FR2947736B1 - Composition solide minerale, son procede de preparation et son utilisation en abattement de metaux lourds des gaz de fumees - Google Patents

Composition solide minerale, son procede de preparation et son utilisation en abattement de metaux lourds des gaz de fumees

Info

Publication number
FR2947736B1
FR2947736B1 FR1055740A FR1055740A FR2947736B1 FR 2947736 B1 FR2947736 B1 FR 2947736B1 FR 1055740 A FR1055740 A FR 1055740A FR 1055740 A FR1055740 A FR 1055740A FR 2947736 B1 FR2947736 B1 FR 2947736B1
Authority
FR
France
Prior art keywords
shaping
preparing
same
heavy metal
solid composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR1055740A
Other languages
English (en)
French (fr)
Other versions
FR2947736A1 (fr
Inventor
Alain Brasseur
Jean-Paul Pirard
Alain Laudet
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lhoist Recherche et Développement SA
University of Liège
Original Assignee
Lhoist Recherche et Développement SA
University of Liège
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lhoist Recherche et Développement SA, University of Liège filed Critical Lhoist Recherche et Développement SA
Publication of FR2947736A1 publication Critical patent/FR2947736A1/fr
Application granted granted Critical
Publication of FR2947736B1 publication Critical patent/FR2947736B1/fr
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/64—Heavy metals or compounds thereof, e.g. mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/041—Oxides or hydroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/043—Carbonates or bicarbonates, e.g. limestone, dolomite, aragonite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/046—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium containing halogens, e.g. halides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/165—Natural alumino-silicates, e.g. zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
    • B01J20/28004—Sorbent size or size distribution, e.g. particle size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3078—Thermal treatment, e.g. calcining or pyrolizing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
    • B01J20/3204—Inorganic carriers, supports or substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3234—Inorganic material layers
    • B01J20/3236—Inorganic material layers containing metal, other than zeolites, e.g. oxides, hydroxides, sulphides or salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/30—Alkali metal compounds
    • B01D2251/306—Alkali metal compounds of potassium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/40—Alkaline earth metal or magnesium compounds
    • B01D2251/402—Alkaline earth metal or magnesium compounds of magnesium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/40—Alkaline earth metal or magnesium compounds
    • B01D2251/404—Alkaline earth metal or magnesium compounds of calcium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/60—Inorganic bases or salts
    • B01D2251/604—Hydroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/60—Inorganic bases or salts
    • B01D2251/606—Carbonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/60—Heavy metals or heavy metal compounds
    • B01D2257/602—Mercury or mercury compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/02—Other waste gases
    • B01D2258/0283—Flue gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
    • B01J2220/42—Materials comprising a mixture of inorganic materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/50—Aspects relating to the use of sorbent or filter aid materials
    • B01J2220/56—Use in the form of a bed

Landscapes

  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Thermal Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Treating Waste Gases (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
FR1055740A 2009-07-13 2010-07-13 Composition solide minerale, son procede de preparation et son utilisation en abattement de metaux lourds des gaz de fumees Expired - Fee Related FR2947736B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
BE200900426 2009-07-13
US33225610P 2010-05-07 2010-05-07

Publications (2)

Publication Number Publication Date
FR2947736A1 FR2947736A1 (fr) 2011-01-14
FR2947736B1 true FR2947736B1 (fr) 2015-09-18

Family

ID=41429652

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1055740A Expired - Fee Related FR2947736B1 (fr) 2009-07-13 2010-07-13 Composition solide minerale, son procede de preparation et son utilisation en abattement de metaux lourds des gaz de fumees

Country Status (15)

Country Link
US (1) US8871006B2 (enExample)
EP (1) EP2454006B1 (enExample)
JP (1) JP5689878B2 (enExample)
CN (1) CN102574054A (enExample)
AU (1) AU2010272565A1 (enExample)
BE (1) BE1019419A5 (enExample)
CA (1) CA2767281A1 (enExample)
FR (1) FR2947736B1 (enExample)
IL (1) IL217479A0 (enExample)
MA (1) MA33459B1 (enExample)
NZ (1) NZ598094A (enExample)
PL (1) PL2454006T3 (enExample)
SG (1) SG177538A1 (enExample)
UA (1) UA108616C2 (enExample)
WO (1) WO2011006890A1 (enExample)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL1866057T3 (pl) 2005-03-17 2022-05-16 Nox Ii International, Ltd. Redukcja emisji rtęci ze spalania węgla
CA2601325C (en) 2005-03-17 2014-06-17 Douglas C. Comrie Reducing mercury emissions from the burning of coal
SG177490A1 (en) * 2009-07-13 2012-02-28 Lhoist Rech & Dev Sa Solid inorganic composition, method for preparing same, and use thereof for reducing dioxins and heavy metals in flue gases
US20180169573A1 (en) * 2015-06-03 2018-06-21 Solvay Sa Process for treating a gas contaminated by metals or organics compounds using a calcium-phosphate reactant comprising apatite

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1907076A (en) * 1930-08-28 1933-05-02 Texaco Salt Products Company Hygroscopic salts and their preparation
US2276503A (en) * 1935-11-06 1942-03-17 Calcium Carbonate Company Iodized calcium carbonate
US3345265A (en) * 1963-10-09 1967-10-03 Kendall & Co Multiple layer tablet with calcium salt central core separated from soluble fluoride outer coating
US3576666A (en) * 1969-05-05 1971-04-27 Ivan B Cutler Coated refractory structural members
JPS4884727A (enExample) * 1972-02-16 1973-11-10
JPS4974195A (enExample) * 1972-11-16 1974-07-17
US4094686A (en) * 1974-06-07 1978-06-13 Plastiroute S.A. Road-surface additive for preventing ice and melting snow
NL7513232A (nl) * 1975-11-12 1977-05-16 Seikisui Chemical Co Ltd Werkwijze ter bereiding van stabilisatoren voor chloorhoudende harsen.
JPS56113330A (en) * 1980-02-09 1981-09-07 Mitsubishi Metal Corp Removal of mercury in smelting gas
DE3117542A1 (de) * 1981-05-04 1983-02-10 Franz Josef Gattys Ingenieurbüro für Chem. Maschinen- und Apparatebau, 6078 Neu-Isenburg Verfahren zur stabilisierung von dehydratisiertem magnesiumschlorid gegen rueck-hydratisierung
ES8704428A1 (es) 1986-02-11 1987-04-16 Consejo Superior Investigacion Procedimiento de fabricacion de un adsorbente azufrado, util para retener vapores de metal, como mercurio.
KR0184681B1 (ko) * 1995-01-24 1999-05-15 구보타 다다시 탄산가스 흡착제를 가지는 발포 단열재와 그 발포 단열재의 제조방법
ES2136496B1 (es) 1996-06-18 2000-10-01 Consejo Superior Investigacion Procedimiento de sulfuracion de silicatos naturales para retener vapores de metales.
JP4241693B2 (ja) * 1999-11-26 2009-03-18 メタウォーター株式会社 燃焼排ガスの処理方法
US6582497B1 (en) 2000-06-09 2003-06-24 Merck & Co., Inc. Adsorption power for removing mercury from high temperature high moisture gas streams
NL1017206C2 (nl) * 2001-01-26 2002-07-29 Cdem Holland Bv Werkwijze voor het verwijderen van kwik uit een gasstroom.
BE1015949A3 (fr) * 2004-03-15 2005-12-06 Lhoist Rech & Dev Sa Procede d'abattement de mercure et de metaux lourds des gaz de fumees.
US20060016690A1 (en) * 2004-07-23 2006-01-26 Ilya Ostrovsky Method for producing a hard coating with high corrosion resistance on articles made anodizable metals or alloys
WO2007053786A1 (en) 2005-11-05 2007-05-10 Radway Jerrold E Control of combustion system emissions
US7858061B2 (en) 2005-12-15 2010-12-28 The United States Of America As Represented By The Administrator Of The United States Environmental Protection Agency Compositions and methods for removing mercury from mercury-containing fluids
US20070267343A1 (en) 2006-05-17 2007-11-22 Keith Edward Forrester Heavy metal particulate emission speciation modification wet process
US8906823B2 (en) 2007-09-24 2014-12-09 Basf Corporation Pollutant emission control sorbents and methods of manufacture and use
US8450232B2 (en) 2009-01-14 2013-05-28 Lummus Technology Inc. Catalysts useful for the alkylation of aromatic hydrocarbons
EP2482970B1 (en) 2009-09-28 2018-08-08 Calgon Carbon Corporation Sorbent formulation for removal of mercury from flue gas

Also Published As

Publication number Publication date
AU2010272565A1 (en) 2012-02-23
US20120167762A1 (en) 2012-07-05
RU2012104805A (ru) 2013-08-20
WO2011006890A1 (fr) 2011-01-20
SG177538A1 (en) 2012-02-28
EP2454006B1 (fr) 2015-09-02
CN102574054A (zh) 2012-07-11
IL217479A0 (en) 2012-02-29
PL2454006T3 (pl) 2016-04-29
US8871006B2 (en) 2014-10-28
JP2012532753A (ja) 2012-12-20
FR2947736A1 (fr) 2011-01-14
NZ598094A (en) 2013-06-28
BE1019419A5 (fr) 2012-07-03
EP2454006A1 (fr) 2012-05-23
CA2767281A1 (fr) 2011-01-20
JP5689878B2 (ja) 2015-03-25
UA108616C2 (ru) 2015-05-25
MA33459B1 (fr) 2012-07-03

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Year of fee payment: 6

ST Notification of lapse

Effective date: 20170331