippery, disintegration, thickness and homogeneity of the deposit formed, decreasing the stickiness during drying) that the port to know softness, no feeling of stickiness and feeling of tightness or dryness and according to some embodiments, a non-transfer effect. This particular embodiment can in particular make it possible to obtain compositions, especially make-up compositions, the deposition of which on keratin materials, and in particular the lips and / or the skin, is homogeneous and / or non-sticky. Such a deposit can in particular provide a feeling of comfort at the port (softness, sliding property of the deposit formed). In addition, such a composition may have improved properties in terms of non-transfer, deposition behavior, especially in terms of color (no embrittlement or fragmentation of the deposit which remains homogeneous and / or resistant to friction), and holding to fat. Moreover, in the case of lipsticks, this improvement is not obtained at the expense of shine, another property generally sought for this type of makeup product. Indeed, against all odds, there is no noted phenomenon of matification of the cosmetic product containing the combination considered according to the invention. In addition, in the case of foundations, its non-transfer properties are also significantly improved.

According to another of its aspects, the present invention relates to a cosmetic process for makeup and / or care of the skin and / or the lips comprising at least the application on said skin and / or said lips of a composition according to the invention. invention. The compositions considered according to the invention and used in the processes according to the invention can be in solid or liquid form at 20 ° C.

It may especially, in particular in the case of a makeup composition of the skin, such as a foundation, a loose or compact powder or a formulation that can be anhydrous or oil-like emulsion type in the form of water or water in oil. According to a preferred embodiment, in particular in the context of a composition dedicated to the care and / or makeup of the lips, the composition used according to the invention is anhydrous or contains less than 3% by weight of water, preferably less than 1% by weight of water relative to the total weight of the composition. By "anhydrous" in particular means that the water is preferably not deliberately added to the composition but may be present in trace amounts in the various compounds used in the composition.

According to some embodiments, it can be envisaged that the compositions according to the invention and used in the processes according to the invention are free of ethanol. A composition according to the invention may be in the form of a makeup composition for the skin and / or the lips, in particular the skin of the face or of the body; it can be a product for the complexion such as a foundation, a blush or eyeshadow; a lip product such as a lipstick or a lip care; a concealer product; a blush, an eyeliner; a lip or eye pencil; a body make-up product; a gloss (lip gloss). According to a first advantageous embodiment of the invention, a composition according to the invention is dedicated to the makeup of the lips and it is more particularly a lipstick (lipstick) or a gloss (red to liquid lips).

Advantageously, the lipstick compositions according to the invention are anhydrous. For the purposes of the invention the term "solid" characterizes the state of the composition at a temperature of 20 ° C. In particular, a solid composition according to the invention has, at a temperature of 20 ° C and at atmospheric pressure (760 mmHg), a hardness greater than 30 Nm-1, preferably greater than 40 Nm-1.

Protocol for measuring the hardness: The hardness of a composition, in particular of the lipstick stick type, is measured according to the following protocol: The lipstick stick is stored at 20 ° C. for 24 hours before measuring the hardness . The hardness can be measured at 20 ° C. by the so-called "butter-cutting thread" method, which consists in cutting a product stick, preferably cylindrical of revolution, transversely, using a rigid tungsten wire. diameter 250 μm by moving the wire relative to the stick at a speed of 100 mm / min. The hardness of the samples of compositions of the invention, expressed in Nm 1, is measured by means of a DFGS2 dynamometer marketed by INDELCOCHATILLON. The measurement is reproduced three times and then averaged. The average of the three values read using the dynamometer mentioned above, denoted Y, is given in grams. This average is converted to Newton and divided by L which represents the highest dimension traversed by the wire. In the case of a cylindrical stick, L is equal to the diameter (in meters). The hardness is converted to Nm-1 by the following equation: (Yx 10 "3 x 9.8) / L For measurement at a different temperature, the stick is kept at this new temperature for 24 hours before measurement. According to this measurement method, a solid composition according to the invention has a hardness at 20 ° C of greater than or equal to 30 Nm-1, preferably greater than 40 Nm-1, preferably greater than 50 Nm-1.

Preferably, the composition according to the invention has in particular a hardness at 20 ° C of less than 500 Nm 1 in particular less than 400 Nm-1, preferably less than 300 Nm-1. In particular, a composition whose hardness is greater than 30 Nm 1 is a so-called "solid" composition at 20 ° C and at atmospheric pressure (760 mmHg). More particularly, a solid lipstick composition as defined above may comprise at least 0.1% by weight of at least one supramolecular polymer relative to its total weight, especially between 0.1 and 60%. Advantageously, a composition according to the invention comprises from 0.2% to 50% by weight of at least one supramolecular polymer relative to the total weight of the composition. Preferably, the composition comprises 0.5 to 30% by weight of supramolecular polymer relative to the total weight of the composition. According to a second advantageous embodiment of the invention, a composition according to the invention is dedicated to make-up of the skin, in particular of the face, and is then more particularly a foundation, a blush or eyelids, a body make-up product. Supramolecular Polymer The cosmetic compositions according to the invention thus comprise a supramolecular polymer based on polyalkene (i.e. polyolefin). For the purposes of the present invention, the term supramolecular polymer based on polyalkene, a polymer resulting from the reaction, in particular condensation, of at least one polyalkene polymer functionalized with at least one reactive group, with at least one group of junction functionalized with at least one reactive group capable of reacting with the reactive group or groups of the functionalized polyalkene polymer, said joining group being capable of forming at least 3 H (hydrogen) bonds, preferably at least 4 H bonds, preferably 4 H. "Polyalkene" or "polyolefin" means a polymer resulting from the polymerization of at least one alkene-type monomer, comprising ethylenic unsaturation, said monomer may be during or in the main chain of said polymer. The term "polyalkene" or "polyolefin" therefore refers to polymers that may or may not include a double bond. Preferably, the supramolecular polymers used according to the invention are prepared from a polymer resulting from the polymerization of an alkene comprising at least two ethylenic unsaturations. The supramolecular polymer according to the invention is capable of forming a supramolecular polymer chain or network by (self) assembling said polymer according to the invention with at least one other polymer according to the invention, which is identical or different, each assembly involving at least one at least one pair of paired joining groups, identical or different, carried by each of the polymers according to the invention. For the purposes of the invention, the term "linking group" means any group comprising donor groups or acceptors of H bonds and capable of establishing at least three H bonds, preferably at least four H bonds, preferably four H bonds, with a partner junction group, identical or not. These linking groups may be lateral to the polymeric backbone (in lateral branching), and / or carried by the ends of the polymeric backbone, and / or in the chain forming the polymeric backbone. They can be randomly or controlled.

Functionalized polyalkene The polyalkene polymers are functionalized with at least one reactive group, preferably with at least two reactive groups. The functionalization is preferably at the end of chains. We are talking about telechelic polymers.

The functionalization groups, or reactive groups, may be attached to the polyalkene polymer via linkers, preferably linear or branched C1-C4 alkylene groups, or directly by a single bond. Preferably, the functionalized polyalkene polymers have a number-average molecular weight (Mn) of between 1000 and 8000.

More preferably, they have a number-average molecular weight of between 1000 and 5000, or even between 1500 and 4500. More preferably, they have a number-average molecular weight of between 2000 and 4000. Preferably, the polyalkene polymer functionalized, capable of forming all or part of the polymeric backbone of the supramolecular polymer according to the invention (preferably it forms the entire backbone of the polymer), is of formula HO-P-OH in which: - P represents a homo- or a copolymer obtainable by polymerization of one or more linear, cyclic and / or branched, polyunsaturated (preferably diunsaturated), C2-C10, preferably C2-C4, alkenes. P preferably represents a homo- or a copolymer obtainable by polymerization of one or more di-unsaturated alkenes, linear or branched, C 2 -C 4. More preferably, P represents a polymer chosen from a polybutylene, a polybutadiene (such as 1,4-polybutadiene or 1,2-polybutadiene), polyisoprene, poly (1,3-pentadiene), polyisobutylene, and copolymers thereof. According to a preferred embodiment, P represents a poly (ethylene / butylene) copolymer. The preferred poly (ethylene / butylene) are butene-1 and ethylene copolymers. They can be schematized by the following sequence of units: [-CH 2 -CH 2 -] and [-CH 2 CH (CH 2 -CH 3) -] According to a second preferred embodiment, P is a polybutadiene homopolymer, preferably chosen from a 1,4-polybutadiene or 1,2-polybutadiene. The polybutadienes may be 1,4-polybutadienes or 1,2-polybutadienes, which may be schematically represented by the following sequences of units: [-CH 2 -CH = CH-CH 2 -] (1,4-polybutadienes) [- CH 2 -CH (CH = CH 2) -] (1,2-polybutadienes) Preferably these are 1,2-polybutadienes. Preferably, P is a 1,2-polybutadiene homopolymer. According to another embodiment, P is a polyisoprene. The polyisoprenes can be schematized by the following sequences of units: ## STR1 ## It is of course also possible to use a mixture of the above units in order to form copolymers. The functionalized polyalkene polymers may be hydrogenated to avoid the risk of crosslinking. Preferably, the functionalized polyalkene polymers used in the compositions according to the invention are hydrogenated. Preferably, the polyalkene polymers are hydrogenated and functionalized with at least 2 OH reactive groups, preferably at the ends of the polymers. Preferably, they have a functionality at the hydroxyl ends of 1.8 to 3, and preferably close to 2. The polydienes with hydroxyl ends are especially defined for example in FR2782723. They can be chosen from homopolymers and copolymers of polybutadiene, polyisoprene and poly (1,3-pentadiene). Mention may be made in particular of the hydroxylated polybutadienes marketed by Sartomer, such as Krasol® Resins and Polybd® Resins. Preferably, these are dihydroxylated hydrogenated 1,2-polybutadiene homopolymers, such as the Nisso-PB 1, GI3000, GI2000 and GI1000 range marketed by the company Nisso, which can be represented schematically by the following formula: Preferably, it is between 14 and 105, preferably between 20 and 85. These polymers have the following number-average molecular weights: GI3000 of Mn = 4700, GI2000 of Mn = 3300 and GI1000 of Mn = 1,500. These values were measured by GPC according to the following protocol:

PROTOCOL FOR DETERMINING THE MOLECULAR MASSES OF THE SUPRAMOLECULAR POLYMER BY GPC Determining the number-average molecular weights Mn, by weight Mw, as well as the polydispersity index Mw / Mn in Polystyrene equivalent. - Preparation of standard solutions Prepare polystyrene standards from VARIAN kits (ref: PS-H (PL2010-0200) The standards are: PS 6035000 - PS 3053000 PS 915000 - PS 483000 - PS 184900 - PS 60450 - PS 19720 - PS 8450 - PS 3370 - PS 1260 - PS 580 Inject 100 μl of each of the solutions into the column to be calibrated - Preparation of the sample: Prepare a solution of 0.5% dry matter in THF Prepare the solution about 24 hours before the injection.

Filter the solution on Millex FH filter (0.45μm). Inject in the column. Chromatographic conditions: Columns: PL Rapid M (batch 5M-Poly-008-15) from Polymer labs PL-gel HTS-D (batch 5M-MD-72-2) from Polymer labs PL-gel HTS-F ( 10M-2-169B-25) from Polymer labs PL-Rapid-F (6M-OL1-011-6) from Polymer labs Length: 150 mm - internal diameter: 7.5 mm Pump: isocratic M1515 Waters Eluent: THF Flow rate: 1 ml / min Temperature: ambient Injection: 100 μl at 0.5% MA in the eluent Detection: RI 64mV (WATERS 2424 refractometer) Temperature: 45 ° C UV at 254 nm in 0.1 DO (Waters 2487 UV detector) Integrator: Empower GPC option - Determination of molar masses The average molar mass is determined by plotting the calibration curve: log Molar mass = f (elution volume at the peak of the RI detection peak) and using the Empower option GPC software from WATERS.30 Among the polyolefins with hydroxyl ends, there may be mentioned preferably polyolefins, homopolymers or copolymers, with ends a, hydroxyls such as polyisobutylenes having α, hydrox hydroxyl ends; and copolymers of formula: ## STR2 ## especially those marketed by Mitsubishi under the brand name POLYTAIL. Junction Group The supramolecular polymers according to the invention also have in their structure at least one remainder of a junction group capable of forming at least 3 H bonds, preferably at least 4 H bonds, said junction group being initially functionalized by at least one reactive group.

Unless otherwise specified, the term "joining group" in the present description means the group without its reactive function.

The reactive groups are attached to the linking group via L-linkers.

L is a single bond or a divalent, saturated or unsaturated C 1 -C 20 carbon group, in particular chosen from linear or branched C 1 -C 20 alkylene; C 5 -C 20 (alkyl) cycloalkylene C 5 -C 20 alkylene (preferably cyclohexylene methylene), C 11 -C 20 alkylene-biscycloalkylene (preferably alkylene-biscyclohexylene, C 6 -C 20 (alkyl) arylene, alkylene-bisarylene (preferably alkylene-biphenylene), the linker L possibly being substituted with at least one alkyl group and / or possibly comprising 1 to 4 N and / or O heteroatoms, especially in the form of a NO2 substituent.

Preferably, the linker is selected from a phenylene group; 1,4-nitrophenyl; 1,2-ethylene; 1,6-hexylene; 1,4-butylene; 1,6- (2,4,4-trimethylhexylene); 1,4- (4-methylpentylene); 1,5- (5-méthylhexylène); 1,6- (6-méthylheptylène); 1,5- (2,2,5-

trimethylhexylene); 1,7- (3,7-dimethyloctylene); -isophorone-; 4,4 '-methylene

biscyclohexylène; tolylene; 2-methyl-1,3-phenylene; 4-methyl-1,3-phenylene; 4,4-biphénylèneméthylène.

Preferably, the linker is selected from the groups: - (alkyl) cycloalkylene C5-C20 alkylene, such as isophorone, - C11-C25 alkylene-biscycloalkylene, such as 4,4'-methylene biscyclohexylene, - alkylene C1-C20, such that - (CH2) 2-; - (CH2) 6-; -CH 2 CH (CH 3) -CH 2 -C (CH 3) 2-5 CH 2 -CH 2, and - (alkyl) phenylene C 6 -C 20, such as 2-methyl-1,3-phenylene. Preferably, L is chosen from: -isophorone-; - (CH2) 2-; - (CH2) 6-; CH 2 CH (CH 3) -CH 2 -C (CH 3) 2 -CH 2 -CH 2; 4,4'-methylene biscyclohexylene; 2-methyl-1,3-phenylene. According to a particularly preferred embodiment, the linker is an alkylcycloalkylene alkylene. Preferably, according to this embodiment, the linker is an isophorone group. Isophorone means the following group: CH3 CH3 H3C ~ CHz * These reactive groups functionalizing the junction group must be capable of reacting with the -OH reactive group (s) carried by the functionalized polyalkene.

As reactive group, there may be mentioned isocyanate groups (-N = C = O) or thioisocyanate (-N = C = S). Preferably, it is a group -N = C = O (isocyanate).

The functionalized linking groups capable of forming at least 3 H bonds may comprise at least 3 identical or different functional groups, preferably at least 4, chosen from: ## STR1 ## These functional groups may be classified in two categories: - functional groups giving H: -NH bonds - functional acceptor groups of H: \ \ C = OC = N / / bonds joining groups capable of forming at least 3 H bonds form a basic structural element comprising at least 3 groups, preferably at least 4 groups, and more preferably 4 functional groups capable of establishing H bonds. Said basic structural elements capable of establishing H bonds can be schematized as follows : where Xi is an acceptor functional group of H bonds (identical or different) and Yi is a functional group giving bond H (identiq different or different).

Thus, each structural element must be able to establish H bonds with one or more identical, (ie, self-complementary), or different, partner structural elements, such that each pairing of two structural partner elements is done by formation. at least three H bonds, preferably at least four H bonds, and more preferably four H bonds.

A proton acceptor X will pair with a proton donor Y. Several possibilities are therefore offered, for example pairing: XXXX with YYYY; XXXY with YYYX; XXYX with YYXY; XYYX with YXXY; XXYY with YYXX self-complementary or not XYXY with YXYX self-complementary or not.

Preferably, the linking groups can establish 4 H bonds with an identical (or self-complementary) partner group among which 2 donor (for example NH) and 2 acceptor bonds (for example CO and -C = N-).

Preferably, the linking groups capable of forming at least 4 H bonds are selected from the following family, with the proviso that all tautomeric forms are included:

- (i) ureidopyrimidones of formula (capable of forming at least 4 H bonds):

In this formula, the meaning of the radicals is as follows: ## EQU1 ##

the radicals R 1 (or the radicals R 1 and R 2) are single bonds constituting the point of attachment of the linking group to the linker capable of forming at least 3 H bonds (preferably 4) on the remainder of the graft. Preferably, said point of attachment is borne only by R1 which is a single link.

The radical R2 represents a divalent group chosen from a single bond or a C 1 -C 6 alkylene or a monovalent group chosen from a single bond, a hydrogen atom or a linear or branched C 1 -C 6 monovalent hydrocarbon group; -Clo, saturated, may contain one or more heteroatoms such as O, S, or N these groups being optionally substituted by a hydroxy, amino and / or thio.

Preferably, the radical R 2 can be a single bond or a monovalent group selected from H, CH 2 OH and (CH 2) 2 -OH, CH 3,

According to a particularly preferred embodiment, R2 is H.

the radical R 3 represents a divalent or monovalent group, in particular R 3 is chosen from a hydrogen atom or a monovalent hydrocarbon group, linear or

Branched C1-Clo saturated, which may contain one or more heteroatoms such as O, S, N, said hydrocarbon group being optionally substituted by a hydroxy, amino and / or thio function.

Preferably, the radical R 3 may be a monovalent group chosen from H, CH 2 OH and (CH 2) 2 -OH, CH 3. According to a particularly preferred embodiment, R 3 is a methyl group. . According to a preferred embodiment, the linking groups are chosen from 2-ureidopyrimidone and 6-methyl, 2-ureidopyrimidone.

Preferably, the preferred linking group is 6-methyl, 2-ureidopyrimidone. The joining groups, and especially the ureidopyrimidone junction groups, can be added directly or well formed in situ during the method of preparing the supramolecular polymer. The first and second modes of preparation described below respectively illustrate these two alternatives. In particular, the functionalized junction groups capable of reacting with the functionalized polyalkene polymer to give the supramolecular polymer according to the invention are preferably of the formula: ## STR2 ## in which L is as defined above. Preferably, L is selected from the groups: - (alkyl) cycloalkylene C5-C20 alkylene, such as isophorone, - C11-C25 alkylene-biscycloalkylene, such as 4,4'-methylene biscyclohexylene, - alkylene C1-C20, such that - (CH2) 2-; - (CH2) 6-; -CH2CH (CH3) -CH2-C (CH3) 2-CH2-CH2, and -C6-C20 (alkyl) phenylene, such as 2-methyl-1,3-phenylene. Preferably, L is chosen from: -isophorone-; - (CH2) 6-; 4,4'-methylene biscyclohexylene.

According to a particularly preferred embodiment, the linking group has the formula NH O L ON-NH NH \ NCO in which L is isophorone.

In a particularly preferred embodiment, the supramolecular polymer of the invention has the formula:

Wherein: - L 'and L "have, independently of each other, the meaning indicated above for L; - X X '= O and P has the meaning indicated above for the functionalized polyalkene polymer.

Preferably, L 'and L "represent a divalent, saturated or unsaturated C 1 -C 20 carbon group, in particular chosen from linear or branched C 1 -C 20 alkylene, a C 5 -C 20 (alkyl) cycloalkylene, an alkylene B6cycloalkylene, C6-C20 (alkyl) arylene Preferably L 'and L "are -isophorone-; - (CH2) 2-; - (CH2) 6-; -CH 2 CH (CH 3) -CH 2 -C (CH 3) 2 -CH 2 -CH 2, 4,4'-methylene biscyclohexylene; 2-methyl-1,3-phenylene. Preferably L 'and L "are the same, and L' and L" are preferably an isophorone group. Preferably, P is hydrogenated and represents polyethylene, polybutylene, polybutadiene, polyisoprene, poly (1,3-pentadiene), polyisobutylene, or a copolymer thereof, especially poly (ethylene / butylene). Preferably, P is a hydrogenated polybutadiene, preferably a hydrogenated 1,2-polybutadiene. In a particularly preferred embodiment, the supramolecular polymer of the invention corresponds to the formula: HN ~ NOHH Preparation process The polymer according to the invention can be prepared by the methods usually employed by those skilled in the art, in particular to form a urethane bond between the free OH functions of a polyalkene, and the isocyanate functions carried by the linking group.

By way of non-limiting illustration, a first general method of preparation consists in: - optionally ensuring that the polymer to be functionalized has no residual water, - heating said polymer comprising at least 2 reactive functions OH, at a temperature may be between 60 ° C and 140 ° C; the hydroxyl number of the polymer that can be used as a reference in order to measure the progress of the reaction; - Add, preferably directly, the ureïdopyrimidone junction group carrying the reactive functions, especially isocyanate such as those described in the patent WO 2005/042641; especially as the compounds of case number 32093-85-9 and 709028-42-2 - optionally stir the mixture, under a controlled atmosphere, at a temperature of the order of 90-130 ° C; for 1 to 24 hours; - optionally follow by infrared spectroscopy, the disappearance of the characteristic band of isocyanates (between 2500 and 2800 cm-1) so as to stop the reaction to the total disappearance of the peak, then allow the final product to return to ambient temperature. The reaction can also be followed by assays of the hydroxyl functions; it is also possible to add ethanol to ensure the total disappearance of residual isocyanate functions.

The reaction can be carried out in the presence of a solvent, especially methyltetrahydrofuran, tetrahydrofuran, toluene, propylene carbonate or butyl acetate. It is also possible to add a conventional catalyst for urethane bond formation. By way of example, mention may be made of dibutyl tin dilaurate. The polymer may ultimately be washed and dried, or even purified, according to the general knowledge of the skilled person. According to the preferred second method of preparation, the reaction may comprise the following steps: (i) functionalization of the polymer, preferably dried beforehand, with a diisocyanate according to the reaction scheme: OH-polymer-OH (1 eq.) + NCO-X -NCO (1 eq.) - * OCN-X-NH- (0) CO-polymer-OC (O) -NH-X-NCO The diisocyanate may be optionally in excess relative to the polymer. This first step can be done in the presence of solvent, at a temperature between 20 ° C and 100 ° C. This first step can be followed by a stirring period under a controlled atmosphere for 1 to 24 hours. The mixture can be optionally heated. The state of progress of this first step can be followed by a determination of the hydroxyl functions. then (ii) reaction of the prepolymer obtained above with 6-methylisocytosine of formula: N / ~ NH 2 NO this second step may optionally be carried out in the presence of a co-solvent such as toluene, butyl acetate or propylene carbonate. The reaction mixture can be heated between 80 ° C and 140 ° C for a time varying between 1 to 24 hours. The presence of a catalyst, especially dibutyltin dilaurate, may favor the obtaining of the desired final product.

The reaction can be followed by infrared spectroscopy, following the disappearance of the peak characteristic of the isocyanate between 2200 and 2300 cm-1. At the end of the reaction, ethanol may be added to the reaction medium in order to neutralize any residual isocyanate functional groups. The reaction mixture may be optionally filtered. The polymer can also be stripped directly into a cosmetic solvent. According to a particular embodiment, said supramolecular polymer is solubilized in a hydrocarbon oil, preferably a volatile oil, in particular isododecane.

Thus, the composition of the invention will comprise at least one hydrocarbon oil, preferably a volatile oil, in particular at least one of isododecane, in particular provided by the supramolecular polymer solution. In embodiments of the composition and process according to the invention, the supramolecular polymer (s) may be present in a composition according to the invention in a content ranging from 0.1 to 60% by weight of dry matter, relative to the total weight of the composition. Thus, the supramolecular polymer (s) may be present in a composition according to the invention in a content ranging from 0.2 to 50% by weight, relative to the total weight of the composition. Similarly, the supramolecular polymer (s) may be present in a composition according to the invention in a content ranging from 0.3% to 40% by weight, relative to the total weight of the composition. The supramolecular polymer (s) may also be present in a composition according to the invention in a content ranging from 0.5 to 30% by weight, relative to the total weight of the composition. In a particular embodiment of the invention, a makeup composition is in the form of a makeup product for the skin such as a foundation and the supramolecular polymer (s) may be present in a content ranging from 2.5 to 60% by weight of active material, relative to the total weight of the composition. In another embodiment, a makeup composition is in the form of a skin makeup product such as a foundation and the supramolecular polymer (s) may be present therein content ranging from 2.5 to 40% by weight of active material, relative to the total weight of the composition. According to an even more preferred variant, a makeup composition is in the form of a skin makeup product such as a foundation and the supramolecular polymer (s) may be present therein content ranging from 3 to 30% by weight of active material, relative to the total weight of the composition. In another particular embodiment of the invention, a makeup composition is in the form of a lipstick and the supramolecular polymer (s) may be present therein in a content of from , 1 to 60% by weight of dry matter, relative to the total weight of the composition. According to a preferred variant, a makeup composition is in the form of a lipstick and the supramolecular polymer (s) may be present therein in a content ranging from 0.2 to 40% by weight of dry matter, relative to the total weight of the composition. According to an even more preferred variant, a makeup composition is in the form of a lipstick and the supramolecular polymer (s) may be present in a content ranging from 0.5 to 30% by weight. weight of dry matter, relative to the total weight of the composition. Advantageously, a composition according to the invention, in particular in the case of a makeup composition for the skin and / or the lips, comprises a supramolecular polymer content of between 5 and 99% by weight relative to the weight of the composition excluding volatile compound (s) (in particular with respect to the weight of the composition excluding volatile oil (s), such as isododecane, for example). This content reflects the content of supramolecular polymer (s) resulting in a deposit made with a composition or according to the method of the invention, in particular on keratin materials such as skin and / or lips, for example, after evaporation. volatile compounds.

Preferably, the composition according to the invention, in particular in the case of a make-up composition, comprises a supramolecular polymer content of between 10 and 90% by weight relative to the weight of the composition excluding the volatile compound (s) ( s), preferably between 15 and 80%.

Silicone load As can be seen from the foregoing, a composition according to the invention comprises at least one silicone filler chosen from: organopolysiloxane powders coated with silicone resin; and polymethylsilsesquioxane powders.

According to a first advantageous embodiment of the invention, the composition comprises, as silicone filler, an organopolysiloxane powder coated with silicone resin. According to this embodiment, the organopolysiloxane powder may in particular be coated with silsesquioxane resin, as described, for example, in patent US5538793, the content of which is incorporated by reference. Such elastomer powder is sold under the names "KSP-100", "KSP-101", "KSP-102", "KSP-103", KSP-104 "," KSP-105 "by the company Shin Etsu INCI: vinyl dimethicone / methicone silsesquioxane Crosspolymer According to a second advantageous embodiment of the invention, the composition may comprise at least one polymethylsilsesquioxane powder, in particular silicone resin microbeads such as those marketed under the name TOSPEARL by the company Momentive Performance Materials, and in particular under the reference Tospearl 145 A, and mixtures thereof, The composition may also advantageously comprise a mixture of organopolysiloxane powder coated with silicone resin and of polymethylsilsesquioxane powder. In particular, the composition according to the invention may comprise a silicone filler chosen from organopolysiloxane powders coated with silicone resin and polymethylenic powders. hylsilsesquioxane, in a content ranging from 1% to 25% by weight, relative to the total weight of the composition, in particular from 1% to 15% by weight, preferably from 2% to 8% by weight, and preferably ranging from 3% to 7% by weight. A composition according to the invention advantageously comprises a silicone filler chosen from organopolysiloxane powders coated with silicone resin and polymethylsilsesquioxane powders and a supramolecular polymer in a weight ratio polymer (s) / silicone filler (s) varying from 0.1 to 50 and more particularly from 0.5 to 40. Preferably, the weight ratio polymer (s) / silicone filler (s) varies from 20.

Additional charges Of course, a make-up and / or care composition according to the invention may comprise, in addition to a filler as defined above, at least one additional filler (silicone or otherwise) distinct from the filler required according to the invention. According to a first embodiment, the composition is free of additional charge.

According to a second embodiment, a composition comprises at least one additional charge. According to this embodiment, such fillers may be present in a proportion of 0.01 to 35% by weight, preferably 0.1 to 20% by weight, of the total weight of the composition.

Preferably, a composition according to the invention, when it is in the form of a makeup product for the skin such as a foundation, comprises at least one additional filler. Of course, the nature and the amount of such additional filler, if present, are adjusted so as not to damage the cosmetic properties sought according to the invention, such as for example gloss if it is particularly desired . As an illustration of these additional charges, mention may be made of talc, mica, silica, kaolin, calcium carbonate, barium sulfate, nylon powders (especially Orgasol) and polyethylene, Teflon, starch, boron nitride, copolymer microspheres such as Expancel (Nobel Industrie); fillers having an oil uptake greater than or equal to 1.5 ml / g and mixtures thereof. Fillers having an oil uptake greater than or equal to 1 ml / g According to one embodiment variant, a composition according to the invention contains at least one filler capable of absorbing an oil.

In particular, a composition according to the invention comprises at least one filler having a capacity to absorb and / or adsorb an oil or a liquid fatty substance such as, for example, sebum (from the skin). This oil-absorbing filler can also advantageously have a BET specific surface area greater than or equal to 300 m 2 / g, preferably greater than 500 m 2 / g, and preferably greater than 600 m 2 / g, and especially less than 1500 m 2 / g . The "BET specific surface area" is determined according to the BET method (BRUNAUER - EMMET - TELLER) described in "The Journal of the American Chemical Society", vol. 60, page 309, February 1938 and corresponding to the international standard ISO 5794/1 ( Appendix D). The BET surface area corresponds to the total specific surface area (therefore micropores included) of the powder. The filler considered according to the invention is thus characterized in that it has an oil uptake greater than or equal to 1 ml / g, especially ranging from 1.5 ml / g to 20 ml / g, or even ranging from 1.5 ml. / g at 15 ml / g. Preferably, it has an oil uptake greater than or equal to 2 ml / g, in particular ranging from 2 ml / g to 20 ml / g, or even ranging from 2 ml / g to 15 ml / g. This oil intake, which corresponds to the amount of oil absorbed and / or adsorbed by the feedstock, can be characterized by measuring the Wet Point according to the method described below.

Measurement method of oil picking of a charge: The oil intake of a powder is measured according to the method of determining the setting of powder oil described in standard NF T 30-022. It corresponds to the amount of oil adsorbed on the available surface of the powdery material by measuring the Wet Point. An amount m (in grams) of powder of between about 0.5 g and 5 g (the amount depends on the density of the powder) is placed on a glass plate and then isononanoate is added dropwise. isononyl. After the addition of 4 to 5 drops of isononyl isononanoate, the isononyl isononanoate is incorporated in the feed with the aid of a spatula and isononyl isononanoate is added to the formation of conglomerates of isononyl isononanoate and powder. From this time isononyl isononanoate is added one drop at a time and the mixture is then triturated with the spatula. The addition of the isononyl isononanoate is discontinued when a firm and smooth paste is obtained. This paste should be spread on the glass plate without cracks or lumps. The volume Vs (expressed in ml) of isononyl isononanoate used is then noted. The oil intake corresponds to the ratio Vs / m. Examples of fillers having an oil uptake greater than or equal to 1.5 ml / g are described below, with their oil intake value measured according to the protocol defined above. As silica powder, mention may be made of: porous silica microspheres, in particular those sold under the name "SUNSPHERE® H53", "SUNSPHERE® H33" (oil intake equal to 3.70 ml / g) by the company ASAHI GLASS; MSS-500-3H by the company KOBO; the amorphous silica microspheres coated with polydimethylsiloxane, in particular those sold under the name SA Sunsphere® H 33 (oil uptake equal to 2.43 ml / g), the powders of silica silylate, in particular those sold under the name 5 Dow Corning VM-2270 Aerogel Fine Particles by Dow Corning (oil intake equal to 10.40 ml / g). hollow particles of amorphous silicas, in particular those sold under the name Silica Shells by the company Kobo (oil intake equal to 5.50 ml / g). precipitated silica powders surface treated with a mineral wax such as precipitated silica treated with a polyethylene wax and in particular those sold under the name ACEMATT OR 412 by the company Evonik Degussa (oil intake equal to 3, 98 ml / g). As the acrylic polymer powder, mention may be made of: the porous spheres of poly methyl methacrylate / ethylene glycol dimethacrylate sold under the name Microsponge 5640, by the company Cardinal Health Technologies (oil intake equal to 1.55 ml) g) - ethylene glycol dimethacrylate / lauryl methacrylate copolymer powders, especially those sold under the name POLYTRAP® 6603 from the company Dow Corning (oil intake equal to 6.56 ml / g). As polyamide powder, mention may be made of: nylon-6 powder, in particular that sold under the name POMP610 by the company UBE INDUSTRIES (oil intake equal to 2.02 ml / g). As pearlite powder, there may be mentioned that sold under the name OPTIMAT 1430 OR by the company WORLD MINERALS (oil intake equal to 2.4 ml / g). As a magnesium carbonate powder, mention may be made especially of the product sold under the name TIPO Carbomagel by the company Buschle & Lepper (oil intake equal to 2.14 ml / g). The particularly preferred oil-absorbing filler is a silica powder and more particularly a silica powder having an oil uptake of at least 3.70 ml / g and especially those sold under the name "SUNSPHERE® H 33". by the company ASAHI GLASS, and under the name Dow Corning VM-2270 Aerogel Fine Particles by Dow Corning. The filler (s) having an oil uptake greater than or equal to 1 ml / g may be present in a composition according to the invention in a content ranging from 0.5% to 40% by weight, preferably from 1% to 20% by weight, and better still from 1% to 15% by weight, relative to the total weight of the composition. A composition according to the invention may use at least one filler and at least one supramolecular polymer in a weight ratio polymer (s) / filler (s) absorbing the oil greater than 1, preferably greater than 1.5, and better than 2.

A cosmetic makeup and / or care composition according to the invention also comprises a cosmetically acceptable medium which can comprise the usual ingredients, depending on the destination of the composition.

Dyeing material (s) Preferably, a composition for makeup and / or care of the skin and / or the lips according to the invention comprises at least one dyestuff, in particular at least one pulverulent dyestuff. The dyestuff is especially chosen from organic or inorganic dyestuffs, in particular of the type of pigment or nacre conventionally used in cosmetic compositions, liposoluble or water-soluble dyes, materials with specific optical effect and mixtures thereof. By pigments, it is necessary to include white or colored particles, mineral or organic, insoluble in an aqueous solution, intended to color and / or opacify the resulting deposit. These pigments can be in the form of powder or pigment paste. They can be coated or uncoated. As inorganic pigments that may be used in the invention, mention may be made of titanium, zirconium or cerium oxides, as well as zinc, iron or chromium oxides, ferric blue, manganese violet, ultramarine blue and Chromium hydrate. In particular, the inorganic pigments are selected from iron oxides, titanium oxides, and mixtures thereof. Among the organic pigments that can be used in the invention, mention may be made of carbon black, D & C type pigments, cochineal carmine, barium, strontium, calcium, aluminum or diketo pyrrolopyrrole (DPP) lacquers. ) described in EP-A-542 669, EP-A-787 730, EP-A-787 731 and WO-A-96/08537. By lacquer is meant dyes adsorbed on insoluble particles, the assembly thus obtained remaining insoluble during use.

The pigments can also be in the form of composite pigments as described in patent EP 1 184 426. These composite pigments can be composed in particular of particles comprising an inorganic core, at least one binder ensuring the attachment of organic pigments on the surface. core, and at least one organic pigment at least partially covering the core.

By "nacres", it is necessary to include colored particles of any shape, iridescent or otherwise, in particular, produced by certain shellfish in their shell or else synthesized and which exhibit a color effect by optical interference. The nacres can be chosen from pearlescent pigments, such as titanium mica coated with an iron oxide, titanium mica coated with bismuth oxychloride, titanium mica coated with chromium oxide, titanium mica coated with with an organic dye, as well as pearlescent pigments based on bismuth oxychloride. It may also be mica particles on the surface of which are superimposed at least two successive layers of metal oxides and / or organic dyestuffs.

Mention may also be made, by way of example of nacres, of natural mica coated with titanium oxide, with iron oxide, with natural pigment or with bismuth oxychloride. Among the nacres available on the market, mention may be made of mother-of-pearl TIMICA, FLAMENCO and DUOCHROME (based on mica) marketed by ENGELHARD, TIMIRON pearls marketed by MERCK, mother-of-pearl containing PRESTIGE mica marketed by the company. ECKART and nacres based on SUNSHINE synthetic mica sold by the company SUN CHEMICAL. The nacres may more particularly have a color or a yellow, pink, red, bronze, orange, brown, gold and / or coppery reflection. As an illustration of nacres that can be used in the context of the present invention, mention may be made especially of gold-colored nacres sold especially by ENGELHARD under the name Brillant gold 212G (Timica), Gold 222C (Cloisonne), Sparkle gold (Timica), Gold 4504 (Chromalite) and Monarch gold 233X (Cloisonne); bronze nacres sold especially by the company Merck under the name Bronze Fine (17384) (Colorona) and Bronze (17353) (Colorona) and by Engelhard under the name Super Bronze (Cloisonne); orange nacres sold especially by the company Engelhard under the name Orange 363C (Cloisonne) and Orange MCR 101 (Cosmica) and by the company Merck under the name Passion Orange (Colorona) and Matte Orange (17449) (Microna); brown-colored pearlescent agents marketed by Engelhard under the name Nu-antique copper 340XB (Cloisonne) and Brown CL4509 (Chromalite); nacres with a copper sheen sold especially by Engelhard under the name Copper 340A (Timica); the nacres with a red glint sold especially by MERCK under the name Sienna fine (17386) (Colorona); yellow-colored pearlescent agents marketed by ENGELHARD under the name Yellow (4502) (Chromalite); the red-colored pearlescent agents with a gold glint sold especially by ENGELHARD under the name Sunstone G012 (Gemtone); pink nacres sold especially by Engelhard under the name Tan opal G005 (Gemtone); the black nacres with gold reflection sold by the company Engelhard under the name Nu antique bronze 240 AB (Timica), the blue nacres sold especially by the company Merck under the name Matte Blue (17433) (Microna), the white nacres with reflection silver sold in particular by the company Merck under the name Xirona Silver and the golden-green orange-colored mother-of-pearl marketed by Merck under the name Indian summer (Xirona) and their mixtures. The cosmetic composition according to the invention may also comprise water-soluble or fat-soluble dyes. By "dyes", it is necessary to include generally organic compounds that are soluble in fatty substances such as oils or in a hydroalcoholic phase. Liposoluble dyes are, for example, Sudan Red, DC Red 17, DC Green 6, 13-carotene, soybean oil, Sudan Brown, DC Yellow 11, DC Violet 2, Orange DC 5 and yellow quinoline. The water-soluble dyes are, for example, beet juice and caramel. The cosmetic composition according to the invention may also contain at least one material with a specific optical effect.

This effect is different from a simple conventional hue effect, i.e. unified and stabilized as produced by conventional dyestuffs, such as, for example, monochromatic pigments. For the purposes of the invention, "stabilized" means devoid of effect of color variability with the angle of observation or in response to a change in temperature. For example, this material may be chosen from particles with a metallic sheen, goniochromatic coloring agents, diffractive pigments, thermochromic agents, optical brighteners, and especially interferential fibers. Of course, these different materials can be combined to provide the simultaneous manifestation of two effects, or even a new effect according to the invention. The particles with a metallic sheen that can be used in the invention are in particular chosen from: the particles of at least one metal and / or at least one metal derivative, the particles comprising an organic or inorganic substrate, monomatiere or multimaterial, covered at least partially by at least one metal-reflecting layer comprising at least one metal and / or at least one metal derivative, and - mixtures of said particles. Among the metals that may be present in said particles, mention may be made, for example, of Ag, Au, Cu, Al, Ni, Sn, Mg, Cr, Mo, Ti, Zr, Pt, Va, Rb, W, Zn, Ge, Te. Se and their mixtures or alloys. Ag, Au, Cu, Al, Zn, Ni, Mo, Cr, and mixtures or alloys thereof (e.g., bronzes and brasses) are preferred metals. As an illustration of these particles, mention may be made of aluminum particles, such as those sold under the names STARBRITE 1200 EAC® by the company SIBERLINE and METALURE® by the company ECKART. Mention may also be made of copper metal powders or alloy blends such as the references 2844 sold by the company Radium Bronze, metallic pigments such as aluminum or bronze, such as those sold under the names ROTOSAFE 700 from the company ECKART the silica-coated aluminum particles sold under the name VISIONAIRE BRIGHT SILVER from ECKART and the metal alloy particles such as bronze powder (copper and zinc alloy) coated with silica marketed under the name of Visionaire Bright Natural Gold from Eckart. It may also be particles comprising a glass substrate such as those marketed by the company NIPPON SHEET GLASS under the names MICROGLASS METASHINE. The goniochromatic coloring agent may be chosen, for example, from interferential multilayer structures and liquid crystal coloring agents. Examples of symmetrical interferential multilayer structures that can be used in compositions produced in accordance with the invention are, for example, the following structures: Al / SiO 2 / Al / SiO 2 / Al, pigments having this structure being marketed by the company DUPONT DE NEMOURS; Cr / MgF 2 / Al / MgF 2 / Cr, pigments having this structure being marketed under the name CHROMAFLAIR by the company FLEX; MoS2 / SiO2 / Al / SiO2 / MoS2 Fe2O3 / SiO2 / Al / SiO2 / Fe2O3, and Fe2O3 / SiO2 / Fe2O3 / SiO2 / Fe2O3, pigments having these structures being marketed under the name SICOPEARL by BASF MoS2 / SiO2 / mica-oxide / SiO2 / MoS2; Fe2O3 / SiO2 / mica-oxide / SiO2 / Fe2O3; TiO2 / SiO2 / TiO2 and TiO2 / Al2O3 / TiO2; SnO / TiO2 / SiO2 / TiO2 / SnO; Fe 2 O 3 / SiO 2 / Fe 2 O 3 SnO / mica / TiO 2 / SiO 2 / TiO 2 / micalSnO, pigments having these structures being sold under the name XIRONA by the company Merck (Darmstadt). By way of example, these pigments may be the pigments of silica / titania / tin oxide structure marketed under the trademark Xirona Magic by Merck, the silica / brown iron oxide structural pigments marketed under the name XIRONA INDIAN SUMMER by the company MERCK and silica structural pigments / titanium oxide / mica / tin oxide marketed under the name XIRONA 25 CARRIBEAN BLUE by MERCK. Mention may also be made of the INFINITE COLORS pigments from SHISEIDO. Depending on the thickness and nature of the different layers, different effects are obtained. Thus, with the Fe 2 O 3 / SiO 2 / Al / SiO 2 / Fe 2 O 3 structure, grey-green to gray-red is passed for SiO 2 layers of 320 to 350 nm; from red to golden for layers of SiO2 from 380 to 400 nm; from violet to green for SiO2 layers from 410 to 420 nm; from copper to red for SiO2 layers from 430 to 440 nm.

Mention may be made, by way of example of pigments with a polymeric multilayer structure, those marketed by the company 3M under the name COLOR GLITTER. As liquid crystal goniochromatic particles, it is possible to use, for example, those sold by the company CHENIX as well as those marketed under the name HELICONE® HC by the company WACKER. Preferably, the amount of dyestuff (s) in a composition according to the invention is between 0.01 and 40% by weight, especially 0.1 and 30% by weight, or even 1 and 20% by weight. , the total weight of the composition. Fatty phase A composition according to the invention may comprise a fatty phase, which may represent 1 to 98% by weight, especially 5 to 95% by weight, or even 10 to 90% by weight, of the total weight of the composition. This fatty phase may comprise oils, waxes and / or pasty compounds and / or silicone compounds as defined below. Preferably, the composition comprises at least one oil, preferably a silicone oil, and / or a silicone compound. , other than the silicone filler, especially in a content of between 0.1 and 60% by weight relative to the total weight of the composition. Thus, a composition according to the invention may advantageously comprise one or more oils, which may be chosen from hydrocarbon oils, fluorinated oils and mixtures thereof. The oils can be of animal, vegetable, mineral or synthetic origin. By "oil" is meant a non-aqueous compound, immiscible with water, liquid at room temperature (25 ° C) and atmospheric pressure (760 mm Hg). The oils can be volatile or nonvolatile. For the purposes of the invention, the term "volatile oil" means any oil capable of evaporating on contact with keratin materials in less than one hour at ambient temperature and atmospheric pressure. The volatile oils preferably have a non-zero vapor pressure, at ambient temperature and atmospheric pressure, ranging from 0.13 Pa to 40,000 Pa, in particular from 1.3 Pa to 13,000 Pa, more particularly from 1.3 Pa to Pa at 1300 Pa. The term "fluorinated oil" means an oil comprising at least one fluorine atom.

By "hydrocarbon oil" is meant an oil containing mainly hydrogen and carbon atoms. The oils may optionally comprise oxygen, nitrogen, sulfur and / or phosphorus atoms, for example in the form of hydroxyl or acid radicals.

The volatile oils may be chosen from hydrocarbon-based oils containing from 8 to 16 carbon atoms, and especially branched C 8 -C 16 alkanes (also known as isoparaffins), such as isododecane, isodecane and isohexadecane. The volatile hydrocarbon oil may also be a linear volatile alkane comprising 7 to 17 carbon atoms, in particular 9 to 15 carbon atoms, and more particularly 11 to 13 carbon atoms. There may be mentioned in particular n-nonadecane, n-decane, n-undecane, n-dodecane, n-tridecane, n-tetradecane, n-pentadecane, n-hexadecane, and mixtures thereof. Non-volatile oils that may especially be mentioned include: - hydrocarbon-based oils of animal origin, - hydrocarbon-based oils of plant origin, such as phytostearyl esters, such as phytostearyl oleate, phytostearyl isostearate and lauroyl glutamate / octyldodecyl / phytostearyl; triglycerides consisting of esters of fatty acids and of glycerol, in particular, whose fatty acids may have chain lengths ranging from C4 to C36, and especially from C18 to C36, these oils possibly being linear or branched, saturated or unsaturated; these oils may, in particular, be heptanoic or octanoic triglycerides, shea, alfalfa, poppy, pumpkin, millet, barley, quinoa, rye, bancoulier, passionflower oil, shea butter, aloe oil, sweet almond oil, peach almond oil, peanut oil, argan oil, avocado oil, oil baobab, borage oil, broccoli oil, calendula oil, camelina oil, carrot oil, safflower oil, hemp oil, rapeseed oil , cottonseed oil, coconut oil, pumpkin seed oil, wheat germ oil, jojoba oil, lily oil, macadamia oil, oil corn oil, meadowfoam oil, St. John's wort oil, monoi oil, hazelnut oil, apricot kernel oil, walnut oil, olive oil, Evening Primrose Oil, Palm Oil, Blackcurrant Seed Oil, Kiwi Seed Oil, Grape Seed Oil, Pea Oil istache, pumpkin oil, pumpkin oil, quinoa oil, rose hip oil, sesame oil, soybean oil, sunflower oil, castor oil , and watermelon oil, and mixtures thereof, or caprylic / capric acid triglycerides, especially those sold by Stéarineries Dubois or in particular those sold under the names Miglyol 810®, 812® and 818® by the company Dynamit Nobel, - synthetic ethers having from 10 to 40 carbon atoms; synthetic esters, such as the oils of formula R10OOR2, in which R1 represents a residue of a linear or branched fatty acid containing from 1 to 40 carbon atoms and R2 represents a hydrocarbon chain, in particular, a branched chain containing from 1 to 40 carbon atoms provided that R 1 + R 2 is greater than or equal to 10. The esters may be, in particular, chosen from alcohol and fatty acid esters, such as, for example, cetostearyl octanoate, esters of isopropyl alcohol, such as isopropyl myristate, isopropyl palmitate, ethyl palmitate, 2-ethylhexyl palmitate, stearate or isopropyl isostearate, isostearyl isostearate, octyl stearate, hydroxylated esters, such as isostearyl lactact, octyl hydroxystearate, diisopropyl adipate, heptanoates, and especially isostearyl heptanoate, octanoates, decanoates or ricinoleates of alcohols or polyalcohols, such as dioctanoate of propylene glycol, cetyl octanoate, tridecyl octanoate, 4-diheptanoate and 2-hexyl ethyl palmitate, alkyl benzoate, polyethylene glycol diheptanoate, diethyl 2-hexanoate, propylene glycol and mixtures thereof, C12-C15 alcohol benzoates, hexyl laurate, esters of neopentanoic acid, such as isodecyl neopentanoate, isotridecyl neopentanoate, isostearyl neopentanoate, neopentanoate octyldodecyl, esters of isononanoic acid, such as isononyl isononanoate, isotridecyl isononanoate, octyl isononanoate, hydroxylated esters such as isostearyl lactate, di-isostearyl malate, ; esters of polyols and pentaerythritol esters, such as dipentaerythritol tetrahydroxystearate / tetraisostearate, esters of diol dimers and of diacid dimers, copolymers of diol dimer and diacid dimer and their esters, such as dimeric dilinoleyl copolymers; dilinoleic diol / dimers and their esters, - copolymers of polyols and diacid dimers, and their esters, - branched-chain and / or unsaturated carbon-chain liquid fatty alcohols having 12 to 26 carbon atoms, such as 2 -octyldodecanol, isostearyl alcohol, oleic alcohol, 2-hexyldecanol, 2-butyloctanol, and 2-undecylpentadecanol; - higher C12-C22 fatty acids, such as oleic acid, linoleic acid; linolenic acid and mixtures thereof; - Di-alkyl carbonates, the 2 alkyl chains may be identical or different, such as dicaprylyl carbonate; oils with a molar mass ranging from about 400 to about 10,000 g / mol, in particular from about 650 to about 10,000 g / mol, in particular from about 750 to about 7500 g / mol, and more particularly varying from about 1000 to about 5000 g / mol; mention may be made, alone or as a mixture, of (i) lipophilic polymers such as polybutylenes, polyisobutylenes, for example hydrogenated, polydecenes and hydrogenated polydecenes, copolymers of vinylpyrrolidone, such as vinylpyrrolidone / 1-copolymer hexadecene, and polyvinylpyrrolidone (PVP) copolymers, such as copolymers of a C2-C30 alkene, such as C3-C22, and combinations thereof; (ii) linear fatty acid esters having a total carbon number ranging from 35 to 70, such as pentaerythrityl tetrapelargonate; (iii) hydroxylated esters such as polyglycerol-2 triisostearate; (iv) aromatic esters such as tridecyl trimellitate; (v) esters of C24-C28 branched fatty alcohols or fatty acids, such as those described in US Pat. No. 6,491,927 and the pentaerythritol esters, and in particular triisoarachidyl citrate, pentaerythrityl tetraisonanoate, glyceryl triisostearate, glyceryl tri-2-tetradecanoate, pentaerythrityl tetraisostearate, polyglyceryl-2 tetraisostearate or pentaerythrityl tetra decyl-2 tetradecanoate; (vi) dimer diol esters and polyesters, such as diol dimer and fatty acid esters, and dimer diol and diacid esters.

In particular, one or more oils according to the invention may be present in a composition according to the invention in a content ranging from 1 to 90% by weight, preferably from 2 to 75% by weight, or even from 3 to 60% by weight, relative to the total weight of the composition. It is understood that this weight percentage of oil takes into account the weight of oil used for the formulation of the associated supramolecular polymer, if present.

Silicone compound As specified above, the fatty phase of a composition according to the invention may comprise at least one silicone compound having a viscosity of less than 10,000,000 at 25 ° C. Such a compound is advantageously chosen from silicone gums, volatile silicone oils and non-volatile silicone oils. In particular, the silicone compound considered according to the invention may be a silicone oil having a viscosity of between 3 centistokes (cSt) (3 × 10 -6 m 2 / s) and 800,000 centistokes (cSt) (800,000 × 10 -6 Preferably, the silicone compound considered according to the invention can be a nonvolatile silicone oil having a viscosity of between 9 centistokes (cSt) (3 × 10 -6 m 2 / s) and 600,000 centistokes ( cSt) (600,000 x 10 "6 m2 / s).

Silicone Oils By "oil" is meant a non-aqueous, water-immiscible compound, liquid at room temperature (25 ° C) and atmospheric pressure (760 mmHg). For the purposes of the present invention, the term "silicone oil" means an oil comprising at least one silicon atom, and in particular at least one Si-O group. In particular, the volatile or nonvolatile silicone oils that can be used in the invention preferably have a viscosity at 25 ° C. of less than 800,000 cSt), preferably less than or equal to 600,000 cSt, preferably less than or equal to 500 000 cSt. The viscosity of these silicone oils can be measured according to ASTM D-445. As is apparent from the foregoing, a composition according to the invention and / or considered according to a process of the invention contains at least one silicone oil other than cyclopentasiloxane. Such an oil, also called decamethylcyclopentasiloxane, is especially sold under the name DC-245 by Dow Corning or Mirasil CM 5. Naturally, a composition according to the invention or considered according to a process of the invention may contain a silicone oil mixture formed only in part of such an oil. The silicone oils which can be used according to the invention can be volatile and / or nonvolatile.

Thus a composition according to the invention or considered according to a process of the invention may contain a mixture of volatile and nonvolatile silicone oil. By "volatile" is meant an oil capable of evaporating on contact with the skin in less than one hour at ambient temperature (25 ° C.) and atmospheric pressure.

The volatile oil is a volatile cosmetic oil which is liquid at ambient temperature, in particular having a non-zero vapor pressure, at ambient temperature and atmospheric pressure, in particular having a vapor pressure ranging from 0.13 Pa to 40 000 Pa (10 3 to 300 mm Hg), and preferably ranging from 1.3 Pa to 13 000 Pa (0.01 to 100 mm Hg), and preferably ranging from 1.3 Pa to 1300 Pa (0.1 to 10 mm). mm Hg).

By "non-volatile" is meant an oil whose vapor pressure at ambient temperature and atmospheric pressure is non-zero and less than 0.02 mm Hg (2.66 Pa) and better still less than 10-3 mm Hg (0.13 Pa).

Volatile silicone oils According to a first embodiment, the compositions according to the invention comprise at least one volatile silicone oil. The volatile silicone oil that may be used in the invention may be chosen from silicone oils having in particular an 8 centistokes viscosity (cSt) (8 × 10 -6 m 2 / s). In addition, the volatile silicone oil that may be used in the invention may be chosen preferably from silicone oils having a flash point ranging from 40 ° C. to 102 ° C., preferably having a flash point greater than 55 ° C. and less than or equal to at 95 ° C, and preferably ranging from 65 ° C to 95 ° C. As volatile silicone oils, mention may be made of volatile linear or cyclic silicone oils, in particular those having a viscosity of 8 centistokes (cSt) (8 × 10 6 m 2 / s at 25 ° C.), and having, in particular, from 2 to 10 silicon atoms, and in particular from 2 to 7 silicon atoms, these silicones optionally containing alkyl or alkoxy groups having from 1 to 10 carbon atoms. More particularly, the volatile silicone oils are non-cyclic and in particular are chosen from: - non-cyclic linear silicones of formula (1): R 3 SiO- (R 2 SiO) SiR 3 (1) in which R, identical or different, denotes: a hydrocarbon radical, saturated or unsaturated, having from 1 to 10 carbon atoms, preferably from 1 to 6 carbon atoms, optionally substituted by one or more fluorine atoms or by one or more hydroxyl groups, or - a hydroxyl group , one of the radicals R possibly being a phenyl group, n is an integer ranging from 0 to 8, preferably ranging from 2 to 6, and better still ranging from 3 to 5, the silicone compound of formula (I) containing at most 15 atoms of carbon. the branched silicones of formula (II) or (III) below: R3SiO - [(R3SiO) RSiO] - (R2SiO) X-SiR3 (II) [R3SiO] 4Si (III) in which R, identical or different, denotes: a hydrocarbon radical, saturated or unsaturated, having from 1 to 10 carbon atoms, optionally substituted by one or more fluorine atoms or by one or more hydroxyl groups, or - a hydroxyl group, one of the radicals R possibly being a grouping phenyl, x is an integer ranging from 0 to 8, the silicone compound of formula (II) or (III) containing at most 15 carbon atoms. Preferably, for the compounds of formulas (1), (II), (III), the ratio between the number of carbon atoms and the number of silicon atoms is between 2.25 and 4.33. The silicones of formulas (I) to (III) may be prepared according to the known processes for the synthesis of silicone compounds. Among the silicones of formula (I), mention may be made of: the following disiloxanes: hexamethyldisiloxane (surface tension = 15.9 mN / m), in particular sold under the name DC 200 FLUID O. 65 cst by the company Dow Corning 1,3-di-tert-butyl-1,1,3,3-tetramethyl disiloxane; 1,3-dipropyl 1,1,3,3-tetramethyl disiloxane; heptyl pentamethyl disiloxane; 1,1,1-triethyl 3,3,3-trimethyl disiloxane; hexaethyl disiloxane; 1,1,3,3-tetramethyl-1,3-bis (2-methylpropyl) disiloxane; pentamethyl octyl disiloxane; 1,1,1-trimethyl 3,3,3-tris (1-methylethyl) disiloxane; 1-butyl-3-ethyl-1,1,3-trimethyl-3-propyl disiloxane; pentamethyl pentyl disiloxane; 1-butyl 1,1,3,3-tetramethyl-3- (1-methylethyl) disiloxane; 1,1,3,3-tetramethyl-1,3-bis (1-methylpropyl) disiloxane; 1,1,3-triethyl-1,3,3-tripropyl disiloxane; (3,3-dimethylbutyl) pentamethyl disiloxane; (3-methylbutyl) pentamethyl disiloxane; (3-methylpentyl) pentamethyl disiloxane; 1,1,1-triethyl 3,3-dimethyl-3-propyl disiloxane; 1- (1,1-dimethylethyl) 1,1,3,3,3-pentamethyl disiloxane; 1,1,1-trimethyl 3,3,3-tripropyl disiloxane; 1,3-dimethyl-1,1,3,3-tetrakis (1-methylethyl) disiloxane; 1,1-dibutyl 1,3,3,3-tetramethyl disiloxane; 1,1,3,3-tetramethyl-1,3-bis (1-methylethyl) disiloxane; 1,1,1,3-tetramethyl 3,3-bis (1-methylethyl) disiloxane; 1,1,1,3-tetramethyl 3,3-dipropyl disiloxane; 1,1,3,3-tetramethyl-1,3-bis (3-methylbutyl) disiloxane; butyl pentamethyl disiloxane; pentaethyl methyl disiloxane; 1,1,3,3-tetramethyl-1,3-dipentyl disiloxane; 1,3-dimethyl-1,1,3,3-tetrapropyl disiloxane; 1,1,1,3-tetraethyl 3,3-dimethyl disiloxane; 1,1,1-triethyl 3,3,3-tripropyl disiloxane; 1,3-dibutyl 1,1,3,3-tetramethyl disiloxane and hexyl pentamethyl disiloxane. the following trisiloxanes: octamethyltrisiloxane (surface tension = 17.4 mN / m), sold in particular under the name DC 200 FLUID 1 cst by the company Dow Corning 3-pentyl 1,1,1,3,5,5, 5-heptamethyl trisiloxane; 1-hexyl-1,1,3,3,5,5,5-heptamethyl trisiloxane; 1,1,1,3,3,5,5-heptamethyl-5-octyl trisiloxane; 1,1,1,3,5,5,5-heptamethyl-3-octyl trisiloxane, especially sold under the name "Silsoft 034" by the company OSI; 1,1,1,3,5,5,5-heptamethyl-3-hexyltrisiloxane (surface tension = 20.5 mN / m), especially sold under the name "DC 2-1731" by the company Dow Corning; 1,1,3,3,5,5-hexamethyl 1,5-dipropyl trisiloxane; 3- (1-ethylbutyl) 1,1,1,3,5,5,5-heptamethyltrisiloxane; 1,1,1,3,5,5,5-heptamethyl-3- (1-methylpentyl) trisiloxane; 1,5-diethyl-1,1,3,3,5,5-hexamethyltrisiloxane; 1,1,1,3,5,5,5-heptamethyl-3- (1-methylpropyl) trisiloxane; 3- (1,1-dimethylethyl) 1,1,1,3,5,5,5-heptamethyl trisiloxane; 1,1,1,5,5,5-hexamethyl-3,3-bis (1-methylethyl) trisiloxane; 1,1,1,3,3,5,5-hexamethyl 1,5-bis (1-methylpropyl) trisiloxane; 1,5-bis (1,1-dimethylethyl) -1,1,3,3,5,5-hexamethyl tri siloxane; 3 - (3,3-dimethylbutyl) 1,1,1,3,5,5,5-heptamethyltrisiloxane; 1,1,1,3,5,5,5-heptamethyl-3- (3-methylbutyl) trisiloxane; 1,1,1,3,5,5,5-heptamethyl-3- (3-methylpentyl) trisiloxane; 1,1,1,3,5,5,5-heptamethyl-3- (2-methylpropyl) trisiloxane; 1-butyl 1,1,3,3,5,5,5-heptamethyltrisiloxane; 1,1,1,3,5,5,5-heptamethyl-3-propyl trisiloxane; 3-isohexyl 1,1,1,3,5,5,5-heptamethyltrisiloxane; 1,3,5-triethyl-1,1,3,5,5-pentamethyltrisiloxane; 3-butyl 1,1,1,3,5,5,5-heptamethyltrisiloxane; 3-tert-pentyl 1,1,1,3,5,5,5-heptamethyltrisiloxane; 1,1,1,5,5,5-hexamethyl 3,3-dipropyl trisiloxane; 3,3-diethyl 1,1,1,5,5,5-hexamethyltrisiloxane; 1,5-dibutyl 1,1,3,3,5,5-hexamethyltrisiloxane; 1,1,1,5,5,5-hexaethyl-3,3-dimethyltrisiloxane; 3,3-dibutyl 1,1,1,5,5,5-hexamethyltrisiloxane; 3-ethyl-1,1,1,3,5,5,5-heptamethyltrisiloxane; 3-heptyl 1,1,1,3,5,5,5-heptamethyltrisiloxane and 1-ethyl-1,1,3,3,5,5,5-heptamethyltrisiloxane. the following tetrasiloxanes: decamethyltetrasiloxane (surface tension = 18 mN / m), sold in particular under the name DC 200 FLUID 1.5 is by the company Dow Corning; 1,1,3,3,5,5,7,7-octamethyl 1,7-dipropyl tetrasiloxane; 1,1,1,3,3,5,7,7,7-nonamethyl 5- (1-methylethyl) tetrasiloxane; 1-butyl 1,1,3,3,5,5,7,7,7-nonamethyl tetrasiloxane; 3,5-diethyl-1,1,1,3,5,7,7,7-octamethyl tetrasiloxane; 1,3,5,7-tetraethyl-1,1,3,5,7,7-hexamethyltetrasiloxane; 3,3,5,5-tetraethyl 1,1,1,7,7,7-hexamethyltetrasiloxane; 1,1,1,3,3,5,5,7,7-nonamethyl 7-phenyltetrasiloxane; 3,3-diethyl 1,1,1,5,5,7,7,7-octamethyl tetrasiloxane; 1,1,1,3,3,5,7,7,7-nonamethyl-5-phenyltetrasiloxane; the following pentasiloxanes: dodecamethylpentasiloxane (surface tension = 18.7 mN / m), sold in particular under the name DC 200 FLUID 2 is by the company Dow Corning; 1,1,3,3,5,5,7,7,9,9-decamethyl-1,9-dipropyl pentasiloxane 3,3,5,5,7,7-hexaethyl-1,1,1, 9,9,9-hexamethylpentasiloxane; 1,1,1,3,3,5,7,7,9,9,9-undecamethyl 5-phenyl pentasiloxane 1-butyl 1,1,3,3,5,5,7,7,9, 9,9-undecamethylpentasiloxane; 3,3-diethyl-1,1,1,5,5,7,7,9,9,9-decamethylpentasiloxane; 1,3,5,7,9-pentaethyl 1,1,3,5,7,9,9-heptamethylpentasiloxane; 3,5,7-triethyl 1,1,1,3,5,7,9,9,9-nonamethyl pentasiloxane and 1,1,1-triethyl 3,3,5,5,7,7,9 , 9,9-nonamethylpentasiloxane. the following hexasiloxanes: 1-butyl-1,1,3,3,5,5,7,7,9,9,11,11,11-tridecamethyl hexasiloxane; 3,5,7,9-tetraethyl 1,1,1,3,5,7,9,11,11,11-decamethyl hexasiloxane and tetradecamethyl hexasiloxane. hexadecamethyl heptasiloxane. octadecamethyl octasiloxane. Among the silicones of formula (II), mention may be made of: - the following tetrasiloxanes: [3,3,3-trimethyl] bis [(trimethylsilyl) oxy] disiloxanyl] ethyl; 1,1,1,5,5,5-hexamethyl-3- (2-methylpropyl) 3 - [(trimethylsilyl) oxy] trisiloxane; 3- (1,1-dimethylethyl) 1,1,1,5,5,5-hexamethyl-3 - [(trimethylsilyl) oxy] trisiloxane; 3-butyl 1,1,1,5,5,5-hexamethyl-3 - [(trimethylsilyl) oxy] trisiloxane; 1,1,1,5,5,5-hexamethyl-3-propyl-3 - [(trimethylsilyl) oxy] trisiloxane; 3-ethyl-1,1,1,5,5,5-hexamethyl-3 - [(trimethylsilyl) oxy] trisiloxane; 1,1,1-triethyl 3,5,5,5-tetramethyl-3- (trimethylsiloxy) trisiloxane; 3-methyl-1,1,1,5,5,5-hexamethyl-3- [trimethylsilyl] oxy] trisiloxane; 3 - [(dimethylphenylsilyl) oxy] 1,1,1,3,5,5,5-heptamethyltrisiloxane; 1,1,1,5,5,5-hexamethyl-3- (2-methylpentyl) 3 - [(trimethylsilyl) oxy] trisiloxane 1,1,1,5,5,5-hexamethyl-3- (4-methylpentyl) 3- (trimethylsilyl) oxy] trisiloxane; 3-hexyl-1,1,1,5,5,5-hexamethyl-3 - [(trimethylsilyl) oxy] trisiloxane and 1,1,1,3,5,5,5-heptamethyl-3 - [(trimethylsilyl) oxy] trisiloxane. the following pentasiloxanes: 1,1,1,3,5,5,7,7,7 nonamethyl 3 (trimethylsiloxy) tetrasiloxane and 1,1,1,3,3,7,7,7-octamethyl 5- phenyl 5- [(trimethylsilyl) oxy] tetrasiloxane. the following heptasiloxanes: 1,1,1,3,5,5,7,7,9,9,11,11,11-tridecamethyl-3 - [(trimethylsilyl) oxy] hexasiloxane.

Among the silicones of formula (III), mention may be made of: 1,1,1,5,5,5-hexamethyl-3,3-bis (trimethylsiloxy) trisiloxane. It is also possible to use other volatile silicone oils chosen from: the following tetrasiloxanes: 2,2,8,8-tetramethyl-5 [(pentamethyldisiloxanyl) methyl] -3,7-dioxa-2,8-disilanonane; 2,2,5,8,8-pentamethyl-5 - [(trimethylsilyl) methoxy] 4,6-dioxa-2,5,8-trisilanonane; 1,3-dimethyl-1,3-bis [(trimethylsilyl) methyl] 1,3-disiloxanediol; 3-ethyl-1,1,1,5,5,5-hexamethyl-3- [3- (trimethylsiloxy) propyl] trisiloxane and 1,1,1,5,5,5-hexamethyl-3-phenyl-3- [(trimethylsilyl) oxy] trisiloxane (Dow 556 Fluid). the following pentasiloxanes: 2,2,7,7,9,9,11,11,16,16-decamethyl-3,8,10,15-tetraoxa-2,7,9,11,16-pentasilaheptadecane and the tetrakis [(trimethylsilyl) methyl] silicic acid ester. the following hexasiloxanes: 3,5-diethyl-1,1,1,7,7,7-hexamethyl-3,5-bis [(trimethylsilyl) oxy] tetrasiloxane and 1,1,1,3,5,7, 7,7-octamethyl 3,5-bis [(trimethylsilyl) oxy] tetrasiloxane. heptasiloxane: 1,1,1,3,7,7,7-heptamethyl-3,5,5-tris [(trimethylsilyl) oxy] tetrasiloxane. the following octasiloxanes: 1,1,1,3,5,5,9,9,9-nonamethyl-3,7,7-tris [(trimethylsilyl) oxy] pentasiloxane; 1,1,1,3,5,7,9,9,9-nonamethyl-3,5,7-tris [(trimethylsilyl) oxy] pentasiloxane and 1,1,1,7,7,7-hexamethyl 3,3,5,5-tetrakis [(trimethylsilyl) oxy] tetrasiloxane.

As volatile silicone oils, mention may more particularly be made of decamethylcyclopentasiloxane, sold especially under the name DC-245 by the company Dow Corning, and dodecamethylcyclohexasiloxane sold especially under the name DC-246 by Dow Corning, and octamethyltrisiloxane sold in particular. under the name DC-200 Fluid 1 cst by Dow Corning, decamethyltetrasiloxane sold especially under the name DC-200 Fluid 1.5 cSt by Dow Corning and DC-200 Fluid 5 cst marketed by Dow Corning, octamethylcyclotetrasiloxane, heptamethylhexyltri-siloxane, heptamethylethyltrisiloxane, heptamethyloctyltrisiloxane, dodecamethylpentasiloxane, and mixtures thereof. It should be noted that among the above-mentioned oils, linear oils are particularly advantageous.

Non-volatile silicone oils According to a second embodiment, the compositions according to the invention comprise at least one non-volatile silicone oil. The silicone nonvolatile oil that may be used in the invention may be chosen from silicone oils having a viscosity at 25 ° C. of greater than or equal to 9 centistokes (cSt) (9 × 10 -6 m 2 / s) and less than 800,000 cSt, preferably between 50 and 600,000 cSt, preferably between 100 and 500,000 cSt. The viscosity of this silicone can be measured according to ASTM D-445. Among these silicone oils, two types of oils can be distinguished according to whether or not they are phenylated. As representative of these non-volatile linear silicone oils, mention may be made of polydimethylsiloxanes; alkyldimethicones; vinylmethylmethicones; and silicones modified with aliphatic groups, optionally fluorinated, or with functional groups such as hydroxyl groups, thiols and / or amines. Thus, as non-volatile, non-phenyl silicone oils, mention may be made of: PDMSs comprising pendant alkyl or alkoxy groups and / or silicone chain ends, groups each having from 2 to 24 carbon atoms, PDMSs comprising aliphatic groups, or functional groups such as hydroxyl, thiol and / or amine groups, polyalkylmethylsiloxanes optionally substituted by a fluorinated group such as polymethyltrifluoropropyldimethylsiloxanes, polyalkylmethylsiloxanes substituted with functional groups such as hydroxyl groups, thiol groups; and / or amine, polysiloxanes modified with fatty acids, fatty alcohols or polyoxyalkylenes, and mixtures thereof. According to one embodiment, a composition according to the invention contains at least one non-phenylated linear silicone oil.

The non-phenyl linear silicone oil may in particular be chosen from silicones of formula: ## STR1 ## in which: R 1, R 2, R 5 and R 6 are, together or separately, an alkyl radical having 1 to 6 carbon atoms , R3 and R4 are, together or separately, an alkyl radical having 1 to 6 carbon atoms, a vinyl radical, an amine radical or a hydroxyl radical, X is an alkyl radical having 1 to 6 carbon atoms, a radical hydroxyl or an amine radical, wherein n and p are integers selected to have a fluid compound.

As non-volatile silicone oils that may be used according to the invention, mention may be made of those for which the substituents R 1 to R 6 and X represent a methyl group, p and n are such that the viscosity is 500,000 cst, such as that sold under the name SE30 by the company General Electric, the one sold under the name AK 500000 by Waker, the one sold under the name Mirasil DM 500,000 by Bluestar and that sold under the name Dow Corning 200 Fluid 500,000 cst by Dow Corning. the substituents R 1 to R 6 and X represent a methyl group, p and n are such that the viscosity is 60,000 cst, such as that sold under the name Dow Corning 200 Fluid 60000 CS by Dow Corning and that sold under the name Wacker Belsil DM 60,000 by the company Wacker. the substituents R 1 to R 6 and X represent a methyl group, p and n are such that the viscosity is 350 cst, such as that sold under the name Dow Corning 200 Fluid 350 CS by the company Dow Corning. methyl group, the group X - the substituents R1 to R6 represents a hydroxyl group, n and p are such a composition that sold under the name Baysilone Fluid that the viscosity is 700 cst, as an embodiment variant, T0. 7 by the Momentive company. less a phenyl silicone oil. According to the invention, representative of these phenylated non-volatile silicone oils, mention may be made of: phenyl silicone oils corresponding to the following formula: ## STR2 ##

R-Si O 1 R (I) in which the R groups independently of each other represent a methyl or a phenyl, provided that at least one R group represents a phenyl. Preferably in this formula, the phenyl silicone oil comprises at least three phenyl groups, for example at least four, at least five or at least six. the phenyl silicone oils corresponding to the following formula: ## STR1 ## in which the R groups independently represent a methyl or a phenyl, provided that at least one R group represents a phenyl. Preferably in this formula, said organopolysiloxane comprises at least three phenyl groups, for example at least four or at least five. Mixtures of the phenyl organopolysiloxanes described above can be used. For example, mixtures of organopolysiloxane triphenyl, tetra- or penta-phenyl. the phenyl silicone oils corresponding to the following formula: ## STR1 ## in which Me represents methyl, Ph represents phenyl. Such phenyl silicone is especially manufactured by Dow Corning under the reference PH-1555 HRI or Dow Corning 555 Cosmetic Fluid (chemical name: 1,3,5-trimethyl 1,1,3,5,5-pentaphenyl trisiloxane, INCI name : trimethyl pentaphenyl trisiloxane). The reference Dow Corning 554 Cosmetic Fluid can also be used.

the phenyl silicone oils corresponding to the following formula: (IV) in which Me represents methyl, y is between 1 and 1000, and X represents -CH 2 -CH (CH 3) (Ph). the phenyl silicone oils corresponding to the following formula (V): ## STR2 ## Si Me-Si Si Me-OR Si-O Si Si In which Me is methyl and Ph is phenyl, OR 'represents a group - OSiMe3 and y is 0 or varies between 1 and 1000, z varies between 1 and 1000, so that the compound (V) is a non-volatile oil.

According to a first embodiment, y varies between 1 and 1000. It is possible to use, for example, trimethyl Siloxyphenyl Dimethicone, sold in particular under the reference BELSIL PDM 1000 sold by the company Wacker. According to a second embodiment y is equal to 0. It is possible to use for example PHENYL TRIMETHYLSILOXY TRISILOXANE, sold in particular under the reference DOW CORNING 556 COSMETIC GRADE FLUID.

the phenyl silicone oils corresponding to the following formula (VI), and their mixtures: embedded image in which: R 1 to R 10, independently of one another, are linear or saturated hydrocarbon radicals, saturated or unsaturated; , cyclic or branched, in C 1 -C 30, m, n, p and q are, independently of each other, integers between 0 and 900, provided that the sum 'm + n + q' is different from Preferably, the sum 'm + n + q' is between 1 and 100. Preferably, the sum 'm + n + p + q' is between 1 and 900, more preferably between 1 and 800. Preferably, q is equal to 0. The phenyl silicone oils corresponding to the following formula (VII), and their mixtures: ## STR1 ## wherein R 1 is SiO 2 R 1 to R 6, independently of one another, are cyclic or branched, linear or branched C 1 -C 30 hydrocarbon radicals, m, n and p, independently of one another; very, integers between 0 and 100, provided that the sum 'n + m' is between 1 and 100. Preferably, R1 to R6, independently of each other, represent a saturated hydrocarbon radical, linear or branched , C1-C30, especially C1-C12, and in particular a methyl, ethyl, propyl or butyl radical.

In particular, R1 to R6 may be identical, and may furthermore be a methyl radical. Preferably, one can have m = 1 or 2 or 3, and / or n = 0 and / or p = 0 or 1, in formula (VII). the phenyl silicone oils corresponding to formula (VIII), and their mixtures: ## STR2 ## in which: ## STR1 ## in which: R is a C 1 -C 30 alkyl radical, an aryl radical or an aralkyl radical, n is an integer ranging from 0 to 100, and m is an integer ranging from 0 to 100, provided that the sum n + m ranges from 1 to 100. In particular, the radicals R of formula (VIII) and R1 to R10 previously defined, may each represent a linear or branched, saturated or unsaturated, especially C 2 -C 20, alkyl radical, in particular C3-C16 and more particularly C4-Clo, or a C6-C14 mono- or polycyclic aryl radical, especially C10-C13 or an aralkyl radical whose aryl and alkyl residues are as defined above. Preferably, R of the formula (VIII) and R1 to R10 may each represent a methyl, ethyl, propyl, isopropyl, decyl, dodecyl or octadecyl radical, or a phenyl, tolyl, benzyl or phenethyl radical. According to one embodiment, it is possible to use a phenyl silicone oil of formula (VIII) having a viscosity at 25 ° C. of between 5 and 1500 mm 2 / s (ie 5 to 1500 cSt), preferably having a viscosity of between 5 and 1000 mm2 / s (ie 5 to 1000 cSt). As the phenyl silicone oil of formula (VIII), phenyltrimethicones such as DC556 from Dow Corning (22.5 cSt), Silbione 70663V30 from Rhône Poulenc (28 cSt), or diphenyldimethicones such as Belsil oils, including Belsil PDM1000 (1000cSt), Belsil PDM 200 (200 cSt) and Belsil PDM 20 (20cSt) from Wacker. Values in parentheses represent viscosities at 25 ° C. The phenyl silicone oils corresponding to the following formula, and their mixtures: RI X - Si. Wherein R 1, R 2, R 5, and R 6 are, together or separately, an alkyl radical having 1 to 6 carbon atoms, wherein R 1, R 2, R 5 and R 6 are, together or separately, an alkyl radical having 1 to 6 carbon atoms; R3 and R4 are, together or separately, an alkyl radical having 1 to 6 carbon atoms, or an aryl radical, X is an alkyl radical having 1 to 6 carbon atoms, a hydroxyl radical or a vinyl radical, n and p being selected so as to impart to the oil a weight average molecular weight of less than 200,000 g / mol, preferably less than 150,000 g / mol and more preferably less than 100,000 g / mol. The phenyl silicones that are particularly suitable for the invention are those corresponding to formulas (II) (and in particular formula (III) and V above, more particularly the phenyl silicones are chosen more from phenyl trimethicones, phenyl dimethicones, phenyl trimethylsiloxy diphenylsiloxanes, diphenyl dimethicones, diphenyl methyldiphenyl trisiloxanes, and 2-phenylethyl trimethylsiloxysilicates, and mixtures thereof Preferably, the weight-average molecular weight of the nonvolatile phenyl silicone oil according to the invention varies from 500 to 10. 000 g / mol.

Silicone rubber According to another variant embodiment, a composition according to the invention contains at least one silicone gum. The silicone gum that may be used in the invention may be chosen from silicone gums having a viscosity at 25 ° C above 800,000 centistokes (cSt) (9 × 10-6 m2 / s) and in particular between 800,000 and 10,000,000 cSt. preferably between 1,000,000 and 5,000,000 cSt, preferably between 1,000,000 and 2,500,000 cSt. The viscosity of this silicone can be measured according to ASTM D-445. The molecular weight of the silicone gums is generally greater than 350,000 g / mol, ranging from 350,000 to 800,000 g / mol, preferably from 450,000 to 700,000 g / mol.

The silicone gum may in particular be chosen from silicones of formula: ## STR1 ## Wherein R 1, R 2, R 5 and R 6 are, together or separately, an alkyl radical having 1 to 6 carbon atoms, R 3 and R 4 are, together or separately, an alkyl radical having from 1 to 6 atoms of carbon, a vinyl radical, an amine radical or a hydroxyl radical, X is an alkyl radical having from 1 to 6 carbon atoms, a hydroxyl radical or an amine radical, n and p being integers chosen so that the viscosity of the compound is greater than 800,000 cst.

As silicone gum that may be used according to the invention, mention may be made of those for which: the substituents R 1 to R 6 represent a methyl group, the X group represents a methyl group, n and p are such that the molecular weight of the polymer is 600; 000 g / mol, such as that sold under the name Mirasil CDPDM by Bluestar; the substituents R 1 to R 6 represent a methyl group, the X group represents a hydroxyl group, n and p are such that the molecular weight of the polymer is 600 000 g / mol, such as that sold under the name SGM 36 by the Dow company Corning; dimethicones of the (polydimethylsiloxane) (methylvinylsiloxane) type such as SE63 marketed by GE BAYER Silicones, poly (dimethylsiloxane) (diphenyl) (methylvinylsiloxane) copolymers, and mixtures thereof.

A cosmetic makeup and / or care composition according to the invention may furthermore comprise the usual ingredients, depending on the destination of the composition.

Solid fatty substances A composition according to the invention may also comprise at least one solid fatty substance, in particular chosen from waxes and / or pasty fatty substances. Preferably, the amount of paste in the make-up and / or care composition according to the invention is between 0.5 and 50% by weight, especially 1 to 40% by weight, or even 2 to 30% by weight, of total weight of the composition.

Waxes According to a first embodiment, the composition is free of wax.

According to a second embodiment, the composition comprises at least one wax. According to this embodiment, preferably, the amount of wax (es) in the makeup and / or care composition according to the invention is between 0.5 and 30% by weight, especially 1 to 20% by weight, or 2 to 15% by weight, of the total weight of the composition. By "wax" is meant a lipophilic compound, solid at room temperature (25 ° C.), with a reversible solid / liquid state change, having a melting point greater than or equal to 30 ° C. of up to 200 ° C. vs. The waxes may be chosen from waxes of animal, vegetable, mineral or synthetic origin and mixtures thereof. There may be mentioned hydrocarbon-based waxes such as beeswax, lanolin wax, and Chinese insect waxes; rice bran wax, Carnauba wax, Candelilla wax, Ouricury wax, Alfa wax, berry wax, shellac wax, Japanese wax and sumac wax; montan wax, orange and lemon waxes, microcrystalline waxes, paraffins and ozokerite; polyethylene waxes, waxes obtained by Fisher-Tropsch synthesis and waxy copolymers and their esters. There may also be mentioned waxes obtained by catalytic hydrogenation of animal or vegetable oils having linear or branched C8-C32 fatty chains. Among these, there may be mentioned hydrogenated sunflower oil, hydrogenated castor oil, hydrogenated coconut oil, hydrogenated lanolin oil, and di- (1,1-trimethylol) tetrastearate. 1 propane). Mention may also be made of silicone waxes and fluorinated waxes. It is also possible to use the waxes obtained by hydrogenation of castor oil esterified with cetyl alcohol. Pasty fatty substances According to a first embodiment, the composition is free of pasty fatty substances. According to a second embodiment, the composition comprises at least one pasty fatty substance. According to this embodiment, preferably, the amount of pasty fatty substance in the make-up and / or care composition according to the invention is between 0.5 and 30% by weight, especially 1 to 20% by weight, or even 2 to 15% by weight, of the total weight of the composition. The term "pasty fatty substance" is understood to mean a lipophilic fat compound with a reversible solid / liquid state change and comprising, at a temperature of 23 ° C., a liquid fraction and a solid fraction. The pasty compound preferably has a hardness at 20 ° C ranging from 0.001 to 0.5 MPa, preferably from 0.002 to 0.4 MPa. The pasty compound is preferably chosen from synthetic compounds and compounds of plant origin. A pasty compound can be obtained synthetically from starting materials of plant origin. The following may be mentioned, alone or as a mixture: lanolin and its derivatives, such as lanolin alcohol, oxyethylenated lanolines, acetylated lanolin, lanolin esters such as isopropyl lanolate, oxypropylenated lanolines, polymeric or non-polymeric silicone compounds, such as polydimethylsiloxanes of high molecular weight, polydimethylsiloxanes with side chains of the alkyl or alkoxy type having from 8 to 24 carbon atoms, in particular stearyl dimethicones, - fluorinated compounds which may or may not be polymeric, - polymers vinyl, especially homopolymers of olefins; olefin copolymers; homopolymers and copolymers of hydrogenated dienes; linear or branched oligomers, homo or copolymers of alkyl (meth) acrylates preferably having a C8-C30 alkyl group; homo and copolymer oligomers of vinyl esters having C8-C30 alkyl groups; homo- and copolymer oligomers of vinyl ethers having C8-C30 alkyl groups; liposoluble polyethers resulting from the polyetherification between one or more C2-Ci00 diols, preferably C2-050 diols; and in particular copolymers of ethylene oxide and / or propylene oxide with C6-C30 long-chain alkylene oxides, more preferably such as the weight ratio of ethylene oxide and / or propylene oxide with alkylene oxides in the copolymer is from 5:95 to 70:30; polyol ethers chosen from pentaerythritol ethers and polyalkylene glycol ethers, fatty alcohol and sugar ethers, and mixtures thereof, pentaerythritol ether and polyethylene glycol containing 5 oxyethylenated units (50E) (CTFA name: PEG-5 Pentaerythrityl Ether), pentaerythritol ether and polypropylene glycol comprising 5 oxypropylene units (5 OP) (CTFA name: PPG-5 Pentaerythrityl Ether), and mixtures thereof; esters and polyesters; and in particular (i) the esters of an oligomeric glycerol, in particular the diglycerol esters, in particular the adipic acid and glycerol condensates, for which part of the hydroxyl groups of the glycerols has reacted with a mixture of fatty acids such as stearic acid, capric acid, stearic acid and isostearic acid and 12-hydroxystearic acid; (ii) phytosterol esters, (iii) pentaerythritol esters; (iv) esters formed from at least one alcohol, at least one of the alcohols being a Guerbet alcohol and a diacid dimer formed from at least one unsaturated fatty acid; (v) the uncrosslinked polyesters resulting from the polycondensation between a linear or branched C 4 -C 50 dicarboxylic acid or polycarboxylic acid and a C2-050 diol or polyol, (vi) the polyesters which result from the esterification, by a polycarboxylic acid of an aliphatic hydroxycarboxylic acid ester; (vii) aliphatic ester esters resulting from the esterification of an aliphatic hydroxycarboxylic acid ester with an aliphatic carboxylic acid comprising in particular 4 to 30 carbon atoms. The aliphatic hydroxycarboxylic acid ester is advantageously derived from a hydroxylated aliphatic carboxylic acid having 2 to 40 carbon atoms and 1 to 20 hydroxyl groups; (viii) the aliphatic ester esters selected from the ester resulting from the esterification reaction of hydrogenated castor oil with isostearic acid (hydrogenated castor oil mono-, di- or tri-isostearate) . The pasty compound may also be of plant origin. Isomérisée jojoba oil may be mentioned such as isomérisée partially hydrogenated jojoba oil trans isomerized; orange wax, shea butter, partially hydrogenated olive oil, cocoa butter, mango oil.

Aqueous Phase A composition according to the invention may also comprise an aqueous phase, which may represent 0 to 80% by weight, especially 1 to 70% by weight, or even 3 to 60% by weight, of the total weight of the composition. This aqueous phase may consist essentially of water, or may comprise a mixture of water and of a solvent which is miscible with water (miscibility in water greater than 50% by weight at 25 ° C.), chosen in particular from monoalcohols having 1 to 5 carbon atoms such as ethanol, isopropanol, glycols having 2 to 8 carbon atoms such as propylene glycol, ethylene glycol, 1,3-butylene glycol, dipropylene glycol, ketones C3-C4, C2-C4 aldehydes and mixtures thereof. However, as specified above, advantageously the compositions according to the invention are anhydrous or contain less than 3% by weight of water, preferably less than 1% by weight of water relative to the total weight of the composition. By "anhydrous" is meant in particular that the water is preferably not deliberately added to the composition but may be present in trace amounts in the various compounds used in the composition.

Surfactant (s) A composition according to the invention may also comprise at least one surfactant, which may be present in a proportion of 0.1 to 10% by weight, in particular 0.5 to 8% by weight, or even 1 to 6%. by weight, the total weight of the composition. The surfactant may be chosen from amphoteric, anionic, cationic or nonionic surfactants, preferably nonionic surfactants. In particular, the following may be mentioned, alone or as a mixture: a) nonionic surfactants with a HLB of less than 8 at 25 ° C., optionally combined with one or more nonionic surfactants with a HLB greater than 8 at 25 ° C., as mentioned lower, such as: ose esters and ethers such as sucrose stearates, sucrose cocoate, sorbitan stearate and mixtures thereof; esters of fatty acids, in particular of C 8 -C 24, and preferably of C 16 -C 22, and of polyol, in particular glycerol or sorbitol, such as glyceryl stearate, glyceryl laurate or polyglyceryl stearate; -2, sorbitan tristearate, and glyceryl ricinoleate; Lecithins, such as soy lecithins; oxyethylenated and / or oxypropylenated ethers (which can contain from 1 to 150 oxyethylenated and / or oxypropylenated groups) of fatty alcohols (in particular of C8-C24 and preferably of C12-C18 alcohols) such as oxyethylenated ether; stearyl alcohol with 2 oxyethylene units (CTFA name: Steareth-2); silicone surfactants such as dimethicone copolyols and alkyldimethicone copolyols, and for example the mixture of cyclomethicone / dimethicone copolyol sold especially under the name Q2-3225C® by the company Dow Corning; B) nonionic surfactants with HLB greater than or equal to 8 at 25 ° C, such as: esters and ethers of oses such as the mixture of cetylstearyl glucoside and cetyl and stearyl alcohols such as Montanov 68 from Seppic ; the glycerol ethers, oxyethylenated and / or oxypropylenated, which can comprise from 1 to 150 oxyethylene and / or oxypropylene units; oxyethylenated and / or oxypropylenated ethers (which may contain from 1 to 150 oxyethylene and / or oxypropylene units) of fatty alcohols, in particular of C8-C24, and preferably of C12-C18, such as the oxyethylenated ether of the stearyl alcohol containing 20 oxyethylene units (CTFA name: Steareth-20), oxyethylenated ether of oxyethylene cetearyl alcohol (Ceteareth-30) and oxyethylenated ether of the C12-C15 fatty alcohol mixture comprising 7 oxyethylene units (C12-15 Pareth-7); esters of fatty acids, in particular of C8-C24, and preferably of C16-C22, and of polyethylene glycol (or PEG) (which may comprise from 1 to 150 oxyethylene units), such as PEG-50 stearate and PEG-40 monostearate; The fatty acid esters, in particular C 8 -C 24, and preferably C 16 -C 22, and oxyethylenated and / or oxypropylenated glycerol ethers (which may contain from 1 to 150 oxyethylene and / or oxypropylene units), such as polyoxyethylenated glyceryl monostearate with 200 oxyethylene units; polyoxyethylenated glyceryl stearate with 30 oxyethylene units, polyoxyethylenated glyceryl oleate with oxyethylene units, polyoxyethylenated glyceryl cocoate with 30 oxyethylene units, polyoxyethylenated glyceryl isostearate with 30 oxyethylene units and polyoxyethylene glyceryl laurate with 30 units; oxyethylene units; the fatty acid esters, in particular C 8 -C 24, and preferably C 16 -C 22, and oxyethylenated and / or oxypropylene sorbitol ethers (which may comprise from 1 to 150 oxyethylene and / or oxypropylene units), such as polysorbate 20 and polysorbate 60; dimethicone copolyol, in particular that sold under the name Q2-52020® from Dow Corning; dimethicone copolyol benzoate, in particular those sold under the names FINSOLV SLB 101® and 201® from FINETEX; copolymers of propylene oxide and ethylene oxide, also called EO / PO polycondensates, which are copolymers consisting of polyethylene glycol and polypropylene glycol blocks, for example the polyethylene glycol / polypropylene glycol triblock polycondensates; polyethylene glycol. c) anionic surfactants such as: salts of C16-C30 fatty acids, in particular amine salts such as triethanolamine stearate or 2-amino-2-methylpropane-1,3-diol stearate; Polyoxyethylenated fatty acid salts, in particular aminoxides or alkali metal salts, and mixtures thereof - phosphoric esters and their salts, such as "DEA oleth-10 phosphate" (Crodafos N 10N from CRODA) or monocotyl monopotassium phosphate; sulfosuccinates such as "Disodium PEG-5 citrate lauryl sulphosuccinate" and "Disodium ricinoleamido MEA sulphosuccinate"; alkyl ether sulfates, such as sodium lauryl ether sulphate; isethionates; acylglutamates such as the "Disodium hydrogenated tallow glutamate" (AMISOFT HS-21 R® from AJINOMOTO) and sodium stearoyl glutamate (AMISOFT HS-25 11 PF® from AJINOMOTO); - soy derivatives such as potassium soyate; citrates, such as glyceryl stearate citrate; proline derivatives, such as sodium palmitoyl proline or the mixture of sodium palmitoyl sarcosinate, palmitoyl magnesium glutamate, palmitoyl acid and palmitoyl proline (Sepifeel One from Seppic) - lactylates, such as sodium stearoyl lactylate; sarcosinates, such as sodium palmitoyl sarcosinate or the mixture of stearoyl sarcosine and myristoyl sarcosine 75/25; sulfonates, such as C14-17 sodium alkyl-sec-sulfonate; glycinates, such as sodium cocoyl glycinate. d) cationic surfactants, such as: alkylimidazolidiniums such as isostearyl ethylimidonium ethosulphate, ammonium salts such as (C1-C3 alkyl) -tri (C1-C4) alkyl halides ) ammonium such as N, N, N-trimethyl-1-docosanaminium chloride (or Behentrimonium chloride). e) amphoteric surfactants such as N-acyl amino acids such as N-alkyl-aminoacetates and disodium cocoamphodiacetate, and amine oxides such as stearamine oxide.

Additive (s) A make-up and / or care composition according to the invention may also comprise at least one agent usually used in cosmetics chosen, for example, from reducing agents, thickening agents, film-forming agents in particular hydrophobic, elastomers silicone, softeners, anti-foam agents, moisturizers, UV filters, ceramides; cosmetic assets; peptizers, perfumes, proteins, vitamins, propellants, film-forming or non-film-forming polymers, hydrophilic or lipophilic; lipophilic or hydrophilic gelling agents. The above additives are generally present between 0.01 and 10% by weight, for each of them, relative to the total weight of the composition. Of course, one skilled in the art will take care to choose the constituents of the composition such that the advantageous properties attached to the invention are not, or not substantially impaired.

Thickeners Thus, a composition according to the invention may further comprise a thickening agent. The thickening agent may be chosen from: - organomodified clays which are clays treated with compounds chosen in particular from quaternary amines, tertiary amines. As organomodified clays, mention may be made of organomodified bentonites such as those sold under the name "Bentone 34" by the company RHEOX, organomodified hectorites such as those sold under the name "Bentone 27", "Bentone 38" by the company Rheox. hydrophobic fumed silica. Such silicas are, for example, sold under the references "AEROSIL R812®" by Degussa, "CAB-O-SIL TS-530®" by Cabot and under the references "AEROSIL R972®", "AEROSIL R974®" by the company Degussa, "CAB-O-SIL TS-610®", "CAB-O-SIL TS-720®" by Cabot. The thickener may be present in an amount of from 0.1% to 5% by weight, based on the total weight of the composition, and more preferably from 0.4% to 3% by weight.

Hydrophobic film-forming polymer According to one embodiment variant, a composition according to the invention may comprise at least one film-forming polymer, in particular hydrophobic polymer. A cosmetic composition for makeup and / or care of the skin or lips according to the invention may comprise from 0.1 to 30% by weight, preferably from 0.2 to 20% by weight and even more preferably from 0 to 30% by weight. , 5 to 15% by weight of hydrophobic polymer (s) film (s). This hydrophobic organic film-forming polymer may be a polymer selected from the group comprising: polyamide silicone block polymers, block ethylenic polymers, vinyl polymers comprising at least one carbosiloxane dendrimer derivative, copolymers comprising carboxylate groups and polydimethylsiloxane groups, silicone resins (T resin, MQ resin) and water-dispersible polymers in non-aqueous dispersion form of polymer particles and mixtures thereof.

a) Silicone resins According to an alternative embodiment, a composition according to the invention may comprise, as hydrophobic film-forming polymer, at least one silicone resin. Silicone resins which can be used in the compositions according to the invention can be used, for example, silicone resins of MQ type, T type or MQT type.

MQ resins As an example of silicone resins of the MQ type, mention may be made of alkylsiloxysilicates of formula [(R 1) 3 SiO 1/2] X (SiO 4/2) y (MQ units) in which x and y are integers ranging from 50 to 80, and such that the group R 1 represents a radical as defined above, and preferably is an alkyl group having 1 to 8 carbon atoms or a hydroxyl group, preferably a methyl group. Examples of solid silicone resins of the MQ type of trimethylsiloxysilicate type that may be mentioned are those sold under the reference SR1000 by the company General Electric, under the reference TMS 803 by the company Wacker, under the name "KF-7312J" by the company Shin -Etsu, "DC 749", "DC 593" by Dow Corning. As silicone resins comprising MQ siloxysilicate units, mention may also be made of phenylalkylsiloxysilicate resins, such as phenylpropyldimethylsiloxysilicate (Silshine 151 sold by General Electric). The preparation of such resins is described in particular in US5817302.

TA resins as an example of T type silicone resins, there may be mentioned polysilsesquioxanes of formula (RSiO3i2) X (T units) in which x is greater than 100 and such that the R group is an alkyl group having from 1 to 10 carbon atoms, said polysilsesquioxanes may further comprise Si-OH end groups. Preferably, it is possible to use the polymethylsilsesquioxane resins in which R represents a methyl group, for instance those marketed: by the company Wacker under the reference Resin MK such as Belsil PMS MK: polymer comprising CH3SiO3 / 2 repeating units (units T), which may also comprise up to 1% by weight of (CH 3) 2 SiO 2 12 units (D units) and having an average molecular weight of about 10,000 g / mol, or - by the company SHIN-ETSU under the references KR -220L which are composed of T units of formula CH3SiO3i2 and have Si-OH end groups (silanol), under the reference KR-242A which comprise 98% of T units and 2% of dimethyl D units and have groups Si-OH terminals or also under the reference KR-251 comprising 88% of T units and 12% of dimethyl D units and have Si-OH end groups.

MOT resins As a resin comprising MQT units, those known from US 5,110,890 are particularly known. A preferred form of MQT type resins are MQT-propyl resins (also called MQTPr). Such resins that can be used in the compositions according to the invention are in particular those described and prepared in application WO 2005/075542, the content of which is incorporated herein by reference. Preferably, the silicone resin is chosen from the group comprising: a) an MQ-type resin, chosen in particular from (i) alkylsiloxysilicates, which may be trimethylsiloxysilicates, of formula [(R 1) 3 SiO 2), (SiO 4 / 2) y, wherein x and y are integers ranging from 50 to 80, and such that the group R 1 represents a hydrocarbon radical having from 1 to 10 carbon atoms, a phenyl group, a phenylalkyl group or a hydroxyl group, and preferably is an alkyl group having 1 to 8 carbon atoms, preferably a methyl group, and (ii) phenylalkylsiloxysilicate resins, such as phenylpropyldimethylsiloxysilicate, and / or b) a type T resin, especially selected from polysilsesquixanes of formula (RSiO3i2) X, in which x is greater than 100 and the group R is an alkyl group having from 1 to 10 carbon atoms, for example a methyl group, said polysilsesquioxanes also being capable of take Si-OH end groups, and / or c) a MQT-type resin, especially of the MQT-propyl type, which may comprise the units (i) (R 13 SiO 11) a, (ii) (R 22 SiO 2/2) b, (iii ) (R3SiO3i2), and (iv) SiO4 / 2) d, with R1, R2 and R3 independently representing a hydrocarbon radical, in particular alkyl, having from 1 to 10 carbon atoms, a phenyl group, a phenylalkyl group or else a hydroxyl group and preferably an alkyl radical having 1 to 8 carbon atoms or a phenyl group, a being between 0.05 and 0.5, b being between zero and 0.3, c being greater than zero, d being between 0.05 and 0.6, a + b + c + d = 1, a, b, c and d being mole fractions, provided that more than 40 mol% of the R 3 groups of the siloxane resin are propyl groups. b) Lipodispersible film-forming polymers in the form of non-aqueous dispersions of polymer particles, also called "NAD" According to another variant embodiment, a composition according to the invention can comprise, as hydrophobic film-forming polymer, at least one polymer chosen from lipodispersible film-forming polymers in the form of non-aqueous dispersions of polymer particles, also called "NAD".

As the non-aqueous dispersion of hydrophobic film-forming polymer, the dispersions of particles of a grafted ethylenic polymer, preferably acrylic, can be used in a liquid oily phase: either in the form of ethylenic polymer particles dispersed in the absence of stabilizer additional surface of the particles as described in particular in WO 04/055081, or in the form of particles, surface-stabilized, dispersed in the liquid fatty phase. The dispersion of surface-stabilized polymer particles can be manufactured as described in EP-A-749747. The polymer particles may be surface stabilized by a stabilizer which may be a block polymer, a graft polymer, and / or a random polymer, alone or in admixture. Dispersions of film-forming polymer in the liquid fatty phase, in the presence of stabilizing agents, are described in particular in documents EP-A-748746, EP-A-923928 and EP-A-930060, the contents of which are incorporated as reference in this application.

Advantageously, dispersions of dispersed ethylenic polymer particles are used in the absence of additional stabilizer at the surface of said particles. By way of examples of "NAD" type polymers, mention may be made more particularly of acrylic dispersions in isododecane, such as Mexomere PAP® (acrylic copolymer dispersed in isododecane (25%) with pyrene / isoprene copolymer). marketed by the company CHIMEX c) Block ethylenic copolymer According to one embodiment of the invention, the film-forming polymer is a block ethylenic copolymer, containing at least a first block having a glass transition temperature (Tg) of greater than or equal to 40 ° C. C and being derived in whole or in part from one or more first monomers, which are such that the homopolymer prepared from these monomers has a glass transition temperature greater than or equal to 40 ° C, and at least one second block having a glass transition temperature less than or equal to 20 ° C and being issued in whole or in part from one or more second mol namers, which are such that the homopolymer prepared from these monomers has a glass transition temperature of less than or equal to 20 ° C, said first sequence and said second sequence being interconnected by a random intermediate segment comprising at least one of said first constituent monomers of the first block and at least one of said second constituent monomers of the second block, and said block copolymer having a polydispersity index of greater than 2

The block polymer used according to the invention thus comprises at least a first block and at least a second block and is prepared exclusively from monofunctional monomers. This means that the sequenced ethylenic polymer used according to the present invention does not contain multifunctional monomers, which make it possible to break the linearity of a polymer in order to obtain a connected or even cross-linked polymer, as a function of the multifunctional monomer content. The polymer used according to the invention also does not contain macromonomers ("macromonomer" means a monofunctional monomer having a pendant group of a polymeric nature, and preferably having a molecular weight greater than 500 g / mol, or a polymer having on one of its ends a polymerizable terminal group (or ethylenically unsaturated)), which are used in the preparation of a graft polymer. By "sequenced" polymer is meant a polymer comprising at least 2 distinct sequences, preferably at least 3 distinct sequences. By "ethylenic" polymer is meant a polymer obtained by polymerization of monomers comprising ethylenic unsaturation.

It is specified that in what precedes and what follows the terms "first" and "second" sequences do not condition the order of said sequences (or blocks) in the structure of the polymer. The first and second sequences of the polymer used in the invention may be advantageously incompatible with each other. By "sequences incompatible with each other" is meant that the mixture formed by a polymer corresponding to the first block and by a polymer corresponding to the second block, is not miscible in the polymerization solvent, predominant in weight, of the sequenced polymer, at ambient temperature (25 ° C.) and atmospheric pressure (105 Pa), for a content of the mixture of said polymers greater than or equal to 5% by weight, relative to the total weight of the mixture of said polymers and of said solvent method of polymerization, it being understood that: i) said polymers are present in the mixture in a content such that the respective weight ratio ranges from 10/90 to 90/10, and that ii) each of the polymers corresponding to the first and second blocks has a average molecular weight (in weight or in number) equal to that of the sequenced polymer +/- 15%. In the case of a mixture of polymerization solvents, assuming two or more solvents present in identical mass proportions, said polymer mixture is immiscible in at least one of them. Of course, in the case of a polymerization carried out in a single solvent, the latter is the majority solvent. The sequenced polymer according to the invention comprises at least a first sequence and at least a second sequence linked together by an intermediate segment comprising at least one constituent monomer of the first block and at least one constituent monomer of the second block. The intermediate segment (also called intermediate sequence) has a glass transition temperature Tg between the glass transition temperatures of the first and second sequences. The intermediate segment is a sequence comprising at least one constituent monomer of the first block and at least one constituent monomer of the second block of the polymer makes it possible to "compatibilize" these blocks.

Advantageously, the intermediate segment comprising at least one constituent monomer of the first block and at least one constituent monomer of the second block of the polymer is a random polymer. Preferably, the intermediate sequence is derived essentially from 5 monomers constituting the first sequence and the second sequence. By "essentially" is meant at least 85%, preferably at least 90%, better at 95% and even better at 100%. The block polymer according to the invention is advantageously a film-forming ethylenic block polymer. By "ethylenic" polymer is meant a polymer obtained by polymerization of monomers comprising ethylenic unsaturation. By "film-forming" polymer is meant a polymer capable of forming on its own or in the presence of an auxiliary film-forming agent, a continuous deposit on a support, in particular on keratin materials.

Preferably, the polymer according to the invention does not comprise silicon atoms in its backbone. By "skeleton" is meant the main chain of the polymer, as opposed to the pendant side chains. Preferably, the polymer according to the invention is not water-soluble, that is to say that the polymer is not soluble in water or in a mixture of water and linear or branched lower monoalcohols having 2 to 5 carbon atoms such as ethanol, isopropanol or n-propanol, without pH modification, at a solids content of at least 1% by weight, at room temperature (25 ° C). Preferably, the polymer according to the invention is not an elastomer. The polydispersity index of the polymer of the invention is greater than 2, for example ranging from 2 to 9. Preferably, it is greater than or equal to 2.5, for example ranging from 2.5 to 8, and better than or equal to 2.8 and in particular ranging from 2.8 to 6. The polydispersity index I of the polymer is equal to the ratio of the weight average mass Mw to the number average mass Mn. The weight average (Mw) and number (Mn) molar masses were determined by gel permeation liquid chromatography (THF solvent, calibration curve established with linear polystyrene standards, refractometric detector).

The weight average mass (Mw) of the polymer according to the invention is preferably less than or equal to 300,000, it ranges, for example, from 35,000 to 200,000, and more preferably from 45,000 to 150,000 g / mol. The number average mass (Mn) of the polymer according to the invention is preferably less than or equal to 70,000, for example from 10,000 to 60,000, and more preferably from 12,000 to 50,000 g / mol.

First sequence before a Tg greater than or equal to 40 ° C. The sequence having a Tg greater than or equal to 40 ° C. has, for example, a Tg ranging from 40 to 150 ° C., preferably greater than or equal to 50 ° C., example of 50 ° C to 120 ° C, and better still or equal to 60 ° C, for example from 60 ° C to 120 ° C. The indicated glass transition temperatures of the first and second sequences may be theoretical Tg determined from the theoretical Tg of the constituent monomers of each of the sequences, which can be found in a reference manual such as Polymer Handbook, 3 '. The sequence having a Tg greater than or equal to 40 ° C can be a homopolymer or a copolymer. The sequence having a Tg greater than or equal to 40 ° C may be derived in whole or in part from one or more monomers, which are such that the homopolymer prepared from these monomers has a glass transition temperature greater than or equal to 40 ° C. This sequence can also be called "rigid sequence". In the case where this sequence is a homopolymer, it is derived from a single type of monomer whose Tg of the corresponding homopolymer is greater than or equal to 40 ° C). In the case where the first block is a copolymer, it may be issued in whole or in part from one or more monomers, the nature and concentration of which are chosen such that the Tg of the resulting copolymer is greater than or equal to 40 ° C. vs. The copolymer may for example comprise: - monomers which are such that the homopolymers prepared from these monomers have Tg greater than or equal to 40 ° C, for example a Tg ranging from 40 ° C to 150 ° C , preferably greater than or equal to 50 ° C, ranging for example from 50 ° C to 120 ° C, and better still greater than or equal to 60 ° C, ranging for example from 60 ° C to 120 ° C, and - monomers which are such that the homopolymers prepared from these monomers have Tg's lower than 40 ° C, chosen from monomers having a Tg of between 20 ° C and 40 ° C and / or monomers having a Tg of less than or equal to at 20 ° C, for example a Tg ranging from -100 ° C to 20 ° C, preferably below 15 ° C, in particular ranging from -80 ° C to 15 ° C and better still below 10 ° C, for example ranging from from -50 ° C to 0 ° C to, as described below. The monomers and their proportions are preferably chosen so that the glass transition temperature of the first block is greater than or equal to 40 ° C. The first monomers whose homopolymers have a glass transition temperature greater than or equal to 40 ° C. are preferably chosen from the following monomers, also called main monomers: methacrylates of formula CH 2 = C (CH 3) COOR 1 in which R 1 represents a linear or branched, unsubstituted alkyl group containing from 1 to 4 carbon atoms, such as a methyl, ethyl, propyl or isobutyl group or R 1 represents a C 4 to C 12 cycloalkyl group, preferably a C 8 to C 12 cycloalkyl group; , such as isobornyl methacrylate, - acrylates of formula CH2 = CH-COOR2 in which R2 represents a C4-C12 cycloalkyl group such as an isobornyl group or a tert-butyl group,

the (meth) acrylamides of formula R 'CH2 = C CO

wherein R7 and R8, which are identical or different, each represents a hydrogen atom or a linear or branched C1-C12 alkyl group such as n-butyl, t-butyl, isopropyl, isohexyl, isooctyl, or isononyl; or R7 is H and R8 is 1,1-dimethyl-3-oxobutyl, and R 'is H or methyl. Examples of monomers that may be mentioned include N-butylacrylamide, N-t-butylacrylamide, N-isopropylacrylamide, N, N-dimethylacrylamide and N, N-dibutylacrylamide,

- and their mixtures.

According to one embodiment, the first block is obtained from: i) at least one acrylate monomer of formula CH 2 CHCH-COOR 2 in which R 2 represents a C 4 to C 12 cycloalkyl group, preferably a C 8 cycloalkyl group C12, such as isobornyl, ii) and at least one methacrylate monomer of formula CH2 = C (CH3) -COOR'2 wherein R'2 is C4-C12 cycloalkyl, preferably a group C8-C12 cycloalkyl, such as isobornyl. Preferably, R2 and R'2 represent independently or simultaneously an isobornyl group. The first block can be obtained exclusively from said acrylate monomer and said methacrylate monomer. Preferably, these monomers are in mass proposals of between 30:70 and 70:30, preferably between 40:60 and 60:40, in particular of the order of 50:50. The proportion of the first block is preferably 20 to 90% by weight of the polymer, more preferably 30 to 80% and more preferably 60 to 80%. According to one embodiment, the first block is obtained by polymerization of isobornyl methacrylate and isobornyl acrylate.

Second glass transition temperature sequence below 20 ° C. The second block advantageously has a glass transition temperature Tg of less than or equal to 20 ° C., for example a Tg ranging from -100 ° C. to 20 ° C., preferably less than or equal to 15 ° C., in particular ranging from -80 ° C. ° C at 15 ° C and better still less than or equal to 10 ° C, for example ranging from - 100 ° C to 10 ° C, in particular ranging from - 30 ° C to 10 ° C. The second sequence is derived in whole or in part from one or more second monomers, which are such that the homopolymer prepared from these monomers has a glass transition temperature of less than or equal to 20 ° C. The monomer having a Tg of less than or equal to 20 ° C (called the second monomer) is preferably chosen from the following monomers:

the acrylates of formula CH 2 = CHCOOR 3, R 3 representing a linear or branched C 1 to C 12 unsubstituted alkyl group, with the exception of the tert-butyl group, in which is (are) optionally intercalated one or more selected heteroatoms; among O, N, S,

the methacrylates of formula CH 2 = C (CH 3) -COOR 4, R 4 representing a linear or branched C 6 to C 12 unsubstituted alkyl group in which one or more heteroatoms selected from 0 are optionally intercalated; and S; vinyl esters of formula R 5 -CO-O-CH =CH 2 where R 5 represents a linear or branched C 4 to C 12 alkyl group; C4-C12 vinyl alcohol and alcohol ethers; C4-C12 N-alkyl acrylamides, such as N-octylacrylamide; and mixtures thereof.

The monomers having a Tg of less than or equal to 20 ° C are preferred isobutyl acrylate, 2-ethylhexyl acrylate or mixtures thereof in all proportions. Each of the first and second sequences may contain, in a minority proportion, at least one constituent monomer of the other sequence. Each of the first and / or second sequence may comprise, in addition to the monomers indicated above, one or more other monomers called additional monomers, different from the main monomers mentioned above.

The nature and amount of this additional monomer (s) are chosen so that the sequence in which they are located has the desired glass transition temperature. This additional monomer is for example selected from (meth) acrylic acid, preferably acrylic acid and mixtures thereof. The additional monomer can represent 0.5 to 30% by weight of the weight of the polymer. According to one embodiment, the polymer of the invention does not contain additional monomer. According to one embodiment, the first sequence does not comprise additional monomer. According to a preferred embodiment, the second block comprises acrylic acid as additional monomer. Preferably, the polymer of the invention comprises at least isobornyl acrylate and isobornyl methacrylate monomers in the first block and Isobutyl acrylate and acrylic acid monomers in the second block. Preferably, the polymer comprises at least isobornyl acrylate and isobornyl methacrylate monomers in an equivalent proportion by weight in the first block, and isobutyl acrylate and acrylic acid monomers in the second block. Advantageously, the first block represents 70% by weight of the polymer. . Preferably, the acrylic acid represents 5% by weight of the polymer. The block copolymer may advantageously comprise more than 2% by weight of acrylic acid monomers, and especially from 2 to 15% by weight, for example from 3 to 15% by weight, in particular from 4 to 15% by weight, or even from 4 to 15% by weight. 10% by weight of acrylic acid monomers, based on the total weight of said copolymer. Preferably, the block copolymer comprises from 50 to 80% by weight of methacrylate / isobornyl acrylate, from 10 to 30% by weight of isobutyl acrylate and from 2 to 10% by weight of acrylic acid.

Intermediate Segment The intermediate segment (also called intermediate sequence) connects the first sequence and the second sequence of the polymer used according to the present invention. The intermediate segment results from the polymerization of: i) the first monomer or monomers, and optionally the additional monomer or monomers, remaining available after their polymerization at a conversion rate of at most 90% to form the first sequence, ii) and the or second monomers, and optionally additional monomer (s) added to the reaction mixture. The formation of the second sequence is initiated when the first monomers no longer react or become incorporated in the polymer chain either because they are all consumed or because their reactivity no longer allows them to be.

Thus the intermediate segment comprises the first available monomers, resulting from a conversion rate of these first monomers of less than or equal to 90%, during the introduction of the second monomer or monomers during the synthesis of the polymer.

The intermediate segment of the block polymer is a random polymer (may also be called a statistical sequence). That is to say, it comprises a statistical distribution of the first monomer (s) and second monomer (s) and any additional monomer (s) that may be present.

Thus, the intermediate segment is a statistical sequence, as is the first sequence and the second sequence if they are not homopolymers (i.e., both are formed from at least two monomers different).

Process for preparing the copolymer: The block ethylenic copolymer according to the invention is prepared by free radical polymerization, according to the techniques well known in this type of polymerization. In particular, it can be prepared according to the method described in application FR0953625, the content of which is incorporated by reference. Preferably, the block ethylenic copolymer is present in the composition in an active content of from 0.1 to 60%, more preferably 0.5 to 50%, more preferably 1 to 30% and more preferably 1 to 40% by weight. relative to the total weight of the composition Distillation of the synthesis solvent It is possible to carry out a step of total or partial elimination of said solvent or volatile oil (typically isododecane). It is then carried out in particular by distillation, optionally under vacuum, and optional addition of nonvolatile hydrocarbon ester oil comprising at least 16 carbon atoms and having a molar mass of less than 650 g / mol, such as octyledodecyl neopentanoate (especially 2-octyledodecyl neopentanoate) This step is carried out hot and optionally under vacuum to distill a maximum volatile synthesis solvent and is known to those skilled in the art. d) Polyamide silicone block polymer According to another embodiment variant, a composition according to the invention comprises, as hydrophobic film-forming polymer, at least one polyamide silicone block polymer, also called silicone polyamide.

The silicone polyamides are preferably solid at room temperature (25 ° C.) and atmospheric pressure (760 mmHg). For the purposes of the invention, the term "polymer" means a compound having at least 2 repeating units, preferably at least 3 repeating units and more preferably 10 repeating units.

The silicone polyamides of the composition of the invention may be polymers of the polyorganosiloxane type, for instance those described in documents US Pat. No. 5,874,069, US Pat. No. 5,919,441, US Pat. No. 6,051,216 and US Pat. No. 5,981,680. . According to the invention, the silicone polymers may belong to the following two families: (1) polyorganosiloxanes comprising at least two amide groups, these two groups being located in the polymer chain, and / or (2) polyorganosiloxanes comprising at least two amide groups, these two groups being located on grafts or branches.

According to one variant of the invention, it is also possible to use a polymer comprising at least one unit of formula (III) or (IV): ## STR1 ## Wherein: 1) R4, R5, R6 and R7, which may be identical or different, represent a group chosen from: saturated or unsaturated, linear, branched or cyclic, C1 to C40 hydrocarbon groups, which may contain in their chain a or more oxygen, sulfur and / or nitrogen atoms, and which may be substituted in part or totally by fluorine atoms, - C6 to C10 aryl groups, optionally substituted with one or more C1 to C4 alkyl groups. C4, - the polyorganosiloxane chains containing or not one or more oxygen, sulfur and / or nitrogen atoms, 2) the X, which are identical or different, represent a linear or branched C1 to C30 alkylene di-yl group; , which may contain in its chain one or more oxygen and / or nitrogen atoms, 3) Y is a divalent group linear or branched alkylene, arylene, cycloalkylene, alkylarylene or arylalkylene, saturated or unsaturated, C1 to C50, which may contain n or include one or more oxygen, sulfur and / or nitrogen atoms, and / or carry as substituting one of the following atoms or groups of atoms: fluorine, hydroxy, C3 to C8 cycloalkyl, C1 to C40 alkyl, C5 to C10 aryl, phenyl optionally substituted with 1 to 3 C1 to C3 alkyl groups, hydroxyalkyl C1 to C3 and amino C1 to C6 alkyl, or 4) Y is a group of the formula: R8 T /

in which - T represents a linear or branched, saturated or unsaturated, C 3 to C 24, trivalent or tetravalent hydrocarbon group optionally substituted by a polyorganosiloxane chain, and which may contain one or more atoms chosen from O, N and S, or T represents a trivalent atom selected from N, P and Al, and - R8 represents a linear or branched C1-C50 alkyl group, or a polyorganosiloxane chain, which may comprise one or more ester, amide, urethane, thiocarbamate, urea or thiourea groups; and / or sulfonamide which may or may not be linked to another chain of the polymer and, 5) n is an integer ranging from 2 to 500, preferably from 2 to 200, and m is an integer ranging from 1 to 1000, preferably from 1 to 700 and more preferably from 6 to 200. According to the invention, 80% of the R4, R5, R6 and R7 of the polymer are preferably selected from methyl, ethyl, phenyl and 3.3, 3-trifluoropropyl.

According to the invention, Y may represent various divalent groups, optionally additionally having one or two free valences to establish bonds with other units of the polymer or copolymer. Preferably, Y represents a group chosen from: a) linear C 1 to C 20, preferably C 1 to C 10, alkylene groups, b) branched alkylene groups which may comprise non-conjugated C 3 to C 56 rings and unsaturations, c) C5-C6 cycloalkylene groups; d) phenylene groups optionally substituted with one or more C1-C4 alkyl groups; e) C1-C20 alkylene groups having from 1 to 5 amide groups; C1 to C20 alkylene having one or more substituents selected from hydroxyl, C3 to C8 cycloalkane, C1 to C3 hydroxyalkyl and C1 to C6 alkylamines, and g) polyorganosiloxane chains of the formula: wherein R4, R5 , R6, R7, T and m are as defined above, and h) polyorganosiloxane chains of formula: R5 In these polyamides of formula (III) or (IV), m ranges from 1 to 700, in particular from 15 to 500 and in particular from 50 to 200 and n is particularly 1 to 500 preferably, from 1 to 100 and more preferably from 4 to 25, X is preferably a linear or branched alkylene chain having from 1 to 30 carbon atoms, in particular 1 to 20 carbon atoms, in particular from 5 to 15 carbon atoms, carbon and more particularly 10 carbon atoms, and 20 - Y is preferably a linear or branched alkylene chain or which may comprise rings and / or unsaturations, having from 1 to 40 carbon atoms, in particular from 1 to 20 atoms carbon, and more preferably 2 to 6 carbon atoms, in particular 6 carbon atoms.

In the formulas (III) and (IV), the alkylene group representing X or Y may optionally contain in its alkylene part at least one of the following: 1) 1 to 5 amide groups, urea, urethane, or carbamate, 2) a C5 or C6 cycloalkyl group, and 3) a phenylene group optionally substituted with 1 to 3 identical or different C1 to C3 alkyl groups. In the formulas (III) and (IV), the alkylene groups may also be substituted with at least one member selected from the group consisting of: hydroxy group, C3-C8 cycloalkyl group, one to three C1-alkyl groups at Cao, phenyl optionally substituted with one to three C 1 to C 3 alkyl groups, a C 1 to C 3 hydroxyalkyl group, and a C 1 to C 6 aminoalkyl group. In these formulas (III) and (IV), Y may also represent: where R8 represents a polyorganosiloxane chain, and T represents a group of formula: ## STR3 ## (CH 2) a R 13 C (CH 2) b or (CH 2) a N ( CH2) b - (CH2) c (CH2) c wherein a, b and c are independently integers from 1 to 10, and R13 is a hydrogen atom or a group such as those defined for R4, R5, R6 and R7. In the formulas (III) and (W), R4, R5, R6 and R7 preferably represent, independently, a linear or branched C1-C40 alkyl group, preferably a CH3, C2H5, n-C3H7 or isopropyl group, a polyorganosiloxane chain or a phenyl group optionally substituted with one to three methyl or ethyl groups. As seen above, the polymer may comprise identical or different units of formula (III) or (IV). Advantageously, the composition according to the invention comprises at least one polydimethylsiloxane block polymer of general formula (III) and (W) having a m value of about 15. More preferably, the composition according to the invention comprises at least one polymer comprising at least one unit of formula (III) wherein m ranges from 5 to 100, in particular from 10 to 75 and more particularly is of the order of 15; more preferably, R4, R5, R6 and R7 independently represent a linear or branched C1-C40 alkyl group, preferably a CH3, C2H5, n-C3H7 or isopropyl group in formula (III). By way of example of a silicone polymer which may be used, mention may be made of one of the silicone polyamides obtained according to Examples 1 to 3 of US Pat. No. 5,981,680. According to a particularly preferred embodiment, the composition according to the invention comprises at least one polydimethylsiloxane block polymer of general formula (III) and (W) having a m value of approximately 100. Preferably, the composition according to the invention comprises at least one polymer comprising at least one unit of formula ( III) where m ranges from 50 to 200, in particular from 75 to 150 and more particularly is of the order of 100; more preferably, R4, R5, R6 and R7 independently represent a linear or branched C1-C40 alkyl group, preferably a CH3, C2H5, n-C3H7 or isopropyl group in formula (III). As an example of a silicone polymer that can be used in a preferred manner according to this embodiment, mention may be made of the silicone polyamides marketed by Dow Corning under the name DC 2-8179 (DP 100). According to one preferred embodiment, the polyamide silicone comprises units of formula III, preferably in which the groups R4, R5, R6 and R7 represent methyl groups, one of X and Y represents an alkylene group of 6 carbon atoms and the other an alkylene group of 11 carbon atoms, where n is the degree of polymerization DP of the polymer. By way of example of such silicone polyamides, mention may be made of the compounds sold by Dow Corning under the name DC 2-8179 (DP 100) and DC 2-8178 (DP 15) whose INCI name is "Nylon-611 / dimethicone copolymers ". e) Vinyl polymer comprising at least one unit derived from carbosiloxane dendrimer According to a particular embodiment, a composition used according to the invention may comprise, as hydrophobic film-forming polymer, at least one vinyl polymer comprising at least one dendrimer derived unit carbosiloxane. The vinyl polymer may in particular have a skeleton and at least one side chain, which comprises a carbosiloxane dendrimer structure. The term "carbosiloxane dendrimer structure" in the context of the present invention represents a molecular structure having branched groups having high molecular weights, said structure having a high regularity in the radial direction from the backbone bond. Such carbosiloxane dendrimer structures are described in the form of a highly branched siloxane-silylalkylene copolymer in Japanese Laid-open Patent Application Kokai 9-171,154. According to a preferred embodiment, the dendrimer-grafted vinyl polymer carbosiloxane used comprises at least one butyl acrylate monomer. According to one embodiment, the vinyl polymer further comprises at least one fluorinated organic group. The vinyl polymers represented by the formulas presented below are preferable: CH 2 = CHCOO-CH 2 CH 2 (CF 2) 6F. CI-HCOO-CH2CH2 (CF2) 8F. CH 2 CCH 3 COO-CH 2 CH 2 (CF 2) 6 F. CH 3 CH 3 COO-CH 2 CH 2 (CF 2) 8 F. CH 2 = CHCOO-CH 2 CF 3. CH2-CCH3COO-CH2CF3 The vinyl polymers represented by the formulas presented below are particularly preferable: CH 2 CHCOO-CH 2 CF 3. CH2 = CCH3CQO-CH2CF3. According to a preferred embodiment, grafted vinyl polymers in the sense of the present invention are carried in an oil, preferably volatile, selected from silicone oils, and / or hydrocarbon oils. According to one particular embodiment, the silicone oil may be cyclopentasiloxane. According to another particular embodiment, the hydrocarbon oil may be isododecane. The vinyl polymers grafted with at least one carbosiloxane dendrimer-derived unit that may be particularly suitable for the present invention are the polymers sold under the names TIB 4-100, TIB 4-101, TIB 4-120, TIB 4-130, TIB 4- 200, FA 4002 ID (TIB 4-202), TIB 4-220, FA 4001 CM (TIB 4-230) by Dow Corning. Preferably, the vinyl polymer grafted with at least one unit derived from a carbosiloxane dendrimer that can be used in a composition of the invention is an acrylate / polytrimethylsiloxymethacrylate copolymer, in particular that marketed in isododecane under the name Dow Corning FA 4002 ID silicone acrylate by the Dow Corning company. f) Copolymers comprising carboxylate groups and polydimethylsiloxane groups By "copolymer comprising carboxylate groups and polydimethylsiloxane groups" is meant in the present application, a copolymer obtained from (a) one or more carboxylic monomers (acid or ester) and (b) one or more polydimethylsiloxane (PDMS) chains. As used herein, the term "carboxylic monomer" means both the carboxylic acid monomers and the carboxylic acid ester monomers. Thus, the monomer (a) may be chosen for example from acrylic acid, methacrylic acid, maleic acid, fumaric acid, itaconic acid, crotonic acid, their esters and mixtures thereof. monomers. As esters, mention may be made of the following monomers: acrylate, methacrylate, maleate, fumarate, itaconoate and / or crotonoate. According to a preferred embodiment of the invention, the monomers in the form of esters are more particularly chosen from linear or branched, preferably C 1 -C 24 and better still C 1 -C 22 alkyl acrylates and methacrylates, the alkyl radical being preferably selected from methyl, ethyl, stearyl, butyl, 2-ethylhexyl, and mixtures thereof. Thus, according to a particular embodiment of the invention, the copolymer comprises, as carboxylate groups, at least one group chosen from acrylic acid, methacrylic acid, methyl, ethyl and stearyl acrylates or methacrylates. butyl, 2-ethylhexyl, and mixtures thereof. In the present application, the term "polydimethylsiloxanes" (also called organopolysiloxanes or, in abbreviation, PDMS) is understood to mean, in accordance with general acceptance, any organosilicon polymer or oligomer with a linear structure, of variable molecular weight, obtained by polymerization and and / or polycondensation of suitably functionalized silanes, essentially constituted by a repetition of main units in which the silicon atoms are connected to each other by oxygen atoms (siloxane bond -Si-O-Si-), comprising trimethyl radicals directly bonded via a carbon atom to said silicon atoms. The PDMS chains that can be used to obtain the copolymer used according to the invention comprise at least one polymerizable radical group, preferably located on at least one end of the chain, that is to say that the PDMS may have for example a polymerizable radical group at both ends of the chain or have a radical group polymerizable on one end of the chain and a trimethylsilyl end group on the other end of the chain. The polymerizable radical group may in particular be an acrylic or methacrylic group, in particular a CH2 = CRI-CO-O-R2 group, where R1 represents a hydrogen or a methyl group, and R2 represents -CH2-, - (CH2) 'with n = 3, 5, 8 or 10, -CH 2 -CH (CH 3) -CH 2 -, -CH 2 -CH 2 -O-CH 2 -CH 2 -, -CH 2 -CH 2 -O-CH 2 -CH 2 -CH (CH 3) -CH 2 -, -CH2-CH2-O-CH2 CH2-O-CH2-CH2-CH2-. The copolymers used in the composition of the invention are generally obtained according to the usual methods of polymerization and grafting, for example by radical polymerization (A) of a PDMS comprising at least one radical polymerizable group (for example on one of the ends of the chain or both) and (B) of at least one carboxylic monomer, as described for example in US-A-5,061,481 and US-A-5,219,560. The copolymers obtained generally have a molecular weight ranging from about 3000 to 200 000 and preferably from about 5000 to 100 000. The copolymer used in the composition of the invention may be present as it is or in dispersed form in a solvent. such as lower alcohols having 2 to 8 carbon atoms, such as isopropyl alcohol, or oils such as volatile silicone oils (eg cyclopentasiloxane). Examples of copolymers that can be used in the composition of the invention include, for example, copolymers of acrylic acid and polydimethylsiloxane grafted stearyl acrylate, polydimethylsiloxane grafted stearyl methacrylate copolymers, acrylic acid copolymers and of polydimethylsiloxane grafted stearyl methacrylate, copolymers of methyl methacrylate, butyl methacrylate, ethyl-2-hexyl acrylate and stearyl methacrylate with polydimethylsiloxane grafts. In particular, the copolymers sold by the company SHIN-ETSU under the names KP-561 (CTFA name: acrylates / dimethicone), KP-541, where the copolymer is dispersed at 60, can be mentioned in particular as copolymers that can be used in the composition of the invention. % by weight in isopropyl alcohol (CTFA name: acrylates / dimethicone and isopropyl alcohol), KP-545 where the copolymer is 30% dispersed in cyclopentasiloxane (CTFA name: acrylates / dimethicone and cyclopentasiloxane). According to a preferred embodiment of the invention, KP561 is preferably used; this copolymer is not dispersed in a solvent, but is in a waxy form, its melting point being about 30 ° C. Mention may also be made of the graft copolymer of polyacrylic and dimethylpolysiloxane dissolved in isododecane marketed by Shin Etsu under the name KP-550.

Silicone Elastomer According to another variant embodiment, a composition according to the invention may comprise, in addition to a silicone filler, at least one silicone elastomer, otherwise known as an organopolysiloxane elastomer. By "organopolysiloxane elastomer" is meant a flexible, deformable organopolysiloxane having viscoelastic properties and especially the consistency of a sponge or a flexible sphere. Its modulus of elasticity is such that this material resists deformation and has limited capacity for extension and contraction. This material is able to recover its original shape after stretching. It is more particularly a crosslinked organopolysiloxane elastomer. Preferably, the organopolysiloxane elastomer is obtained by addition reaction crosslinking (A) of diorganopolysiloxane containing at least two hydrogens each bonded to a silicon, and (B) diorganopolysiloxane having at least two ethylenically unsaturated groups bonded to a silicon. silicon, especially in the presence (C) of platinum catalyst, as for example described in application EP-A-295886. In particular, the organopolysiloxane elastomer can be obtained by reaction of dimethylvinylsiloxy-terminated dimethylpolysiloxane and trimethylsiloxy-terminated methylhydrogenpolysiloxane in the presence of platinum catalyst. The compound (A) may in particular be chosen from trimethylsiloxy-terminated methylhydrogenpolysiloxanes, trimethylsiloxy-terminated dimethylsiloxane-methylhydrogenosiloxane copolymers and cyclic dimethylsiloxane-methylhydrogensiloxane copolymers. The organopolysiloxanes (B) may in particular be chosen from methylvinylpolysiloxanes, methylvinylsiloxane-dimethylsiloxane copolymers, dimethylvinylsiloxy-terminated dimethylpolysiloxanes, dimethylvinylsiloxy-terminated dimethylsiloxane-methylphenylsiloxane copolymers, dimethylvinylsiloxy-terminated dimethylsiloxane-diphenylsiloxane-methylvinylsiloxane copolymers, dimethylvinylsiloxy-terminated copolymers, trimethylsiloxy-terminated methylvinylsiloxane, trimethylsiloxy-terminated dimethylsiloxane-methylphenylsiloxane-methylvinylsiloxane copolymers, dimethylvinylsiloxy-terminated methyl (3,3,3-trifluoropropyl) polysiloxane, and dimethylsiloxane-methyl (3,3,3-trifluoropropyl) siloxane terminated copolymers dimethylvinylsiloxy. It is advantageous that the compound (A) is added in an amount such that the molecular ratio between the total amount of hydrogen atoms bonded to silicon atoms in the compound (A) and the total amount of all the groups ethylenically unsaturated in the compound (B) is in the range of 1.5: 1 to 20: 1. Compound (C) is the catalyst of the crosslinking reaction, and is especially chloroplatinic acid, chloroplatinic acid-olefin complexes, chloroplatinic acid-alkenylsiloxane complexes, chloroplatinic acidketone complexes, platinum black, and platinum on support. The catalyst (C) is preferably added from 0.1 to 1000 parts by weight, more preferably from 1 to 100 parts by weight, as a clean platinum metal per 1000 parts by weight of the total amount of the compounds (A) and (B). The elastomer is advantageously a non-emulsifying elastomer. The term "non-emulsifying" defines organopolysiloxane elastomers that do not contain a hydrophilic chain, and in particular that do not contain polyoxyalkylene (especially polyoxyethylene or polyoxypropylene) units or polyglyceryl units. The organopolysiloxane elastomer particles are conveyed in the form of a gel consisting of an elastomeric organopolysiloxane included in at least one hydrocarbon oil and / or a silicone oil. In these gels, the organopolysiloxane particles are often non-spherical particles. Non-emulsifying elastomers are described in EP 242 219, EP 285 886, EP 765 656 and JP-A-61-194009, the contents of which are incorporated by reference.

As spherical non-emulsifying elastomers, those sold under the names "DC 9040", "DC 9041" "DC 9509", "DC 9505", "DC 9506" by the company Dow Corning can be used. MQ group organopolysiloxane elastomers, such as those sold by Wacker under the names Belsil RG100, Belsil RPG33 and preferentially RG80, may also be used in the compositions according to the invention. The elastomer may also be an emulsifying elastomer. By "emulsifying organopolysiloxane elastomer" is meant an organopolysiloxane elastomer comprising at least one hydrophilic chain, such as polyoxyalkylenated organopolysiloxane elastomers and polyglycerolated silicone elastomers. The emulsifying organopolysiloxane elastomer may be chosen from polyoxyalkylenated organopolysiloxane elastomers. The polyoxyalkylenated organopolysiloxane elastomer is a crosslinked organopolysiloxane elastomer obtainable by crosslinking addition reaction of diorganopolysiloxane containing at least one silicon-bonded hydrogen and a polyoxyalkylene having at least two ethylenically unsaturated groups. Advantageously, the polyoxyalkylenated organopolysiloxane elastomers may be formed from divinyl compounds, in particular polyoxyalkylenes having at least two vinyl groups, reacting with Si-H bonds of a polysiloxane. Polyoxyalkylenated elastomers are described in particular in patents US5236986, US5412004, US5837793 and US5811487, the contents of which are incorporated by reference.

As polyoxyalkylenated organopolysiloxane elastomer, those sold under the names "KSG-21", "KSG-20", "KSG-30", "KSG-31", "KSG-32", "KSG-33" can be used. , "KSG-210", "KSG-310", "KSG-320", "KSG-330", "KSG-340" by Shin Etsu, "DC9010", "DC9011" by Dow Corning.

The emulsifying organopolysiloxane elastomer may also be chosen from polyglycerolated organopolysiloxane elastomers.

The polyglycerolated organopolysiloxane elastomer according to the invention is an organopolysiloxane elastomer obtainable by crosslinking addition reaction of diorganopolysiloxane containing at least one silicon-bonded hydrogen and polyglycerolated compounds having ethylenically unsaturated groups, especially in the presence of of platinum catalyst. The polyglycerolated organopolysiloxane elastomer according to the invention is transported in gel form in at least one hydrocarbon oil and / or a silicone oil. In these gels, the polyglycerolated elastomer is often in the form of nonspherical particles. As polyglycerolated organopolysiloxane elastomers, those sold under the names "KSG-710", "KSG-810", "KSG-820", "KSG-830", "KSG-840" by the company Shin Etsu can be used. As non-emulsifying elastomers, those sold under the names "KSG-6", "KSG-15", "KSG-16", "KSG-18", "KSG-41", "KSG-42" can more particularly be used. , "KSG-43", "KSG-44", by the company Shin Etsu, "DC9040", "DC9041", by the company Dow Corning, "SFE 839" by the company General Electric. Exemplary elastomers which may be used include those sold under the names "KSG-31", "KSG-32", "KSG-33", "KSG-210" and "KSG-710" by the company Shin Etsu. Advantageously, the organopolysiloxane elastomer considered according to the invention is chosen from spherical non-emulsifying organopolysiloxane elastomers, polyglycerolated organopolysiloxane elastomers and polyoxyalkylenated organopolysiloxane elastomers. It is more particularly a polyoxyalkylenated organopolysiloxane elastomer.

The composition according to the invention may comprise an organopolysiloxane elastomer, alone or as a mixture, in a content ranging from 0.1 to 20% by weight, preferably from 0.2 to 15% by weight, and even more preferred from 0.5 to 12% by weight A make-up and / or care composition according to the invention may be in particular in the form of a suspension, a dispersion, a solution, a gel or an emulsion, in particular an oil-in-oil emulsion. water (W / O) or water-in-oil (W / O), or multiple (W / O / E or polyol / H / E or O / W / H), in the form of cream, foam, stick, dispersion of vesicles including ionic lipids or not, biphase lotion or multiphase, spray, powder, paste. Those skilled in the art may choose the appropriate dosage form, as well as its method of preparation, on the basis of its general knowledge, taking into account, on the one hand, the nature of the constituents used, in particular their solubility in the support, and on the other hand, of the application envisaged for the composition. In the following description and examples, unless otherwise indicated, percentages are percentages by weight and ranges of values in the form "between ... and ..." include the specified lower and upper bounds.

The following examples are presented by way of illustration and not limitation of the field of the invention.

Synthetic Example 1 of a Supramolecular Polymer 100 g of hydrogenated dihydroxy 1,2-polybutadiene polymer (GI3000 from the company Nisso, Mn = 4700 measured by GPC according to the protocol described above) is dried at 80 ° C. reduced pressure, overnight. This polymer is dissolved in 400 ml of anhydrous toluene. 25 μl of catalyst (dibutyltin dilaurate) are added and the mixture is heated at 80 ° C. with stirring until a homogeneous solution is obtained. 15 g of isocyanate functionalized molecule of structure following ONN ~ N NCO 1 1 H H (CAS No. 32093-85-9) in solution in 300 ml of anhydrous toluene are added under a controlled atmosphere at 40 ° C. The reaction mixture is heated to 100 ° C and stirred at this temperature for 4 hours. The reaction is monitored by infrared spectroscopy, followed by the total disappearance of the characteristic isocyanate peak at 2260 cm -1. At the end of the reaction, 100 ml of ethanol are added to remove any residual isocyanate, and then the mixture is filtered after addition of isododecane to make the solution less viscous. The polymer solution is then directly stripped with isododecane.

A solution of the final polymer in isododecane at 21% solids is obtained; the polymer is characterized by GPC (Mn = 6400 and polydispersity index = 1.85) and 1H NMR (spectrum according to what is expected).

Synthetic Example 2 of a Supramolecular Polymer Synthesis of the Difunctionalized GI2000 Polymer Ureidopyrrimidone 106.1 g of dihydroxy-hydrogenated 1,2-polybutadiene polymer (Nisso GI2000, Mn = 3300 measured by GPC according to the protocol described previously) are heated. in the presence of 22 mg of catalyst (dibutyltin dilaurate) at 80 ° C. under reduced pressure for 2 hours. The temperature of the mixture was lowered to 20 ° C., under argon, followed by the addition of 10 ml of isododecane and 19.3 g of isophorone diisocyanate (IPDI). The mixture is stirred for 16 hours at 20 ° C under a controlled atmosphere and is then heated to 120 ° C followed by the addition of 25 ml of propylene carbonate. 12 g of 6-methylisocytosine are added, resulting in a homogeneous white suspension. This suspension is heated to 140 ° C. and is stirred at this temperature for 6 hours. The reaction is monitored by infrared spectroscopy until the characteristic peak of the isocyanates (2250 cm -1) has completely disappeared. The mixture is then lowered to 30 ° C., and 400 ml of heptane, 200 ml of THF and 50 ml of ethanol are added thereto before filtration over celite. The mixture is then stripped with isododecane. Finally, a solution of the polymer in isododecane at 25% by weight of polymer is obtained; the polymer is characterized by GPC (Mn = 7000 and polydispersity index = 2.05).

EXAMPLE NO. 3 Synthesis of a Supramolecular Polymer 99 g of dihydroxy-hydrogenated 1,2-polybutadiene polymer (Nisso GI3000, Mn = 4700, measured by GPC according to the protocol described above, were heated in the presence of 22 mg of catalyst ( dibutyltin dilaurate) at 80 ° C. under reduced pressure for 2 hours The temperature of the mixture was lowered to 20 ° C. under argon followed by the addition of 30 ml of isododecane and 11 g of isophorone diisocyanate (IPDI) The mixture is stirred for 16 hours at 20 ° C., under a controlled atmosphere, then is heated to 120 ° C., followed by the addition of 25 ml of propylene carbonate, and 8.1 g of 6-methyl are added. isocytosine, resulting in a homogeneous white suspension This suspension is heated to 140 ° C. and is stirred at this temperature for 6 hours The reaction is monitored by infrared spectroscopy until the characteristic peak of the isocyanates (2250 cm -1) has completely disappeared 1). The mixture is then It is lowered to 30 ° C., and 1 liter of heptane is added thereto, before filtration on celite. The mixture is then stripped with isododecane.

Finally, a solution of the polymer in isododecane at 20% solids is obtained; the polymer is characterized by GPC (Mn = 4200 and polydispersity index = 2.34).

EXAMPLE 4 Synthesis of a Supramolecular Polymer 89 g of dihydroxy-hydrogenated 1,2-polybutadiene polymer (Nisso GI3000, Mn = 4700, measured by GPC according to the protocol described above, in the presence of 22 mg of catalyst ( dibutyltin dilaurate) at 80 ° C. under reduced pressure for 2 hours The temperature of the mixture was lowered to 20 ° C. under argon, followed by the addition of 60 ml of isododecane and 11.6 g of 4 , 4'-dicyclohexylmethane diisocyanate.

The mixture is stirred for 16 hours at 20 ° C, under a controlled atmosphere, and is then heated to 120 ° C, followed by the addition of 40 ml of propylene carbonate. 6.64 g of 6-methylisocytosine is added, resulting in a homogeneous white suspension. This suspension is heated to 140 ° C and is stirred at this temperature for 8 hours. The reaction is monitored by infrared spectroscopy until the characteristic peak of the isocyanates (2250 cm -1) has completely disappeared. The mixture is then lowered to 30 ° C., and 250 ml of isododecane and 500 ml of heptane are added thereto, before filtration on celite. The mixture is then stripped with isododecane. In the end, a solution of the polymer in isododecane with a solids content of 22% is obtained; the polymer is characterized by GPC (Mn = 10700 and polydispersity index 30 = 2.26).

EXAMPLE 5 Synthesis of a Supramolecular Polymer 143.1 g of dihydroxy-hydrogenated 1,2-polybutadiene polymer (Nisso GI2000, Mn = 3300, measured by GPC) are heated according to the protocol described above, in the presence of 33 mg of catalyst (dibutyltin dilaurate) at 80 ° C., under reduced pressure, for 2 hours The temperature of the mixture was lowered to 20 ° C., under argon, followed by the addition of 85 ml of isododecane and 30.8 g 4,4'-dicyclohexylmethane diisocyanate The mixture is stirred for 16 hours at 20 ° C., under a controlled atmosphere, and is then heated to 120 ° C., followed by the addition of 70 ml of propylene carbonate. 6-methylisocytosine, resulting in a homogeneous white suspension, which suspension is heated to 140 ° C. and is stirred at this temperature for 8 hours, followed by infrared spectroscopy until the peak of the characteristic isocyanates (2250 cm-1). The mixture is then lowered to 20 ° C., and 700 ml of isododecane and 500 ml of heptane are added thereto before filtration over celite. The mixture is then stripped with isododecane.

Finally, a solution of the polymer in isododecane at 20% solids is obtained; the polymer is characterized by GPC (Mn = 8400 and polydispersity index 2.00).

Examples No. 1 to 13 of Cosmetic Formulations: Liquid Lipsticks (Gloss) Two liquid lipstick formulations according to the invention were prepared and a comparative formula outside the invention having the following compositions (see Table 1) (percentages indicated are percentages by weight) Table 1 Formula 1 Formula 2 Formula 3 according to according to the invention the invention (excluding the invention) Polymer solution 90 (ie 22 5 90 (or 22.5 90 (ie 22.5 supramolecular GI2000% as a% dry matter) dry matter) dry) difunctionalized 25% ureidopyrrimidone in isododecane as prepared in Example 2 Polymethylsilsesquioxane 5 (Momentive performance materials Tospearl 145 A) Vinyl dimethocine / 5 methicone silsesquioxane crosspolymer (KSP 100 of Shin Etsu) Isododecane 4 4 9 Pigments 1 1 1 Total 100 100 100 Similarly, 5 other comparative compositions were made under the same conditions and with the same properties. urs by weight of supramolecular polymer and fillers. Table 2 below reports the comparative (i.e., non-invention) charges used in these compositions. Table 2: Hectorite Disteardimonuim Comparative Formula 4 (Elementis Bentone 38 VCG) Mica Formula 5 (Mearlica CF Comparative BASF Personal Care Ingredient) Formula 6 Talc Comparative Formula 7 Kaolin (Comparative Imerys Kaolin polwhite B) Formula 8 Comparative Lauroyl Lysine Procedure: A pigmentary morsel of the pigments was made in the isododecane by carrying out 3 passages of the mixture with the tri-roll mill. In a beaker, the ground material necessary for the composition was weighed.

The other constituents of formulas 1 to 3 were weighed and mixed with mechanical stirring at 50 ° C until the mixture was homogeneous and then added to the powdered mash. Then, the mixture was stirred with RAYNERI until homogeneous.

Evaluation of the Formulas: The tacky appearance of the deposits of each of the formulas 1 to 8 thus obtained was evaluated according to the protocol defined below.

Sticky Evaluation Protocol: 10 g masses of each of the compositions were removed. Each of the samples of compositions were brought to 50 ° C. and then heat-spread on a contrast card so as to form a deposit 150 μm thick. The stickiness was evaluated during the drying of a deposit made with the formula to be evaluated after 1 minute at 50 ° C. and 24 hours at room temperature (25 ° C.). For this, a finger was applied, at the end of the specified drying time, on the deposit made from the formula to be evaluated and the sticky was appreciated by the subject to the withdrawal of his finger. The appearance of the composition, the gloss and the non-transfer properties of the deposit formed on the lips were also evaluated. The following results were obtained: Table 3 Appearance of the Evaluation Appearance of the deposits composition card deposition after t = 24h contrast at 25 ° C. mmn, comparison with the comparative formula No. 3 Formula 1 according to Gel, homogeneous Very glossy, little Remains shiny and the invention sticky, not sticky, no transfer transfer Formula 2 according to Gel, homogeneous High gloss, little Remains shiny and the invention sticky, not sticky, no transfer transfer Formula 3 Gel, homogeneous very bright , very glossy, Comparative sticky, transfers tacky, transfers a little a little Formula 5 Gel very little gloss, low gloss, Comparative viscous, sticky, tacky transfer, transfer homogeneous a little a little Formule 6 Gel, homogeneous low gloss, low gloss, Comparative sticky, tacky transfer, transfers a little bit Formula 7 Gel, homogeneous little gloss, low gloss, Comparative sticky, tacky transfer, transfers a little bit a little Formule 8 Gel, homogeneous The result of these results is that the deposits made with the lipstick compositions according to the invention exhibit a significantly reduced tackiness, a glossy appearance and a good glossy appearance. non-transfer property with regard to the deposits made with the comparative compositions outside the invention

Example 9 of the Cosmetic Formula Fluid Foundation Type Composition According to the Invention The following table shows the formulation of a composition according to the invention.

Compounds Formula 9 According to the Invention Al Solution of Supramolecular GI2000 Polymer 48 Difunctionalized 25% Ureidopyrrimidone in Isododecane As Prepared as Example 2 Isododecane 34.5 A2 Isododecane 2.5 Pigments 10 B Micro-spheres of amorphous silica 5 (particle size: 3 microns) (Miyoshi Kasei, H-33 Sunsphere, AGC Si-TECH) Total: 100 Procedure: The components of phase A2 are weighed. The mixture is passed on tri-cylinder mill. Then, the constituents of the Al phase are weighed in the main beaker and placed in the Raynerie. Phase A2 is then added. After a few minutes of stirring, phase B is incorporated.

Non-transfer evaluation protocol: The forearm is cleansed with a non-greasy make-up remover (Lancôme Effacil type) and then with a cotton of water. After 5 minutes, the foundation formula is applied to the finger on the forearm. The amount applied is 0.05g over an area of 5cm by 5cm. 10 minutes after the application, a Kleenex is passed 5 times on the forearm, for this the Kleenex is folded in four, it is placed with a fairly strong pressure on the skin at one end of the deposit of the foundation formula then moved on the forearm quite slowly towards the other end. The amount of foundation transferred to the kleenex is then evaluated.

The composition obtained is homogeneous. It makes it possible to obtain a homogeneous deposit and little stickiness on the skin.

Claims (14)

REVENDICATIONS1. Makeup composition and / or care of the skin and / or lips comprising in a physiologically acceptable medium S - at least one functionalized polyalkene-based supramolecular polymer of formula HO-P-OH in which P represents a homo- or a copolymer obtainable by polymerization of one or more linear, cyclic and / or branched, C 2 -C 10, preferably C 2 -C 4, polyunsaturated alkenes which may be derived from the reaction, in particular from condensation, said polyalkene polymer functionalized with at least one linking group functionalized with at least one reactive group capable of reacting with the reactive group or groups of the functionalized polyalkene polymer, said joining group being capable of forming at least 3 H bonds (hydrogen), preferably at least 4 H bonds, preferably 4 H bonds, 15 - and at least one silicone filler selected from the following organopolysiloxane powders are silicone resin; and polymethylsilsesquioxane powders. 2. Composition according to the preceding claim, wherein the functionalized polyalkene of formula HO-P-OH is hydrogenated. 20 3. Composition according to any one of the preceding claims, in which P represents a homo- or a copolymer obtainable by polymerization of one or more di-unsaturated alkenes, linear or branched, C2-C4. 4. A composition according to any one of the preceding claims wherein P is polybutylene, polybutadiene, polyisoprene, poly (1,3-pentadiene), polyisobutylene, and copolymers thereof, and preferably poly (ethylene) / butylene). 5. Composition according to any one of the preceding claims, in which the functionalized junction group is of formula: ## STR2 ## in which L represents a divalent, saturated or unsaturated carbon group containing 1 to 20 carbon atoms; , in particular chosen from linear or branched C1-C20 alkylene; a C 5 -C 20 (alkyl) cycloalkylene, an alkylene-biscycloalkylene, a C 6 -C 20 (alkyl) arylene, preferably an isophorone group. 6. Composition according to any one of the preceding claims, in which the supramolecular polymer corresponds to the formula: ## STR2 ## NH-NH-NH-CXP-X'-NH-L-NH-II Wherein: L 'and L "are, independently of each other, as defined for L in the preceding claim; X, X '= O and P is as defined in one of the preceding claims. 7. Composition according to the preceding claim, in which: L 'and L "are both isophorone groups, - X and X' = O and P represents a polybutylene, a polybutadiene, a polyisoprene, a poly (1,3-pentadiene), a polyisobutylene, and copolymers thereof, and preferably poly (ethylene / butylene). 8. Composition according to any one of the preceding claims comprising from 0.1 to 60% by weight, preferably from 0.2 to 50% by weight, or even from 0.3% to 40%, and better still from 0.5% by weight. % to 30% by weight of supramolecular polymer (s) dry matter relative to the total weight of said composition. A composition according to any one of the preceding claims comprising from 1% to 25% by weight, preferably from 1% to 15% by weight, and more preferably from 2% to 8% by weight, and more preferably from 3% to 7% by weight. % by weight of silicone filler (s) relative to the total weight of said composition. 25 10. Composition according to any one of the preceding claims wherein said silicone filler and said supramolecular polymer are present in a weight ratio polymer (s) / silicone filler (s) range from 0.1 to 50, preferably from 0 to , 5 to 40 and more particularly from 1 to 20. 11. Composition according to any one of the preceding claims, characterized in that it is anhydrous. 12. Composition according to any one of the preceding claims, further comprising at least one fatty phase and in particular at least one oil, preferably a silicone oil. 13. Composition according to any one of the preceding claims in the form of a complexion product such as a foundation, a blusher or eyeshadow; a lip product such as lipstick or lip care; a concealer product; a blush, an eyeliner; a lip or eye pencil; a body make-up product or a gloss (lip gloss). 14. A cosmetic process for making up and / or caring for the skin and / or the lips comprising at least the application to said skin and / or said lips of a composition according to any one of the preceding claims.